CN106939136A - A kind of special artistic effect latex paint compositions and its preparation and application - Google Patents
A kind of special artistic effect latex paint compositions and its preparation and application Download PDFInfo
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- CN106939136A CN106939136A CN201610004193.7A CN201610004193A CN106939136A CN 106939136 A CN106939136 A CN 106939136A CN 201610004193 A CN201610004193 A CN 201610004193A CN 106939136 A CN106939136 A CN 106939136A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of special artistic effect latex paint compositions and its preparation and application.Specifically, the invention discloses a kind of composition, the composition is used as color stuffing using pearlescent pigment and bead.More specifically, the composition contains following components：The pearlescent pigment of 3-30 parts by weight；The bead of 20-25 parts by weight；The emulsion of 10-40 parts by weight；The optionally water of 10-60 parts by weight.The invention also discloses the preparation method and application of the composition.The composition, which has, easily constructs, is difficult that after being stained with ash, life length and application excellent artistic effect can be showed, and has broad application prospects.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of special artistic effect latex paint compositions and its system
It is standby with application.
Background technology
Art coatings are originating from Europe, and advanced technique is also spread by Europe to come, into after domestic market,
With its novel decorated style and unusual decorative effect, welcomed by the people again and high praise.Art
Coating is a kind of new wall decoration art paint, along with present high-tech handling process so that product
With it is nontoxic, environmentally friendly the features such as, while being also equipped with waterproof and dustproof and the function, high-quality art coatings such as fire-retardant
It can criticize that brush, adsorptivity be strong, color sustains its quality through age.
However, domestic existing art coatings are generally texture or illusion-colour art coatings, it exist moulding hardening,
The deficiency such as unitary function or what no feature, construction complexity.
Therefore, it is badly in need of a kind of new art paint for having high decoration functions, easy construction, health environment-friendly concurrently of exploitation,
To meet the market demand.
The content of the invention
New high decoration functions, easily construction, health environment-friendly are had concurrently it is an object of the invention to provide a kind of
Art paint.
The first aspect of the present invention is made there is provided a kind of composition, the composition with pearlescent pigment and bead
For color stuffing.
In another preference, the composition is only used as color stuffing using pearlescent pigment and bead.
In another preference, the composition contains following components：
The pearlescent pigment of 3-30 parts by weight；
The bead of 20-25 parts by weight；
The emulsion of 10-40 parts by weight；With
The optionally water of 10-60 parts by weight.
In another preference, the composition contains following components：
The pearlescent pigment of 5-25 parts by weight；
The bead of 21-24 parts by weight；
The emulsion of 15-35 parts by weight；With
The optionally water of 15-50 parts by weight.
In another preference, the composition contains following components：
The pearlescent pigment of 8-20 parts by weight；
The bead of 22-23 parts by weight；
The emulsion of 20-30 parts by weight；With
The optionally water of 20-45 parts by weight.
In another preference, by the gross weight meter of the composition, the content of the bead is 20-25wt%.
In another preference, the composition is also containing the one or more components being selected from the group：
The thickener of 0.1-10 parts by weight；
The pH adjusting agent of 0.01-1 parts by weight；
The wetting agent of 0.01-1 parts by weight；
The defoamer of 0.2-10 parts by weight；With
The coalescents of 0.3-5 parts by weight.
In another preference, the composition is also containing the one or more components being selected from the group：
The antifreezing agent of 0.5-10 parts by weight；
The preservative of 0.1-5 parts by weight；With
The mould inhibitor of 0.1-5 parts by weight.
In another preference, the pearlescent pigment is the mica that metal oxide layer is coated；And/or
The particle diameter of the pearlescent pigment is 6-200um；And/or
The mesh number of the bead is 100-150 mesh；And/or
Glass transition temperature >=10 DEG C of the emulsion.
In another preference, the particle diameter of the pearlescent pigment is 8-150um, preferably 10-100um, more preferably
Ground is 20-80um.
In another preference, the mesh number of the bead is 110-140 mesh, preferably 120-130 mesh.
In another preference, the bead is formed by big particle diameter bead and small particle bead compounding.
In another preference, the content ratio of the big particle diameter bead and the small particle bead is 1-15, compared with
It is goodly 2-12, is more preferably 3-10.
In another preference, the mesh number of the big particle diameter bead is 130-150 mesh, preferably 135-145
Mesh.
In another preference, the mesh number of the small particle bead is 100-130 mesh, preferably 105-125
Mesh, is more preferably 110-120 mesh.
In another preference, glass transition temperature >=12 DEG C of the emulsion, preferably >=14 DEG C, more preferably >=
16℃。
In another preference, content >=85wt% of silica, preferably >=90wt% in the bead,
More preferably >=95wt%.
In another preference, the emulsion is pure-acrylic emulsion, preferably SF-266.
In another preference, the solid content of the pure-acrylic emulsion is 35-60wt%, preferably 40-50wt%,
More preferably 44.5-45.5wt%.
In another preference, the metallic element for constituting the metal oxide layer is selected from the group：Titanium dioxide,
Di-iron trioxide or its combination；And/or
The particle diameter of the kernel mica of the pearlescent pigment is 6-160um.
In another preference, the particle diameter of the kernel mica of the pearlescent pigment is 8-100 μm, preferably
10-50um。
In another preference, the thickener is selected from the group：Cellulose thickener, polyurethanes thickener,
Alkali swelling type thickener or its combination.
In another preference, the cellulose thickener is selected from the group：NATROSOL 250MBR、
NATROSOL 250HBR or its combination.
In another preference, the polyurethanes thickener is selected from the group：Acrysol RM-12W、Acrysol
RM-8W or its combination.
In another preference, the thickener is cellulose thickener and polyurethanes thickener.
In another preference, the content ratio of the cellulose thickener and the polyurethanes thickener is 1-5：
5-1, preferably 1-4：4-1, is more preferably 2-3：3-2.
In another preference, the pH adjusting agent is preferably Organic Alcohol amine, such as AMP95.
In another preference, the wetting agent is selected from the group：Nonionic macromolecule alkyl ether, nonionic
Macromolecule Arrcostab, nonionic macromolecule alkylol or its combination.
In another preference, the nonionic macromolecule alkyl ether is preferably SN996.
In another preference, the defoamer is selected from the group：Organic silicon defoamer, mineral oil defoaming agent,
Or its combination.
In another preference, the organic silicon defoamer is selected from the group：SN154、SN-DEFOAMER
154 or its combination.
In another preference, the mineral oil defoaming agent is selected from the group：NXZ, Foamstar A10 or its
Combination.
In another preference, the defoamer is organic silicon defoamer and mineral oil defoaming agent.
In another preference, the content ratio of the organic silicon defoamer and the mineral oil defoaming agent is 1-5：
5-1, preferably 1-4：4-1, is more preferably 2-3：3-2.
In another preference, the coalescents are selected from the group：Alkoxide, ethers or its combination.
In another preference, the composition is prepared using the method described in second aspect present invention.
There is provided a kind of preparation method of composition described in first aspect present invention, bag for the second aspect of the present invention
Include following steps：
1) the first mixed liquor and the second mixed liquor are provided, wherein,
First mixed liquor contains：The pearlescent pigments of 3-30 parts by weight, the bead of 20-25 parts by weight and optionally
25-50 parts by weight water；
Second mixed liquor contains：The emulsion of 10-40 parts by weight；
2) first mixed liquor and second mixed liquor under agitation, are mixed, the present invention the is obtained
On the one hand the composition.
In another preference, first mixed liquor is also containing the one or more components being selected from the group：
0.1-5 part by weight of cellulose class thickeners；
The pH adjusting agent of 0.01-1 parts by weight；
The wetting agent of 0.01-1 parts by weight；
The organic silicon defoamer of 0.2-5 parts by weight；With
The antifreezing agent of 0-10 parts by weight.
In another preference, second mixed liquor is also containing the one or more components being selected from the group：
The coalescents of 0.3-5 parts by weight；
The mineral oil defoaming agent of 0.2-5 parts by weight；
0.2-6 parts by weight of polyurethane class thickeners；
The preservative of 0-5 parts by weight；With
The mould inhibitor of 0-5 parts by weight.
In another preference, the pearlescent pigment, the bead, the emulsion, the thickener, institute
State pH adjusting agent, the wetting agent, the defoamer, the coalescents, the antifreezing agent, the anti-corrosion
Agent, the mould inhibitor are as described in the first aspect of the invention.
In another preference, step 2) mixing speed of the stirring is 700-2000 revs/min, preferably
800-1500 revs/min, be more preferably 900-1200 revs/min.
In another preference, step 2) mixing time of the stirring under the mixing speed be 5-60 minutes,
Preferably 10-50 minutes, preferably 15-45 minutes.
In another preference, in step 1) before, the pearlescent pigment carries out pre-soaking processing in water.
The third aspect of the present invention is there is provided a kind of coating, and the coating is as the group described in first aspect present invention
Compound is coated on base material and obtained.
The fourth aspect of the present invention contains there is provided a kind of product, the product：
Base material；
Coating described in third aspect present invention；And
It is optionally coated with the priming paint of the substrate surface.
In another preference, the base material is selected from the group：Metope, putty plate, without asbestos fiber sheet, fire prevention
Plate.
There is provided a kind of metope coating process, including step for the fifth aspect of the present invention：
1) optionally the composition described in first aspect present invention is stirred；
2) composition is coated to metope after being stirred described in；
3) after optionally spontaneously drying, subsequent treatment is carried out.
In another preference, step 2) coating includes：
2-1) abovementioned steps resulting composition is picked using bristles brush；
2-2) brushed on metope；
2-3) optionally scratched with 35-60 ° of angle using scraper plate.
In another preference, the width of the bristles brush is 50-200mm, preferably 80-150mm, more preferably
Ground is 90-120mm.
In another preference, the bristles brush was carrying out anti-depilation processing using preceding cleaned through water.
In another preference, step 2-1) it is described pick in step, the amount that the bristles brush is picked≤brush hair on the neck
Hair 1/3rd.
In another preference, step 2-2) brushing carried out using following steps：
I) brushed using crossing method；With
Ii) combed with 35-60 ° of angle along the direction in opposite direction with the brushing of the step i) crossing methods.
In another preference, it is 5-10cm that distance is brushed in step i), described in single.
In another preference, the direction of the combing is in opposite direction with the blade coating.
It should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the invention and below (such as embodiment)
It can be combined with each other between each technical characteristic of middle specific descriptions, so as to constitute new or preferred technical side
Case.As space is limited, no longer tire out one by one herein and state.
Brief description of the drawings
Fig. 1 is the process schematic representation of method of application of the present invention.
Fig. 2 is the coating result of the gained of embodiment 1 paint 1.
Fig. 3 is the coating result of the gained of embodiment 2 paint 2.
Fig. 4 is the coating result of the gained of embodiment 3 paint 3.
Fig. 5 is the coating result of the gained of embodiment 4 paint 4.
Fig. 6 is the gained paint of comparative example 1 C1 coating result.
Fig. 7 is the gained paint of comparative example 2 C2 coating result.
Fig. 8 is the gained paint of comparative example 3 C3 coating result.
Fig. 9 is the gained paint of comparative example 4 C4 coating result.
Embodiment
The present inventor's in-depth study by long-term, is unexpectedly prepared a kind of with specific composition and spy
Determine the multi-functional latex paint of excellent properties.Specifically, the present inventor in the multi-functional latex paint by adopting
With the pearlescent pigment of specified quantitative and the bead of specific dimensions and specified quantitative as color stuffing, with reference to higher
The pure-acrylic emulsion of glass transition temperature is prepared and a kind of has being good for for emulsion paint and artistic paint function concurrently as emulsion
Kang Huanbao and the new paint composite for being easy to construction.On this basis, inventor completes the present invention.
Term
As used herein, term " multi-functional latex paint ", " multi-functional paint ", " art paint ", " skill
Art coating ", " multifunctional artistic paint ", " paint ", " composition ", " paint " or " coating "
It is used interchangeably, the composition of color stuffing is used as using pearlescent pigment and bead.
As used herein, term " containing " represent various composition can together be applied to the present invention mixture or
In composition.Therefore, term " mainly by ... constitute " and " consist of " are included in term " containing "
In.
Paint
The invention provides a kind of composition, the composition is used as color stuffing using pearlescent pigment and bead.
In another preference, the composition is only used as color stuffing using pearlescent pigment and bead.
Typically, the composition contains following components：
The pearlescent pigment of 3-30 parts by weight；
The bead of 20-25 parts by weight；
The emulsion of 10-40 parts by weight；With
The optionally water of 10-60 parts by weight.
In another preference, the composition contains following components：
The pearlescent pigment of 5-25 parts by weight；
The bead of 21-24 parts by weight；
The emulsion of 15-35 parts by weight；With
The optionally water of 15-50 parts by weight.
In another preference, the composition contains following components：
The pearlescent pigment of 8-20 parts by weight；
The bead of 22-23 parts by weight；
The emulsion of 20-30 parts by weight；With
The optionally water of 20-45 parts by weight.
In another preference, by the gross weight meter of the composition, the content of the bead is 20-25wt%.
More typically, the composition is also containing the one or more components being selected from the group：
The thickener of 0.1-10 parts by weight；
The pH adjusting agent of 0.01-1 parts by weight；
The wetting agent of 0.01-1 parts by weight；
The defoamer of 0.2-10 parts by weight；With
The coalescents of 0.3-5 parts by weight.
In another preference, the composition is also containing the one or more components being selected from the group：
The antifreezing agent of 0.5-10 parts by weight；
The preservative of 0.1-5 parts by weight；With
The mould inhibitor of 0.1-5 parts by weight.
In the present invention, the pearlescent pigment, the bead, the emulsion, the thickener, the pH
Conditioning agent, the wetting agent, the defoamer, the coalescents, the antifreezing agent, the preservative, institute
Mould inhibitor is stated to be not particularly limited, can be from the conventional material in this area, or prepared with conventional method, or from city
Field is commercially available.
In the present invention, bead, its chemical composition is inertia silica, no chemism interference misgivings,
Transparency is high, and size is available in all varieties, widely used.When preparing art coatings, bead is added,
Good sense of touch and gloss change can be provided for artistic effect coating lacquer.Plus the extensive color of pearlescent pigment
Selection, it is possible to provide abundant artistic color.
In the present invention, the effect of the pearlescent pigment is to provide basic color and shadow for artistic effect coating.
According to different demands, different pearlescent pigments are added, so as to realize the different basic tones of product.
In the present invention, the emulsion is preferably the emulsion with high glass transition temperature.In order that art coatings
Have the film performance of traditional emulsion paint coating concurrently, hardness of paint film is high, preferable rub resistance can be brought to paint film
And high dirt resistance ability and after tack is low, after inventor is screened by substantial amounts of emulsion, have chosen with compared with
The pure-acrylic emulsion of high glass transition temperature is used as the film forming matter in art coatings.
In the present invention, the pearlescent pigment is the mica that metal oxide layer is coated；And/or
The particle diameter of the pearlescent pigment is 6-180um；And/or
The mesh number of the bead is 100-150 mesh；And/or
Glass transition temperature >=10 DEG C of the emulsion.
In another preference, the particle diameter of the pearlescent pigment is 8-150um, preferably 10-100um, more preferably
Ground is 20-80um.
In the present invention, the particle diameter and addition of the bead to the feel of art coatings, stereoeffect,
Consumption paint amount etc., which has, to be significantly affected.Special artistic effect emulsion paint of the present invention requires to be presented a kind of after application
Desert modeling effect with metallic luster.Inventor by substantial amounts of conceptual design and it is data-optimized after find,
When the adding proportion of bead is less than 20wt%, its stereoeffect is not notable, sense of touch plane, in order to reach
Suitable effect, consumption paint amount is big；And when adding proportion is more than 25wt%, effect sense of touch is relatively rough, and
There is no stereovision；It is final to determine bead adding proportion between 20wt%-25wt%.It is identical adding
During ratio, the bead of big particle diameter is only chosen, after construction, particle is substantially, too three-dimensional, and sense of touch is coarse；
And only choose the bead of small particle, then the desert effect showed is not notable, and bead accumulation is inadequate, effect
More plane, it is impossible to desert moulding is presented；So inventor by substantial amounts of conceptual design and it is data-optimized after,
The glass microballoon phase compounded combination of a diameter of 100-150 mesh is selected, and determines both suitable adding proportion models
Enclose.
In another preference, the mesh number of the bead is 110-140 mesh, preferably 120-130 mesh.
In another preference, the bead is formed by big particle diameter bead and small particle bead compounding.
In another preference, the content ratio of the big particle diameter bead and the small particle bead is 1-15, compared with
It is goodly 2-12, is more preferably 3-10.
In another preference, the mesh number of the big particle diameter bead is 130-150 mesh, preferably 135-145
Mesh.
In another preference, the mesh number of the small particle bead is 100-130 mesh, preferably 105-125
Mesh, is more preferably 110-120 mesh.
In another preference, glass transition temperature >=12 DEG C of the emulsion, preferably >=14 DEG C, more preferably >=
16℃。
In another preference, content >=85wt% of silica, preferably >=90wt% in the bead,
More preferably >=95wt%.
In another preference, the emulsion is pure-acrylic emulsion, preferably SF-266.
In another preference, the solid content of the pure-acrylic emulsion is 35-60wt%, preferably 40-50wt%,
More preferably 44.5-45.5wt%.
In the present invention, constituting the metallic element of the metal oxide layer includes (but being not limited to)：Dioxy
Change titanium, di-iron trioxide or its combination；And/or
The particle diameter 6-160um of the kernel mica of the pearlescent pigment.
In another preference, the particle diameter 8-100um of the kernel mica of the pearlescent pigment, preferably
10-50um。
In another preference, the thickener includes (but being not limited to)：Cellulose thickener, poly- ammonia
Type thickener, alkali swelling type thickener or its combination.
In another preference, the cellulose thickener includes (but being not limited to)：NATROSOL 250
MBR, NATROSOL 250HBR or its combination.
In another preference, the polyurethanes thickener includes (but being not limited to)：Acrysol RM-12W、
Acrysol RM-8W or its combination.
In another preference, the thickener is cellulose thickener and polyurethanes thickener.
In another preference, the content ratio of the cellulose thickener and the polyurethanes thickener is 1-5：
5-1, preferably 1-4：4-1, is more preferably 2-3：3-2.
In another preference, the pH adjusting agent is preferably Organic Alcohol amine, such as AMP95.
In another preference, the wetting agent includes (but being not limited to)：Nonionic macromolecule alkyl ether,
Nonionic macromolecule Arrcostab, nonionic macromolecule alkylol or its combination.
In another preference, the nonionic macromolecule alkyl ether is preferably SN996.
In another preference, the defoamer includes (but being not limited to)：Organic silicon defoamer, mineral
Oils defoamer or its combination.
In another preference, the organic silicon defoamer includes (but being not limited to)：SN154、
SN-DEFOAMER 154 or its combination.
In another preference, the mineral oil defoaming agent includes (but being not limited to)：NXZ、Foamstar
A10 or its combination.
In another preference, the defoamer is organic silicon defoamer and mineral oil defoaming agent.
In another preference, the content ratio of the organic silicon defoamer and the mineral oil defoaming agent is 1-5：
5-1, preferably 1-4：4-1, is more preferably 2-3：3-2.
In another preference, the coalescents include (but being not limited to)：Alkoxide, ethers or its
Combination.
It should be understood that other components can also be included in composition of the present invention, as long as not influenceing gained to combine
The performance of thing.
In another preference, the composition is prepared using method of the present invention.
Preparation method
Present invention also offers a kind of preparation method of the composition, comprise the following steps：
1) the first mixed liquor and the second mixed liquor are provided, wherein,
First mixed liquor contains：The pearlescent pigments of 3-30 parts by weight, the bead of 20-25 parts by weight and optionally
25-50 parts by weight water；
Second mixed liquor contains：The emulsion of 10-40 parts by weight；
2) first mixed liquor and second mixed liquor under agitation, are mixed, the combination is obtained
Thing.
In another preference, first mixed liquor is also containing the one or more components being selected from the group：
0.1-5 part by weight of cellulose class thickeners；
The pH adjusting agent of 0.01-1 parts by weight；
The wetting agent of 0.01-1 parts by weight；
The organic silicon defoamer of 0.2-5 parts by weight；With
The antifreezing agent of 0-10 parts by weight.
In another preference, second mixed liquor is also containing the one or more components being selected from the group：
The coalescents of 0.3-5 parts by weight；
The mineral oil defoaming agent of 0.2-5 parts by weight；
0.2-6 parts by weight of polyurethane class thickeners；
The preservative of 0-5 parts by weight；With
The mould inhibitor of 0-5 parts by weight.
In another preference, the pearlescent pigment, the bead, the emulsion, the thickener, institute
State pH adjusting agent, the wetting agent, the defoamer, the coalescents, the antifreezing agent, the anti-corrosion
Agent, the mould inhibitor are as described above.
In another preference, step 2) mixing speed of the stirring is 700-2000 revs/min, preferably
800-1500 revs/min, be more preferably 900-1200 revs/min.
In another preference, step 2) mixing time of the stirring under the mixing speed be 5-60 minutes,
Preferably 10-50 minutes, preferably 15-45 minutes.
In another preference, in step 1) before, the pearlescent pigment carries out pre-soaking processing in water.
Using
Present invention also offers a kind of coating, the coating is coated on base material by described composition and obtained.
Present invention also offers a kind of product, the product contains：
Base material；
Described coating；And
It is optionally coated with the priming paint of the substrate surface.
In another preference, the base material includes (but being not limited to)：It is metope, putty plate, fine without asbestos
Tie up plate, PLASTIC LAMINATED.
Method of application
Present invention also offers a kind of metope coating process, including step：
1) optionally described composition is stirred；
2) composition is coated to metope after being stirred described in；
3) after optionally spontaneously drying, subsequent treatment is carried out.
In another preference, step 2) coating includes：
2-1) abovementioned steps resulting composition is picked using bristles brush；
2-2) brushed on metope；
2-3) optionally scratched with 35-60 ° of angle using scraper plate.
In another preference, the width of the bristles brush is 50-200mm, preferably 80-150mm, more preferably
Ground is 90-120mm.
In another preference, the bristles brush was carrying out anti-depilation processing using preceding cleaned through water.
In another preference, step 2-1) it is described pick in step, the amount that the bristles brush is picked≤brush hair on the neck
Hair 1/3rd.
In another preference, step 2-2) brushing carried out using following steps：
I) brushed using crossing method；With
Ii) combed with 35-60 ° of angle along the direction in opposite direction with the brushing of the step i) crossing methods.
In another preference, it is 5-10cm that distance is brushed in step i), described in single.
In another preference, the direction of the combing is in opposite direction with the blade coating.
Compared with prior art, the present invention has following major advantage：
(1) composition has excellent film performance, easy construction, consumption paint amount is few, be difficult to be stained with ash, mission longevity
The characteristics of excellent artistic effect being showed after life length and application；
(2) composition have health environment-friendly, safety non-toxic, without formaldehyde, heavy metal free, smell it is low,
And VOC it is low the characteristics of；
(3) due to using the composition, the coating process only needs painting to brush one times, substantially reduces construction
Time；
(4) composition is multi-functional paint, has the function of emulsion paint and art paint concurrently；
(5) the coating stereoeffect is notable.
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate
The present invention rather than limitation the scope of the present invention.The experimental method of unreceipted actual conditions in the following example, leads to
Often according to normal condition or according to the condition proposed by manufacturer.Unless otherwise indicated, otherwise percentage and number
Calculate by weight.
Unless otherwise defined, all specialties used in text are familiar with scientific words with one skilled in the art
Meaning it is identical.In addition, any method similar or impartial to described content and material all can be applied to the present invention
In method.Preferable implementation described in text only presents a demonstration with material to be used.
Raw material used in following examples is as shown in table 1.
Table 1
Universal testing method
Prepared art coatings are applied to interior wall, so in terms of environmental-protecting performance test, detection method defers to GB18582-2008
《Limits of harmful substances in indoor decorating and refurnishing materials interior wall coating》.It is specific as shown in table 2：
Table 2
The paint of embodiment 11
Preparation process
It is the golden pearlescent pigments of 10-60um that ratio, which weighs 18 parts of water with tank, adding 10 parts of particle diameters, by weight
(its metal oxide outer layer is titanium dioxide and di-iron trioxide, and the particle diameter of kernel mica is 7-40um) immersion
It is stand-by, weigh 18 parts of water and add in dispersion tank, rotating speed is controlled at 200-300 revs/min, is sequentially added：It is fine
Tie up 0.75 part of element class thickener NATROSOL 250MBR, Organic Alcohol amine PH conditioning agents AMP950.1
Part, 0.2 part of wetting agent SN996,3 parts of antifreezing agent PEG400,0.3 part of organic silicon defoamer SN154,
The pearlescent pigment soaked in advance starches 28 parts, and 100 3 parts of mesh beades, 150 17 parts of mesh beades adjust rotating speed
To 1000 revs/min, again by rotating speed control at 700-800 revs/min after disperseing 15 minutes, sequentially add：
0.5 part of 0.5 part of preservative BIOX CM, mould inhibitor BIOX M248,25 parts of pure-acrylic emulsion SF-266, alcohol
12 parts of esters coalescents alcohol ester, 0.3 part of mineral oil defoaming agent NXZ, polyurethanes thickener
0.85 part of Acrysol RM-12W, 1.8 parts of water.Rotating speed is maintained into 700-800 revs/min to disperse 15 minutes
Paint 1 is made.
Application process
On 1 supporting priming paint is painted, coating is picked for 100 millimeters of bristles brush with width, with ten on priming paint
The brush method brushing that word intersects is uniform, after with about 45 degree of angles, gently combed from lower-left to upper right side, use scraper plate
From brushing position at first, oblique 45 ° by upper right to left down, equidirectional blade coating can obtain coating 1.
As a result
Fig. 1 is the process schematic representation of method of application of the present invention.It will be seen from figure 1 that of the present invention apply
Coating method has technique simple, only with the mode of a brushing, can the effectively save engineering time, enter
And improve efficiency of construction.Further, since construction used tool only needs bristles brush, its mao of matter is harder, is easy to handle
Paint vehicle is uniformly brushed and combed；Scratched afterwards with scraper plate, just can form three-dimensional effect of shadow.
Fig. 2 is the coating result of the gained of embodiment 1 paint 1.Figure it is seen that though the metope constructed is
Plane, but with stereoeffect, and have certain metallic luster, but it is not dazzling.The accumulation of bead is caused
Desert wind shadow effect substantially, but is unlikely to lofty, overall very harmonious.
In addition, the environmental-protecting performance test result of the gained of embodiment 1 paint 1 is as shown in table 3.
Table 3
From table 3 it can be seen that the VOC content of paint 1 is does not detect, and other are such as benzene homologues, formaldehyde, a huge sum of money
Category etc., which is also, not to be detected, and this shows that the gained of embodiment 1 paint 1 complies fully with limits of harmful substances in interior wall coating
Requirement, be a kind of environmentally friendly paint vehicle in the pink of condition.
The paint of embodiment 22
Preparation process
Ratio weighs 15 parts of water with tank, adding the golden pearly-lustre face that 10 parts of particle diameters are 10-60um by weight
Material (its metal oxide outer layer is titanium dioxide and di-iron trioxide, and the particle diameter of kernel mica is 7-40um) leaching
Bubble is stand-by, weighs 16 parts of water and adds in dispersion tank, rotating speed is controlled at 200-300 revs/min, is sequentially added：
0.75 part of cellulose thickener NATROSOL 250MBR, Organic Alcohol amine PH conditioning agents AMP950.1
Part, 0.2 part of wetting agent SN996,3 parts of antifreezing agent PEG400,0.3 part of organic silicon defoamer SN154,
The pearlescent pigment soaked in advance starches 25 parts, and 100 5 parts of mesh beades, 150 20 parts of mesh beades adjust rotating speed
To 1000 revs/min, again by rotating speed control at 700-800 revs/min after disperseing 15 minutes, sequentially add：
0.5 part of 0.5 part of preservative BIOX CM, mould inhibitor BIOX M248,25 parts of pure-acrylic emulsion SF-266, alcohol
12 parts of esters coalescents alcohol ester, 0.3 part of mineral oil defoaming agent NXZ, polyurethanes thickener
0.85 part of Acrysol RM-12W, 1.8 parts of water.Rotating speed is maintained into 700-800 revs/min to disperse 15 minutes
Paint 2 is made.
Application process
On 2 supporting priming paint are painted, coating is picked for 100 millimeters of bristles brush with width, with ten on priming paint
The brush method brushing that word intersects is uniform, after with about 45 degree of angles, gently combed from lower-left to upper right side, use scraper plate
From brushing position at first, oblique 45 ° by upper right to left down, equidirectional blade coating can obtain coating 2.
As a result
Fig. 3 is the coating result of the gained of embodiment 2 paint 2.From figure 3, it can be seen that though the metope constructed is
Plane, but with stereoeffect, and have certain metallic luster, but it is not dazzling.The relatively bead ratio of paint 1
Though example has adjustment, it, which is accumulated, causes desert wind shadow effect substantially, but is unlikely to lofty, overall harmonious fine and smooth.
In addition, the environmental-protecting performance test result of the gained of embodiment 2 paint 2 is as shown in table 4.
Table 4
From table 4, it can be seen that the VOC content of paint 2 is does not detect, and other are such as benzene homologues, formaldehyde, a huge sum of money
Category, which is also, not to be detected, and this shows that the gained of embodiment 2 paint 2 is also fully consistent with limits of harmful substances in interior wall coating
Requirement.
The paint of embodiment 33
Preparation process
Ratio weighs 18 parts of water with tank, adding the silvery white pearly-lustre face that 12 parts of particle diameters are 8-48um by weight
Material (its metal oxide outer layer is titanium dioxide, and the mesh number of kernel mica is 6-40um) immersion is stand-by, weighs
20 parts of water are added in dispersion tank, and rotating speed is controlled at 200-300 revs/min, is sequentially added：Cellulose family is thickened
0.7 part of agent NATROSOL 250MBR, 0.1 part of Organic Alcohol amine PH conditioning agents AMP95, wetting agent SN996
0.18 part, 3 parts of antifreezing agent PEG400,0.3 part of organic silicon defoamer SN154, the pearly-lustre soaked in advance
Rotating speed is adjusted to 1000 revs/min by 30 parts of graining paste, 100 3 parts of mesh beades, 150 20 parts of mesh beades,
Again by rotating speed control at 700-800 revs/min after scattered 15 minutes, sequentially add：Preservative BIOX CM 0.5
Part, 0.5 part of mould inhibitor BIOX M248,20 parts of pure-acrylic emulsion SF-266, alkoxide coalescents alcohol ester ten
2 0.5 parts, 0.3 part of mineral oil defoaming agent NXZ, polyurethanes thickener Acrysol RM-12W 0.8
Part, 0.12 part of water.Rotating speed is maintained into 700-800 revs/min of scattered 15 minutes, the gross weight painted with gained
Meter, is subsequently added into 1wt% COLOEMAX mill base INDIAN RED colors number toning, that is, paint 3 is made.
Application process
On 3 supporting priming paint are painted, coating is picked for 100 millimeters of bristles brush with width, with ten on priming paint
The brush method brushing that word intersects is uniform, after with about 45 degree of angles, gently combed from lower-left to upper right side, use scraper plate
From brushing position at first, oblique 45 ° by upper right to left down, equidirectional blade coating can obtain coating 3.
As a result
Fig. 4 is the coating result of the gained of embodiment 3 paint 3.From fig. 4, it can be seen that though the metope constructed is
Plane, but with stereoeffect, pearlescent pigment provides soft metallic luster, but not dazzling.And glass
The accumulation of glass pearl causes desert wind shadow effect substantially, but is unlikely to lofty, overall harmonious fine and smooth.
In addition, the environmental-protecting performance test result of the gained of embodiment 3 paint 3 is as shown in table 5.
Table 5
The paint of embodiment 44
Preparation process
Ratio weighs 15 parts of water with tank, adding the silvery white pearlescent pigment that 8 parts of particle diameters are 8-48um by weight
(its metal oxide outer layer is titanium dioxide, and the particle diameter of kernel mica is 6-40um) immersion is stand-by, weighs 15
Part water is added in dispersion tank, and rotating speed is controlled at 200-300 revs/min, is sequentially added：Cellulose thickener
0.8 part of NATROSOL 250MBR, AMP950.1 parts of Organic Alcohol amine PH conditioning agents, wetting agent SN996 0.25
Part, 3 parts of antifreezing agent PEG400,0.3 part of organic silicon defoamer SN154, the pearlescent pigment soaked in advance
23 parts of slurry, rotating speed is adjusted to 1000 revs/min by 100 7 parts of mesh beades, 150 18 parts of mesh beades, is disperseed
Again by rotating speed control at 700-800 revs/min after 15 minutes, sequentially add：0.5 part of preservative BIOX CM,
0.5 part of mould inhibitor BIOX M248, SF-26628 parts of pure-acrylic emulsion, alkoxide coalescents alcohol ester 12
Part, 0.3 part of mineral oil defoaming agent NXZ, 0.85 part of polyurethanes thickener Acrysol RM-12W, water
1.4 parts.Rotating speed is maintained into 700-800 revs/min to disperse 15 minutes, the gross weight meter painted with gained connects
The COLOEMAX mill base INDIAN RED colors number toning for adding 1wt%, that is, paint 4 is made.
Application process
On 4 supporting priming paint are painted, coating is picked for 100 millimeters of bristles brush with width, with ten on priming paint
The brush method brushing that word intersects is uniform, after with about 45 degree of angles, gently combed from lower-left to upper right side, use scraper plate
From brushing position at first, oblique 45 ° by upper right to left down, equidirectional blade coating can obtain coating 4.
As a result
Fig. 5 is the coating result of the gained of embodiment 4 paint 4.From fig. 5, it can be seen that though the metope constructed is
Plane, but with stereoeffect, pearlescent pigment provides soft metallic luster, but not dazzling.And glass
The accumulation of glass pearl causes desert wind shadow effect substantially, but is unlikely to lofty, overall harmonious fine and smooth.
In addition, the environmental-protecting performance test result of the gained of embodiment 4 paint 4 is as shown in table 6.
Table 6
The content of each component is as shown in table 7 in embodiment 1-4.
Table 7
Comparative example 1 paints C1
Be the same as Example 1, difference is：100 mesh beades and 150 are replaced using the big particle diameter bead of 80 purposes
Mesh bead, and pearlescent pigment chooses particle diameter 8-48um silvery white pearl essence.
As a result
Fig. 6 is the gained paint of comparative example 1 C1 coating result.From fig. 6, it can be seen that paint C1 coating gained coatings
Whole structure is coarse, and accumulation is substantially and third dimension is too strong, and feel is not good.
Comparative example 2 paints C2
Be the same as Example 1, difference is：100 mesh beades and 150 are replaced using the small particle bead of 200 mesh
Mesh bead, and pearlescent pigment chooses particle diameter 8-48um silvery white pearl essence.
As a result
Fig. 7 is the gained paint of comparative example 2 C2 coating result.From figure 7 it can be seen that paint C2 coating gained coatings
Whole structure is not three-dimensional enough, too plane, and effect, wind shadow DeGrain are accumulated without obvious bead.
Comparative example 3 paints C3
Be the same as Example 1, difference is：The usage amount of 100 mesh beades is 2.5 parts, and 150 mesh beades make
Consumption is 12.5 parts, and the percentage that 100 mesh beades and 150 mesh beades account for gained paint C3 is 15wt% (≤20
), and pearlescent pigment chooses particle diameter 8-48um silvery white pearl essence wt%.
As a result
Fig. 8 is the gained paint of comparative example 3 C3 coating result.Although from figure 8, it is seen that paint C3 in use with
The similar bead ratio of embodiment 1, but be due to percentage≤20wt% of wherein bead, it is coated
The effect of gained coating is compared with embodiment 1 compared to not enough significantly, and without obvious stereoeffect, and consumption paint amount is big.
Comparative example 4 paints C4
Be the same as Example 1, difference is：The usage amount of 100 mesh beades is 4.5 parts, and 150 mesh beades make
Consumption is 25.5 parts, and the percentage that 100 mesh beades and 150 mesh beades account for gained paint is 27wt% (>=25wt
%), and pearlescent pigment chooses particle diameter 8-48um silvery white pearl essence.
As a result
Fig. 9 is the gained paint of comparative example 4 C4 coating result.Although from fig. 9, it can be seen that paint C4 in use with
The similar bead ratio of embodiment 1, but be due to percentage >=25wt% of wherein bead, it is coated
The effect of gained, compared to too coarse, integrally has accumulation substantially compared with embodiment 1, without stereovision, and touches
Sense is coarse.
All documents referred in the present invention are all incorporated as reference in this application, just as each document
It is individually recited as with reference to such.In addition, it is to be understood that after the above-mentioned instruction content of the present invention has been read,
Those skilled in the art can make various changes or modifications to the present invention, and these equivalent form of values equally fall within this Shen
Please appended claims limited range.
Claims (10)
1. a kind of composition, it is characterised in that the composition is used as color stuffing using pearlescent pigment and bead.
2. composition as claimed in claim 1, it is characterised in that the composition contains following components：
The pearlescent pigment of 3-30 parts by weight；
The bead of 20-25 parts by weight；
The emulsion of 10-40 parts by weight；With
The optionally water of 10-60 parts by weight.
3. composition as claimed in claim 2, it is characterised in that the composition is also containing one be selected from the group
Plant or various ingredients：
The thickener of 0.1-10 parts by weight；
The pH adjusting agent of 0.01-1 parts by weight；
The wetting agent of 0.01-1 parts by weight；
The defoamer of 0.2-10 parts by weight；With
The coalescents of 0.3-5 parts by weight.
4. composition as claimed in claim 2, it is characterised in that the pearlescent pigment is metal oxide layer bag
The mica covered；And/or
The mesh number of the pearlescent pigment is 6-180 mesh；And/or
The mesh number of the bead is 100-150 mesh；And/or
Glass transition temperature >=10 DEG C of the emulsion.
5. composition as claimed in claim 4, it is characterised in that the metal member of the composition metal oxide layer
Element is selected from the group：Titanium dioxide, di-iron trioxide or its combination；And/or
The mesh number of the kernel mica of the pearlescent pigment is 6-160 μm.
6. the preparation method of composition described in a kind of claim 1, it is characterised in that comprise the following steps：
1) the first mixed liquor and the second mixed liquor are provided, wherein,
First mixed liquor contains：The pearlescent pigments of 3-30 parts by weight, the bead of 20-25 parts by weight and optionally
25-50 parts by weight water；
Second mixed liquor contains：The emulsion of 10-40 parts by weight；
2) first mixed liquor and second mixed liquor under agitation, are mixed, claim 1 is obtained
The composition.
7. method as claimed in claim 6, it is characterised in that in step 1) before, the pearlescent pigment exists
Pre-soaking processing is carried out in water.
8. a kind of coating, it is characterised in that the coating is coated on base material as the composition described in claim 1
Obtain.
9. a kind of product, it is characterised in that the product contains：
Base material；
Coating described in claim 8；And
It is optionally coated with the priming paint of the substrate surface.
10. a kind of metope coating process, it is characterised in that including step：
1) optionally the composition described in claim 1 is stirred；
2) composition is coated to metope after being stirred described in；
3) after optionally spontaneously drying, subsequent treatment is carried out.
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Cited By (3)
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| CN112175467A (en) * | 2020-10-23 | 2021-01-05 | 三棵树(上海)新材料研究有限公司 | Sand sweeping pearlescent art paint and preparation method thereof |
| CN112852231A (en) * | 2020-12-30 | 2021-05-28 | 广东嘉宝莉科技材料有限公司 | Pearlescent art paint and preparation method and application thereof |
| CN114761494A (en) * | 2019-11-18 | 2022-07-15 | 墨水科技运营公司 | Retroreflective aqueous pseudoplastic gel composition for industrial spray coating |
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| CN112175467A (en) * | 2020-10-23 | 2021-01-05 | 三棵树(上海)新材料研究有限公司 | Sand sweeping pearlescent art paint and preparation method thereof |
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| CN106939136B (en) | 2019-08-23 |
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