CN105926294A - Novel environment-friendly waterborne textile coating polyfoam - Google Patents
Novel environment-friendly waterborne textile coating polyfoam Download PDFInfo
- Publication number
- CN105926294A CN105926294A CN201610312089.4A CN201610312089A CN105926294A CN 105926294 A CN105926294 A CN 105926294A CN 201610312089 A CN201610312089 A CN 201610312089A CN 105926294 A CN105926294 A CN 105926294A
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- parts
- foamed glue
- novel environment
- weight portion
- water
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- 238000000576 coating method Methods 0.000 title claims abstract description 70
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/04—Processes in which the treating agent is applied in the form of a foam
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses novel environment-friendly waterborne textile coating polyfoam. The textile coating polyfoam is prepared from waterborne acrylate emulsion, a stearyl amine additive, a TiO2 additive, thickener, mould inhibitor, preservative, dispersant and a leveling agent. The invention further discloses a method for preparing the novel environment-friendly waterborne textile coating polyfoam.
Description
Technical field
The present invention relates to a kind of spinning coating finishing agent, a kind of textile aqueous foaming coating adhesive and system thereof
Preparation Method.
Technical background
What fabric intumescent coating was fabric with high molecular polymer mixed foaming colloid is compound, compound after properties of textile
Significantly change can occur, and it not only retains the original function of fabric, further increases the function of cover layer, significantly widened weaving
The purposes of product, the fabric of foamed top finish has a water-proof air-moisture-permeable, heat insulation noise, shading anti-ultraviolet, antifouling anti-
Bacterium, the effect such as abundant plentiful softness of feel.At industrial cloth, material clothing, the first-class grade of domestic wall paper all occupies critically important ground
Position, weaving foaming industry, owing to foamed glue complex process is complicated, (includes Stearyl Amine and TiO the most at home2Synthesis) work
The operation technique of factory workman is the most different, often occurs that foamed glue compounds imperfection in compound process, causes product to go out secondary
Rate improves repeatedly, greatly reduces yarn fabric quality stability, and novel environment-friendly spinning coating foamed glue instead of factory voluntarily
The compounding time, can directly carry out intumescent coating, convenient succinct.Improve Client Work efficiency, band when reducing compounding synthesis for client
The risk come.Therefore the foaming environment-friendly type coating adhesive providing a kind of high-quality can become the required of numerous textile enterprise development.
Summary of the invention
It is an object of the invention to provide a kind of textile aqueous foaming coating adhesive, it can meet wanting of foaming finishing process
Ask, directly to after its physical blowing, fabric can be carried out top finish by mechanical foaming.
In order to reach this purpose, the invention provides a kind of textile aqueous foaming coating adhesive, by including following weight
The raw material of part is prepared from: water-and acrylate emulsion 60-70 weight portion, Stearyl Amine additive 10-20 weight portion, TiO2Add
Add agent 10-30 weight portion, thickening agent 4-6 weight portion, antifungus agent 1 weight portion, preservative 1 weight portion, dispersant 1.5-2.5 weight
Part, levelling agent 1.5-2.5 weight portion.
As a kind of preferred implementation of the present invention, described spinning coating foamed glue solid content 45%-50%, pH value 8-
10。
As a kind of preferred implementation of the present invention, described water-and acrylate emulsion is expandable pure third self-crosslinking
Emulsion, TG is-20 DEG C--30 DEG C, solid content is 30%-55%, and pH value is 2-5.
As a kind of preferred implementation of the present invention, described Stearyl Amine additive mass concentration is 15%-20%.
As a kind of preferred implementation of the present invention, described TiO2Brightening additive for powder, mass concentration is
60%-70%。
As a kind of preferred implementation of the present invention, described thickening agent is association type aqueous PU emulsion.
As a kind of preferred implementation of the present invention, described antifungus agent is N-(2-benzimidazole base)-carbamic acid
Methyl ester and/or tetramethylthiuram disulfide.
As a kind of preferred implementation of the present invention, described preservative be 2-methyl-4-different plug oxazoline-3-ketone and/
Or 5-chloro-2-methyl-4-different plug oxazoline-3-ketone.
Present invention also offers the preparation method of a kind of novel environment-friendly water-based spinning coating foamed glue, it is characterised in that tool
Body step is as follows:
1) in the reactor with agitating device, put into water-and acrylate emulsion, start at a slow speed stirring, obtain mixture A.
2) in the mixture A that step 1) obtains, ammonium stearate additive, TiO are added successively2Titanium dioxide slurry, stirs,
Obtain mixture B.
3) last successively to step 2) obtained by mixture B add Antisepticize and mildew preventive, thickening agent, levelling agent.Fully stir
Mix, get product after filtration.
Preferably, ammonium stearate and TiO in second step2Needing through dispersant high speed dispersion, turbine sand mill surpasses
Micronization processes.
Compared with prior art, the invention has the beneficial effects as follows:
Foaming finishing technique requirement can be met, directly it is carried out physical blowing by mechanical foaming machine, meet textile
The new demand of top finish.By regulating its composition and ratio, can prepare and meet different fabric to performance requirements such as pliabilitys
Coating adhesive, be applied to curtain, sofa, the top finish of the yarn fabric such as wall paper.Also be adapted for fabric shading arrange, overcome with
Front window shade uses multilamellar aqueous cutter to be coated with, and feel is endured with all one's will, the defects such as frangibility comes off, and appearance is undesirable.Have employed thing
The process technique that reason and chemistry combine is to ammonium stearate and TiO2Carry out super-refinement sand milling so that coating adhesive has well storage
Deposit stability.
Detailed description of the invention
Participate in the election of the detailed description being preferable to carry out method of the invention below and the embodiment that includes can be more easily understood these public affairs
Open content.Can mention a large amount of term in description below and claims, these terms are defined as following meanings.
Term as used herein " by ... preparation " and " comprising " synonym.Term used herein " comprises ", " including ",
" have ", " containing " or its other deformation any, it is intended that cover the including of non-exclusionism.Such as, the combination of listed elements is comprised
Thing, step, method, goods or device are not necessarily solely those key elements, but can include other not expressly listed key element or
The key element that this kind of compositions, step, method, goods or device are intrinsic.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise.
" optional " or " optionally " refers to that the item described thereafter or event may or may not occur, and this is retouched
State and include situation that event occurs and the situation that event does not occurs.
Approximation term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this concrete
Quantity, also includes close to this quantity acceptable without causing the part of the correction of the change of relevant basic function.Phase
Answer, modify a numerical value with " about ", " about " etc., mean and the invention is not restricted to this exact numerical.In some example, approximation
Term likely corresponds to measure the precision of the instrument of numerical value.In present specification and claims, scope limits permissible
Combination and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
One aspect of the present invention provides a kind of textile aqueous foaming coating adhesive, the raw material including following weight portion prepare
Form: water-and acrylate emulsion 60-70 weight portion, Stearyl Amine additive 10-20 weight portion, TiO2Additive 10-30 weight
Amount part, thickening agent 4-6 weight portion, antifungus agent 1 weight portion, preservative 1 weight portion, dispersant 1.5-2.5 weight portion, levelling agent
1.5-2.5 weight portion.
Water-and acrylate emulsion
Water-and acrylate emulsion of the present invention is expandable pure third self-crossing emulsion, and addition is 60-70 weight portion.
Acrylic acid ester emulsion polymer is widely used in pigment printing, electrostatic spinning, fabric laminating, warp sizing and coating and adds
Works etc., the esters of acrylic acid of various different performances also has the most different purposes because of the difference of its raw material used and proportioning.
Organosilicon-modified acrylic emulsion is the emulsion polymer of organo-silicon compound and acrylate, and its emulsion particle diameter is evenly distributed,
Stability of emulsion is high, and film good combination property, water resistance is good, and water resistance is up to higher level.
Ammonium stearate
Ammonium stearate of the present invention, addition is 10-20 weight portion.
Ammonium stearate, is mainly used in waterproofing agent and the cosmetics industry of concrete, paper and yarn fabric.
TiO2Titanium dioxide slurry
TiO of the present invention2Titanium dioxide slurry, addition is 10-30 weight portion.
Titanium dioxide formal name used at school is titanium dioxide, and it is a kind of dyestuff and pigment.For painting, ink, plastics, rubber, papermaking,
The industries such as chemical fibre.Titanium dioxide belongs to the material of Heat stability is good.In conventional Chinese white, the relative density of titanium dioxide
Minimum, in the Chinese white of equal quality, the largest surface area of titanium dioxide, pigment volume concentration is the highest.Titanium dioxide is Chinese white
The one that middle tinting strength, tinting power is the strongest, has excellent covering power and color fastness, it is adaptable to opaque white article.Rutile-type
It is particularly well-suited to the plastic of outdoor application, the light stability that goods are good can be given.Anatase titanium dioxide is mainly used in indoor use
Goods, but slightly blue light, whiteness is high, covering power big, strong coloring force and dispersibility preferable.Titanium dioxide be widely used as paint, paper,
The pigment of rubber, plastics, enamel, glass, cosmetics, ink, watercolor and greasepaint, it may also be used for metallurgy, radio, pottery, electricity
Welding rod.
The production method of titanium dioxide has sulfuric acid process and chloridising two kinds.Sulfuric acid process is that ilmenite powder and concentrated sulphuric acid are carried out acid
Solve reaction and generate titanyl sulfate, generate metatitanic acid through water, more i.e. obtain titanium dioxide product through calcining, pulverizing.This method can produce sharp
Titanium-type and Rutile type titanium dioxide.Chloridising be rutile or high titanium slag powder are mixed with coke after carry out high-temp chlorination generation
Titanium tetrachloride, generates titanium dioxide through high-temperature oxydation, then filters, washes, is dried, pulverizes and i.e. obtain titanium dioxide product.
Thickening agent
Thickening agent of the present invention is association type aqueous PU emulsion, and addition is 4-6 weight portion.
Thickening agent has a following classification: (1) inorganic thickening agent (fume colloidal silica, sodium bentonite, organic swelling
Soil, kieselguhr, attapulgite soil, molecular sieve, Silica hydrogel).(2) cellulose ether (methylcellulose, hydroxypropyl methyl cellulose,
Sodium carboxymethyl cellulose, hydroxyethyl cellulose).(3) natural polymer and derivant (starch, gelatin, sodium alginate, cheese
Element, guar gum, chitosan, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber, lanoline, agar).(4) synthesis height
Molecule (polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, carbomer, polyacrylic acid, polyacrylic acid
Sodium, Polyacrylate Emulsion, butadiene rubber, butadiene-styrene rubber, polyurethane, modified polyurea, low-molecular polyethylene wax).(5) network
Mould assembly organo-metallic compound (amino alcohol solvay-type titanate esters).(6) printing thickening agent (dispersion thickening agent, coating thickener, work
Property thickening agent).
The molecular structure of association type polyurethanes thickening agent introduces hydrophilic group and hydrophobic group so that it is present one
The character of fixed surfactant.When its concentration of aqueous solution exceedes a certain certain concentration, form micelle, micelle and polymer
Particle association forms network structure, makes system viscosity increase.On the other hand a several micelle of molecular band, reduces hydrone
Animal migration, makes aqueous phase viscosity also improve.This kind of thickening agent not only produces impact to the rheological characteristic of coating, and with adjacent latex
Exist between particle and interact, if this effect is too strong, easily cause latex to be layered.
This associative structure of association type polyurethanes thickening agent is destroyed under the effect of shearing force, and viscosity reduces, when
Shearing force disappearance viscosity can recover again, can prevent work progress from sagging phenomenon occur.And its viscosity recovers to have certain stagnant
Rear property, beneficially film levelling.The relative molecular mass (thousands of to tens thousand of) of polyurethane thickener is than the phase of front two class thickening agents
Much lower to molecular mass (hundreds thousand of to millions of), splashing will not be encouraged.The water solublity of cellulose thickener height can shadow
Ring the resistance to water of film, but there is on polyurethanes thickener molecule hydrophilic and hydrophobic group simultaneously, hydrophobic group and film
Matrix has stronger affinity, can strengthen the resistance to water of film.Owing to latex particle take part in association, flocculation will not be produced, because of
And film can be made smooth, there is higher glossiness.Association type polyurethane thickener many performances are better than other thickening agent, but due to
The micelle thickening mechanism of its uniqueness, thus in formulation for coating material, those components affecting micelle will necessarily produce impact to thickening property.
During with this type of thickening agent, the various factors impact on thickening properties should be taken into full account, do not change the most easily the emulsion used by coating,
Defoamer, dispersant, coalescents etc..
Antifungus agent
Antifungus agent of the present invention is N-(2-benzimidazole base)-methyl carbamate and/or tetramethylthiuram disulfide,
Addition is 1 weight portion.
Antifungus agent, refers to prevent microorganism from causing mouldy medicament.There are phenols (such as phenol), chlorophenols (such as pentachloro-
Phenol), organic mercury salt (such as phenyl mercury oleate), organic copper salt (such as copper 8-quinolinolate), organic tin salt is (such as chlorination three second or three
Butyl tin etc.), and inorganic salt copper sulfate, mercuric chloride, sodium fluoride etc..For plastics, rubber, textile, paint and insulant
Deng.The effect of antifungus agent is the most unalterable, and it is influenced by factors.1. microbiology factor.2. chemical factors.1. feedstuff
Water content；2. temperature；3. feed components；4. feed dosage form.
Preservative
Preservative of the present invention is 2-methyl-4-different plug oxazoline-3-ketone and/or 5-chloro-2-methyl-4-different plug oxazoline-3-
Ketone, addition is 1 weight portion.
Preservative refers to naturally occurring or synthetic chemical composition, is used for adding food, medicine, pigment, biological sample etc., to prolong
The corruption that growth of microorganism or chemical change cause late.Nitrite and sulfur dioxide are one of conventional preservative.
The antiseptic principle of preservative, substantially has following 3 kinds: one, be the enzyme system of interference microorganism, destroys it the oldest
Metabolism, inhibitory activity.Two, it is protein coagulating and the degeneration making microorganism, disturbs its existence and breeding.Three, it is to change cell
Slurry permeability of the membrane, suppresses its internal enzyme and the eliminating of metabolite, causes it to inactivate.
Dispersant
Dispersant of the present invention is polyacrylic acid sodium salt, and addition is 1.5-2.5 weight portion.
The effect of dispersant is to use wetting dispersing agent to reduce the time required for dispersive process and energy, stablizes institute
Scattered pigment dispersion, modified pigment particle surface properties, adjust the mobility of pigment particles, be embodied in following
Aspect: shorten jitter time, improves gloss, improves tinting strength, tinting power and covering power, improves color developing and toning property, prevents loose colour from sending out
Flower, prevents flocculation, prevents sedimentation.
Levelling agent
Levelling agent of the present invention is EU-carbitol, and addition is 1.5-2.5 weight portion.
Levelling agent is a kind of conventional coating additive, it can promote coating formed during drying and forming-film one smooth,
Film smooth, uniform.Can effectively reduce covering with paint liquid surface tension, improve a class material of its levelability and uniformity.Can change
The permeability of kind covering with paint liquid, produces speckle and the probability of spot when can reduce brushing, increases spreadability, makes film forming uniformly, certainly
So.Mainly surfactant, organic solvent etc..Levelling agent kind is a lot, and different levelling agent kinds used by coating are the most not to the utmost
Identical.Available high boiling solvent or butyl cellulose in solvent-borne type finishing agent.Surface activity is then used in aqua type finishing agent
Agent or polyacrylic acid, carboxymethyl cellulose etc..
Levelling agent is roughly divided into two big classes.A kind of work by adjusting paint film viscosity and flow time, this kind of
Levelling agent is some high boiling organic solvents or its mixture mostly, such as isophorone, DAA etc.;Another kind is to pass through
Adjusting what coating surface character worked, the levelling agent described in general people refers to this class levelling agent mostly.This kind of levelling
Agent migrates to coating surface by the limited compatibility, affects the surface naturies such as paint film interfacial tension, makes paint film obtain good
Levelling.According to the difference of chemical constitution, this kind of levelling agent mainly has a three major types: acrylic compounds, silicone and fluorocarbons
Class.
Below by embodiment, the present invention is specifically described.Be necessary it is pointed out here that, following example are only used
In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field
Some nonessential improvement and adjustment that content according to the invention described above is made, still fall within protection scope of the present invention.
It addition, illustrate without other, raw materials used is all commercially available.
Embodiment:
Embodiment 1
The preparation method of coating foamed glue:
1) in the reactor with agitating device, put into water-and acrylate emulsion, start at a slow speed stirring, obtain mixture A.
2) in the mixture A that step 1) obtains, ammonium stearate additive, TiO are added successively2Titanium dioxide slurry, stirs,
Obtain mixture B, wherein ammonium stearate and TiO2Needing through dispersant high speed dispersion, turbine sand mill is carried out at super-refinement
Reason.
3) last successively to step 2) obtained by mixture B add preservative, antifungus agent, thickening agent, levelling agent.Fully
Stirring, gets product after filtration.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 2
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
5-chloro-2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 3
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
Tetramethylthiuram disulfide 2 parts
5-chloro-2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 4
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
Tetramethylthiuram disulfide 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 5
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 30 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 6
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO230 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 7
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 36 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 8
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 40 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 9
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 40 parts
TiO230 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 10
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 20 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Embodiment 11
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 30 parts
TiO220 parts
Black slurry 10 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Comparative example 1:
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 40 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
5-chloro-2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Comparative example 2
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
TiO240 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 2 parts
Comparative example 3
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Ammonia 10 parts
Comparative example 4
The preparation method of coating foamed glue is with embodiment 1.
The coating adhesive formula of window shade fabric is as follows:
Water polyacrylic acid 100 parts
Ammonium stearate solution 20 parts
TiO220 parts
Black slurry 15 parts
N-(2-benzimidazole base)-methyl carbamate 2 parts
2-methyl-4-different plug oxazoline-3-ketone 2 parts
EU-carbitol 5 parts
Association type aqueous PU emulsion 5 parts
Method of testing
To above-described embodiment 1～11 and the window shade fabric that obtains of comparative example 1～4 test, method of testing is as follows:
Select Lambda 900 ultraviolet/visible closely/infrared spectrophotometer, according to FZ/01,009 2008 " textile fabrics
The mensuration of light transmission " method of testing sample is carried out light transmission test.
Above-mentioned test result is shown in Table 1.
Data above it can be seen that with do not use TiO2The product of additive is compared, foamed glue prepared by the present invention, adds curtain
In, curtain shading rate is greatly improved, and data have significant difference, is thus provided that the Advantageous Effects of the present invention.
Aforesaid example is merely illustrative, for explaining some features of the feature of the disclosure.Appended claim
It is intended to the widest scope that requirement it is contemplated that, and embodiments as presented herein is only according to all possible embodiment
The explanation of embodiment of selection of combination.Therefore, the purpose of applicant is that appended claim is not by the explanation present invention
The selectional restriction of example of feature.And the progress in science and technology will be formed due to language performance inaccurate reason and not
The possible equivalent or the son that are presently considered are replaced, and these changes also should be interpreted in the conceived case by appended
Claim covers.
Claims (10)
1. a novel environment-friendly water-based spinning coating foamed glue, it is characterised in that described water-based spinning coating foamed glue, by including
The raw material of following weight portion is prepared from: water-and acrylate emulsion 60-70 weight portion, Stearyl Amine additive 10-20 weight
Part, TiO2Additive 10-30 weight portion, thickening agent 4-6 weight portion, antifungus agent 1 weight portion, preservative 1 weight portion, dispersant
1.5-2.5 weight portion, levelling agent 1.5-2.5 weight portion.
2. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that spinning coating foamed glue
Solid content 45%-50%, pH value 8-10.
3. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that water-and acrylate breast
Liquid is expandable pure third self-crossing emulsion, and TG is-20 DEG C--30 DEG C, solid content is 30%-55%, and pH value is 2-5.
4. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that Stearyl Amine additive
Mass concentration is 15%-20%.
5. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that TiO2Brighten for powder
Additive, mass concentration is 60%-70%.
6. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that thickening agent is association type
Aqueous PU emulsion.
7. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that described antifungus agent is
N-(2-benzimidazole base)-methyl carbamate and/or tetramethylthiuram disulfide.
8. the one novel environment-friendly water-based spinning coating foamed glue described in claim 1, it is characterised in that described preservative is
2-methyl-4-different plug oxazoline-3-ketone and/or 5-chloro-2-methyl-4-different plug oxazoline-3-ketone.
9. the preparation method of a novel environment-friendly water-based spinning coating foamed glue, it is characterised in that specifically comprise the following steps that
1) in the reactor with agitating device, put into water-and acrylate emulsion, start at a slow speed stirring, obtain mixture A.
2) in the mixture A that step 1) obtains, ammonium stearate additive, TiO are added successively2Titanium dioxide slurry, stirs, and is mixed
Compound B.
3) last successively to step 2) obtained by mixture B add preservative, antifungus agent, thickening agent, levelling agent.Fully stir
Mix, get product after filtration.
The preparation method of a kind of novel environment-friendly water-based spinning coating foamed glue the most according to claim 9, its feature exists
In, described step 2) in, ammonium stearate and TiO2Needing through dispersant high speed dispersion, turbine sand mill is carried out at super-refinement
Reason.
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| CN107502104A (en) * | 2017-09-26 | 2017-12-22 | 句容市后白镇迎瑞印花厂 | A kind of textile anticorrosive heat insulating coating and preparation method thereof |
| CN108914607A (en) * | 2018-07-18 | 2018-11-30 | 常州雅美特窗饰股份有限公司 | A kind of slurry preparation method for window curtain fabric foam coating |
| CN115262239A (en) * | 2022-07-19 | 2022-11-01 | 北京七特丽装饰材料有限公司 | Cold-insulation and heat-insulation functional textile |
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| CN105926294B (en) | 2019-09-13 |
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