CN104803797A - Rice humic acid leaf fertilizer containing alkaloid, and preparation method of leaf fertilizer - Google Patents

Rice humic acid leaf fertilizer containing alkaloid, and preparation method of leaf fertilizer Download PDF

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CN104803797A
CN104803797A CN201510221601.XA CN201510221601A CN104803797A CN 104803797 A CN104803797 A CN 104803797A CN 201510221601 A CN201510221601 A CN 201510221601A CN 104803797 A CN104803797 A CN 104803797A
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rice
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humic acid
alkaloid
leaf fertilizer
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郜红建
钱新春
马静静
魏俊岭
胡芹远
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Anhui Agricultural University AHAU
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Abstract

The invention discloses a rice humic acid leaf fertilizer containing alkaloid, and a preparation method of the leaf fertilizer. The leaf fertilizer comprises the following components in parts by weight: 4-6 parts of humic acid, 20-30 parts of aliphatic polyoxyethylene ether, 0.1-1 part of alkaloid, 8-15 parts of 1% celastrus angulatus cream, 25-30 parts of urea, 4-6 parts of monopotassium phosphate, 15-20 parts of potassium nitrate, 10-15 parts of boric acid, 5-10 parts of zinc sulfate, 5-10 parts of manganese sulfate and 10-15 parts of sodium silicate. The rice humic acid leaf fertilizer can meet growth and development nutrients of rice; a plant source insecticide and a nutrient synergist are added, so that the immunity of the rice is improved, plant diseases and insect pests are effectively reduced, utilization ratios of the nutrients are increased, and effects of improving the quality of the rice and increasing the yield are achieved; and the rice humic acid leaf fertilizer is an ideal fertilizer for developing nuisanceless agriculture and soilless culture.

Description

含生物碱水稻腐殖酸叶面肥及其制备方法Rice humic acid foliar fertilizer containing alkaloid and preparation method thereof

技术领域technical field

本发明涉及叶面肥领域,特别是一种含生物碱水稻腐植酸叶面肥及其制备方法。The invention relates to the field of foliar fertilizers, in particular to a rice humic acid foliar fertilizer containing alkaloids and a preparation method thereof.

背景技术Background technique

肥料是作物生长所需养分的直接或间接供给体,具有改良土壤性状,提高作物产量和品质的功能。但是普通肥料作物的有效吸收低,肥效慢。大量、过量施用化肥,不仅造成土壤肥力利用率低,养分不均衡,土壤板结,而且造成环境污染,营养富集化等一系列环境问题。Fertilizer is a direct or indirect supplier of nutrients needed for crop growth, and has the function of improving soil properties and improving crop yield and quality. However, the effective absorption of ordinary fertilizer crops is low, and the fertilizer effect is slow. Excessive application of chemical fertilizers not only causes low soil fertility utilization rate, nutrient imbalance, soil compaction, but also causes environmental pollution, nutrient enrichment and other environmental problems.

在田间病虫害防治中,传统化学农药防治农业病虫害具有快速、高效、广谱和适合工业化大生产的优势,但随着时间的推移,化学农药的弊端逐渐暴露出来,尤其是化学农药典型的抗性(resistance)、再增猖獗(resurence)和残留(residue)的“3R”问题促使人们寻找化学农药的替代品,从传统的有机化学农药向环境和谐农药转化。在很多植物中含有大量的活性次代谢物质,以这些次代谢物开发的植物源农药往往具有对环境友好、毒性普遍较低、选择性高、不易使害虫产生抗性、作用机理独特和开发成本低等优点,表现出明显的生态效益、经济效益和社会效益,是生产新型绿色无公害农产品应优先选用的农药品种,研究开发植物源杀虫剂在当前备受关注。In field pest control, traditional chemical pesticides have the advantages of being fast, efficient, broad-spectrum and suitable for large-scale industrial production. However, as time goes by, the disadvantages of chemical pesticides are gradually exposed, especially the typical resistance of chemical pesticides. The "3R" problems of (resistance), resurgence and residue (residue) have prompted people to look for alternatives to chemical pesticides, transforming from traditional organic chemical pesticides to environmentally harmonious pesticides. Many plants contain a large number of active secondary metabolites. The botanical pesticides developed with these secondary metabolites are often environmentally friendly, generally low in toxicity, high in selectivity, difficult to cause pest resistance, unique mechanism of action, and development costs. Low-level advantages, showing obvious ecological benefits, economic benefits and social benefits, are the preferred pesticide varieties for the production of new green and pollution-free agricultural products. The research and development of botanical insecticides is currently attracting attention.

目前市面上出现的腐植酸叶面肥,虽满足了水稻对养分的需求,却不能抑制水稻生长过程中病虫害的侵扰。Humic acid foliar fertilizers currently on the market, although meeting the nutrient requirements of rice, cannot inhibit the infestation of diseases and insect pests during the growth of rice.

生物碱(C10H14N2)是世界上一种广泛使用的杀虫剂,其作用于烟碱型乙酰胆碱受体,干扰昆虫神经系统的刺激传导,引起神经通路阻塞,进而造成神经传导物质-乙酰胆碱的积累,从而导致昆虫麻痹,并最终死亡。其对果树、棉花、蔬菜、水稻、水稻等作物的蚜虫、钻心虫、螟虫等杀虫效果很好,且容易降解,对环境无污染、无毒害。Alkaloids (C 10 H 14 N 2 ) are widely used insecticides in the world. They act on nicotinic acetylcholine receptors, interfere with the stimulation conduction of the nervous system of insects, cause nerve pathway blockage, and then cause neurotransmitter substances - Accumulation of acetylcholine, which leads to paralysis and eventual death of the insect. It has good insecticidal effects on aphids, borers, stem borers and other crops such as fruit trees, cotton, vegetables, rice, rice, etc., is easy to degrade, and is non-polluting and non-toxic to the environment.

苦皮藤素具有驱避、拒食、胃毒及触杀作用,主要作用于昆虫的消化系统,能和中肠细胞质膜上的特异受体结合,从而破坏膜的结构,造成肠穿孔,昆虫大量失水而死亡。苦皮藤素既作用于神经与肌肉节点也作用于肌细胞,对昆虫飞行肌和体壁肌有强烈毒性,明显破坏肌细胞的质膜和内膜细胞,该要作用机理独特,不易产生抗药性。Paretin has the functions of repelling, antifeedant, stomach poisoning and contact killing. It mainly acts on the digestive system of insects. It can bind to specific receptors on the plasma membrane of midgut cells, thereby destroying the structure of the membrane, causing intestinal perforation, and killing a large number of insects. die by water. Paretin acts not only on nerve and muscle nodes but also on muscle cells. It has strong toxicity to insect flight muscles and body wall muscles, and obviously destroys the plasma membrane and inner membrane cells of muscle cells. The main mechanism of action is unique, and it is not easy to produce resistance Medicinal properties.

表面活性剂——脂肪醇聚氧乙烯醚不仅能够增加养分与水稻叶面的接触润湿度,有关研究也表明其对水稻叶面吸收硼、锰、腐植酸有促进作用。Surfactant-fatty alcohol polyoxyethylene ether can not only increase the contact wetness between nutrients and rice leaves, but related studies have also shown that it can promote the absorption of boron, manganese and humic acid by rice leaves.

发明内容Contents of the invention

本发明目的是提供一种含生物碱水稻腐植酸叶面肥及其制备方法。本发明巧妙地结合了肥料与植物源杀虫剂、养分增效剂,不仅满足水稻对养分的需求,而且在一定程度上有效地抑制了水稻生长期内出现的病虫害。The object of the present invention is to provide a rice humic acid foliar fertilizer containing alkaloids and a preparation method thereof. The invention skillfully combines the fertilizer, the botanical insecticide and the nutrient synergist, which not only satisfies the nutrient requirement of rice, but also effectively suppresses the diseases and insect pests occurring in the growth period of rice to a certain extent.

为了上述目的,本发明采用的技术方案如下:For above-mentioned purpose, the technical scheme that the present invention adopts is as follows:

一种含生物碱水稻腐植酸叶面肥,其特征在于,其配方由以下重量份的组分组成:腐植酸4-6、脂肪族聚氧乙烯醚20-30、生物碱0.1-1、1%苦皮藤素乳油8-15、尿素25-30、磷酸二氢钾4-6、硝酸钾15-20、硼酸10-15、硫酸锌5-10、硫酸锰5-10、硅酸钠10-15。An alkaloid-containing rice humic acid foliar fertilizer is characterized in that its formula consists of the following components in parts by weight: 4-6 parts by weight of humic acid, 20-30 parts of aliphatic polyoxyethylene ether, 0.1-1 part of alkaloid, 1 % Phyllanthine EC 8-15, urea 25-30, potassium dihydrogen phosphate 4-6, potassium nitrate 15-20, boric acid 10-15, zinc sulfate 5-10, manganese sulfate 5-10, sodium silicate 10 -15.

优选地,一种含生物碱腐植酸水稻叶面肥,其特征在于,其配方由以下重量份的组分组成:腐植酸5、脂肪族聚氧乙烯醚25、生物碱0.5、1%苦皮藤素乳油10、尿素27、磷酸二氢钾5、硝酸钾16、硼酸11.5、硫酸锌9、硫酸锰6.5、硅酸钠13。Preferably, a rice foliar fertilizer containing alkaloid humic acid is characterized in that its formula consists of the following components in parts by weight: humic acid 5, aliphatic polyoxyethylene ether 25, alkaloid 0.5, 1% bitter bark Rattan EC 10, urea 27, potassium dihydrogen phosphate 5, potassium nitrate 16, boric acid 11.5, zinc sulfate 9, manganese sulfate 6.5, sodium silicate 13.

本发明的含生物碱水稻腐植酸叶面肥的制备方法,包括以下步骤:The preparation method of the rice humic acid foliar fertilizer containing alkaloid of the present invention comprises the following steps:

(1)按配方称取硫酸锌、硫酸锰、硼酸、硅酸钠,加入适量的水中搅拌溶解,得澄清透明的营养液;(1) Weigh zinc sulfate, manganese sulfate, boric acid, sodium silicate according to the formula, add appropriate amount of water and stir to dissolve to obtain a clear and transparent nutrient solution;

(2)按配方称取腐植酸,加入适量的水溶解,得螯合剂溶液;(2) Take humic acid by formula, add appropriate amount of water to dissolve, and obtain chelating agent solution;

(3)将营养液与螯合剂溶液混合,搅拌均匀,进行螯合反应,得螯合反应液;按照配方称取尿素、磷酸二氢钾、硝酸钾、生物碱、1%苦皮藤素乳油加入螯合反应液,搅拌后调节pH,再加入脂肪族聚氧乙烯醚搅拌均匀后去水成粉末。(3) Mix the nutrient solution with the chelating agent solution, stir evenly, and carry out the chelating reaction to obtain the chelating reaction solution; take urea, potassium dihydrogen phosphate, potassium nitrate, alkaloids, and 1% picrophyllin emulsifiable concentrate according to the formula Add the chelating reaction solution, adjust the pH after stirring, then add aliphatic polyoxyethylene ether, stir evenly, and then dehydrate to form a powder.

本发明的含生物碱水稻腐殖酸叶面肥,每亩每次用100g,加水30公斤喷施于水稻叶面即可。The alkaloid-containing paddy humic acid foliage fertilizer of the present invention can be sprayed on paddy paddy leaves with 100 g per mu each time and 30 kg of water.

全生育期喷施3次:Spray 3 times during the whole growth period:

第一次:苗期,补充肥力、促根壮苗、防止死棵、苗强苗壮,抗旱;The first time: at the seedling stage, supplement fertility, promote root and seedling growth, prevent dead trees, make seedlings strong, and resist drought;

第二次:拔节期,防止倒伏,防治病害和干热风的发生;The second time: jointing stage, prevent lodging, prevent diseases and dry hot wind;

第三次:扬花期-灌浆期,促进水稻成熟,改善品质,提高产量,防治早衰,提高千粒重。The third time: flowering stage-filling stage, to promote rice maturity, improve quality, increase yield, prevent premature aging, and increase thousand-grain weight.

本发明巧妙地结合了肥料与植物源杀虫剂、养分增效剂,不仅满足水稻对养分的需求,而且在一定程度上有效地抑制了水稻生长期内出现的病虫害。在提高肥料利用率的前提下又能降低化工农药的使用,达到科学施肥、科学防止病虫害的发生,降低对环境的污染,提高作物产量和改善品质。The invention skillfully combines the fertilizer, the botanical insecticide and the nutrient synergist, which not only satisfies the nutrient requirement of rice, but also effectively suppresses the diseases and insect pests occurring in the growth period of rice to a certain extent. On the premise of improving the utilization rate of fertilizers, it can reduce the use of chemical pesticides, achieve scientific fertilization, scientifically prevent the occurrence of diseases and insect pests, reduce environmental pollution, increase crop yield and improve quality.

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下实施例对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用于解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention clearer, the following examples further describe the present invention in detail. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

实施例1Example 1

一种含生物碱水稻腐植酸叶面肥,其配方由以下重量(g)的组分组成:腐植酸4、脂肪族聚氧乙烯醚20、生物碱0.1、1%苦皮藤素乳油8、尿素25、磷酸二氢钾4、硝酸钾15、硼酸10、硫酸锌5、硫酸锰5、硅酸钠10。A rice humic acid foliar fertilizer containing alkaloids, the formula of which consists of the following components by weight (g): humic acid 4, aliphatic polyoxyethylene ether 20, alkaloids 0.1, 1% pachyphyllin emulsifiable concentrate 8, Urea 25, potassium dihydrogen phosphate 4, potassium nitrate 15, boric acid 10, zinc sulfate 5, manganese sulfate 5, sodium silicate 10.

该生物碱水稻腐植酸叶面肥的制备方法,包括以下步骤:The preparation method of the alkaloid rice humic acid foliar fertilizer comprises the following steps:

(1)按配方称取硫酸锌、硫酸锰、硼酸、硅酸钠,加入适量的水中搅拌溶解,得澄清透明的营养液;(1) Weigh zinc sulfate, manganese sulfate, boric acid, sodium silicate according to the formula, add appropriate amount of water and stir to dissolve to obtain a clear and transparent nutrient solution;

(2)按配方称取腐植酸,加入适量的水溶解,得螯合剂溶液;(2) Take humic acid by formula, add appropriate amount of water to dissolve, and obtain chelating agent solution;

(3)将营养液与螯合剂溶液混合,搅拌均匀,进行螯合反应,得螯合反应液;按照配方称取尿素、磷酸二氢钾、硝酸钾、生物碱、1%苦皮藤素乳油加入螯合反应液,搅拌后调节pH,再加入脂肪族聚氧乙烯醚搅拌均匀后去水成粉末。(3) Mix the nutrient solution with the chelating agent solution, stir evenly, and carry out the chelating reaction to obtain the chelating reaction solution; take urea, potassium dihydrogen phosphate, potassium nitrate, alkaloids, and 1% picrophyllin emulsifiable concentrate according to the formula Add the chelating reaction solution, adjust the pH after stirring, then add aliphatic polyoxyethylene ether, stir evenly, and then dehydrate to form a powder.

实施例2Example 2

一种含生物碱水稻腐植酸叶面肥,其配方由以下重量(g)的组分组成:腐植酸5、脂肪族聚氧乙烯醚25、生物碱0.5、1%苦皮藤素乳油10、尿素27、磷酸二氢钾5、硝酸钾16、硼酸11.5、硫酸锌9、硫酸锰6.5、硅酸钠13。A rice humic acid foliar fertilizer containing alkaloids, the formula of which is composed of the following components by weight (g): 5 humic acids, 25 aliphatic polyoxyethylene ethers, 0.5 alkaloids, 10 1% picroderm emulsifiable concentrates, Urea 27, potassium dihydrogen phosphate 5, potassium nitrate 16, boric acid 11.5, zinc sulfate 9, manganese sulfate 6.5, sodium silicate 13.

制备方法同实施例1。The preparation method is the same as in Example 1.

实施例3Example 3

一种含生物碱水稻腐植酸叶面肥,其配方由以下重量(g)的组分组成:腐植酸6、脂肪族聚氧乙烯醚30、生物碱1、1%苦皮藤素乳油15、尿素30、磷酸二氢钾6、硝酸钾20、硼酸15、硫酸锌10、硫酸锰10、硅酸钠15。A rice humic acid foliar fertilizer containing alkaloids, the formula of which is composed of the following components by weight (g): 6 humic acids, 30 aliphatic polyoxyethylene ethers, 1 alkaloids, 1% phyllotine emulsifiable concentrate 15, Urea 30, potassium dihydrogen phosphate 6, potassium nitrate 20, boric acid 15, zinc sulfate 10, manganese sulfate 10, sodium silicate 15.

制备方法同实施例1。The preparation method is the same as in Example 1.

试验基本情况及结果Basic situation and results of the test

试验地概况:安徽农业大学高新农业技术科技园,耕作制度为1年2熟,试验前土壤有机质18.78g/kg、全氮1.03g/kg、有效磷17.37g/kg、速效钾123.61g/kg、pH为7.07。土壤肥力水平中等。General situation of the test site: Anhui Agricultural University High-tech Agricultural Technology Science and Technology Park, the farming system is 1 year and 2 crops, before the test, the soil organic matter is 18.78g/kg, total nitrogen is 1.03g/kg, available phosphorus is 17.37g/kg, and available potassium is 123.61g/kg , pH is 7.07. The soil fertility level is medium.

供试材料:供试肥料为含生物碱水稻腐植酸叶面肥(实施例2);供试水稻为安徽地区常用品种:杂交水稻汕优63Test material: the test fertilizer is rice humic acid foliar fertilizer containing alkaloid (embodiment 2); the test rice is a common variety in Anhui: hybrid rice Shanyou 63

田间管理:每公顷施纯氮225kg、氧化钾90kg、五氧化二磷90kg。六月中旬移栽,栽插密度27万穴/hm2Field management: apply 225kg of pure nitrogen, 90kg of potassium oxide, and 90kg of phosphorus pentoxide per hectare. Transplant in mid-June with a planting density of 270,000 holes/hm 2 .

测定指标:穗长、有效穗数、结实率、穗粒数、千粒重、观察水稻病虫害情况Measuring indicators: panicle length, effective panicle number, seed setting rate, grain number per panicle, thousand-grain weight, observation of rice diseases and insect pests

试验设计:采用随机区组试验,在苗期、拔节期、扬花期-灌浆期用生产的水稻腐殖酸叶面肥稀释后喷施,同时对照组喷施清水,三次重复,小区面积10m2,行距25cm,同时设置保护行。试验于2014年6月上旬开始,各处理栽培及田间管理措施完全一致,于2014年10月上旬收货测试。Experimental design: a randomized block experiment was adopted, and the produced rice humic acid foliar fertilizer was diluted and sprayed at the seedling stage, jointing stage, flowering stage-filling stage, and the control group was sprayed with clear water at the same time, repeated three times, with a plot area of 10m 2 , the line spacing is 25cm, and the protective line is set at the same time. The test started in early June 2014, and the cultivation and field management measures of each treatment were completely consistent. The test was received in early October 2014.

实施效果:水稻收割后,测试结果见下表:Implementation effect: After the rice harvest, the test results are shown in the table below:

试验组与对照组相比,增产55.6kg/667m2,增幅11.1%,平均穗长增加0.7cm,平均穗粒数增加9.6个,千粒重增加1.94g,病虫害发生率减少49.5%。说明施用本发明含生物碱水稻腐殖酸叶面肥可以显著促进水稻生长,减少病虫害发生,提高水稻产量和改善水稻品质,具有重要的经济效益。Compared with the control group, the experimental group increased the yield by 55.6kg/667m 2 , an increase of 11.1%, the average ear length increased by 0.7cm, the average grain number per ear increased by 9.6, the thousand-grain weight increased by 1.94g, and the incidence of diseases and insect pests decreased by 49.5%. It shows that the application of the alkaloid-containing rice humic acid foliar fertilizer of the present invention can significantly promote the growth of rice, reduce the occurrence of diseases and insect pests, increase the yield of rice and improve the quality of rice, and has important economic benefits.

Claims (3)

1.一种含生物碱水稻腐植酸叶面肥,其特征在于,其配方由以下重量份的组分组成:腐植酸4-6、脂肪族聚氧乙烯醚20-30、生物碱0.1-1、1%苦皮藤素乳油8-15、尿素25-30、磷酸二氢钾4-6、硝酸钾15-20、硼酸10-15、硫酸锌5-10、硫酸锰5-10、硅酸钠10-15。 1. An alkaloid-containing rice humic acid foliar fertilizer is characterized in that its formula is made up of the following components by weight: humic acid 4-6, aliphatic polyoxyethylene ether 20-30, alkaloid 0.1-1 , 1% picrophyllin EC 8-15, urea 25-30, potassium dihydrogen phosphate 4-6, potassium nitrate 15-20, boric acid 10-15, zinc sulfate 5-10, manganese sulfate 5-10, silicic acid Sodium 10-15. 2.根据权利要求1所述的含生物碱水稻腐植酸叶面肥,其特征在于,其配方由以下重量份的组分组成:腐植酸5、脂肪族聚氧乙烯醚25、生物碱0.5、1%苦皮藤素乳油10、尿素27、磷酸二氢钾5、硝酸钾16、硼酸11.5、硫酸锌9、硫酸锰6.5、硅酸钠13。 2. the alkaloid-containing rice humic acid foliar fertilizer according to claim 1 is characterized in that its formula is made up of the following components by weight: humic acid 5, aliphatic polyoxyethylene ether 25, alkaloid 0.5, 1% pharethin EC 10, urea 27, potassium dihydrogen phosphate 5, potassium nitrate 16, boric acid 11.5, zinc sulfate 9, manganese sulfate 6.5, sodium silicate 13. 3.根据权利要求1或2所述的含生物碱水稻腐植酸叶面肥的制备方法,其特征在于,包括以下步骤: 3. the preparation method of alkaloid-containing rice humic acid foliar fertilizer according to claim 1 or 2, is characterized in that, comprises the following steps:     (1)按配方称取硫酸锌、硫酸锰、硼酸、硅酸钠,加入适量的水中搅拌溶解,得澄清透明的营养液; (1) Weigh zinc sulfate, manganese sulfate, boric acid, and sodium silicate according to the formula, add an appropriate amount of water and stir to dissolve to obtain a clear and transparent nutrient solution;     (2)按配方称取腐植酸,加入适量的水溶解,得螯合剂溶液; (2) Weigh humic acid according to the formula, add an appropriate amount of water to dissolve, and obtain a chelating agent solution;     (3)将营养液与螯合剂溶液混合,搅拌均匀,进行螯合反应,得螯合反应液; (3) Mix the nutrient solution and the chelating agent solution, stir evenly, and carry out the chelation reaction to obtain the chelation reaction solution;     (4)按照配方称取尿素、磷酸二氢钾、硝酸钾、生物碱、1%苦皮藤素乳油加入螯合反应液,搅拌后调节pH,再加入脂肪族聚氧乙烯醚搅拌均匀后去水成粉末。 (4) According to the formula, weigh urea, potassium dihydrogen phosphate, potassium nitrate, alkaloids, and 1% pachyphyllin emulsifiable concentrate and add them to the chelation reaction solution, adjust the pH after stirring, then add aliphatic polyoxyethylene ether and stir evenly before removing Water into powder.
CN201510221601.XA 2015-04-30 2015-04-30 Rice humic acid leaf fertilizer containing alkaloid, and preparation method of leaf fertilizer Pending CN104803797A (en)

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CN107244993A (en) * 2017-04-26 2017-10-13 上海联业农业科技有限公司 Rhamnolipid siliceous fertilizer and preparation method thereof
CN107739238A (en) * 2017-10-20 2018-02-27 刘青亚 A kind of production method of the chelating type foliar fertilizer containing Celastrus angulatus
CN111848298A (en) * 2020-07-31 2020-10-30 陕西科技大学 A kind of alkaloid-containing humic acid insect-proof and antibacterial silicon fertilizer and preparation method thereof
CN113213999A (en) * 2021-04-30 2021-08-06 华强化工集团股份有限公司 Shrimp-rice mode leaf fertilizer for rice and preparation method thereof
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105646038A (en) * 2016-03-10 2016-06-08 河南力浮科技有限公司 Production method of nano humic acid chelation iron fertilizer
CN107244993A (en) * 2017-04-26 2017-10-13 上海联业农业科技有限公司 Rhamnolipid siliceous fertilizer and preparation method thereof
CN107739238A (en) * 2017-10-20 2018-02-27 刘青亚 A kind of production method of the chelating type foliar fertilizer containing Celastrus angulatus
CN111848298A (en) * 2020-07-31 2020-10-30 陕西科技大学 A kind of alkaloid-containing humic acid insect-proof and antibacterial silicon fertilizer and preparation method thereof
CN113213999A (en) * 2021-04-30 2021-08-06 华强化工集团股份有限公司 Shrimp-rice mode leaf fertilizer for rice and preparation method thereof
CN113213999B (en) * 2021-04-30 2023-01-17 华强化工集团股份有限公司 A kind of foliage fertilizer for rice with shrimp and rice pattern and preparation method thereof
CN114456005A (en) * 2022-02-23 2022-05-10 兴安盟博源化学有限公司 Special humic acid foliar fertilizer for rice as well as preparation method and use method thereof

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Application publication date: 20150729