CN107244993A - Rhamnolipid siliceous fertilizer and preparation method thereof - Google Patents
Rhamnolipid siliceous fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN107244993A CN107244993A CN201710281518.0A CN201710281518A CN107244993A CN 107244993 A CN107244993 A CN 107244993A CN 201710281518 A CN201710281518 A CN 201710281518A CN 107244993 A CN107244993 A CN 107244993A
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- Prior art keywords
- rhamnolipid
- fertilizer
- kilograms
- siliceous fertilizer
- water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of rhamnolipid siliceous fertilizer, wherein, including:Rhamnolipid 0.1 0.5%, stabilizer 0.02%-0.05%, potassium silicate 5% 10%, sodium metasilicate 20 25%, surplus is water.The invention also discloses a kind of preparation method of rhamnolipid siliceous fertilizer, wherein, water is put into a kettle. to be heated in advance;Start stirring in reactor, be slowly added to sodium metasilicate, potassium silicate, rhamnolipid, stabilizer;The chuck of reactor is heated to starting insulation after a design temperature;Soaking time reaches a setting time value, stops stirring, is cooled to room temperature, and dispensed.Chelated by using silicate and rhamnolipid, can play good cushioning effect to its strong basicity, and can effectively improve the stability of silicate ion, base, which applies, rush silicate ion when applying not easily runs off, and extends fertilizer efficiency, raising utilization rate of fertilizer.
Description
Technical field
The present invention relates to a kind of siliceous fertilizer, more particularly to a kind of rhamnolipid siliceous fertilizer and preparation method thereof.
Background technology
Silicon is increasingly paid attention to the trophism of crops by world agriculture scientific and technological circle, and Japan is that research siliceous fertilizer is earliest
One of country, element silicon is now classified as to the indispensable element of crops, and ranking is after n-p-k element, as crops
The fourth-largest element.After largely nitrogen, phosphorus, potash fertilizer is applied, to make healthy growth of crops, the soda-silica slags of Natural Circulation offer are provided
It far can not meet, therefore soda-silica slags, just into the limiting factor of plant growth, science supplement soda-silica slags turn into existing
For the focus of attention of agricultural production.Applying silicon fertilizer can not only improve yield, improved soil, and can be obviously improved the product of agricultural product
Matter, plays an important role during crop production, and has Resistant, drought-resistant, promotion root growth and development, promotees
Enter effective utilization of nutrient.
China is that fertilizer production big country is also fertilizer consumption big country, it is well known that the utilization rate of fertilizer is generally relatively low.Mesh
Preceding in the market Water-soluble silicon fertilizer is mainly sodium silicate salt and silicic acid sylvite, and available silicon content is higher, with quick-acting, but sprays plant
Thing blade face is easy to run off after being manured into soil, and fertilizer efficiency is short, low by plant utilization rate.
In view of the deficiency of existing product, it is an object of the invention to provide a kind of liquid silicon fertilizer and its production technology, it is intended to
Solve the problem of existing siliceous fertilizer its absorptivity, stability, fertilizer efficiency have much room for improvement.
The content of the invention
The invention discloses a kind of rhamnolipid siliceous fertilizer and preparation method thereof, to solve its absorption of siliceous fertilizer in the prior art
The problem of rate, stability, fertilizer efficiency have much room for improvement.
The above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of rhamnolipid siliceous fertilizer, wherein, including:Rhamnolipid 0.1-0.5%, stabilizer 0.02%-0.05%, potassium silicate 5%--
10%th, sodium metasilicate 20-25%, surplus is water.
A kind of preparation method of rhamnolipid siliceous fertilizer, wherein, water is put into a kettle. to be heated in advance;In reactor
Start stirring, be slowly added to sodium metasilicate, potassium silicate, rhamnolipid, stabilizer;The chuck of reactor is heated to after a design temperature
Start insulation;Soaking time reaches a setting time value, stops stirring, is cooled to room temperature, and dispensed.
The preparation method of rhamnolipid siliceous fertilizer as described above, wherein, 479 kilograms of water is put into a kettle., is added in advance
Hot temperature is 60 degrees Celsius;450 kilograms of sodium metasilicate, 70 kilograms of potassium silicate, 1 kilogram of rhamnolipid, 0.02 kilogram of stabilizer;Setting
Temperature is 80 degrees Celsius;Setting time value is 4 hours.
The preparation method of rhamnolipid siliceous fertilizer as described above, wherein, 495 kilograms of water is put into a kettle., is added in advance
Hot temperature is 60 degrees Celsius;420 kilograms of sodium metasilicate, 80 kilograms of potassium silicate, 5 kilograms of rhamnolipid, 0.05 kilogram of stabilizer;Setting
Temperature is 80 degrees Celsius;Setting time value is half an hour.
In summary, by adopting the above-described technical solution, the present invention solves its absorptivity of siliceous fertilizer, steady in the prior art
The problem of qualitative, fertilizer efficiency has much room for improvement, chelates by using silicate and rhamnolipid, its strong basicity can be played well
Cushioning effect, and can effectively improve the stability of silicate ion, base, which applies, rush silicate ion when applying not easily runs off, and extends
Fertilizer efficiency, improves utilization rate of fertilizer.Further, rhamnolipid in the basic conditions, ionizes out Rh- and H+ performance, with alkalescence
OH- in soil is neutralized, and improves the alkalescence of soil, so as to relax soil hardening.Rhamnolipid biological surface activator can be made
For wetting agent, make an addition in siliceous fertilizer, adsorbed with hydrophobic group by dispersion force on the surface of wax coat, hydrophilic group is then stretched into solution
Form oriented attachment film and instead of hydrophobic wax coat, improve foliar fertilizer in the wetting situation of wax coat, fertilizer is fully spread
Exhibition, promotes Fertilizer nutrient material to be absorbed and used to greatest extent.Further, this product rhamnolipid and silicate are respectively provided with
The effect of repairing heavy metal in soil, and this product has controlling plant diseases, strengthens the resistance against diseases of plant.
Embodiment
The present invention is described further with reference to embodiment:
The invention discloses a kind of rhamnolipid siliceous fertilizer, wherein, including:Rhamnolipid 0.1-0.5%, stabilizer 0.02%-
0.05%th, potassium silicate 5%--10%, sodium metasilicate 20-25%, surplus is water.
Rhamnolipid used in the present invention is lived as a kind of biosurfactant with stronger surface and interface
Property, low toxicity, biodegradable are widely used in oil exploitation, environmental protection, medication chemistry, food and agriculturally.It is this kind of
Biosurfactant is substantially combined into by carbohydrate and long chain fatty acids or hydroxy fatty acid in covalent bond form,
With sugar for hydrophilic group, using aliphatic acid as hydrophobic group.Its chemical constitution is typically all to be made up of polar group and nonpolar base.
Plant leaf blade is all covered with coating of wax matter layer, blade surface is turned into a kind of diaphragm, and rhamnolipid biological surface is lived
Property agent make an addition in siliceous fertilizer, with hydrophobic group by dispersion force adsorb on the surface of wax coat, hydrophilic group then stretch into solution formed
Oriented attachment film instead of hydrophobic wax coat, improves foliar fertilizer in the wetting situation of wax coat, fertilizer is fully sprawled, promotees
Enter Fertilizer nutrient material to be absorbed and used to greatest extent.
Silicate is chelated with rhamnolipid, and good cushioning effect on the one hand can be played to its strong basicity, is on the other hand had
Effect improves the stability of silicate ion, and base applies, rush silicate ion when applying not easily runs off in soil, extends fertilizer efficiency, raising
Utilization rate of fertilizer.
The invention also discloses a kind of preparation method of rhamnolipid siliceous fertilizer, wherein, water is put into a kettle. to carry out in advance
First heat;Start stirring in reactor, be slowly added to sodium metasilicate, potassium silicate, rhamnolipid, stabilizer;The chuck of reactor adds
Start insulation after heat a to design temperature;Soaking time reaches a setting time value, stops stirring, is cooled to room temperature, and carry out
Packing.
Further, in one embodiment of the invention, the present invention can specifically be used:Water is put into a kettle.
479 kilograms, advance heating-up temperature is 60 degrees Celsius;450 kilograms of sodium metasilicate, 70 kilograms of potassium silicate, 1 kilogram of rhamnolipid is stable
0.02 kilogram of agent;Design temperature is 80 degrees Celsius;Setting time value is 4 hours.
Further, in another embodiment of the present invention, the present invention can specifically be used:Water is put into a kettle.
495 kilograms, advance heating-up temperature is 60 degrees Celsius;420 kilograms of sodium metasilicate, 80 kilograms of potassium silicate, 5 kilograms of rhamnolipid is stable
0.05 kilogram of agent;Design temperature is 80 degrees Celsius;Setting time value is half an hour.
Specifically, the specific implementation effect in order to verify the present invention:Experiment sets 4 processing, is repeated 3 times, plot area
For 50 m2, random district's groups arrangement, minizone ridging is isolated, and sets protection to go.Each process content is as follows:
Processing 1:Conventional fertilizer application+spray clear water
Processing 2:Conventional fertilizer application+spray equivalent rhamnolipid
Processing 3:Conventional fertilizer application+spray the equal conventional siliceous fertilizer of silicone content.
Processing 4:Conventional fertilizer application+spray equivalent product of the present invention.
Apply every mu of g biodegradable chelating agent of paddy field application by throwing them 600 by spraying, application in two dressings, for the first time using when
Between be that before rice transplanting during 1-2 days site preparations, amount of application is 200 g/ mus;Second fertilising be 30-40 days after rice transplanting,
Amount of application is 400 g/ mus.Equivalent rhamnolipid volume increase 2.5% is sprayed, 5.6% is increased production using the conventional siliceous fertilizer rice yield of equivalent, its
Silicone content is 22g/Kg in middle stalk stem.
Using rice yield increase by 9.1% after equivalent product of the present invention, silicone content is 35g/Kg wherein in stalk.
Specifically, the present invention additionally uses in the following manner, implementation result is further verified:Experiment sets 4 processing, weight
Multiple 3 times, plot area is 50 m2, random district's groups arrangement, the isolation of minizone ridging, and sets protection to go.Each process content is such as
Under:
Processing 1:Clear water is applied in conventional fertilizer application+punching
Processing 2:Equivalent rhamnolipid is applied in conventional fertilizer application+punching
Processing 3:The equal conventional siliceous fertilizer of silicone content is applied in conventional fertilizer application+punching.
Processing 4:Equivalent product of the present invention is applied in conventional fertilizer application+punching.
Every mu of g biodegradable chelating agent of paddy field application by throwing them 2000 is applied by punching, application in two dressings is applied for the first time
Time is that before rice transplanting during 1-2 days site preparations, amount of application is 1000 g/ mus;Second of fertilising is the 30-40 after rice transplanting
My god, amount of application is 1000 g/ mus.Equivalent rhamnolipid volume increase 2.4% is sprayed, is increased production using the conventional siliceous fertilizer rice yield of equivalent
5.8%, silicone content is 25g/Kg wherein in stalk stem.Using rice yield increase by 8.9%, wherein stalk after equivalent product of the present invention
Middle silicone content is 36g/Kg.
Sum it up, fertilizer produced by the invention shows through agricultural experiment, its effect of increasing production is not only better than single group of equivalent
The rhamnolipid and siliceous fertilizer divided, and higher than both rate of growth sums, illustrate that rhamnolipid and siliceous fertilizer have good collaboration
Effect.Absorption of the plant to silicon is also relatively significantly increased using the conventional siliceous fertilizer of equivalent.And carried using rhamnolipid and siliceous fertilizer compounding
The utilization rate of high silicon is not disclosed in the prior art, and result on trial shows that the total effect of increasing production of siliceous fertilizer produced by the invention is more than equivalent
Rhamnolipid distinguishes the summation of trial effect with siliceous fertilizer.
Claims (4)
1. a kind of rhamnolipid siliceous fertilizer, it is characterised in that including:Rhamnolipid 0.1-0.5%, stabilizer 0.02%-0.05%, silicon
Sour potassium 5%--10%, sodium metasilicate 20-25%, surplus is water.
2. a kind of preparation method of rhamnolipid siliceous fertilizer, it is characterised in that put into water in a kettle. and heated in advance;Reaction
Start stirring in kettle, be slowly added to sodium metasilicate, potassium silicate, rhamnolipid, stabilizer;The chuck of reactor is heated to a setting temperature
Start insulation after degree;Soaking time reaches a setting time value, stops stirring, is cooled to room temperature, and dispensed.
3. the preparation method of rhamnolipid siliceous fertilizer according to claim 2, it is characterised in that put into water in a kettle.
479 kilograms, advance heating-up temperature is 60 degrees Celsius;450 kilograms of sodium metasilicate, 70 kilograms of potassium silicate, 1 kilogram of rhamnolipid is stable
0.02 kilogram of agent;Design temperature is 80 degrees Celsius;Setting time value is 4 hours.
4. the preparation method of rhamnolipid siliceous fertilizer according to claim 2, it is characterised in that put into water in a kettle.
495 kilograms, advance heating-up temperature is 60 degrees Celsius;420 kilograms of sodium metasilicate, 80 kilograms of potassium silicate, 5 kilograms of rhamnolipid is stable
0.05 kilogram of agent;Design temperature is 80 degrees Celsius;Setting time value is half an hour.
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CN201710281518.0A CN107244993A (en) | 2017-04-26 | 2017-04-26 | Rhamnolipid siliceous fertilizer and preparation method thereof |
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CN201710281518.0A CN107244993A (en) | 2017-04-26 | 2017-04-26 | Rhamnolipid siliceous fertilizer and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108530187A (en) * | 2018-06-12 | 2018-09-14 | 安徽省国壬农业科技有限公司 | A kind of water-soluble silicon element fertilizer and preparation method thereof containing organosilicon |
US20190037844A1 (en) * | 2017-06-19 | 2019-02-07 | Keith DeSanto | Cure and prevent diseases in plants, bushes and trees using rhamnolipid |
CN110526772A (en) * | 2019-08-30 | 2019-12-03 | 广东省生物工程研究所(广州甘蔗糖业研究所) | The antibacterial fertilizer and preparation method thereof for preventing and treating crop bacterial wilt |
CN114702353A (en) * | 2022-03-14 | 2022-07-05 | 湖南师范大学 | Rice hull ash liquid silicon fertilizer, preparation and application methods thereof, and rice hull ash low-temperature carbonization furnace |
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CN1785922A (en) * | 2004-12-06 | 2006-06-14 | 邵建华 | Amino acid silicon foliage fertilizer |
CN101519323A (en) * | 2009-04-16 | 2009-09-02 | 齐绍春 | Soluble silicon-nitrogen-kalium liquid fertilizer |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20190037844A1 (en) * | 2017-06-19 | 2019-02-07 | Keith DeSanto | Cure and prevent diseases in plants, bushes and trees using rhamnolipid |
CN108530187A (en) * | 2018-06-12 | 2018-09-14 | 安徽省国壬农业科技有限公司 | A kind of water-soluble silicon element fertilizer and preparation method thereof containing organosilicon |
CN110526772A (en) * | 2019-08-30 | 2019-12-03 | 广东省生物工程研究所(广州甘蔗糖业研究所) | The antibacterial fertilizer and preparation method thereof for preventing and treating crop bacterial wilt |
CN114702353A (en) * | 2022-03-14 | 2022-07-05 | 湖南师范大学 | Rice hull ash liquid silicon fertilizer, preparation and application methods thereof, and rice hull ash low-temperature carbonization furnace |
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