CN104981552B - 从旧原电池的含有锂锰氧化物的级分中湿法冶金回收锂的方法 - Google Patents

从旧原电池的含有锂锰氧化物的级分中湿法冶金回收锂的方法 Download PDF

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Publication number
CN104981552B
CN104981552B CN201380053321.1A CN201380053321A CN104981552B CN 104981552 B CN104981552 B CN 104981552B CN 201380053321 A CN201380053321 A CN 201380053321A CN 104981552 B CN104981552 B CN 104981552B
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China
Prior art keywords
lithium
manganese oxide
solution
lithium manganese
fraction containing
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Chinese (zh)
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CN104981552A (zh
Inventor
D·沃尔格姆特
M·A·施奈德
R·施皮劳
J·威廉斯
M·斯坦比尔德
N·克利姆
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Albemarle Germany GmbH
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Rockwood Lithium GmbH
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN201380053321.1A 2012-10-10 2013-10-09 从旧原电池的含有锂锰氧化物的级分中湿法冶金回收锂的方法 Active CN104981552B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102012218468.6 2012-10-10
DE102012218468 2012-10-10
PCT/EP2013/003029 WO2014056610A1 (de) 2012-10-10 2013-10-09 Verfahren zur hydrometallurgischen rückgewinnung von lithium aus der lithium-manganoxid haltigen fraktion gebrauchter galvanischer zellen

Publications (2)

Publication Number Publication Date
CN104981552A CN104981552A (zh) 2015-10-14
CN104981552B true CN104981552B (zh) 2018-04-10

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CN201380053321.1A Active CN104981552B (zh) 2012-10-10 2013-10-09 从旧原电池的含有锂锰氧化物的级分中湿法冶金回收锂的方法

Country Status (9)

Country Link
US (1) US10711326B2 (ru)
EP (1) EP2906729B1 (ru)
JP (1) JP6400014B2 (ru)
KR (1) KR102214420B1 (ru)
CN (1) CN104981552B (ru)
DE (1) DE102013016672A1 (ru)
IL (1) IL238121B (ru)
RU (1) RU2639416C2 (ru)
WO (1) WO2014056610A1 (ru)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6289411B2 (ja) * 2015-03-31 2018-03-07 Ｊｘ金属株式会社 鉄含有溶液からの鉄の除去方法及び、有価金属の回収方法
CN110205491B (zh) * 2019-06-25 2020-05-15 中南大学 一种金属锂单质及其制备方法与应用
CN113737018A (zh) * 2021-08-25 2021-12-03 金川集团股份有限公司 一种废旧电池正极原料的回收方法
KR102446860B1 (ko) * 2022-01-19 2022-09-23 (주)에코프로머티리얼즈 혼합 탄산 침전물의 리튬 및 알루미늄의 선택적 침출 방법

Citations (4)

* Cited by examiner, † Cited by third party
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FR2796207A1 (fr) * 1999-07-07 2001-01-12 Tredi Procede de recuperation d'especes metalliques a partir de piles et accumulateurs au lithium
CN1973399A (zh) * 2004-06-21 2007-05-30 丰田自动车株式会社 锂电池处理方法
CN102163760A (zh) * 2011-03-17 2011-08-24 江西格林美资源循环有限公司 一种从锂电池正极材料中分离回收锂和钴的方法
KR20120031831A (ko) * 2010-09-27 2012-04-04 한국과학기술연구원 리튬전지 양극활물질로부터의 리튬 회수 방법

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US4434241A (en) * 1982-09-27 1984-02-28 Eastman Kodak Company Catalyst recovery process from tar from carbonylation reactions
JPH01154159A (ja) 1987-12-11 1989-06-16 Konica Corp 湿し水不要平版印刷版及びその製造方法
RU2016140C1 (ru) 1991-12-23 1994-07-15 Уральский государственный технический университет Способ извлечения лития из отходов алюминиево-литиевых сплавов
RU2067126C1 (ru) * 1993-07-01 1996-09-27 Институт химии твердого тела и переработки минерального сырья СО РАН Способ извлечения лития из литий-, алюминийсодержащих отходов
JP3676926B2 (ja) * 1997-06-04 2005-07-27 株式会社日鉱マテリアルズ 電池正極廃材からコバルト、ニッケルもしくはマンガンおよびリチウムを回収および再生する方法ならびに電池正極材原料
JP4217292B2 (ja) * 1998-03-17 2009-01-28 株式会社東芝 リチウム回収方法
IL131110A (en) 1999-07-26 2003-10-31 Ariel Rosenberg Omer High efficiency process for treating mixed metal waste
JP2002198103A (ja) 2000-12-22 2002-07-12 Toshiba Electronic Engineering Corp 電極構成金属の回収方法
EP1333522A1 (en) * 2002-02-01 2003-08-06 Batrec Industrie AG Method of and apparatus for storage and handling of objects comprising alkali metals, such as alkali metal containing batteries
FR2868603B1 (fr) 2004-04-06 2006-07-14 Recupyl Sa Sa Procede de recyclage en melange de piles et batteries a base d'anode en lithium
JP4412412B2 (ja) 2008-05-28 2010-02-10 トヨタ自動車株式会社 リチウム電池の処理方法
KR100961820B1 (ko) * 2008-07-18 2010-06-08 한국과학기술원 하이브리드 다채널 통신 프로토콜 네트워크 환경에서다채널의 상태 모니터링 방법
KR20100093451A (ko) * 2009-02-16 2010-08-25 윤강준 Ｓｃｙｅ1을 인지하는 단클론 항체 및 이의 용도
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KR101219515B1 (ko) * 2010-07-02 2013-01-11 한국기계연구원 본드자석용 Ｒ―Ｆｅ―Ｂ계 희토류 자성분말의 제조방법, 이에 의해 제조된 자성분말 및 상기 자성분말을 이용한 본드자석의 제조방법, 이에 의해 제조된 본드자석
WO2012072619A1 (en) * 2010-11-29 2012-06-07 Umicore Process for the recovery of lithium and iron from lfp batteries
CN102208706A (zh) 2011-05-04 2011-10-05 合肥国轩高科动力能源有限公司 一种废旧磷酸铁锂电池正极材料的回收再生处理方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2796207A1 (fr) * 1999-07-07 2001-01-12 Tredi Procede de recuperation d'especes metalliques a partir de piles et accumulateurs au lithium
CN1973399A (zh) * 2004-06-21 2007-05-30 丰田自动车株式会社 锂电池处理方法
KR20120031831A (ko) * 2010-09-27 2012-04-04 한국과학기술연구원 리튬전지 양극활물질로부터의 리튬 회수 방법
CN102163760A (zh) * 2011-03-17 2011-08-24 江西格林美资源循环有限公司 一种从锂电池正极材料中分离回收锂和钴的方法

Also Published As

Publication number Publication date
KR102214420B1 (ko) 2021-02-08
EP2906729A1 (de) 2015-08-19
IL238121B (en) 2019-07-31
US10711326B2 (en) 2020-07-14
JP6400014B2 (ja) 2018-10-03
IL238121A0 (en) 2015-05-31
RU2015117381A (ru) 2016-12-10
WO2014056610A1 (de) 2014-04-17
CN104981552A (zh) 2015-10-14
JP2015534610A (ja) 2015-12-03
EP2906729B1 (de) 2019-04-24
RU2639416C2 (ru) 2017-12-21
US20150267278A1 (en) 2015-09-24
DE102013016672A1 (de) 2014-04-10
KR20150063575A (ko) 2015-06-09

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