CN104861595B - 无卤阻燃pbt材料及其制备方法 - Google Patents
无卤阻燃pbt材料及其制备方法 Download PDFInfo
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- CN104861595B CN104861595B CN201510309013.1A CN201510309013A CN104861595B CN 104861595 B CN104861595 B CN 104861595B CN 201510309013 A CN201510309013 A CN 201510309013A CN 104861595 B CN104861595 B CN 104861595B
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- fire retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 72
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 35
- 150000002367 halogens Chemical class 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000002131 composite material Substances 0.000 claims abstract description 29
- -1 pentaerythrite diphosphate ester melamine salt Chemical class 0.000 claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 13
- 239000001177 diphosphate Substances 0.000 claims abstract description 13
- 235000011180 diphosphates Nutrition 0.000 claims abstract description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 57
- 229920001707 polybutylene terephthalate Polymers 0.000 description 39
- 238000005452 bending Methods 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 3
- 239000012757 flame retardant agent Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- WSEFPKKOUNRCAJ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;octadecanoic acid Chemical compound OCC(CO)(CO)CO.CCCCCCCCCCCCCCCCCC(O)=O WSEFPKKOUNRCAJ-UHFFFAOYSA-N 0.000 description 1
- DBKFYOISCCPYTQ-UHFFFAOYSA-K C1(=CC=CC=C1)P([O-])=O.[Al+3].C1(=CC=CC=C1)P([O-])=O.C1(=CC=CC=C1)P([O-])=O Chemical compound C1(=CC=CC=C1)P([O-])=O.[Al+3].C1(=CC=CC=C1)P([O-])=O.C1(=CC=CC=C1)P([O-])=O DBKFYOISCCPYTQ-UHFFFAOYSA-K 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg | 100kg | 100kg |
季戊四醇双磷酸酯密胺盐 | 4kg | 4kg | 5kg | 5kg | 6kg | 6kg |
三聚氰胺氰尿酸盐 | 1kg | 1.5kg | 2kg | 3kg | 3kg | 4kg |
次磷酸铝 | 13kg | 16kg | 20kg | 21kg | 20kg | 18kg |
磷酸三苯酯 | 2kg | 1.5kg | 3kg | 4kg | 2kg | 1kg |
聚硅氧烷 | 1.5kg | 2kg | 2kg | 2.5kg | 3kg | 3kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.03kg | 0.03kg | 0.03kg |
抗氧剂168 | 0.04kg | 0.05kg | 0.06kg | 0.04kg | 0.05kg | 0.06kg |
测试性能 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
拉伸强度/MPa | 39.03 | 38.17 | 37.58 | 36.53 | 37.68 | 38.32 |
悬臂梁抗缺口冲击强度/KJ·m-2 | 3.68 | 3.91 | 3.32 | 3.67 | 3.15 | 3.44 |
弯曲强度/MPa | 64.12 | 63.89 | 62.15 | 61.38 | 60.54 | 63.56 |
弯曲模量/MPa | 2200 | 2130 | 2080 | 2090 | 1890 | 1960 |
氧指数/% | 33.2 | 34.6 | 35.0 | 36.4 | 34.9 | 33.8 |
垂直燃烧 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
微卡软化温度/℃ | 182 | 183 | 184 | 182 | 184 | 182 |
对比例1 | 对比例2 | 对比例3 | 对比例4 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg |
阻燃剂 | 20g阻燃剂A | 45g阻燃剂A | 20g阻燃剂B | 45g阻燃剂B |
聚硅氧烷 | 1.5kg | 1.5kg | 1.5kg | 1.5kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.02kg |
抗氧剂168 | 0.04kg | 0.04kg | 0.04kg | 0.04kg |
实施例1 | 对比例5 | 对比例6 | 对比例7 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg |
季戊四醇双磷酸酯密胺盐 | 4kg | 4kg | - | - |
三聚氰胺氰尿酸盐 | 1kg | - | 1kg | - |
次磷酸铝 | 13kg | 13kg | 13kg | 13kg |
磷酸三苯酯 | 2kg | - | - | 2kg |
聚硅氧烷 | 1.5kg | 1.5kg | 1.5kg | 1.5kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.02kg |
抗氧剂168 | 0.04kg | 0.04kg | 0.04kg | 0.04kg |
实施例1 | 对比例8 | 对比例9 | 对比例10 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg |
季戊四醇双磷酸酯密胺盐 | 4kg | 4kg | 4kg | - |
三聚氰胺氰尿酸盐 | 1kg | 1kg | - | 1kg |
次磷酸铝 | 13kg | - | - | - |
磷酸三苯酯 | 2kg | - | 2kg | 2kg |
聚硅氧烷 | 1.5kg | 1.5kg | 1.5kg | 1.5kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.02kg |
抗氧剂168 | 0.04kg | 0.04kg | 0.04kg | 0.04kg |
实施例1 | 对比例11 | 对比例12 | 对比例13 | 对比例14 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg | 100kg |
季戊四醇双磷酸酯密胺盐 | 4kg | 4kg | 4kg | 4kg | - |
三聚氰胺氰尿酸盐 | 1kg | 1kg | 1kg | - | 1kg |
次磷酸铝 | 13kg | 13kg | - | 13kg | 13kg |
磷酸三苯酯 | 2kg | - | 2kg | 2kg | 2kg |
聚硅氧烷 | 1.5kg | 1.5kg | 1.5kg | 1.5kg | 1.5kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.02kg | 0.02kg |
抗氧剂168 | 0.04kg | 0.04kg | 0.04kg | 0.04kg | 0.04kg |
实施例1 | 对比例15 | 对比例16 | 对比例17 | 对比例18 | |
PBT树脂 | 100kg | 100kg | 100kg | 100kg | 100kg |
季戊四醇双磷酸酯密胺盐 | 4kg | 4kg | - | - | - |
三聚氰胺氰尿酸盐 | 1kg | - | 1kg | - | - |
次磷酸铝 | 13kg | - | - | 13kg | - |
磷酸三苯酯 | 2kg | - | - | - | 2kg |
聚硅氧烷 | 1.5kg | 1.5kg | 1.5kg | 1.5kg | 1.5kg |
抗氧剂1076 | 0.02kg | 0.02kg | 0.02kg | 0.02kg | 0.02kg |
抗氧剂168 | 0.04kg | 0.04kg | 0.04kg | 0.04kg | 0.04kg |
测试性能 | 实施例1 | 对比例1 | 对比例2 | 对比例3 | 对比例4 |
拉伸强度/MPa | 39.03 | 37.58 | 34.58 | 36.58 | 35.58 |
悬臂梁抗缺口冲击强度/kJ·m-2 | 3.68 | 3.92 | 2.72 | 3.72 | 2.32 |
弯曲强度/MPa | 64.12 | 61.15 | 60.35 | 63.18 | 62.54 |
弯曲模量/MPa | 2200 | 2180 | 1986 | 2140 | 2030 |
氧指数/% | 33.2 | 27.3 | 32.0 | 27.2 | 33.1 |
垂直燃烧 | V-0 | V-2 | V-0 | V-2 | V-0 |
微卡软化温度/℃ | 182 | 170 | 178 | 173 | 175 |
测试性能 | 对比例5 | 对比例6 | 对比例7 | 对比例8 | 对比例9 | 对比例10 |
拉伸强度/MPa | 39.82 | 40.15 | 39.78 | 40.65 | 40.33 | 40.31 |
悬臂梁抗缺口冲击强度/kJ·m-2 | 4.11 | 4.15 | 4.07 | 4.25 | 4.05 | 4.45 |
弯曲强度/MPa | 64.15 | 64.48 | 63.58 | 65.08 | 64.83 | 65.16 |
弯曲模量/MPa | 2198 | 2210 | 2243 | 2190 | 2210 | 2240 |
氧指数/% | 22.1 | 22.0 | 22.4 | 18.0 | 18.0 | 18.0 |
垂直燃烧 | - | - | - | - | - | - |
微卡软化温度/℃ | 183 | 184 | 183 | 182 | 182 | 182 |
测试性能 | 对比例11 | 对比例12 | 对比例13 | 对比例14 |
拉伸强度/MPa | 39.65 | 40.72 | 39.88 | 39.62 |
悬臂梁抗缺口冲击强度/kJ·m-2 | 3.25 | 3.91 | 3.43 | 3.46 |
弯曲强度/MPa | 63.08 | 64.47 | 62.08 | 62.38 |
弯曲模量/MPa | 2090 | 2180 | 1990 | 1980 |
氧指数/% | 31.8 | 18.0 | 29.8 | 29.3 |
垂直燃烧 | V-0 | - | V-1 | V-1 |
微卡软化温度/℃ | 179 | 180 | 178 | 178 |
测试性能 | 对比例15 | 对比例16 | 对比例17 | 对比例18 |
拉伸强度/MPa | 40.62 | 41.61 | 39.48 | 41.93 |
悬臂梁抗缺口冲击强度/kJ·m-2 | 4.21 | 4.45 | 3.36 | 4.32 |
弯曲强度/MPa | 65.36 | 64.95 | 63.15 | 63.43 |
弯曲模量/MPa | 2245 | 2283 | 2128 | 2260 |
氧指数/% | 18.0 | 18.0 | 28.5 | 18.0 |
垂直燃烧 | - | - | V-2 | - |
微卡软化温度/℃ | 180 | 180 | 178 | 180 |
Claims (6)
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CN201510309013.1A CN104861595B (zh) | 2015-06-08 | 2015-06-08 | 无卤阻燃pbt材料及其制备方法 |
CN201610602000.8A CN106243638B (zh) | 2015-06-08 | 2015-06-08 | 一种无卤阻燃pbt材料 |
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CN106189221B (zh) * | 2016-08-05 | 2018-10-02 | 江苏晋伦塑料科技有限公司 | 一种无卤阻燃玻纤增强尼龙及其制备方法和应用 |
CN106700440B (zh) * | 2016-12-16 | 2019-02-19 | 佛山市三水金戈新型材料有限公司 | 一种导热阻燃聚酯复合材料及其制备方法 |
CN108203526A (zh) * | 2016-12-20 | 2018-06-26 | 上海杰事杰新材料(集团)股份有限公司 | 一种无卤阻燃tpo弹性体材料及其制备方法 |
CN106832419B (zh) * | 2017-01-05 | 2019-04-12 | 东莞市宏泰基阻燃材料有限公司 | 一种阻燃剂及其制备方法和应用 |
CN107266786B (zh) * | 2017-07-11 | 2020-03-17 | 江苏理工学院 | 一种聚丙烯无卤阻燃母粒及其制备方法 |
CN111234312B (zh) * | 2020-03-27 | 2020-11-10 | 北京理工大学 | 一种次磷酸铝复合无卤阻燃剂、制备及其应用 |
CN113502035A (zh) * | 2021-07-26 | 2021-10-15 | 洪湖市一泰科技有限公司 | 无卤阻燃聚酯复合材料及其制备方法 |
CN115197551B (zh) * | 2022-08-10 | 2023-08-22 | 金发科技股份有限公司 | 一种低模垢无卤阻燃pbt复合材料及其制备方法和应用 |
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CN1268686C (zh) * | 2003-07-27 | 2006-08-09 | 横店集团得邦工程塑料有限公司 | 耐湿热增强阻燃聚对苯二甲酸丁二醇酯复合材料及其制法 |
AU2003278444A1 (en) * | 2003-11-07 | 2005-05-26 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polycarbonate compositions |
CN101575351B (zh) * | 2009-05-30 | 2012-02-01 | 山东天一化学股份有限公司 | 一种磷氮系膨胀型阻燃剂的制备方法 |
CN101928448B (zh) * | 2010-08-16 | 2013-03-13 | 中国科学技术大学 | 一种纳米复合阻燃增强聚酯工程塑料及其制备方法 |
CN102002218B (zh) * | 2010-11-24 | 2013-01-09 | 广东省石油化工研究院 | 一种用于玻纤增强pbt材料的无卤复合阻燃剂及其制备方法 |
CN103122120B (zh) * | 2013-03-08 | 2015-07-29 | 上海安凸塑料添加剂有限公司 | 一种无卤阻燃丙烯腈-丁二烯-苯乙烯共聚物组合物 |
CN103342880B (zh) * | 2013-07-29 | 2016-02-03 | 广东顺德顺炎新材料有限公司 | 一种高光表面环保无卤阻燃pbt复合材料及其制备方法 |
CN103483670A (zh) * | 2013-10-10 | 2014-01-01 | 长园集团股份有限公司 | 一种150℃高阻燃无卤无红磷改性材料 |
CN103756269B (zh) * | 2013-12-31 | 2015-12-09 | 东莞市松燊塑料科技有限公司 | 一种耐高温无卤阻燃pbt材料及其制备方法 |
CN104327467B (zh) * | 2014-11-21 | 2016-06-08 | 古道尔工程塑胶(深圳)有限公司 | 一种膨胀型高灼热丝点燃温度pbt复合材料及其制备方法 |
CN104479353B (zh) * | 2014-12-19 | 2017-09-22 | 西华大学 | 一种新型无卤阻燃组合物、无卤阻燃pbt工程塑料复合材料及其制备方法 |
CN107201028B (zh) * | 2014-12-29 | 2019-08-23 | 江苏理工学院 | 环保型阻燃pa6材料 |
CN104650441B (zh) * | 2015-03-16 | 2017-10-17 | 四川大学 | 一种可陶瓷化阻燃高分子复合材料及应用 |
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