CN106280842A - A kind of quick-dry type wallpaper basement membrane and preparation method thereof - Google Patents
A kind of quick-dry type wallpaper basement membrane and preparation method thereof Download PDFInfo
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- CN106280842A CN106280842A CN201610794444.6A CN201610794444A CN106280842A CN 106280842 A CN106280842 A CN 106280842A CN 201610794444 A CN201610794444 A CN 201610794444A CN 106280842 A CN106280842 A CN 106280842A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paper (AREA)
Abstract
The invention belongs to wallpaper adjuvant field, particularly to a kind of quick-dry type wallpaper basement membrane and preparation method thereof.This quick-dry type wallpaper basement membrane is to be mixed by the raw material stirring of following weight parts: acrylic emulsion 130 155 parts, fast dry mash 50 80 parts, sodium stearate 6 10 parts, sodium hexameta phosphate 23 parts, dill seed 25 parts, butyl acrylate 9 10 parts, ethyl acrylate 15 16 parts, acrylic acid methyl ester. 89 parts, methyl methacrylate 35 37 parts, acrylonitrile 70 75 parts, sodium lauryl sulphate 3 3.5 parts, emulsifying agent 9 10 parts, sodium acetate 2 2.4 parts, potassium peroxydisulfate 1.2 1.4 parts, Ammonium persulfate. 0.8 0.9 parts, divinylbenzene 1.5 1.6 parts, sodium hydroxide 57 parts and suitable quantity of water.
Description
Technical field
The invention belongs to wallpaper adjuvant field, particularly to a kind of quick-dry type wallpaper basement membrane and preparation method thereof.
Background technology
Common wallpaper basement membrane is the process material of the body of wall basic unit before wallpaper construction, primarily serves the purpose of: 1) moistureproof；2) anti-
Mould；3) alkali resistant；4) improve the combination of wallpaper and body of wall, prevent alice；5) protection body of wall, it is simple to the construction of secondary wallpaper does not destroy wall
Body basic unit, improves work efficiency, energy-saving and cost-reducing.Exempt from glue-type wall paper different from the easy construction of common wall paper, exempt from glue-type wall paper and execute
Work, is directly to use special steam flatiron to add ironing wall cloth surface, makes the wall cloth back side melt so that wall cloth is bonded to for glue
Body of wall basal plane, it is achieved wall cloth is pasted.With the universal basement membrane in market or other base treatment material, work progress there will be drum
Wrap, warp, affect wall paper using effect and service life.Existing like product surface drying time is usually 2h, and the time of doing solid work is
24h, causes wallpaper or the defect of wall paper engineering time length.
Summary of the invention
The present invention solves the said goods mass defect, it is achieved exempt from glue wall paper normal construction and paste, it is provided that a kind of quick-dry type
Wallpaper basement membrane.
The present invention also provides for the preparation method of described quick-dry type wallpaper basement membrane.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of quick-dry type wallpaper basement membrane, it is to be mixed by the raw material stirring of following weight parts: acrylic emulsion 130-
155 parts, fast dry mash 50-80 part, sodium stearate 6-10 part, sodium hexameta phosphate 2-3 part, dill seed 2-5 part, acrylic acid
Butyl ester 9-10 part, ethyl acrylate 15-16 part, acrylic acid methyl ester. 8-9 part, methyl methacrylate 35-37 part, acrylonitrile 70-
75 parts, sodium lauryl sulphate 3-3.5 part, emulsifying agent 9-10 part, sodium acetate 2-2.4 part, potassium peroxydisulfate 1.2-1.4 part, over cure
Acid ammonium 0.8-0.9 part, divinylbenzene 1.5-1.6 part, sodium hydroxide 5-7 part and suitable quantity of water.Product of the present invention is mainly applied
In exempting from the formation level of glue-type wall paper, solve that common basement membrane cannot meet exempts from glue-type wall paper formation level demand.Exempt from glue-type wall
Cloth normally to be pasted, and needs formation level to process material and can meet protection against the tide, alkali resistant, mildew-resistant, the requirement such as high temperature resistant, is just avoided that wall
The defect of the wall paper constructions such as cloth construction later stage bulge, alice.The formula of basement membrane of the present invention with the addition of fast dry mash, fast dry mash
With other components with the use of rear, while not reducing viscosity, accelerate the rate of drying of basement membrane, and it is dry to improve basement membrane
Hardness after dry and intensity, extend wallpaper service life.The dill seed added in formula improves the antibacterial of product
Function, safety and environmental protection.
The formula of the present invention is added with acrylonitrile monemer, needs could be polymerized for cross-linking agent with divinylbenzene, reach
Product meets resistant to elevated temperatures performance requirement.
As preferably, described emulsifying agent is emulsifying agent MS-1 and/or emulsifier op-10.Preferably, emulsifying agent MS-1 4
Part and emulsifier op-10 5 parts.
As preferably, described water is deionized water 730-750 part.
As preferably, fast dry mash is inorganic powder or the surface grafting hydrophilic polymer of surface grafting hydrophilic polymer
The organic dust of thing.As preferably, fast dry mash is selected from the calcium carbonate powder of surface-grafted polyacrylic acid, surface grafting polypropylene
Acid titania powder, the polyurethane powder of surface-grafted polyacrylic acid, the titania powder of surface grafting Polyethylene Glycol,
The titania powder of surface grafting polyvinyl alcohol, the crosslinked starch powder of surface grafting sodium carboxymethyl cellulose.Preferred surface
The crosslinked starch powder of grafting sodium carboxymethyl cellulose.
The preparation method of a kind of described quick-dry type wallpaper basement membrane, the method comprises the steps:
1) dispensing:
By water-soluble for the deionization of sodium stearate, sodium hexameta phosphate, potassium peroxydisulfate and 23-25 times of gross weight of Ammonium persulfate.
Solve, obtain initiator solution；
Sodium lauryl sulphate appropriate amount of deionized water is dissolved, prepares the dodecyl that mass fraction is 13%-15%
Metabisulfite solution；
By good for sodium hydroxide appropriate amount of deionized water dissolved dilution, obtaining mass fraction is 0.38%-0.47% hydroxide
Sodium solution is standby；
2) pre-emulsion is prepared:
Under agitation, by deionized water, sodium dodecyl sulfate solution and appropriate emulsifying agent mixing, it is subsequently adding cross-linking agent
Divinylbenzene, and acrylic emulsion, fast dry mash, acrylonitrile, butyl acrylate, ethyl acrylate, acrylic acid methyl ester., first
Base acrylic acid methyl ester., stirs 20-25 minute, obtains pre-emulsion standby；The consumption of described deionized water adds equal to acrylic acid
Entering weight, the addition of sodium dodecyl sulfate solution is the 56-58% of preparation total amount；
3) polymerization:
Appropriate amount of deionized water is added in polymerization reaction kettle, open stirring, be simultaneously introduced sodium acetate, sodium lauryl sulphate
Aqueous solution and emulsifier for mixing, add appropriate initiator solution and pre-emulsion, is slowly ramped to 68 DEG C and terminates to reaction, still
Interior system is micro-blue light colloidal；
4) dropping:
Dripping remaining pre-emulsion in above-mentioned system, reaction temperature controls at 72 DEG C～78 DEG C, completes complete in 4 hours
Portion drips, and period adds appropriate initiator solution in batches；All dropping is complete, makes system be warming up to 85 DEG C, adds last
Secondary initiator solution, is incubated 15-20 minute, is then cooled to sodium hydroxide solution regulation system pH value when less than 45 DEG C and is
6.8～7, add dill seed stirring and fully obtain product.
The application in terms of the basal plane process exempting from glue wall paper of a kind of described quick-dry type wallpaper basement membrane.Quick-dry type wallpaper basement membrane
Specifically used method be: 1, first by basement membrane brushing (directly brushing or spraying, roller coating can be used) to metope, wait completely dry
Wall cloth stickup is carried out again after dry；When 2, pasting, carry out cutting according to body of wall bonding area, complete opening of upper wall by flatiron afterwards
Patch, wall cloth is pasted smooth firm；3, room ventilation should be strengthened after wall cloth has been pasted, eliminate wall paper and press because constructing scattered
The abnormal smells from the patient sent out.
It is that monomer carries out pre-emulsification process that the present invention prepares the purpose of pre-emulsion, on the one hand W-response can be made steady
Carry out, it is to avoid W-response implode, occur emitting still, caking；On the other hand, monomer reaction more uniform and complete can be made, can avoid
Product flocculation and monomer abnormal smells from the patient exceed standard.Potassium peroxydisulfate and Ammonium persulfate. make the aqueous solution initiator as system, react the time-division
Batch adds system, it is to avoid reaction excessively acutely produces and emits still phenomenon.
The invention has the beneficial effects as follows: product of the present invention is to exempt from the special basement membrane of glue-type wall paper, can meet exempt from glue-type wall paper glue
The actual demand of base treatment of constructing before patch；Also the process requirement of other all wallpaper formation levels can be met.Conventional glue
Water non-refractory, is easily generated bulge phenomenon.And the quick-dry type wallpaper basement membrane of the present invention is high temperature resistant when using, fast drying, will not produce
Raw bulge phenomenon.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.Should be appreciated that this
Bright enforcement is not limited to the following examples, and any pro forma accommodation and/or the change of being made the present invention all will fall
Enter scope.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, the equipment used and raw material etc.
All it is commercially available or commonly used in the art.Method in following embodiment, if no special instructions, is the normal of this area
Rule method.
The preparation method of the dill seed used by following example is:
After the Fructus anethi ball mill pulverizing being dried, weigh the powder of below 30 mesh, add deionized water distillation, distillating of distillation
Thing molecular sieve drying is dehydrated, and obtains dill seed；Wherein, the addition of deionized water is can be by abundant for Fructus anethi powder
Covering is as the criterion.Being tested the water content of dill seed by coulomb Moisture Meter, after dehydrate, its water content meets
Less than 5ppm.
Embodiment 1:
A kind of quick-dry type wallpaper basement membrane, composition of raw materials is: acrylic emulsion 150kg, surface grafting sodium carboxymethyl cellulose
Crosslinked starch powder 80kg, sodium stearate 10kg, sodium hexameta phosphate 3kg, dill seed 5kg, butyl acrylate 10kg,
Ethyl acrylate 15kg, acrylic acid methyl ester. 8kg, methyl methacrylate 35kg, acrylonitrile 70kg, sodium lauryl sulphate 3kg,
Emulsifying agent MS-1 4kg, emulsifier op-10 5kg, sodium acetate 2kg, potassium peroxydisulfate 1.2kg, Ammonium persulfate. 0.8kg, divinyl
Benzene 1.5kg, sodium hydroxide 5kg.
1) dispensing:
By 10kg sodium stearate, 3kg sodium hexameta phosphate, 1.2kg potassium peroxydisulfate and 0.8kg Ammonium persulfate. 50kg deionization
Water dissolution, obtains initiator solution, and initiator solution cumulative volume is designated as 100%, adds system during reaction in batches, it is to avoid reaction
Excessively acutely produce and emit still phenomenon；
By good for 3kg sodium lauryl sulphate 20kg deionized water dissolving, obtain sodium dodecyl sulfate solution；
5kg sodium hydroxide 8kg deionized water dissolving is diluted, obtains sodium hydroxide solution standby.
2) pre-emulsion is prepared:
In pre-emulsification still, add deionized water 160kg, while stirring, add sodium dodecyl sulfate solution 13kg, breast
Agent MS-1 3kg, emulsifier op-10 3kg stir 10 minutes, when stirring, add cross-linker divinylbenzene 1.5kg,
Acrylic emulsion 160kg, the crosslinked starch powder 80kg of surface grafting sodium carboxymethyl cellulose, acrylonitrile 70kg, acrylic acid fourth
Ester 10kg, ethyl acrylate 15kg, acrylic acid methyl ester. 8kg, methyl methacrylate 35kg, stir 20 minutes, obtain pre-emulsification
Liquid is standby.
3) polymerization:
500kg deionized water is added in polymerization reaction kettle, open stirring, meanwhile, add sodium acetate 2kg, dodecyl
Aqueous sodium persulfate solution 10kg, emulsifier op-10 2kg, emulsifying agent MS-1 1kg stirs 10 minutes.Addition prepares cumulative volume about
The initiator solution of 30%, adds 100kg pre-emulsion, stops heating after being slowly ramped to the initial reaction temperature of 68 DEG C,
In exothermic reaction after in still, material adds with initiator, material reaction there will be backflow phenomenon because temperature raises, reaction 30～
After 45min, no longer there is backflow phenomenon after terminating in reaction, and in still, system is micro-blue light colloidal.
4) dropping production technology
In micro-blue light colloid in still, start to drip remaining pre-emulsion.Reaction temperature controls to be advisable at 72 DEG C～78 DEG C,
Time is within 4 hours, to complete all to drip.An initiator solution was added at interval of 30 minutes after starting dropping.After all dripping
When being slowly ramped to 85 DEG C, add last initiator solution, constant temperature 15 minutes, be cooled to less than 45 DEG C and add sodium hydroxide
Solution regulation system pH value is 6.8～7, is subsequently adding dill seed stirring and can filter discharging in 20 minutes.The product obtained
Product, deposit at cool place, sealed storage, 2 years room temperature lower shelf-lifves.
Embodiment 2:
A kind of quick-dry type wallpaper basement membrane, composition of raw materials is: acrylic emulsion 130kg, surface grafting sodium carboxymethyl cellulose
Crosslinked starch powder 50kg, sodium stearate 6kg, sodium hexameta phosphate 2kg, dill seed 3kg, butyl acrylate 10kg,
Ethyl acrylate 16kg, acrylic acid methyl ester. 8kg, methyl methacrylate 37kg, acrylonitrile 75kg, sodium lauryl sulphate
3.5kg, emulsifying agent MS-1 5kg, emulsifier op-10 5kg, sodium acetate 2.4kg, potassium peroxydisulfate 1.4kg, Ammonium persulfate. 0.9kg,
Divinylbenzene 1.6kg, sodium hydroxide 7kg.Preparation method is with embodiment 1.
Embodiment 3:
A kind of quick-dry type wallpaper basement membrane, composition of raw materials is: acrylic emulsion 145kg, the height of surface grafting polyacrylamide
Ridge soil powder 60kg, sodium stearate 8kg, sodium hexameta phosphate 3kg, dill seed 4kg, butyl acrylate 9kg, acrylic acid second
Ester 15kg, acrylic acid methyl ester. 9kg, methyl methacrylate 35kg, acrylonitrile 70kg, sodium lauryl sulphate 3kg, emulsifying agent
MS-1 4kg, emulsifier op-10 5kg, sodium acetate 2kg, potassium peroxydisulfate 1.2kg, Ammonium persulfate. 0.8kg, divinylbenzene
1.5kg, sodium hydroxide 5kg.Preparation method is with embodiment 1.
Embodiment 4:
A kind of quick-dry type wallpaper basement membrane, composition of raw materials with embodiment 1, difference is: fast dry mash is that surface grafting gathers
The titania powder of ethylene glycol.
The wallpaper basement membrane that various embodiments of the present invention obtain, compares test table 1 with other common basement membrane performance.
Table 1
The specifically used method of quick-dry type wallpaper basement membrane is: 1, first by basement membrane brushing (can use directly brushing or spraying,
Roller coating) on metope, wait and after being completely dried, carry out wall cloth stickup again；When 2, pasting, carry out cutting according to body of wall bonding area, it
Completing putting up of upper wall by flatiron afterwards, wall cloth is pasted smooth firm；3, should strengthen indoor logical after wall cloth has been pasted
Wind, eliminates the abnormal smells from the patient that wall paper distributes because of construction flatiron.
The product of the present invention can meet the process material of the body of wall basal plane of the wallpaper (wall cloth) of construction at high temperature, it is ensured that construction
Body of wall basal plane not bulge, bubbling and be layered, drying time is quick, shortens the engineering time of wallpaper, improves basement membrane dried
Hardness and intensity, extend the similar life-span exempting from glue-type wall paper.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma
Limit, on the premise of without departing from the technical scheme described in claim, also have other variant and remodeling.
Claims (7)
1. a quick-dry type wallpaper basement membrane, it is characterised in that it is to be mixed by the raw material stirring of following weight parts: acrylic acid
Emulsion 130-155 part, fast dry mash 50-80 part, sodium stearate 6-10 part, sodium hexameta phosphate 2-3 part, dill seed 2-5
Part, butyl acrylate 9-10 part, ethyl acrylate 15-16 part, acrylic acid methyl ester. 8-9 part, methyl methacrylate 35-37 part,
Acrylonitrile 70-75 part, sodium lauryl sulphate 3-3.5 part, emulsifying agent 9-10 part, sodium acetate 2-2.4 part, potassium peroxydisulfate 1.2-
1.4 parts, Ammonium persulfate. 0.8-0.9 part, divinylbenzene 1.5-1.6 part, sodium hydroxide 5-7 part and suitable quantity of water.
Quick-dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: described emulsifying agent is emulsifying agent MS-1
And/or emulsifier op-10.
Quick-dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: described water is deionized water 730-750
Part.
Quick-dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: fast dry mash is that surface grafting hydrophilic gathers
The inorganic powder of compound or the organic dust of surface grafting hydrophilic polymer.
Quick-dry type wallpaper basement membrane the most according to claim 1, it is characterised in that: fast dry mash is selected from surface grafting polypropylene
The calcium carbonate powder of acid, the titania powder of surface-grafted polyacrylic acid, the polyurethane powder of surface-grafted polyacrylic acid, table
The face grafting titania powder of Polyethylene Glycol, the titania powder of surface grafting polyvinyl alcohol, surface grafting carboxymethyl are fine
The crosslinked starch powder of dimension element sodium.
6. the preparation method of the quick-dry type wallpaper basement membrane described in a claim 1, it is characterised in that the method includes walking as follows
Rapid:
1) dispensing:
By sodium stearate, sodium hexameta phosphate, potassium peroxydisulfate and the Ammonium persulfate. deionized water dissolving of 23-25 times of gross weight,
To initiator solution；
Sodium lauryl sulphate appropriate amount of deionized water is dissolved, prepares the sodium lauryl sulphate that mass fraction is 13%-15%
Solution；
By good for sodium hydroxide appropriate amount of deionized water dissolved dilution, obtaining mass fraction is 0.38%-0.47% sodium hydroxide solution
Standby；
2) pre-emulsion is prepared:
Under agitation, by deionized water, sodium dodecyl sulfate solution and appropriate emulsifying agent mixing, it is subsequently adding cross-linking agent diethyl
Alkenyl benzene, and acrylic emulsion, fast dry mash, acrylonitrile, butyl acrylate, ethyl acrylate, acrylic acid methyl ester., methyl-prop
E pioic acid methyl ester, stirs 20-25 minute, obtains pre-emulsion standby；The consumption of described deionized water adds weight equal to acrylic acid
Amount, the addition of sodium dodecyl sulfate solution is the 56-58% of preparation total amount；
3) polymerization:
Appropriate amount of deionized water is added in polymerization reaction kettle, open stirring, be simultaneously introduced sodium acetate, sodium lauryl sulphate water-soluble
Liquid and emulsifier for mixing, add appropriate initiator solution and pre-emulsion, is slowly ramped to 68 DEG C and terminates to reaction, body in still
System is in micro-blue light colloidal；
4) dropping:
Dripping remaining pre-emulsion in above-mentioned system, reaction temperature controls at 72 DEG C ~ 78 DEG C, completes all to drip in 4 hours
Adding, period adds appropriate initiator solution in batches；All dropping is complete, makes system be warming up to 85 DEG C, adds and draw for the last time
Sending out agent solution, be incubated 15-20 minute, being then cooled to sodium hydroxide solution regulation system pH value when less than 45 DEG C is 6.8 ~ 7
, add dill seed stirring and fully obtain product.
7. the application in terms of the basal plane process exempting from glue wall paper of the quick-dry type wallpaper basement membrane described in a claim 1.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112724972A (en) * | 2020-11-03 | 2021-04-30 | 河北地质大学 | Quick-drying durable luminescent material and preparation method thereof |
| CN114507463A (en) * | 2022-02-08 | 2022-05-17 | 浙江汇明提花织造股份有限公司 | Wall cloth mate capable of eliminating peculiar smell and enhancing surface hardness and preparation process thereof |
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| CN102757672A (en) * | 2012-05-22 | 2012-10-31 | 杭州嘉力丰化工有限公司 | Nano-silver wallpaper primer and preparation method thereof |
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| CN102757672A (en) * | 2012-05-22 | 2012-10-31 | 杭州嘉力丰化工有限公司 | Nano-silver wallpaper primer and preparation method thereof |
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| CN112724972A (en) * | 2020-11-03 | 2021-04-30 | 河北地质大学 | Quick-drying durable luminescent material and preparation method thereof |
| CN114507463A (en) * | 2022-02-08 | 2022-05-17 | 浙江汇明提花织造股份有限公司 | Wall cloth mate capable of eliminating peculiar smell and enhancing surface hardness and preparation process thereof |
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Address after: 314500 Tongxiang Economic Development Zone, Zhejiang City, West Ring Road, No. 106, No. Applicant after: Polytron Technologies Inc Address before: Jiaxing City, Zhejiang province 314500 Tongxiang Wutong Street Huancheng West Road No. 106 building 4 floor 1 Applicant before: Tongxiang Jialifeng Industry Co., Ltd. |
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Application publication date: 20170104 |