CN104903479A - 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池 - Google Patents

贮氢合金和阴电极以及采用它们的ni-金属氢化物电池 Download PDF

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Publication number
CN104903479A
CN104903479A CN201380059787.2A CN201380059787A CN104903479A CN 104903479 A CN104903479 A CN 104903479A CN 201380059787 A CN201380059787 A CN 201380059787A CN 104903479 A CN104903479 A CN 104903479A
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Prior art keywords
hydrogen storage
alloy
storage alloy
phase
capacity
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Pending
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CN201380059787.2A
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English (en)
Chinese (zh)
Inventor
K-H·杨
T·乌奇
J·内
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BASF Battery Materials Ovonic
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BASF Battery Materials Ovonic
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Priority to CN201710091948.6A priority Critical patent/CN106953091A/zh
Publication of CN104903479A publication Critical patent/CN104903479A/zh
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383—Hydrogen absorbing alloys
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C16/00—Alloys based on zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/242—Hydrogen storage electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/34—Gastight accumulators
    • H01M10/345—Gastight metal hydride accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacturing & Machinery (AREA)
CN201380059787.2A 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池 Pending CN104903479A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710091948.6A CN106953091A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/694,299 US20140140885A1 (en) 2012-11-16 2012-11-16 Hydrogen storage alloy and negative electrode and Ni-metal hydride battery employing same
US13/694,299 2012-11-16
PCT/US2013/069797 WO2014078351A1 (en) 2012-11-16 2013-11-13 A hydrogen storage alloy and negative electrode and ni-metal hydride battery employing same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201710091948.6A Division CN106953091A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池

Publications (1)

Publication Number Publication Date
CN104903479A true CN104903479A (zh) 2015-09-09

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CN201380059787.2A Pending CN104903479A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池
CN201710091948.6A Pending CN106953091A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池

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Country Status (5)

Country Link
US (2) US20140140885A1 (enExample)
EP (1) EP2920333A4 (enExample)
JP (1) JP6312692B2 (enExample)
CN (2) CN104903479A (enExample)
WO (1) WO2014078351A1 (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3256615A4 (en) * 2015-02-11 2018-12-05 BASF Corporation Hydrogen storage alloys

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2021806A1 (en) * 1989-07-24 1991-01-25 Michael A. Fetcenko Preparation of vanadium rich hydrogen storage alloy materials
EP0503686A2 (en) * 1987-05-15 1992-09-16 Matsushita Electric Industrial Co., Ltd. Method for making a hydrogen storage electrode
EP0703633A1 (en) * 1994-08-17 1996-03-27 AT&T Corp. Process for activation of metal hydrides
JPH08134567A (ja) * 1994-11-11 1996-05-28 Shin Kobe Electric Mach Co Ltd 水素吸蔵合金及びアルカリ蓄電池用水素吸蔵合金電極
JPH08319529A (ja) * 1995-05-22 1996-12-03 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
CN1236821A (zh) * 1998-05-21 1999-12-01 丰田自动车株式会社 吸氢合金
CN1313910A (zh) * 1999-04-12 2001-09-19 双向电池公司 增大了容量、速率性能和催化活性的改性电化学储氢合金
CN1505190A (zh) * 1996-01-22 2004-06-16 东芝株式会社 储氢合金，电池负极和碱性二次电池

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
JPH0650633B2 (ja) * 1987-07-30 1994-06-29 松下電器産業株式会社 水素吸蔵電極
JPH05287422A (ja) * 1992-04-13 1993-11-02 Matsushita Electric Ind Co Ltd 水素吸蔵合金電極
JPH073365A (ja) * 1993-04-20 1995-01-06 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
JPH09199121A (ja) * 1996-01-22 1997-07-31 Toshiba Corp 水素吸蔵合金及び二次電池
US6682609B1 (en) * 1994-07-22 2004-01-27 Kabushiki Kaisha Toshiba Hydrogen absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery
JP3931518B2 (ja) * 1999-07-08 2007-06-20 松下電器産業株式会社 ニッケル−水素二次電池
CN1162924C (zh) * 2001-05-11 2004-08-18 浙江大学 镍-金属氢化物(Ni-MH)二次电池
CN102683653A (zh) * 2011-03-09 2012-09-19 中国科学院长春应用化学研究所 复合贮氢合金及镍氢蓄电池
CN102738520B (zh) * 2011-04-14 2017-02-15 中国科学院长春应用化学研究所 镍氢蓄电池

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0503686A2 (en) * 1987-05-15 1992-09-16 Matsushita Electric Industrial Co., Ltd. Method for making a hydrogen storage electrode
CA2021806A1 (en) * 1989-07-24 1991-01-25 Michael A. Fetcenko Preparation of vanadium rich hydrogen storage alloy materials
US5002730A (en) * 1989-07-24 1991-03-26 Energy Conversion Devices Preparation of vanadium rich hydrogen storage alloy materials
EP0703633A1 (en) * 1994-08-17 1996-03-27 AT&T Corp. Process for activation of metal hydrides
JPH08134567A (ja) * 1994-11-11 1996-05-28 Shin Kobe Electric Mach Co Ltd 水素吸蔵合金及びアルカリ蓄電池用水素吸蔵合金電極
JPH08319529A (ja) * 1995-05-22 1996-12-03 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
CN1505190A (zh) * 1996-01-22 2004-06-16 东芝株式会社 储氢合金，电池负极和碱性二次电池
CN1236821A (zh) * 1998-05-21 1999-12-01 丰田自动车株式会社 吸氢合金
CN1313910A (zh) * 1999-04-12 2001-09-19 双向电池公司 增大了容量、速率性能和催化活性的改性电化学储氢合金

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
BARKING等: "Effects of annealing on Zr8Ni19X2(X=Ni，Mg，Al，Sc，V，Mn，Co，Sn，La and Hf)：Hyfrogen storage and electrochemical properties", 《INTERNATIONAL JOURNAL OF HYDROGEN ENERGY》 *
HARUO SAWA等: "Electrochemical Properties of Zr-V-Ni System Hydrogen-Absorbing Alloys of Face-Centered Cubic Structure", 《MATERIALS TRANSACTIONS》 *
JIANG等: "An electrochemical investigation of mechanical alloying of MgNi-based hydrogen storage alloys", 《JOURNAL OF POWER SOURCES》 *
LAUSANNE等: "Effects of annealing on Zr8Ni19X2(X=Ni，Mg，Al，Sc，V，Mn，Co，Sn，La and Hf)：Structural characteristics", 《JOUNAL OF ALLOYS AND COMPOUNDS》 *
M.BOUOUDINA等: "Review on hydrogen absorbing materials-structure，microstructure，and thermodynamic properties", 《INTERNATIONAL JOURNAL OF HYDROGEN ENERGY》 *
M.BOUOUDINA等: "Structural investigations by neutron diffraction of equi-atomic Zr-Ti(V)-Ni(Co) compounds and their related hydrides", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *
PAKY等: "Electrochemical Properties of Laves Phase Zr-V System Hydrogen Absorbing Alloys", 《JOURNAL OF THE KOREAN HYDROGEN ENERGY SOCIETY》 *
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熊家林等: "《无机精细化学品的制备和应用》", 31 October 1999, 北京：化学工业出版社 *

Also Published As

Publication number Publication date
WO2014078351A1 (en) 2014-05-22
JP6312692B2 (ja) 2018-04-18
EP2920333A4 (en) 2016-11-16
JP2015537119A (ja) 2015-12-24
US20160204429A1 (en) 2016-07-14
US20140140885A1 (en) 2014-05-22
CN106953091A (zh) 2017-07-14
EP2920333A1 (en) 2015-09-23

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