CN104004473A - Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper - Google Patents
Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper Download PDFInfo
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- CN104004473A CN104004473A CN201410211995.6A CN201410211995A CN104004473A CN 104004473 A CN104004473 A CN 104004473A CN 201410211995 A CN201410211995 A CN 201410211995A CN 104004473 A CN104004473 A CN 104004473A
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Abstract
The invention discloses a foam coating glue of water-based wallpaper. The foam coating glue includes 40-60% of a main body emulsion resin, 35-55% of a compounding agent and 1-10% of water. The main body emulsion resin is selected from one or more of neoprene latex, nitrile rubber latex, styrene-butadiene latex, water-based acrylate resin, water-based polyurethane resin and ethylene-vinyl acetate resin. The compounding agent includes a dispersing agent, an emulsifier, a thickening agent, a foam-starting agent, a foam-stabilizing agent, a foaming agent, a coagulating agent and a foam-densifying agent. Correspondingly, the invention discloses a preparation method of the foam coating glue of the water-based wallpaper and wallpaper prepared by using the foam coating glue of the water-based wallpaper. Through the preparation method, the foam coating glue of the water-based wallpaper is environmental-friendly and energy-saving, has an excellent foaming effect and can form an excellent-performance foam coating on the water-based wallpaper.
Description
Technical field
The present invention relates to water-based decoration material field, particularly a kind of water-based wallpaper intumescent coating glue and preparation method thereof, and a kind of wallpaper that adopts above-mentioned intumescent coating glue to make.
Background technology
Wallpaper is a kind of novel decorative material for wall surface, to be coated on paper substrate with PVC, the upholstery product processing through operations such as stamp, embossing, it is strong with rich color, skin texture texture, pattern abundant, environmental protection, decorative effect elegant and be different from other decorative material for wall surface, is widely used in family and inner wall decoration public, commercial location.Along with improving constantly of domestic resident living level, human consumer proposes requirements at the higher level to the environmental-protecting performance of house decorative material.
Conventional wallpaper by applying foaming PVC (being polyvinyl chloride) thickener on foil paper, this coating is heated and makes its foaming, produce the foaming embossing vinylchlorid wallpaper of embossed pattern, its advantage is to have mildew resistant moistureproof, flexibility and flexible, and stereoscopic sensation is strong and price is lower.But what adopt due to the production of PVC thickener and foaming process is chemical foaming, the a large amount of softening agent and the solvent that add all belong to high pollution chemical, there is the problem grievous injury HUMAN HEALTH such as plasticizer migration in the product of making PVC face wall paper in life-time service process, do not meet the environmental protection policy requirement that country is carrying out, run counter to resident's healthy living theory yet.
Summary of the invention
Technical problem to be solved by this invention is, a kind of environmental protection and energy saving is provided and has good foaming effect, can be on water-based wallpaper the water-based wallpaper intumescent coating glue of the intumescent coating of forming property excellence.
Technical problem to be solved by this invention is also, a kind of method of preparing above-mentioned water-based wallpaper intumescent coating glue is provided.
Technical problem to be solved by this invention is also, a kind of wallpaper that above-mentioned water-based wallpaper intumescent coating glue makes of applying is provided.
For reaching above-mentioned technique effect, the invention provides a kind of water-based wallpaper intumescent coating glue, comprise 40-60% main body emulsion resin, 35-55% Synergist S-421 95 and 1-10% water;
Described main body emulsion resin is selected one or more in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin;
Described Synergist S-421 95 comprises dispersion agent, emulsifying agent, thickening material, pore forming material, suds-stabilizing agent, whipping agent, peptizer and close infusion.
As the improvement of such scheme, comprise 45-55% main body emulsion resin, 40-50% Synergist S-421 95 and 5-10% water;
Described main body emulsion resin is selected one or both in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin.
As the improvement of such scheme, described Synergist S-421 95 is made up of 2-15% dispersion agent, 0.1-6% emulsifying agent, 0.1-5% thickening material, 0.1-6% pore forming material, 0.1-10% suds-stabilizing agent, 1-10% whipping agent, 1-10% peptizer and the close infusion of 0.1-5%.
As the improvement of such scheme, described Synergist S-421 95 also comprises wetting agent, defoamer, anti-webbing agent, stopping composition and thermal stabilizer.
As the improvement of such scheme, described Synergist S-421 95 is made up of 5-10% dispersion agent, 1-3% emulsifying agent, 1-2% thickening material, 1-3% pore forming material, 1-5% suds-stabilizing agent, 2-6% whipping agent, 2-5% peptizer, the close infusion of 0.5-2%, 6-10% wetting agent, 0.1-0.4% defoamer, 0.5-1% anti-webbing agent, 10-30% stopping composition, 2-5% thermal stabilizer.
As the improvement of such scheme, described dispersion agent is selected at least one of acrylic copolymer sodium salt, acrylic copolymer sylvite, poly-alkoxyl group multipolymer, polyacrylic acid sodium salt;
Described emulsifying agent is made up of one or more in anionic emulsifier, nonionic emulsifying agent, reactive emulsifier, wherein, described anionic emulsifier is selected from sodium lauryl sulphate, at least one in Sodium dodecylbenzene sulfonate, potassium oleate, sodium oleate or succinate; Described nonionic emulsifying agent is selected from least one in Vinlub, oleic acid glyceride, ethoxylated dodecyl alcohol, lauric acid polyoxyethylene ester, polyoxyethylene oleic acid ester or tween T-60; Described reactive emulsifier is selected from least one in 2-acrylamido-2-methyl-propyl sulfonic acid, 2-acrylamido-2-methyl-propyl sulfonic acid sodium salt, 2-vinylformic acid amido-2-methyl-propyl sulfonic acid ammonium salt, methacrylic acid hydroxide sodium dimercaptosulphanatein;
Described thickening material is selected at least one in bentonite, acrylic acid synthesizing thickening material, polyether-modified polyurethane thickener, macromolecule modified wilkinite, natural hectorite clay and organically-modified HECTABRITE DP;
Described pore forming material is selected at least one in potassium oleate, ammonium oleate, lauryl alcohol ether sodium sulfate;
Described suds-stabilizing agent is selected at least one in sodium hydroxide, potassium hydroxide, ammoniacal liquor, casein, gelatin, vegetable jelly, water-based silicone oil, oleic acid ammonium soaps, oleic acid potash soap;
Described whipping agent is selected at least one in ammonium hydrogencarbonate, blowing agent H;
Described peptizer is selected at least one in silicofluoride, ammonium persulphate, polyvinylpyrrolidone, Natvosol, sodium alginate;
Described close infusion is selected at least one in Sodium Silicofluoride, polyvinylpyrrolidone, Natvosol, sodium polyacrylate or alkaline acrylic thickener;
Described wetting agent is selected at least one in silicone wetting agent, anion surfactant, nonionogenic tenside, modified polyorganosiloxane;
Described defoamer is selected at least one in propyl carbinol, lauryl alcohol, turps, mineral oil defoaming agent, silicone based defoamer modified polyalcohol;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected at least one in talcum powder, calcium carbonate, wood powder, silicon-dioxide, Semen Maydis powder;
Described thermal stabilizer is selected metallic soap: at least one in calcium stearoyl, stearic barium, Zinic stearas.
As the improvement of such scheme, described main body emulsion resin is selected water-and acrylate resin;
Described dispersion agent is selected acrylic copolymer sodium salt;
Described emulsifying agent is selected sodium lauryl sulphate;
Described thickening material is selected acrylic acid synthesizing thickening material;
Described pore forming material is selected potassium oleate;
Described suds-stabilizing agent is selected oleic acid ammonium soaps;
Described whipping agent is selected ammonium hydrogencarbonate;
Described peptizer is selected polyvinylpyrrolidone;
Described close infusion is selected sodium polyacrylate;
Described wetting agent is selected silicone wetting agent;
Described defoamer is selected mineral oil defoaming agent;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected talcum powder;
Described thermal stabilizer is selected Zinic stearas.
Correspondingly, the invention provides a kind of method of preparing above-mentioned water-based wallpaper intumescent coating glue, comprising:
A, first other raw materials except peptizer are accurately weighed and put into high speed dispersor rapid dispersion;
B, scattered raw material is put into frothing machine after filtering, bubble to specified multiple at a high speed, obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, then through the solidifying bubble of low temperature conjunctiva, hot setting water-based wallpaper mechanical foaming coating.
As the improvement of such scheme, described specified multiple is 3-6 times, and the temperature of the solidifying bubble of low temperature conjunctiva is normal temperature, and the temperature of hot setting is 70-130 DEG C.
Correspondingly, the invention provides a kind of wallpaper, described wallpaper comprises base material and is located at the intumescent coating on described base material, and described intumescent coating adopts intumescent coating glue described above to generate.
Implement the present invention and there is following beneficial effect:
(1) the invention provides a kind of water-based wallpaper intumescent coating glue, comprise main body emulsion resin and Synergist S-421 95, wherein, main body emulsion resin and Synergist S-421 95 are based on water-based system, not containing organic solvent, when the traditional oiliness PVC of raising sticks with paste resin expanded glue sticking power, flexibility, elasticity, foaming height and colouring power, reduce again the concentration of air and living environment objectionable impurities, alleviate or eliminated the sense of discomfort of environment, reached and beautified room and fall oligosaprobic object.
And the traditional chemical that method pollution-free, that nothing is discharged, the mechanical foaming of physics is prepared elastic coating that the present invention adopts has successfully replaced high pollution, high energy consumption and high waste bubbles.In formula, utilize the synergy between multiple special auxiliary agent simultaneously, effectively improved stability and the scrub resistance of intumescent coating, avoided greatly loss and the waste of industry, promoted product competitiveness.
Therefore, water-based wallpaper intumescent coating of the present invention glue environmental protection and energy saving and there is good foaming effect, can be on water-based wallpaper the intumescent coating of forming property excellence.
(2) the present invention also provides a kind of method of preparing above-mentioned water-based wallpaper intumescent coating glue, it makes water-based wallpaper mechanical foaming coating adhesive by mechanical foaming-operations such as steady bubble-Mi bubble, this preparation method's technique is simple, material equipment cost is low, process control is easy, there is great adaptability, can widespread use.
(3) the present invention also provides a kind of wallpaper, comprises base material and intumescent coating, and intumescent coating adopts above-mentioned intumescent coating glue to generate.Because water-based wallpaper intumescent coating glue of the present invention has good sticking power, stereoscopic sensation, scrub resistance and colouring power, therefore, global stereopsis, gloss after described wallpaper coating embossing, natural, true to nature and ply adhesion is all comparatively outstanding, can guarantee that wallpaper has rich color, skin texture texture is strong, pattern abundant, decorative effect elegant texts.
Brief description of the drawings
Fig. 1 is the preparation method's of a kind of water-based wallpaper of the present invention intumescent coating glue schema.
Embodiment
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing, the present invention is described in further detail.
The invention provides a kind of water-based wallpaper intumescent coating glue, comprise 40-60% main body emulsion resin, 35-55% Synergist S-421 95 and 1-10% water; Described main body emulsion resin is selected one or more in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin; Described Synergist S-421 95 comprises dispersion agent, emulsifying agent, thickening material, pore forming material, suds-stabilizing agent, whipping agent, peptizer and close infusion.
Preferably, described water-based wallpaper intumescent coating glue comprises 45-55% main body emulsion resin, 40-50% Synergist S-421 95 and 5-10% water; Described main body emulsion resin is selected one or both in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin; Described Synergist S-421 95 is made up of dispersion agent, emulsifying agent, thickening material, pore forming material, suds-stabilizing agent, whipping agent, peptizer and close infusion.
It should be noted that, polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin can be that the aqueous foaming resin of wallpaper uses, as selection condition, depending on the base-material bond properties of its various types of resins and its coating, select wherein one or two kinds of resins of blending.
Wherein, as Synergist S-421 95 preferred embodiment, described Synergist S-421 95 is made up of 2-15% dispersion agent, 0.1-6% emulsifying agent, 0.1-5% thickening material, 0.1-6% pore forming material, 0.1-10% suds-stabilizing agent, 1-10% whipping agent, 1-10% peptizer and the close infusion of 0.1-5%.
As the better embodiment of Synergist S-421 95, described Synergist S-421 95 also comprises wetting agent, defoamer, anti-webbing agent, stopping composition and thermal stabilizer, and Synergist S-421 95 is made up of 5-10% dispersion agent, 1-3% emulsifying agent, 1-2% thickening material, 1-3% pore forming material, 1-5% suds-stabilizing agent, 2-6% whipping agent, 2-5% peptizer, the close infusion of 0.5-2%, 6-10% wetting agent, 0.1-0.4% defoamer, 0.5-1% anti-webbing agent, 10-30% stopping composition, 2-5% thermal stabilizer.
Concrete, described dispersion agent is selected at least one of acrylic copolymer sodium salt, acrylic copolymer sylvite, poly-alkoxyl group multipolymer, polyacrylic acid sodium salt;
Described emulsifying agent is made up of one or more in anionic emulsifier, nonionic emulsifying agent, reactive emulsifier, wherein, described anionic emulsifier is selected from sodium lauryl sulphate, at least one in Sodium dodecylbenzene sulfonate, potassium oleate, sodium oleate or succinate; Described nonionic emulsifying agent is selected from least one in Vinlub, oleic acid glyceride, ethoxylated dodecyl alcohol, lauric acid polyoxyethylene ester, polyoxyethylene oleic acid ester or tween T-60; Described reactive emulsifier is selected from least one in 2-acrylamido-2-methyl-propyl sulfonic acid, 2-acrylamido-2-methyl-propyl sulfonic acid sodium salt, 2-vinylformic acid amido-2-methyl-propyl sulfonic acid ammonium salt, methacrylic acid hydroxide sodium dimercaptosulphanatein;
Described thickening material is selected at least one in bentonite, acrylic acid synthesizing thickening material, polyether-modified polyurethane thickener, macromolecule modified wilkinite, natural hectorite clay and organically-modified HECTABRITE DP;
Described pore forming material is selected at least one in potassium oleate, ammonium oleate, lauryl alcohol ether sodium sulfate;
Described suds-stabilizing agent is selected at least one in sodium hydroxide, potassium hydroxide, ammoniacal liquor, casein, gelatin, vegetable jelly, water-based silicone oil, oleic acid ammonium soaps, oleic acid potash soap;
Described whipping agent is selected at least one in ammonium hydrogencarbonate, blowing agent H, and wherein, blowing agent H refers to N, N-dinitrosopentamethylene tetramine;
Described peptizer is selected at least one in silicofluoride, ammonium persulphate, polyvinylpyrrolidone, Natvosol, sodium alginate;
Described close infusion is selected at least one in Sodium Silicofluoride, polyvinylpyrrolidone, Natvosol, sodium polyacrylate or alkaline acrylic thickener;
Described wetting agent is selected at least one in silicone wetting agent, anion surfactant, nonionogenic tenside, modified polyorganosiloxane;
Described defoamer is selected at least one in propyl carbinol, lauryl alcohol, turps, mineral oil defoaming agent, silicone based defoamer modified polyalcohol;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected at least one in talcum powder, calcium carbonate, wood powder, silicon-dioxide, Semen Maydis powder;
Described thermal stabilizer is selected metallic soap: at least one in calcium stearoyl, stearic barium, Zinic stearas.
Better, described main body emulsion resin is selected water-and acrylate resin;
Described dispersion agent is selected acrylic copolymer sodium salt;
Described emulsifying agent is selected sodium lauryl sulphate;
Described thickening material is selected acrylic acid synthesizing thickening material;
Described pore forming material is selected potassium oleate;
Described suds-stabilizing agent is selected oleic acid ammonium soaps;
Described whipping agent is selected ammonium hydrogencarbonate;
Described peptizer is selected polyvinylpyrrolidone;
Described close infusion is selected sodium polyacrylate;
Described wetting agent is selected silicone wetting agent;
Described defoamer is selected mineral oil defoaming agent;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected talcum powder;
Described thermal stabilizer is selected Zinic stearas.
The invention provides a kind of water-based wallpaper intumescent coating glue, comprise main body emulsion resin and Synergist S-421 95, wherein, main body emulsion resin and Synergist S-421 95 are based on water-based system, not containing organic solvent, when the traditional oiliness PVC of raising sticks with paste resin expanded glue sticking power, flexibility, elasticity, foaming height and colouring power, reduce again the concentration of air and living environment objectionable impurities, alleviate or eliminated the sense of discomfort of environment, reached and beautified room and fall oligosaprobic object.
And the traditional chemical that method pollution-free, that nothing is discharged, the mechanical foaming of physics is prepared elastic coating that the present invention adopts has successfully replaced high pollution, high energy consumption and high waste bubbles.In formula, utilize the synergy between multiple special auxiliary agent simultaneously, effectively improved stability and the scrub resistance of intumescent coating, avoided greatly loss and the waste of industry, promoted product competitiveness.
Therefore, water-based wallpaper intumescent coating of the present invention glue environmental protection and energy saving and there is good foaming effect, can be on water-based wallpaper the intumescent coating of forming property excellence.
Correspondingly, as shown in Figure 1, the invention provides a kind of method of preparing above-mentioned water-based wallpaper intumescent coating glue, comprising:
S101, first other raw materials except peptizer are accurately weighed and put into high speed dispersor rapid dispersion.
Preferably, the time of rapid dispersion is 2-30 minute, better, and the time of rapid dispersion is 10 minutes.
S102, scattered raw material is put into frothing machine after filtering, bubble to specified multiple at a high speed, obtain foam slurry.
Wherein, described specified multiple is preferably 3-6 doubly.
S103, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, then through the solidifying bubble of low temperature conjunctiva, hot setting water-based wallpaper mechanical foaming coating.
Wherein, the temperature of the solidifying bubble of low temperature conjunctiva is normal temperature, and the temperature of hot setting is 70-130 DEG C.
Preferably, the temperature of hot setting is 80-120 DEG C.
It should be noted that, prepare the composition of raw materials that the method for above-mentioned water-based wallpaper intumescent coating glue adopts identical with the composition of raw materials of above-mentioned water-based wallpaper intumescent coating glue, do not repeat them here.
Described preparation method makes water-based wallpaper mechanical foaming coating adhesive by mechanical foaming-operations such as steady bubble-Mi bubble, and this preparation method's technique is simple, and material equipment cost is low, and process control is easy, has great adaptability, can widespread use.
Correspondingly, the invention provides a kind of wallpaper, described wallpaper comprises base material and is located at the intumescent coating on described base material, and described intumescent coating adopts intumescent coating glue described above to generate.Because water-based wallpaper intumescent coating glue of the present invention has good sticking power, stereoscopic sensation, scrub resistance and colouring power, therefore, global stereopsis, gloss after described wallpaper coating embossing, natural, true to nature and ply adhesion is all comparatively outstanding, can guarantee that wallpaper has rich color, skin texture texture is strong, pattern abundant, decorative effect elegant texts.
It should be noted that, composition of raw materials and the preparation method of wallpaper intumescent coating glue used are same as above, do not repeat them here.
Further set forth the present invention with specific embodiment below
Embodiment 1
(1) composition of raw materials
Main body emulsion resin 50%
Water 8%
Dispersion agent 10%
Emulsifying agent 3%
Thickening material 3%
Pore forming material 4%
Suds-stabilizing agent 6%
Whipping agent 7%
Peptizer 7%
Close infusion 2%
Wherein, main body emulsion resin is selected water-and acrylate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 2
(1) composition of raw materials
Main body emulsion resin 45%
Water 10%
Dispersion agent 15%
Emulsifying agent 1%
Thickening material 1%
Pore forming material 1%
Suds-stabilizing agent 2%
Whipping agent 10%
Peptizer 10%
Close infusion 5%
Wherein, main body emulsion resin is selected water-and acrylate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 3
(1) composition of raw materials
Main body emulsion resin 48%
Water 5%
Dispersion agent 12%
Emulsifying agent 6%
Thickening material 5%
Pore forming material 6%
Suds-stabilizing agent 5%
Whipping agent 5%
Peptizer 5%
Close infusion 3%
Wherein, main body emulsion resin is selected water-and acrylate resin and styrene-butadiene latex (water-and acrylate resin: styrene-butadiene latex=1:1); Described dispersion agent is selected poly-alkoxyl group multipolymer; Described emulsifying agent is selected oleic acid glyceride; Described thickening material is selected bentonite; Described pore forming material is selected ammonium oleate; Described suds-stabilizing agent is selected potassium hydroxide; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected silicofluoride; Described close infusion is selected polyvinylpyrrolidone.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 4
(1) composition of raw materials
Main body emulsion resin 53%
Water 10%
Dispersion agent 2%
Emulsifying agent 4%
Thickening material 2%
Pore forming material 3%
Suds-stabilizing agent 8%
Whipping agent 8%
Peptizer 8%
Close infusion 2%
Wherein, main body emulsion resin is selected ethylene-vinyl acetate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 5
(1) composition of raw materials
Main body emulsion resin 40%
Water 10%
Dispersion agent 15%
Emulsifying agent 2%
Thickening material 2%
Pore forming material 2%
Suds-stabilizing agent 8%
Whipping agent 10%
Peptizer 10%
Close infusion 1%
Wherein, main body emulsion resin is selected polychloroprene latex, butadiene acrylonitrile rubber breast (polychloroprene latex: butadiene acrylonitrile rubber breast=1:1.2); Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 6
(1) composition of raw materials
Main body emulsion resin 60%
Water 2%
Dispersion agent 11%
Emulsifying agent 5%
Thickening material 4%
Pore forming material 6%
Suds-stabilizing agent 2%
Whipping agent 3%
Peptizer 3%
Close infusion 4%
Wherein, main body emulsion resin is selected water-and acrylate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected 2-acrylamido-2-methyl-propyl sulfonic acid; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected lauryl alcohol ether sodium sulfate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected ammonium persulphate; Described close infusion is selected sodium polyacrylate.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 7
(1) composition of raw materials
Main body emulsion resin 50%
Water 5%
Dispersion agent 5%
Emulsifying agent 2%
Thickening material 1%
Pore forming material 1%
Suds-stabilizing agent 2%
Whipping agent 2%
Peptizer 2%
Close infusion 1%
Wetting agent 6%
Defoamer 0.2%
Anti-webbing agent 0.8%
Stopping composition 20%
Thermal stabilizer 2%
Wherein, main body emulsion resin is selected water-and acrylate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate; Described wetting agent is selected silicone wetting agent; Described defoamer is selected mineral oil defoaming agent; Described anti-webbing agent is selected wool lipid anti-webbing agent; Described stopping composition is selected talcum powder; Described thermal stabilizer is selected Zinic stearas.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 8
(1) composition of raw materials
Main body emulsion resin 45%
Water 6%
Dispersion agent 5%
Emulsifying agent 2%
Thickening material 1%
Pore forming material 2%
Suds-stabilizing agent 3%
Whipping agent 3%
Peptizer 3%
Close infusion 1%
Wetting agent 6%
Defoamer 0.2%
Anti-webbing agent 0.8%
Stopping composition 20%
Thermal stabilizer 2%
Wherein, main body emulsion resin is selected water-and acrylate resin; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate; Described wetting agent is selected silicone wetting agent; Described defoamer is selected mineral oil defoaming agent; Described anti-webbing agent is selected wool lipid anti-webbing agent; Described stopping composition is selected calcium carbonate; Described thermal stabilizer is selected calcium stearoyl.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
Embodiment 9
(1) composition of raw materials
Main body emulsion resin 48%
Water 8%
Dispersion agent 6%
Emulsifying agent 2%
Thickening material 1%
Pore forming material 2%
Suds-stabilizing agent 3%
Whipping agent 3%
Peptizer 3%
Close infusion 1%
Wetting agent 7%
Defoamer 0.2%
Anti-webbing agent 0.8%
Stopping composition 12%
Thermal stabilizer 3%
Wherein, main body emulsion resin is selected styrene-butadiene latex; Described dispersion agent is selected acrylic copolymer sodium salt; Described emulsifying agent is selected sodium lauryl sulphate; Described thickening material is selected acrylic acid synthesizing thickening material; Described pore forming material is selected potassium oleate; Described suds-stabilizing agent is selected oleic acid ammonium soaps; Described whipping agent is selected ammonium hydrogencarbonate; Described peptizer is selected polyvinylpyrrolidone; Described close infusion is selected sodium polyacrylate; Described wetting agent is selected silicone wetting agent; Described defoamer is selected mineral oil defoaming agent; Described anti-webbing agent is selected wool lipid anti-webbing agent; Described stopping composition is selected silicon-dioxide; Described thermal stabilizer is selected Zinic stearas.
(2) preparation method
A, other raw materials except peptizer are accurately weighed by (one) composition of raw materials, put into high speed dispersor rapid dispersion 10 minutes;
B, scattered raw material is put into frothing machine after filtering, bubble at a high speed to specified multiple (3-6 doubly), obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, solidifying bubble conjunctiva under normal temperature condition then solidifies under the hot conditions of 80-120 DEG C again, water-based wallpaper mechanical foaming coating.
It should be noted that, in the composition of raw materials of water-based wallpaper intumescent coating glue of the present invention, the % of raw material refers to weight percent wt%.
The intumescent coating glue of embodiment 1-9 gained is applied to wallpaper below and does technology for detection, and stick with paste resin expanded glue with conventional P VC of the prior art and do technology contrast, result is as follows:
As from the foregoing, (1) the invention provides a kind of water-based wallpaper intumescent coating glue, comprise main body emulsion resin and Synergist S-421 95, wherein, main body emulsion resin and Synergist S-421 95 are based on water-based system, not containing organic solvent, when the traditional oiliness PVC of raising sticks with paste resin expanded glue sticking power, flexibility, elasticity, foaming height and colouring power, reduce again the concentration of air and living environment objectionable impurities, alleviated or eliminated the sense of discomfort of environment, reached and beautified room and fall oligosaprobic object.
And the traditional chemical that method pollution-free, that nothing is discharged, the mechanical foaming of physics is prepared elastic coating that the present invention adopts has successfully replaced high pollution, high energy consumption and high waste bubbles.In formula, utilize the synergy between multiple special auxiliary agent simultaneously, effectively improved stability and the scrub resistance of intumescent coating, avoided greatly loss and the waste of industry, promoted product competitiveness.
Therefore, water-based wallpaper intumescent coating of the present invention glue environmental protection and energy saving and there is good foaming effect, can be on water-based wallpaper the intumescent coating of forming property excellence.
(2) the present invention also provides a kind of method of preparing above-mentioned water-based wallpaper intumescent coating glue, it makes water-based wallpaper mechanical foaming coating adhesive by mechanical foaming-operations such as steady bubble-Mi bubble, this preparation method's technique is simple, material equipment cost is low, process control is easy, there is great adaptability, can widespread use.
(3) the present invention also provides a kind of wallpaper, comprises base material and intumescent coating, and intumescent coating adopts above-mentioned intumescent coating glue to generate.Because water-based wallpaper intumescent coating glue of the present invention has good sticking power, stereoscopic sensation, scrub resistance and colouring power, therefore, global stereopsis, gloss after described wallpaper coating embossing, natural, true to nature and ply adhesion is all comparatively outstanding, can guarantee that wallpaper has rich color, skin texture texture is strong, pattern abundant, decorative effect elegant texts.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (10)
1. a water-based wallpaper intumescent coating glue, is characterized in that, comprises 40-60% main body emulsion resin, 35-55% Synergist S-421 95 and 1-10% water;
Described main body emulsion resin is selected one or more in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin;
Described Synergist S-421 95 comprises dispersion agent, emulsifying agent, thickening material, pore forming material, suds-stabilizing agent, whipping agent, peptizer and close infusion.
2. water-based wallpaper intumescent coating glue as claimed in claim 1, is characterized in that, comprises 45-55% main body emulsion resin, 40-50% Synergist S-421 95 and 5-10% water;
Described main body emulsion resin is selected one or both in polychloroprene latex, butadiene acrylonitrile rubber breast, styrene-butadiene latex, water-and acrylate resin, polyurethane aqueous resin and ethylene-vinyl acetate resin.
3. water-based wallpaper intumescent coating glue as claimed in claim 1, it is characterized in that, described Synergist S-421 95 is made up of 2-15% dispersion agent, 0.1-6% emulsifying agent, 0.1-5% thickening material, 0.1-6% pore forming material, 0.1-10% suds-stabilizing agent, 1-10% whipping agent, 1-10% peptizer and the close infusion of 0.1-5%.
4. the water-based wallpaper intumescent coating glue as described in claim 1,2 or 3, is characterized in that, described Synergist S-421 95 also comprises wetting agent, defoamer, anti-webbing agent, stopping composition and thermal stabilizer.
5. water-based wallpaper intumescent coating glue as claimed in claim 4, it is characterized in that, described Synergist S-421 95 is made up of 5-10% dispersion agent, 1-3% emulsifying agent, 1-2% thickening material, 1-3% pore forming material, 1-5% suds-stabilizing agent, 2-6% whipping agent, 2-5% peptizer, the close infusion of 0.5-2%, 6-10% wetting agent, 0.1-0.4% defoamer, 0.5-1% anti-webbing agent, 10-30% stopping composition, 2-5% thermal stabilizer.
6. water-based wallpaper intumescent coating glue as claimed in claim 5, is characterized in that, described dispersion agent is selected at least one of acrylic copolymer sodium salt, acrylic copolymer sylvite, poly-alkoxyl group multipolymer, polyacrylic acid sodium salt;
Described emulsifying agent is made up of one or more in anionic emulsifier, nonionic emulsifying agent, reactive emulsifier, wherein, described anionic emulsifier is selected from sodium lauryl sulphate, at least one in Sodium dodecylbenzene sulfonate, potassium oleate, sodium oleate or succinate; Described nonionic emulsifying agent is selected from least one in Vinlub, oleic acid glyceride, ethoxylated dodecyl alcohol, lauric acid polyoxyethylene ester, polyoxyethylene oleic acid ester or tween T-60; Described reactive emulsifier is selected from least one in 2-acrylamido-2-methyl-propyl sulfonic acid, 2-acrylamido-2-methyl-propyl sulfonic acid sodium salt, 2-vinylformic acid amido-2-methyl-propyl sulfonic acid ammonium salt, methacrylic acid hydroxide sodium dimercaptosulphanatein;
Described thickening material is selected at least one in bentonite, acrylic acid synthesizing thickening material, polyether-modified polyurethane thickener, macromolecule modified wilkinite, natural hectorite clay and organically-modified HECTABRITE DP;
Described pore forming material is selected at least one in potassium oleate, ammonium oleate, lauryl alcohol ether sodium sulfate;
Described suds-stabilizing agent is selected at least one in sodium hydroxide, potassium hydroxide, ammoniacal liquor, casein, gelatin, vegetable jelly, water-based silicone oil, oleic acid ammonium soaps, oleic acid potash soap;
Described whipping agent is selected at least one in ammonium hydrogencarbonate, blowing agent H;
Described peptizer is selected at least one in silicofluoride, ammonium persulphate, polyvinylpyrrolidone, Natvosol, sodium alginate;
Described close infusion is selected at least one in Sodium Silicofluoride, polyvinylpyrrolidone, Natvosol, sodium polyacrylate or alkaline acrylic thickener;
Described wetting agent is selected at least one in silicone wetting agent, anion surfactant, nonionogenic tenside, modified polyorganosiloxane;
Described defoamer is selected at least one in propyl carbinol, lauryl alcohol, turps, mineral oil defoaming agent, silicone based defoamer modified polyalcohol;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected at least one in talcum powder, calcium carbonate, wood powder, silicon-dioxide, Semen Maydis powder;
Described thermal stabilizer is selected at least one in calcium stearoyl, stearic barium, Zinic stearas.
7. water-based wallpaper intumescent coating glue as claimed in claim 6, is characterized in that, described main body emulsion resin is selected water-and acrylate resin;
Described dispersion agent is selected acrylic copolymer sodium salt;
Described emulsifying agent is selected sodium lauryl sulphate;
Described thickening material is selected acrylic acid synthesizing thickening material;
Described pore forming material is selected potassium oleate;
Described suds-stabilizing agent is selected oleic acid ammonium soaps;
Described whipping agent is selected ammonium hydrogencarbonate;
Described peptizer is selected polyvinylpyrrolidone;
Described close infusion is selected sodium polyacrylate;
Described wetting agent is selected silicone wetting agent;
Described defoamer is selected mineral oil defoaming agent;
Described anti-webbing agent is selected wool lipid anti-webbing agent;
Described stopping composition is selected talcum powder;
Described thermal stabilizer is selected Zinic stearas.
8. a method of preparing the water-based wallpaper intumescent coating glue as described in claim 1-7 any one, is characterized in that, comprising:
A, first other raw materials except peptizer are accurately weighed and put into high speed dispersor rapid dispersion;
B, scattered raw material is put into frothing machine after filtering, bubble to specified multiple at a high speed, obtain foam slurry;
C, foam slurry is put into pneumatics basin, then press filtration is to steady bubble machine, adds peptizer, after Mi Pao, continous way was put cloth machine into and is scraped and starched cloth, then through the solidifying bubble of low temperature conjunctiva, hot setting water-based wallpaper mechanical foaming coating.
9. the preparation method of water-based wallpaper intumescent coating glue as claimed in claim 8, is characterized in that, described specified multiple is 3-6 times, and the temperature of the solidifying bubble of low temperature conjunctiva is normal temperature, and the temperature of hot setting is 70-130 DEG C.
10. a wallpaper, described wallpaper comprises base material and is located at the intumescent coating on described base material, it is characterized in that, described intumescent coating adopts the intumescent coating glue as described in claim 1-7 any one to generate.
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| CN201410211995.6A CN104004473A (en) | 2014-05-20 | 2014-05-20 | Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper |
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| CN104004473A true CN104004473A (en) | 2014-08-27 |
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Inventor after: Lu Kaiquan Inventor after: Liu Huajie Inventor after: Chang Weijie Inventor before: Lu Kaiquan Inventor before: Liu Huajie |
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| COR | Change of bibliographic data | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140827 |