CN104892932B - 聚酯酰胺、其制备方法及其制品纤维 - Google Patents
聚酯酰胺、其制备方法及其制品纤维 Download PDFInfo
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- CN104892932B CN104892932B CN201410077464.2A CN201410077464A CN104892932B CN 104892932 B CN104892932 B CN 104892932B CN 201410077464 A CN201410077464 A CN 201410077464A CN 104892932 B CN104892932 B CN 104892932B
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- polyesteramide
- polyester amide
- polyester
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- 229920006149 polyester-amide block copolymer Polymers 0.000 title claims abstract description 162
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 61
- 238000006243 chemical reaction Methods 0.000 claims description 48
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 37
- 150000003839 salts Chemical class 0.000 claims description 33
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- 229920001778 nylon Polymers 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 25
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- 230000032050 esterification Effects 0.000 claims description 21
- 238000005886 esterification reaction Methods 0.000 claims description 21
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
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- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- ZRSKSQHEOZFGLJ-UHFFFAOYSA-N ammonium adipate Chemical compound [NH4+].[NH4+].[O-]C(=O)CCCCC([O-])=O ZRSKSQHEOZFGLJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000009998 heat setting Methods 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000006266 etherification reaction Methods 0.000 claims description 4
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- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 3
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- 239000011261 inert gas Substances 0.000 claims description 3
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- 239000007858 starting material Substances 0.000 claims description 3
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- 230000000694 effects Effects 0.000 abstract description 5
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- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 13
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- 125000002091 cationic group Chemical group 0.000 description 4
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- 229920000742 Cotton Polymers 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229920002334 Spandex Polymers 0.000 description 3
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- VAYOSLLFUXYJDT-RDTXWAMCSA-N Lysergic acid diethylamide Chemical compound C1=CC(C=2[C@H](N(C)C[C@@H](C=2)C(=O)N(CC)CC)C2)=C3C2=CNC3=C1 VAYOSLLFUXYJDT-RDTXWAMCSA-N 0.000 description 2
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CN108102090A (zh) * | 2016-11-24 | 2018-06-01 | 上海杰事杰新材料(集团)股份有限公司 | 超韧热稳定聚酰胺树脂及其制备方法 |
CN109957107B (zh) * | 2017-12-25 | 2022-07-19 | 上海凯赛生物技术股份有限公司 | 一种聚酯酰胺及其制备方法 |
CN109265353B (zh) * | 2018-10-16 | 2021-06-29 | 南京工业大学 | 戊二胺十二烷二酸盐及其晶体 |
CN109706536B (zh) * | 2018-11-26 | 2020-06-05 | 东华大学 | 一种尼龙6基聚酰胺酯纤维的制备方法 |
CN109880081A (zh) * | 2019-02-15 | 2019-06-14 | 美瑞新材料股份有限公司 | 一种含有聚酰胺链段的聚酯多元醇的制备方法 |
CN111748092B (zh) * | 2019-03-27 | 2023-04-14 | 上海凯赛生物技术股份有限公司 | 聚酯酰胺、其制备方法及其制品纤维 |
CN113087897B (zh) * | 2019-12-23 | 2023-11-17 | 上海凯赛生物技术股份有限公司 | 一种聚酯酰胺及其制备方法和纤维 |
CN111019122B (zh) * | 2019-12-24 | 2021-08-03 | 浙江新和成特种材料有限公司 | 一种半芳香族聚酰胺热塑性弹性体及其连续生产方法 |
CN111440314B (zh) * | 2020-04-17 | 2021-07-06 | 东华大学 | 一种聚酰胺酯及其制备方法和应用 |
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CN1044664A (zh) * | 1989-02-01 | 1990-08-15 | 河北工学院 | 织物用聚酯酰胺热熔胶的制造方法 |
CN1049167A (zh) * | 1989-07-12 | 1991-02-13 | 阿托化学公司 | 热致变的半脂族共聚酯酰胺及其制备方法 |
CN101450990A (zh) * | 2007-12-06 | 2009-06-10 | 中国纺织科学研究院 | 一种酸性可染聚酯和该酸性可染聚酯及其纤维的制备方法 |
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