CN107502104A - A kind of textile anticorrosive heat insulating coating and preparation method thereof - Google Patents
A kind of textile anticorrosive heat insulating coating and preparation method thereof Download PDFInfo
- Publication number
- CN107502104A CN107502104A CN201710883132.7A CN201710883132A CN107502104A CN 107502104 A CN107502104 A CN 107502104A CN 201710883132 A CN201710883132 A CN 201710883132A CN 107502104 A CN107502104 A CN 107502104A
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- CN
- China
- Prior art keywords
- parts
- textile
- heat insulating
- insulating coating
- anticorrosive heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Abstract
The invention provides a kind of textile anticorrosive heat insulating coating, including following components:Acrylic emulsion, stearic acid, polyacrylamide, titanium dioxide, hexamethylene diisocyanate, dibutyl tin laurate, defoamer, coalescents and dispersant.Its preparation method is first to be stirred acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant; mixture is heated under the conditions of inert gas shielding; add dibutyl tin laurate; titanium dioxide, defoamer and coalescents, heating stirring are added after stirring and obtains textile anticorrosive heat insulating coating.The present invention coordinates polyacrylamide, propylene glycol methyl ether acetate to be used as paint film matrix using acrylic emulsion, the coating coefficient of heat conduction it is low, thermal insulation is good, can be widely used for all kinds of to the high textiles of heat-proof quality requirement.
Description
Technical field
The invention belongs to paint field used for textiles, and in particular to a kind of textile anticorrosive heat insulating coating and its preparation side
Method.
Background technology
So-called printing and dyeing stamp, i.e., coating particles are bonded in the surface of yarn fabric by the application of adhesive, just come at present
Say, China's coating dye printing has been increasingly becoming the main stamp mode of blending, cotton and synthetic fibers, in global stamp market
In in occupation of consequence.Pigment dyeing i.e. by dispersion made of the materials such as adhesive and color by pad dyeing and
The application of dip-dye mode is adhered to fiber surface, and uniform color is obtained with this.For general dyestuff, it can pass through
Its affinity on fibrous material is printed and dyed, and because by being influenceed in terms of particle diameter, pigment will not be directly entered
In fiber, and do not have adhesion to fibrous material yet.On the other hand, among this work, then need to enter synthetic resin emulsion
Row application, its performance that can be acted on by excellent bonds lift washability, feel and the rub resistance feature of Printing, can
To say being the factor that there is considerable influence to pigment dyeing effect.
Dyeing work among, it has higher requirement to dyestuff binders, have if desired for it good toughness,
Elasticity and stability, and will not it is necessary to have the epithelium of water white transparency, suitable adhesion for yellowing, aging easily in the application
Power and preferable chemical stability etc., and all there is higher requirement to feel and fastness.For at present, polyurethanes
And polyacrylate adhesive is especially suitable for applying in pigment dyeing, and majority realizes technique with emulsion polymerization way
Prepare.For polyacrylic binder, it has good epithelium transparency height, elasticity, good hand touch, wearability by force and valency
The low feature of lattice, although polyurethane binding also has above-mentioned advantage compared with it, right anti-corrosive properties are slightly worse, grown in application time
After easy yellowing, and for specific textile, such as heat-proof quality, polyurethane binding can not reach preferable
Effect.
The content of the invention
It is an object of the invention to provide a kind of textile anticorrosive heat insulating coating and preparation method thereof, gained coating heat transfer system
Number is low, and thermal insulation is good.
A kind of textile anticorrosive heat insulating coating, include following components with parts by weight:Acrylic emulsion 10-15 parts, stearic acid
2-5 parts, polyacrylamide 1-3 parts, titanium dioxide 1-2 parts, hexamethylene diisocyanate 3-6 parts, dibutyl tin laurate 1-2
Part, defoamer 1-2 parts, coalescents 1-2 parts and dispersant 1-2 parts.
Preferably, the coalescents are propylene glycol methyl ether acetate.
Preferably, the dispersant is barium stearate.
Preferably, the defoamer is silicone emulsion defoamer.
The preparation method of above-mentioned textile anticorrosive heat insulating coating, comprises the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
Preferably, susceptible gas is nitrogen or argon gas in step 2.
Preferably, the heating-up temperature of heating stirring is 40-45 DEG C in step 3.
The present invention coordinates polyacrylamide, propylene glycol methyl ether acetate as paint film matrix using acrylic emulsion,
The coating coefficient of heat conduction is low, and thermal insulation is good, can be widely used for all kinds of textiles high to heat-proof quality requirement.
Embodiment
Embodiment 1
A kind of textile anticorrosive heat insulating coating, include following components with parts by weight:10 parts of acrylic emulsion, 2 parts of stearic acid, poly- third
1 part of acrylamide, 1 part of titanium dioxide, 3 parts of hexamethylene diisocyanate, 1 part of dibutyl tin laurate, 1 part of defoamer, film forming
1 part of 1 part of auxiliary agent and dispersant.
Wherein, the coalescents are propylene glycol methyl ether acetate;The dispersant is barium stearate;The defoamer is
Silicone emulsion defoamer.
The preparation method of above-mentioned textile anticorrosive heat insulating coating, comprises the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
Wherein, susceptible gas is nitrogen in step 2;The heating-up temperature of heating stirring is 40-45 DEG C in step 3.
Embodiment 2
A kind of textile anticorrosive heat insulating coating, include following components with parts by weight:12 parts of acrylic emulsion, 3 parts of stearic acid, poly- third
1.5 parts of acrylamide, 1.3 parts of titanium dioxide, 4 parts of hexamethylene diisocyanate, 1.2 parts of dibutyl tin laurate, defoamer 1.3
Part, 1.4 parts of 1.2 parts of coalescents and dispersant.
Wherein, the coalescents are propylene glycol methyl ether acetate;The dispersant is barium stearate;The defoamer is
Silicone emulsion defoamer.
The preparation method of above-mentioned textile anticorrosive heat insulating coating, comprises the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
Wherein, susceptible gas is nitrogen in step 2;The heating-up temperature of heating stirring is 40-45 DEG C in step 3.
Embodiment 3
A kind of textile anticorrosive heat insulating coating, include following components with parts by weight:14 parts of acrylic emulsion, 4 parts of stearic acid, poly- third
2 parts of acrylamide, 1.7 parts of titanium dioxide, 5 parts of hexamethylene diisocyanate, 1.8 parts of dibutyl tin laurate, defoamer 1.4
Part, 1.7 parts of 1.7 parts of coalescents and dispersant.
Wherein, the coalescents are propylene glycol methyl ether acetate;The dispersant is barium stearate;The defoamer is
Silicone emulsion defoamer.
The preparation method of above-mentioned textile anticorrosive heat insulating coating, comprises the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
Wherein, susceptible gas is nitrogen in step 2;The heating-up temperature of heating stirring is 40-45 DEG C in step 3.
Embodiment 4
A kind of textile anticorrosive heat insulating coating, include following components with parts by weight:15 parts of acrylic emulsion, 5 parts of stearic acid, poly- third
3 parts of acrylamide, 2 parts of titanium dioxide, 6 parts of hexamethylene diisocyanate, 2 parts of dibutyl tin laurate, 2 parts of defoamer, film forming
2 parts of 2 parts of auxiliary agent and dispersant.
Wherein, the coalescents are propylene glycol methyl ether acetate;The dispersant is barium stearate;The defoamer is
Silicone emulsion defoamer.
The preparation method of above-mentioned textile anticorrosive heat insulating coating, comprises the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
Wherein, susceptible gas is nitrogen in step 2;The heating-up temperature of heating stirring is 40-45 DEG C in step 3.
The paint film of the coating preparation of the present invention:Viscosity(Apply 3 glasss, 24 DEG C):50-60s, 2 grades of adhesive force <, impact strength >=64
Kgcm, covering power≤l05g/m2, hardness(Double pendulum):>=0.7, resistance to 3%NaCl(Normal temperature)>=27h coatings are intact, resistance to 15%NaOH
(Normal temperature)>=27h coatings are intact, resistance to 15%H2SO4(Normal temperature)>=27h coatings are intact, water resistance(Normal temperature)>=54h, the coefficient of heat conduction
≤0.0432w/(m·k)。
Claims (7)
1. a kind of textile anticorrosive heat insulating coating, it is characterised in that include following components with parts by weight:Acrylic emulsion 10-15
Part, stearic acid 2-5 parts, polyacrylamide 1-3 parts, titanium dioxide 1-2 parts, hexamethylene diisocyanate 3-6 parts, tin dilaurate two
Butyl tin 1-2 parts, defoamer 1-2 parts, coalescents 1-2 parts and dispersant 1-2 parts.
2. textile anticorrosive heat insulating coating according to claim 1, it is characterised in that coalescents are propylene glycol monomethyl ether vinegar
Acid esters.
3. textile anticorrosive heat insulating coating according to claim 1, it is characterised in that dispersant is barium stearate.
4. textile anticorrosive heat insulating coating according to claim 1, it is characterised in that defoamer defoams for silicone emulsion
Agent.
5. the preparation method of the textile anticorrosive heat insulating coating described in claim 1, it is characterised in that comprise the following steps:
Step 1, acrylic emulsion, stearic acid, polyacrylamide, hexamethylene diisocyanate and dispersant are stirred,
Obtain mixture one;
Step 2, mixture one is heated to 60-70 DEG C under the conditions of inert gas shielding, adds dibutyl tin laurate, stir
60-90 minutes are mixed, obtain mixture two;
Step 3, titanium dioxide, defoamer and coalescents are added in mixture two, textile anti-corrosion is obtained after heating stirring
Insulating moulding coating.
6. the preparation method of textile anticorrosive heat insulating coating according to claim 5, it is characterised in that susceptible in step 2
Gas is nitrogen or argon gas.
7. the preparation method of textile anticorrosive heat insulating coating according to claim 5, it is characterised in that heated in step 3
The heating-up temperature of stirring is 40-45 DEG C.
Priority Applications (1)
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CN201710883132.7A CN107502104A (en) | 2017-09-26 | 2017-09-26 | A kind of textile anticorrosive heat insulating coating and preparation method thereof |
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CN201710883132.7A CN107502104A (en) | 2017-09-26 | 2017-09-26 | A kind of textile anticorrosive heat insulating coating and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN107502104A true CN107502104A (en) | 2017-12-22 |
Family
ID=60698851
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CN201710883132.7A Pending CN107502104A (en) | 2017-09-26 | 2017-09-26 | A kind of textile anticorrosive heat insulating coating and preparation method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105755824A (en) * | 2015-07-31 | 2016-07-13 | 南通德安化工有限公司 | Textile environment-friendly coating |
CN105860669A (en) * | 2016-06-22 | 2016-08-17 | 东莞市竤穗实业投资有限公司 | White glue for paint ink digital printing and preparation process of white glue |
CN105926294A (en) * | 2016-05-12 | 2016-09-07 | 上海保立佳新材料有限公司 | Novel environment-friendly waterborne textile coating polyfoam |
CN107163747A (en) * | 2017-07-27 | 2017-09-15 | 安徽宽居电器有限公司 | A kind of extinguishing waterborn environmental protection paint |
-
2017
- 2017-09-26 CN CN201710883132.7A patent/CN107502104A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105755824A (en) * | 2015-07-31 | 2016-07-13 | 南通德安化工有限公司 | Textile environment-friendly coating |
CN105926294A (en) * | 2016-05-12 | 2016-09-07 | 上海保立佳新材料有限公司 | Novel environment-friendly waterborne textile coating polyfoam |
CN105860669A (en) * | 2016-06-22 | 2016-08-17 | 东莞市竤穗实业投资有限公司 | White glue for paint ink digital printing and preparation process of white glue |
CN107163747A (en) * | 2017-07-27 | 2017-09-15 | 安徽宽居电器有限公司 | A kind of extinguishing waterborn environmental protection paint |
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Application publication date: 20171222 |
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