CN105101626A - Flexible composite aluminum substrate and preparation method thereof - Google Patents

Flexible composite aluminum substrate and preparation method thereof Download PDF

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Publication number
CN105101626A
CN105101626A CN201510469867.6A CN201510469867A CN105101626A CN 105101626 A CN105101626 A CN 105101626A CN 201510469867 A CN201510469867 A CN 201510469867A CN 105101626 A CN105101626 A CN 105101626A
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CN
China
Prior art keywords
silver bromide
flexible
insulating barrier
photosensitive layer
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201510469867.6A
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Chinese (zh)
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CN105101626B (en
Inventor
雷成
张劭群
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DONGGUAN YILIAN ELECTRONIC TECHNOLOGY Co Ltd
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DONGGUAN YILIAN ELECTRONIC TECHNOLOGY Co Ltd
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Priority to CN201510469867.6A priority Critical patent/CN105101626B/en
Publication of CN105101626A publication Critical patent/CN105101626A/en
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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0201Thermal arrangements, e.g. for cooling, heating or preventing overheating
    • H05K1/0203Cooling of mounted components
    • H05K1/0204Cooling of mounted components using means for thermal conduction connection in the thickness direction of the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/05Insulated conductive substrates, e.g. insulated metal substrate
    • H05K1/056Insulated conductive substrates, e.g. insulated metal substrate the metal substrate being covered by an organic insulating layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/02Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
    • H05K3/022Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/08PCBs, i.e. printed circuit boards

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention provides a flexible composite aluminum substrate and a preparation method thereof. The flexible composite aluminum substrate comprises a copper foil conducting layer, a first flexible heat conducting glue layer, an insulation layer, a second flexible heat conducting glue layer and a flexible radiating aluminum foil which are connected successively, a first silver bromide photosensitive layer is arranged between the insulation layer and the first flexible heat conducting glue layer, a second silver bromide photosensitive layer is arranged between the insulation layer and the second flexible heat conducting glue layer, and the total area of the first and second silver bromide photosensitive layers is 1/5 to 2/3 that of the insulation layer. The preparation method is simple, the flexible composite aluminum substrate can be used for information storage innovatively, and the utilization rate of the products is improved.

Description

A kind of flexible compound aluminium base and preparation method thereof
Technical field
The invention belongs to electronic product raw material field, particularly oneplant flexible compound aluminium base and preparation method thereof.
Background technology
Along with electronic product is to future development that is light, little, thin and flexing, flexible circuit board demand is a dark horse, and advancing by leaps and bounds of LED market in recent years, traditional rigid aluminium base cannot meet the demand in market.The structure of current conventional aluminum substrate is aluminium sheet+glue-line+Copper Foil.Utility model patent publication number: CN204157157U implements to be coat thermal insulation layer in aluminium foil one side, and another side coats anticorrosive coat, then on thermal insulation layer, be coated with last layer flexible insulation heat-conducting layer, and thermal insulation layer arranges Copper Foil again.This flexible embodiment relies on the flexible heat-conducting layer of one deck, and this flexibility is poor, frangible easy fracture.And insulation is comparatively really poor.For this problem, the present embodiment fundamentally solves flexibility, and the material used because of this case is flexible material, all selects flexible material from raw material aluminium foil/Copper Foil.Aluminium foil selects thickness to be no more than the flexible aluminium foil of 0.15MM, and the high ductibility Copper Foil of thickness not 0.070MM selected by Copper Foil.Insulating barrier selects insulation property to reach the polyimide film of more than F level, and heat-conducting layer selects flexible rubber and Heat Conduction Material aluminium oxide and boron oxide, to reach flexible and heat-conducting effect.
But flexible PCB shorter mention information storage at present, nobody expects utilizing it to improve information capacity, and small size Large Copacity is the developing direction of current electronic product.
Summary of the invention
In order to solve point to be modified of the prior art, the object of this invention is to provide oneplant flexible compound aluminium base, while can ensuring the quality of products, increase the information capacity of product.
Another object of the present invention is to provide oneplant the preparation method of flexible compound aluminium base.
For realizing above object, technical scheme of the present invention is:
A kind of flexible compound aluminium base, comprise connection copper foil conductive layer, the first flexible heat conduction glue-line, insulating barrier, the second flexible heat conduction glue-line and flexible heat sink aluminium foil successively, the first silver bromide photosensitive layer is provided with between described insulating barrier and the first flexible heat conduction glue-line, be provided with the second silver bromide photosensitive layer between insulating barrier and the second flexible heat conduction glue-line, the gross area of described first silver bromide photosensitive layer and the second silver bromide photosensitive layer is the 1/5-2/3 of insulating barrier.
Described first silver bromide photosensitive layer and the second silver bromide photosensitive layer thickness are 0.1-5 μm.
Described insulating barrier is the polyimide film of thickness 1-20 μm.
The gross area of described first silver bromide photosensitive layer and the second silver bromide photosensitive layer is the 1/3-2/3 of insulating barrier.
Described first silver bromide photosensitive layer and the second silver bromide photosensitive layer are mal-distribution on the two sides of insulating barrier.
A preparation method for flexible compound aluminium base, comprising: a, prepare flexible heat conduction glue; B, flexible heat conduction glue is uniformly coated in release liners, baking; C, the release liners being coated with flexible heat conduction glue-line that step b is obtained and Copper Foil compound, obtained Copper Foil composite bed; The release liners being coated with flexible heat conduction glue-line that step b is obtained and aluminium foil compound, obtained aluminium foil composite bed; D, by insulating barrier two face portion coating silver bromide; Put between the obtained Copper Foil composite bed of step c and aluminium foil composite bed by the insulating barrier of two face portion coating silver bromides, compound again, obtains flexible compound aluminium base of the present invention.
By the detailed step of insulating barrier two face portion coating silver bromide be: first-selection prepares silver bromide film, release liners is put into silver bromide solution 1-5 minute, then takes out oven dry, cut to required size; With release liners and the insulating barrier compound of silver bromide thin layer, after compound, bromination silver layer is attached on insulating barrier, takes off the release liners cut.
The invention has the beneficial effects as follows:
1. the area of silver bromide photosensitive layer accounts for less than 2/3 of insulating barrier, ensure that the adhesion firmness between heat conduction adhesive-layer and insulating barrier.
2. preparation method is simple, and has started the technology space of the information storage of flexible compound aluminium base, improves the utilance of product.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention 1.
In figure: 1, Copper Foil conductive layer; 2, the first flexible heat conduction glue-line; 3, insulating barrier; 4, the second flexible heat conduction glue-line; 5, flexible heat sink aluminium foil; 6, the first silver bromide photosensitive layer; 7, the second silver bromide photosensitive layer.
Embodiment
Further illustrate one embodiment of the present invention with reference to the accompanying drawings.
Embodiment 1: as shown in Figure 1,
A kind of flexible compound aluminium base, comprise the flexible heat conduction glue-line 2 of connection copper foil conductive layer 1, first, insulating barrier 3, second flexible heat conduction glue-line 4 and flexible heat sink aluminium foil 5 successively, the first silver bromide photosensitive layer 6 is provided with between described insulating barrier 3 and the first flexible heat conduction glue-line 2, be provided with the second silver bromide photosensitive layer 7 between insulating barrier 3 and the second flexible heat conduction glue-line 4, the gross area of described first silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 is 1/3 of insulating barrier 3.
First silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 thickness are 1 μm.
Insulating barrier 3 is the polyimide film of thickness 10 μm.
First silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 are mal-distribution on the two sides of insulating barrier.
A preparation method for flexible compound aluminium base, comprising: a, prepare flexible heat conduction glue; B, flexible heat conduction glue is uniformly coated in release liners, baking; C, the release liners being coated with flexible heat conduction glue-line that step b is obtained and Copper Foil compound, obtained Copper Foil composite bed; The release liners being coated with flexible heat conduction glue-line that step b is obtained and aluminium foil compound, obtained aluminium foil composite bed; D, by insulating barrier two face portion coating silver bromide; Put between the obtained Copper Foil composite bed of step c and aluminium foil composite bed by the insulating barrier of two face portion coating silver bromides, compound again, obtains flexible compound aluminium base of the present invention.
By the detailed step of insulating barrier two face portion coating silver bromide be: first-selection prepares silver bromide film, release liners is put into silver bromide solution 1-5 minute, then takes out oven dry, cut to required size; With release liners and the insulating barrier compound of silver bromide thin layer, after compound, bromination silver layer is attached on insulating barrier, takes off the release liners cut.
Embodiment 2:
A kind of flexible compound aluminium base, comprise the flexible heat conduction glue-line 2 of connection copper foil conductive layer 1, first, insulating barrier 3, second flexible heat conduction glue-line 4 and flexible heat sink aluminium foil 5 successively, the first silver bromide photosensitive layer 6 is provided with between described insulating barrier 3 and the first flexible heat conduction glue-line 2, be provided with the second silver bromide photosensitive layer 7 between insulating barrier 3 and the second flexible heat conduction glue-line 4, the gross area of described first silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 is 2/3 of insulating barrier 3.
First silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 thickness are 0.5 μm.
Insulating barrier 3 is the polyimide film of thickness 20 μm.
First silver bromide photosensitive layer 6 and the second silver bromide photosensitive layer 7 are mal-distribution on the two sides of insulating barrier.
A preparation method for flexible compound aluminium base, comprising: a, prepare flexible heat conduction glue; B, flexible heat conduction glue is uniformly coated in release liners, baking; C, the release liners being coated with flexible heat conduction glue-line that step b is obtained and Copper Foil compound, obtained Copper Foil composite bed; The release liners being coated with flexible heat conduction glue-line that step b is obtained and aluminium foil compound, obtained aluminium foil composite bed; D, by insulating barrier two face portion coating silver bromide; Put between the obtained Copper Foil composite bed of step c and aluminium foil composite bed by the insulating barrier of two face portion coating silver bromides, compound again, obtains flexible compound aluminium base of the present invention.
By the detailed step of insulating barrier two face portion coating silver bromide be: first-selection prepares silver bromide film, release liners is put into silver bromide solution 1-5 minute, then takes out oven dry, cut to required size; With release liners and the insulating barrier compound of silver bromide thin layer, after compound, bromination silver layer is attached on insulating barrier, takes off the release liners cut.
The above not imposes any restrictions technical scope of the present invention, all above embodiment is done according to the technology of the present invention essence any amendment, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.

Claims (7)

1. a flexible compound aluminium base, it is characterized in that: comprise connection copper foil conductive layer, the first flexible heat conduction glue-line, insulating barrier, the second flexible heat conduction glue-line and flexible heat sink aluminium foil successively, the first silver bromide photosensitive layer is provided with between described insulating barrier and the first flexible heat conduction glue-line, be provided with the second silver bromide photosensitive layer between insulating barrier and the second flexible heat conduction glue-line, the gross area of described first silver bromide photosensitive layer and the second silver bromide photosensitive layer is the 1/5-2/3 of insulating barrier.
2. flexible compound aluminium base according to claim 1, is characterized in that: described first silver bromide photosensitive layer and the second silver bromide photosensitive layer thickness are 0.1-5 μm.
3. flexible compound aluminium base according to claim 1, is characterized in that: described insulating barrier is the polyimide film of thickness 1-20 μm.
4. flexible compound aluminium base according to claim 1, is characterized in that: the gross area of described first silver bromide photosensitive layer and the second silver bromide photosensitive layer is the 1/3-2/3 of insulating barrier.
5. flexible compound aluminium base according to claim 1, is characterized in that: described first silver bromide photosensitive layer and the second silver bromide photosensitive layer are mal-distribution on the two sides of insulating barrier.
6. a preparation method for flexible compound aluminium base, comprising: a, prepare flexible heat conduction glue; B, flexible heat conduction glue is uniformly coated in release liners, baking; C, the release liners being coated with flexible heat conduction glue-line that step b is obtained and Copper Foil compound, obtained Copper Foil composite bed; The release liners being coated with flexible heat conduction glue-line that step b is obtained and aluminium foil compound, obtained aluminium foil composite bed; D, by insulating barrier two face portion coating silver bromide; Put between the obtained Copper Foil composite bed of step c and aluminium foil composite bed by the insulating barrier of two face portion coating silver bromides, compound again, obtains the flexible compound aluminium base described in any one of the claims in the present invention 1-5.
7. the preparation method of flexible compound aluminium base according to claim 6, by the detailed step of insulating barrier two face portion coating silver bromide be: first-selection prepares silver bromide film, release liners is put into silver bromide solution 1-5 minute, then take out oven dry, cut to required size; With release liners and the insulating barrier compound of silver bromide thin layer, after compound, bromination silver layer is attached on insulating barrier, takes off the release liners cut.
CN201510469867.6A 2015-08-04 2015-08-04 A kind of flexible compound aluminum substrate and preparation method thereof Active CN105101626B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109361050A (en) * 2018-10-09 2019-02-19 合肥联宝信息技术有限公司 The production method of composite substrate, shell and composite substrate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060188701A1 (en) * 2005-02-22 2006-08-24 Andresakis John A Multilayered construction for resistor and capacitor formation
CN103066186A (en) * 2013-01-07 2013-04-24 浙江华正新材料股份有限公司 Insulating layer and aluminum substrate of ceramic chip composite structure and manufacturing method of the same
CN203700246U (en) * 2013-12-04 2014-07-09 天津大学 Structure of nanometer silver bromide-polyimide composite film
CN104754862A (en) * 2015-04-10 2015-07-01 松扬电子材料(昆山)有限公司 Aluminum foil copper plating substrate for flexible circuit board and manufacturing method of aluminum foil copper plating substrate
CN205017685U (en) * 2015-08-04 2016-02-03 东莞市毅联电子科技有限公司 Aluminium base board of flexible composite

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060188701A1 (en) * 2005-02-22 2006-08-24 Andresakis John A Multilayered construction for resistor and capacitor formation
CN103066186A (en) * 2013-01-07 2013-04-24 浙江华正新材料股份有限公司 Insulating layer and aluminum substrate of ceramic chip composite structure and manufacturing method of the same
CN203700246U (en) * 2013-12-04 2014-07-09 天津大学 Structure of nanometer silver bromide-polyimide composite film
CN104754862A (en) * 2015-04-10 2015-07-01 松扬电子材料(昆山)有限公司 Aluminum foil copper plating substrate for flexible circuit board and manufacturing method of aluminum foil copper plating substrate
CN205017685U (en) * 2015-08-04 2016-02-03 东莞市毅联电子科技有限公司 Aluminium base board of flexible composite

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109361050A (en) * 2018-10-09 2019-02-19 合肥联宝信息技术有限公司 The production method of composite substrate, shell and composite substrate

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