CN106281148A - Cover quick permeation dry type wallpaper basement membrane and preparation method thereof - Google Patents
Cover quick permeation dry type wallpaper basement membrane and preparation method thereof Download PDFInfo
- Publication number
- CN106281148A CN106281148A CN201610794585.8A CN201610794585A CN106281148A CN 106281148 A CN106281148 A CN 106281148A CN 201610794585 A CN201610794585 A CN 201610794585A CN 106281148 A CN106281148 A CN 106281148A
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- Prior art keywords
- parts
- sodium
- basement membrane
- dry type
- powder
- Prior art date
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- 210000002469 basement membrane Anatomy 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- 239000000839 emulsion Substances 0.000 claims abstract description 22
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract description 18
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 17
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011256 inorganic filler Substances 0.000 claims abstract description 14
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 14
- 239000001264 anethum graveolens Substances 0.000 claims abstract description 12
- 239000004141 Sodium laurylsulphate Substances 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 10
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 9
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 9
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 9
- 235000019394 potassium persulphate Nutrition 0.000 claims abstract description 9
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 9
- 239000001632 sodium acetate Substances 0.000 claims abstract description 9
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims abstract description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 8
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 8
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 29
- 239000000243 solution Substances 0.000 claims description 29
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 26
- 239000008367 deionised water Substances 0.000 claims description 19
- 229910021641 deionized water Inorganic materials 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 239000003999 initiator Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 13
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 13
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- -1 Alkenyl benzene Chemical compound 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011863 silicon-based powder Substances 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 238000010276 construction Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000035943 smell Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001251094 Formica Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to wallpaper adjuvant field, cover quick permeation dry type wallpaper basement membrane and preparation method thereof particularly to one.This covering quick permeation dry type wallpaper basement membrane is to be mixed by the raw material stirring of following weight parts: inorganic filler 30 50 parts, acrylic emulsion 160 175 parts, fast dry mash 50 80 parts, sodium stearate 6 10 parts, sodium hexameta phosphate 23 parts, dill seed 25 parts, butyl acrylate 9 10 parts, ethyl acrylate 15 16 parts, acrylic acid methyl ester. 89 parts, methyl methacrylate 35 37 parts, acrylonitrile 70 75 parts, sodium lauryl sulphate 3 3.5 parts, emulsifying agent 9 10 parts, sodium acetate 2 2.4 parts, potassium peroxydisulfate 1.2 1.4 parts, Ammonium persulfate. 0.8 0.9 parts, divinylbenzene 1.5 1.6 parts, sodium hydroxide 57 parts and suitable quantity of water.
Description
Technical field
The invention belongs to wallpaper adjuvant field, cover quick permeation dry type wallpaper basement membrane and preparation side thereof particularly to one
Method.
Background technology
Common wallpaper basement membrane is the process material of the body of wall basic unit before wallpaper construction, primarily serves the purpose of: 1) moistureproof；2) anti-
Mould；3) alkali resistant；4) improve the combination of wallpaper and body of wall, prevent alice；5) protection body of wall, it is simple to the construction of secondary wallpaper does not destroy wall
Body basic unit, improves work efficiency, energy-saving and cost-reducing.Exempt from glue-type wall paper different from the easy construction of common wall paper, exempt from glue-type wall paper and execute
Work, is directly to use special steam flatiron to add ironing wall cloth surface, makes the wall cloth back side melt so that wall cloth is bonded to for glue
Body of wall basal plane, it is achieved wall cloth is pasted.With the universal basement membrane in market or other base treatment material, work progress there will be drum
Wrap, warp, affect wall paper using effect and service life.Existing like product surface drying time is usually 2h, and the time of doing solid work is
24h, causes wallpaper or the defect of wall paper engineering time length.
Summary of the invention
The present invention solves the said goods mass defect, it is achieved exempt from glue wall paper normal construction and paste, it is provided that a kind of covering is oozed
Quick-dry type wallpaper basement membrane thoroughly.
The present invention also provides for the preparation method of described covering quick permeation dry type wallpaper basement membrane.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of covering quick permeation dry type wallpaper basement membrane, it is to be mixed by the raw material stirring of following weight parts: inorganic fill out
Material 30-50 part, acrylic emulsion 160-175 part, fast dry mash 50-80 part, sodium stearate 6-10 part, sodium hexameta phosphate 2-3 part,
Dill seed 2-5 part, butyl acrylate 9-10 part, ethyl acrylate 15-16 part, acrylic acid methyl ester. 8-9 part, metering system
Acid methyl ester 35-37 part, acrylonitrile 70-75 part, sodium lauryl sulphate 3-3.5 part, emulsifying agent 9-10 part, sodium acetate 2-2.4 part,
Potassium peroxydisulfate 1.2-1.4 part, Ammonium persulfate. 0.8-0.9 part, divinylbenzene 1.5-1.6 part, sodium hydroxide 5-7 part and appropriate
Water, described inorganic filler is mica powder, aluminium hydroxide, silicon dioxide, magnesium hydroxide, sodium carboxymethyl cellulose, titanium dioxide, silicon
One or more in micropowder, Pulvis Talci.Product of the present invention is mainly used in the formation level exempting from glue-type wall paper, solves common base
What film cannot meet exempts from glue-type wall paper formation level demand.Exempt from glue-type wall paper normally to paste, need formation level to process material
Protection against the tide, alkali resistant, mildew-resistant, the requirement such as high temperature resistant can be met, be just avoided that the wall papers such as wall paper construction later stage bulge, alice are constructed scarce
Fall into.The formula of basement membrane of the present invention with the addition of fast dry mash and inorganic filler, fast dry mash and other components with the use of rear,
While not reducing viscosity, accelerate the rate of drying of basement membrane, and improve the dried hardness of basement membrane and intensity, extend
Wallpaper service life.The dill seed added in formula improves the bacteria resistance function of product, safety and environmental protection.Inorganic filler
Add, be greatly improved the covering effect of basement membrane, effectively eliminated the aberration between body of wall and wallpaper or wallpaper, protect wallpaper
Do not reveal the exact details, extend the service life of wallpaper.
The formula of the present invention is added with acrylonitrile monemer, needs could be polymerized for cross-linking agent with divinylbenzene, reach
Product meets resistant to elevated temperatures performance requirement.
As preferably, described emulsifying agent is emulsifying agent MS-1 and/or emulsifier op-10.Preferably, emulsifying agent MS-1 4
Part and emulsifier op-10 5 parts.
As preferably, described water is deionized water 730-750 part.
As preferably, fast dry mash is inorganic powder or the surface grafting hydrophilic polymer of surface grafting hydrophilic polymer
The organic dust of thing.As preferably, fast dry mash is selected from the calcium carbonate powder of surface-grafted polyacrylic acid, surface grafting polypropylene
Acid titania powder, the polyurethane powder of surface-grafted polyacrylic acid, the titania powder of surface grafting Polyethylene Glycol,
The titania powder of surface grafting polyvinyl alcohol, the crosslinked starch powder of surface grafting sodium carboxymethyl cellulose.Preferred surface
The crosslinked starch powder of grafting sodium carboxymethyl cellulose.
As preferably, described inorganic filler is one or more in mica powder, sodium carboxymethyl cellulose, titanium dioxide.
Optimum formula is that mica powder, sodium carboxymethyl cellulose, titanium dioxide are with the mixing of 1:2:0.3-0.5 weight ratio.
A kind of described preparation method covering quick permeation dry type wallpaper basement membrane, the method comprises the steps:
1) dispensing:
By water-soluble for the deionization of sodium stearate, sodium hexameta phosphate, potassium peroxydisulfate and 23-25 times of gross weight of Ammonium persulfate.
Solve, obtain initiator solution；
Sodium lauryl sulphate appropriate amount of deionized water is dissolved, prepares the dodecyl that mass fraction is 13%-15%
Metabisulfite solution；
By good for sodium hydroxide appropriate amount of deionized water dissolved dilution, obtaining mass fraction is 0.38%-0.47% hydroxide
Sodium solution is standby；
2) pre-emulsion is prepared:
Under agitation, by deionized water, sodium dodecyl sulfate solution and appropriate emulsifying agent mixing, it is subsequently adding cross-linking agent
Divinylbenzene, and acrylic emulsion, inorganic filler, fast dry mash, acrylonitrile, butyl acrylate, ethyl acrylate, propylene
Acid methyl ester, methyl methacrylate, stir 20-25 minute, obtain pre-emulsion standby；The consumption of described deionized water is equal to third
The addition weight of olefin(e) acid, the addition of sodium dodecyl sulfate solution is the 56-58% of preparation total amount；3) polymerization:
Appropriate amount of deionized water is added in polymerization reaction kettle, open stirring, be simultaneously introduced sodium acetate, sodium lauryl sulphate
Aqueous solution and emulsifier for mixing, add appropriate initiator solution and pre-emulsion, is slowly ramped to 68 DEG C and terminates to reaction, still
Interior system is micro-blue light colloidal；
4) dropping:
Dripping remaining pre-emulsion in above-mentioned system, reaction temperature controls at 72 DEG C～78 DEG C, completes complete in 4 hours
Portion drips, and period adds appropriate initiator solution in batches；All dropping is complete, makes system be warming up to 85 DEG C, adds last
Secondary initiator solution, is incubated 15-20 minute, is then cooled to sodium hydroxide solution regulation system pH value when less than 45 DEG C and is
6.8～7, add dill seed stirring and fully obtain product.
A kind of described covering quick permeation dry type wallpaper basement membrane application in terms of the basal plane process exempting from glue wall paper.Covering is oozed
The specifically used method of quick-dry type wallpaper basement membrane is thoroughly: 1, first by basement membrane brushing (can use directly brushing or spraying, roller coating)
On metope, wait and after being completely dried, carry out wall cloth stickup again；When 2, pasting, carry out cutting according to body of wall bonding area, lead to afterwards
Crossing and pressed putting up of wall, wall cloth is pasted smooth firm；3, room ventilation should be strengthened after wall cloth has been pasted, disappear
The abnormal smells from the patient distributed because of construction flatiron except wall paper.
It is that monomer carries out pre-emulsification process that the present invention prepares the purpose of pre-emulsion, on the one hand W-response can be made steady
Carry out, it is to avoid W-response implode, occur emitting still, caking；On the other hand, monomer reaction more uniform and complete can be made, can avoid
Product flocculation and monomer abnormal smells from the patient exceed standard.Potassium peroxydisulfate and Ammonium persulfate. make the aqueous solution initiator as system, react the time-division
Batch adds system, it is to avoid reaction excessively acutely produces and emits still phenomenon.
The invention has the beneficial effects as follows: product of the present invention is to exempt from the special basement membrane of glue-type wall paper, can meet exempt from glue-type wall paper glue
The actual demand of base treatment of constructing before patch；Also the process requirement of other all wallpaper formation levels can be met.Conventional glue
Water non-refractory, is easily generated bulge phenomenon.And the covering quick permeation dry type wallpaper basement membrane of the present invention is high temperature resistant when using, it is dried
Hurry up, covering effect is good, will not produce bulge phenomenon.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.Should be appreciated that this
Bright enforcement is not limited to the following examples, and any pro forma accommodation and/or the change of being made the present invention all will fall
Enter scope.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, the equipment used and raw material etc.
All it is commercially available or commonly used in the art.Method in following embodiment, if no special instructions, is the normal of this area
Rule method.
The preparation method of the dill seed used by following example is:
After the Fructus anethi ball mill pulverizing being dried, weigh the powder of below 30 mesh, add deionized water distillation, distillating of distillation
Thing molecular sieve drying is dehydrated, and obtains dill seed；Wherein, the addition of deionized water is can be by abundant for Fructus anethi powder
Covering is as the criterion.Being tested the water content of dill seed by coulomb Moisture Meter, after dehydrate, its water content meets
Less than 5ppm.
Embodiment 1:
A kind of covering quick permeation dry type wallpaper basement membrane, composition of raw materials is: sodium carboxymethyl cellulose 50kg, acrylic emulsion
175kg, crosslinked starch powder 80kg, sodium stearate 10kg, the sodium hexameta phosphate 3kg of surface grafting sodium carboxymethyl cellulose, transplant
Trailing plants volatile oil 5kg, butyl acrylate 10kg, ethyl acrylate 15kg, acrylic acid methyl ester. 8kg, methyl methacrylate 35kg,
Acrylonitrile 70kg, sodium lauryl sulphate 3kg, emulsifying agent MS-1 4kg, emulsifier op-10 5kg, sodium acetate 2kg, persulfuric acid
Potassium 1.2kg, Ammonium persulfate. 0.8kg, divinylbenzene 1.5kg, sodium hydroxide 5kg.
1) dispensing:
By 10kg sodium stearate, 3kg sodium hexameta phosphate, 1.2kg potassium peroxydisulfate and 0.8kg Ammonium persulfate. 50kg deionization
Water dissolution, obtains initiator solution, and initiator solution cumulative volume is designated as 100%, adds system during reaction in batches, it is to avoid reaction
Excessively acutely produce and emit still phenomenon；
By good for 3kg sodium lauryl sulphate 20kg deionized water dissolving, obtain sodium dodecyl sulfate solution；
5kg sodium hydroxide 8kg deionized water dissolving is diluted, obtains sodium hydroxide solution standby.
2) pre-emulsion is prepared:
In pre-emulsification still, add deionized water 160kg, while stirring, add sodium dodecyl sulfate solution 13kg, breast
Agent MS-1 3kg, emulsifier op-10 3kg stir 10 minutes, when stirring, add cross-linker divinylbenzene 1.5kg,
Acrylic emulsion 160kg, sodium carboxymethyl cellulose 50kg, the crosslinked starch powder 80kg of surface grafting sodium carboxymethyl cellulose,
Acrylonitrile 70kg, butyl acrylate 10kg, ethyl acrylate 15kg, acrylic acid methyl ester. 8kg, methyl methacrylate 35kg, stir
Mix 20 minutes, obtain pre-emulsion standby.
3) polymerization:
500kg deionized water is added in polymerization reaction kettle, open stirring, meanwhile, add sodium acetate 2kg, dodecyl
Aqueous sodium persulfate solution 10kg, emulsifier op-10 2kg, emulsifying agent MS-1 1kg stirs 10 minutes.Addition prepares cumulative volume about
The initiator solution of 30%, adds 100kg pre-emulsion, stops heating after being slowly ramped to the initial reaction temperature of 68 DEG C,
In exothermic reaction after in still, material adds with initiator, material reaction there will be backflow phenomenon because temperature raises, reaction 30～
After 45min, no longer there is backflow phenomenon after terminating in reaction, and in still, system is micro-blue light colloidal.
4) dropping production technology
In micro-blue light colloid in still, start to drip remaining pre-emulsion.Reaction temperature controls to be advisable at 72 DEG C～78 DEG C,
Time is within 4 hours, to complete all to drip.An initiator solution was added at interval of 30 minutes after starting dropping.After all dripping
When being slowly ramped to 85 DEG C, add last initiator solution, constant temperature 15 minutes, be cooled to less than 45 DEG C and add sodium hydroxide
Solution regulation system pH value is 6.8～7, is subsequently adding dill seed stirring and can filter discharging in 20 minutes.The product obtained
Product, deposit at cool place, sealed storage, 2 years room temperature lower shelf-lifves.
Embodiment 2:
A kind of covering quick permeation dry type wallpaper basement membrane, composition of raw materials is: inorganic filler 30kg, acrylic emulsion 160kg, table
The crosslinked starch powder 50kg of face grafting sodium carboxymethyl cellulose, sodium stearate 6kg, sodium hexameta phosphate 2kg, dill seed
3kg, butyl acrylate 10kg, ethyl acrylate 16kg, acrylic acid methyl ester. 8kg, methyl methacrylate 37kg, acrylonitrile
75kg, sodium lauryl sulphate 3.5kg, emulsifying agent MS-1 5kg, emulsifier op-10 5kg, sodium acetate 2.4kg, potassium peroxydisulfate
1.4kg, Ammonium persulfate. 0.9kg, divinylbenzene 1.6kg, sodium hydroxide 7kg.Preparation method is with embodiment 1.Described inorganic fill out
The material that material mixes with 1:2:0.5 weight ratio for mica powder, sodium carboxymethyl cellulose, titanium dioxide.
Embodiment 3:
A kind of covering quick permeation dry type wallpaper basement membrane, composition of raw materials is: inorganic filler 40kg, acrylic emulsion 165kg, table
The kaolin powder 60kg of face grafted polyacrylamide, sodium stearate 8kg, sodium hexameta phosphate 3kg, dill seed 4kg, third
Olefin(e) acid butyl ester 9kg, ethyl acrylate 15kg, acrylic acid methyl ester. 9kg, methyl methacrylate 35kg, acrylonitrile 70kg, dodecane
Base sodium sulfate 3kg, emulsifying agent MS-1 4kg, emulsifier op-10 5kg, sodium acetate 2kg, potassium peroxydisulfate 1.2kg, Ammonium persulfate.
0.8kg, divinylbenzene 1.5kg, sodium hydroxide 5kg.Preparation method is with embodiment 1.Described inorganic filler is mica powder, carboxylic first
The material that base sodium cellulosate, titanium dioxide mix with 1:2:0.5 weight ratio.Basement membrane drying time (doing solid work) phase that this proportioning is made
To shorter, about 10h can be dried；The product covering effect prepared relative to other components promotes higher.
Embodiment 4:
A kind of covering quick permeation dry type wallpaper basement membrane, composition of raw materials with embodiment 1, difference is: fast dry mash is table
The titania powder of face grafting Polyethylene Glycol.Described inorganic filler is that mica powder, sodium carboxymethyl cellulose are with the weight ratio of 1:2
The material of mixing.
The wallpaper basement membrane that various embodiments of the present invention obtain, compares test table 1 with other common basement membrane performance.
Table 1
The most relatively after test, find that the basement membrane covering effect of the present invention is preferable, effectively eliminated body of wall
And the aberration between wallpaper or wallpaper, protection wallpaper is not revealed the exact details, and extends the service life of wallpaper.Additionally, the adding of inorganic filler
Enter to reduce the electrostatic on wallpaper surface and improve the fire-retardant of wallpaper.
The specifically used method covering quick permeation dry type wallpaper basement membrane is: 1, first (basement membrane brushing can be used directly brushing
Or spraying, roller coating) on metope, wait and after being completely dried, carry out wall cloth stickup again；When 2, pasting, enter according to body of wall bonding area
Row cutting, completes putting up of upper wall by flatiron afterwards, and wall cloth is pasted smooth firm；3, should add after wall cloth has been pasted
Strong room ventilation, eliminates the abnormal smells from the patient that wall paper distributes because of construction flatiron.
The product of the present invention can meet the process material of the body of wall basal plane of the wallpaper (wall cloth) of construction at high temperature, it is ensured that construction
Body of wall basal plane not bulge, bubbling and be layered, drying time is quick, shortens the engineering time of wallpaper, improves basement membrane dried
Hardness and intensity, extend the similar life-span exempting from glue-type wall paper.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma
Limit, on the premise of without departing from the technical scheme described in claim, also have other variant and remodeling.
Claims (7)
1. one kind covers quick permeation dry type wallpaper basement membrane, it is characterised in that it is by the raw material stirring mixing of following weight parts
Become: inorganic filler 30-50 part, acrylic emulsion 160-175 part, fast dry mash 50-80 part, sodium stearate 6-10 part, six inclined phosphorus
Acid sodium 2-3 part, dill seed 2-5 part, butyl acrylate 9-10 part, ethyl acrylate 15-16 part, acrylic acid methyl ester. 8-9
Part, methyl methacrylate 35-37 part, acrylonitrile 70-75 part, sodium lauryl sulphate 3-3.5 part, emulsifying agent 9-10 part,
Sodium acetate 2-2.4 part, potassium peroxydisulfate 1.2-1.4 part, Ammonium persulfate. 0.8-0.9 part, divinylbenzene 1.5-1.6 part, hydrogen-oxygen
Changing sodium 5-7 part and suitable quantity of water, described inorganic filler is mica powder, aluminium hydroxide, silicon dioxide, magnesium hydroxide, carboxymethyl fibre
One or more in dimension element sodium, titanium dioxide, silicon powder, Pulvis Talci.
Covering quick permeation dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: described emulsifying agent is emulsifying
Agent MS-1 and/or emulsifier op-10.
Covering quick permeation dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: described water is deionized water
730-750 part.
Covering quick permeation dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: fast dry mash is surface grafting
The inorganic powder of hydrophilic polymer or the organic dust of surface grafting hydrophilic polymer.
Covering quick permeation dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: fast dry mash connects selected from surface
Branch polyacrylic calcium carbonate powder, the titania powder of surface-grafted polyacrylic acid, the poly-ammonia of surface-grafted polyacrylic acid
Ester powder, the titania powder of surface grafting Polyethylene Glycol, the titania powder of surface grafting polyvinyl alcohol, surface grafting
The crosslinked starch powder of sodium carboxymethyl cellulose.
6. the preparation method covering quick permeation dry type wallpaper basement membrane described in a claim 1, it is characterised in that the method bag
Include following steps:
1) dispensing:
By sodium stearate, sodium hexameta phosphate, potassium peroxydisulfate and the Ammonium persulfate. deionized water dissolving of 23-25 times of gross weight,
To initiator solution；
Sodium lauryl sulphate appropriate amount of deionized water is dissolved, prepares the sodium lauryl sulphate that mass fraction is 13%-15%
Solution；
By good for sodium hydroxide appropriate amount of deionized water dissolved dilution, obtaining mass fraction is 0.38%-0.47% sodium hydroxide solution
Standby；
2) pre-emulsion is prepared:
Under agitation, by deionized water, sodium dodecyl sulfate solution and appropriate emulsifying agent mixing, it is subsequently adding cross-linking agent diethyl
Alkenyl benzene, and acrylic emulsion, inorganic filler, fast dry mash, acrylonitrile, butyl acrylate, ethyl acrylate, acrylic acid first
Ester, methyl methacrylate, stir 20-25 minute, obtain pre-emulsion standby；The consumption of described deionized water is equal to acrylic acid
Addition weight, the addition of sodium dodecyl sulfate solution be preparation total amount 56-58%；
3) polymerization:
Appropriate amount of deionized water is added in polymerization reaction kettle, open stirring, be simultaneously introduced sodium acetate, sodium lauryl sulphate water-soluble
Liquid and emulsifier for mixing, add appropriate initiator solution and pre-emulsion, is slowly ramped to 68 DEG C and terminates to reaction, body in still
System is in micro-blue light colloidal；
4) dropping:
Dripping remaining pre-emulsion in above-mentioned system, reaction temperature controls at 72 DEG C ~ 78 DEG C, completes all to drip in 4 hours
Adding, period adds appropriate initiator solution in batches；All dropping is complete, makes system be warming up to 85 DEG C, adds and draw for the last time
Sending out agent solution, be incubated 15-20 minute, being then cooled to sodium hydroxide solution regulation system pH value when less than 45 DEG C is 6.8 ~ 7
, add dill seed stirring and fully obtain product.
7. covering quick permeation dry type wallpaper basement membrane the answering in terms of the basal plane process exempting from glue wall paper described in a claim 1
With.
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