CN108530187A - A kind of water-soluble silicon element fertilizer and preparation method thereof containing organosilicon - Google Patents
A kind of water-soluble silicon element fertilizer and preparation method thereof containing organosilicon Download PDFInfo
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- CN108530187A CN108530187A CN201810619504.XA CN201810619504A CN108530187A CN 108530187 A CN108530187 A CN 108530187A CN 201810619504 A CN201810619504 A CN 201810619504A CN 108530187 A CN108530187 A CN 108530187A
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- China
- Prior art keywords
- water
- organosilicon
- soluble silicon
- silicon element
- modified methyl
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
Abstract
The invention discloses a kind of water-soluble silicon element fertilizer and preparation method thereof containing organosilicon, includes the raw material of following parts by weight:0.1 0.3 parts of 7.5 8.7 parts of water-soluble silicon Element Solution, 1 1.7 parts of modified methyl trisiloxanes organosilicon and coupling agent, modified methyl trisiloxanes organosilicon is by professional production producer, by the silicon oxygen bond of the macromolecule organic silicon molecular resin chain, carries out chain rupture modification and obtain.Raw material sources of the present invention are extensive, the finished product good water solubility of preparation, it is easy to be absorbed by plants, stability is strong, the phenomenon that not having polymeric precipitation or being agglomerated by electrolyte, finished product of the invention can by spraying, trickle irrigation, punching the various ways such as apply and used, and foliage-spray has unique superpower dispersibility and wellability, the using effect for enhancing product, expands use scope.
Description
Technical field
The present invention relates to a kind of fertilizer, specifically a kind of water-soluble silicon element fertilizer containing organosilicon.
Background technology
Element silicon is the second largest element that the earth is only second to oxygen, and the biology such as all people's class, animal and plant is all be unable to do without
The physiology of element silicon participates in, in recent years agricultural experts the study found that crop growth and cultivated land soil degeneration, with element silicon
Shortage has close relationship, especially the stalk toughness in the industrial crops such as gramineous crop and gourd, fruit and vegetable, disease-resistant drought resisting energy
The influences such as power, quality of agricultural product, photosynthesis, the mass color of fruit and increasing both production and income are notable.Siliceous fertilizer, which has become, promotes crops
The important composition of growth and soil improvement, many documents of importance have demonstration, repeat no more.
There are mainly two types of acquisition patterns for existing siliceous fertilizer:First, mineral raw material is obtained by high-temperature calcination, element silicon is in knot
The special construction of crystalline state is the invalid silicon that cannot be directly absorbed by crop root or blade, it is necessary to by for many years in the soil
Slowly conversion, could utilize, therefore fertilizer efficiency is extremely low, stability is very poor, cannot meet the requirement of crop and soil.Second is that by high-purity
The silica of degree is processed as nano level material and obtains, and silica is even worked into tens nanometers, is also to belong to after all
In the particle of small particle, the only very coarse crop of minority blades or root mao mao hole, could be penetrated by coarse pore
It in blade, and is transported in the conduit being also difficult in crop body, is even more difficult to be fixed in cell wall, more crops are because of leaf
Piece pore or Gen Maotai is small is difficult to be utilized.
Effective element silicon that crop can directly be absorbed and utilized, the element silicon of mainly single silicic acid form, but single silicic acid
Stability is extremely weak in aqueous solution, is easy self-polymerization or is agglomerated by electrolyte.Therefore solving soil and crop can directly inhale
The Water-soluble silicon fertilizer of receipts, it is necessary to the form that the performance being dissolved in water is stablized, but there has been no this types in market up to now
The product of type occurs.
Invention content
The purpose of the present invention is to provide a kind of water-soluble silicon element fertilizer containing organosilicon, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides the following technical solutions:
A kind of water-soluble silicon element fertilizer containing organosilicon, includes the raw material of following parts by weight:Water-soluble silicon Element Solution
0.1-0.3 parts of 7.5-8.7 parts, 1-1.7 parts of modified methyl trisiloxanes organosilicon and coupling agent, modified methyl trisiloxanes is organic
Silicon is, by the silicon oxygen bond of the macromolecule organic silicon molecular resin chain, to be carried out chain rupture modification by professional production producer and obtained.
As a further solution of the present invention:The structural formula of modified methyl trisiloxanes organosilicon is
As a further solution of the present invention:Water-soluble silicon Element Solution is that the silica of 85% or more purity exists
It is persistently calcined under 1900-2100 degrees Celsius 4-6 hours, will be dissolved in the water to obtain after the silica separation condensation of gasification, two
The mass fraction of silica in the solution is 22-26%.
The preparation method of the water-soluble silicon element fertilizer containing organosilicon, is as follows:
Step 1 prepares raw material:Proportionally prepare water-soluble silicon Element Solution, modified methyl trisiloxanes organosilicon and
Coupling agent;
Step 2, premix:Modified methyl trisiloxanes organosilicon and coupling agent are uniformly mixed, the first mixture is obtained;
Step 3, it is mixed eventually:First mixture and water-soluble silicon Element Solution are slowly stirred uniformly, uniformly compounds, obtains
Finished product.
As a further solution of the present invention:The mixing velocity of premix is 600-750rpm, and mixed mixing velocity is 90- eventually
120rpm。
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, and the finished product of preparation is water-soluble
It is good, it is easy to be absorbed by plants, stability is strong, and the phenomenon that cohesion without polymeric precipitation or by electrolyte, finished product of the invention can
By spraying, trickle irrigation, punching the various ways such as apply and used, and foliage-spray has unique superpower dispersibility and infiltration
Property, the using effect of product is enhanced, use scope is expanded.
Description of the drawings
Fig. 1 is the autgmentability comparison diagram of water-soluble silicon element fertilizer and common siliceous fertilizer containing organosilicon.
Fig. 2 is the effect of impregnation comparison diagram of water-soluble silicon element fertilizer and common siliceous fertilizer containing organosilicon.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of water-soluble silicon element fertilizer containing organosilicon, includes the raw material of following parts by weight:Water-soluble silicon Element Solution
0.1 part of 7.5 parts, 1 part of modified methyl trisiloxanes organosilicon and coupling agent, modified methyl trisiloxanes organosilicon are raw by profession
Producer is produced, by the silicon oxygen bond of the macromolecule organic silicon molecular resin chain, chain rupture modification is carried out and obtains.Three silica of modified methyl
The structural formula of alkane organosilicon is
The preparation method of the water-soluble silicon element fertilizer containing organosilicon, is as follows:
Step 1 prepares raw material:Proportionally prepare water-soluble silicon Element Solution, modified methyl trisiloxanes organosilicon and
Coupling agent;
Step 2, premix:Modified methyl trisiloxanes organosilicon and coupling agent are uniformly mixed under the rotating speed of 720rpm,
Obtain the first mixture;
Step 3, it is mixed eventually:First mixture is stirred evenly with water-soluble silicon Element Solution with the rotating speed of 105rpm, uniformly
Compounding, obtains finished product.
Embodiment 2
A kind of water-soluble silicon element fertilizer containing organosilicon, includes the raw material of following parts by weight:Water-soluble silicon Element Solution 8
0.2 part of part, 1.1 parts of modified methyl trisiloxanes organosilicon and coupling agent, modified methyl trisiloxanes organosilicon are raw by profession
Producer is produced, by the silicon oxygen bond of the macromolecule organic silicon molecular resin chain, chain rupture modification is carried out and obtains.Water-soluble silicon element is molten
Liquid is that the silica of 85% or more purity is persistently calcined 5 hours under 1980 degrees Celsius, and the silica separation of gasification is cold
It is dissolved in the water to obtain after solidifying, the mass fraction of silica in the solution is 24%.
The preparation method of the water-soluble silicon element fertilizer containing organosilicon, is as follows:
Step 1 prepares raw material:Proportionally prepare water-soluble silicon Element Solution, modified methyl trisiloxanes organosilicon and
Coupling agent;
Step 2, premix:Modified methyl trisiloxanes organosilicon and coupling agent are uniformly mixed with the rotating speed of 690rpm, obtained
To the first mixture;
Step 3, it is mixed eventually:First mixture is stirred evenly with water-soluble silicon Element Solution with the rotating speed of 90rpm, uniformly
Compounding, obtains finished product.
Embodiment 3
A kind of water-soluble silicon element fertilizer containing organosilicon, includes the raw material of following parts by weight:Water-soluble silicon Element Solution
0.3 part of 8.7 parts, 1.7 parts of modified methyl trisiloxanes organosilicon and coupling agent, modified methyl trisiloxanes organosilicon is by profession
The silicon oxygen bond of the macromolecule organic silicon molecular resin chain is carried out chain rupture modification and obtained by manufacturer.Three silicon of modified methyl
The structural formula of oxygen alkane organosilicon is
Water-soluble silicon Element Solution is that the silica of 85% or more purity is persistently calcined 6 hours under 2060 degrees Celsius, by gas
It is dissolved in the water to obtain after the silica separation condensation of change, the mass fraction of silica in the solution is 25%.
The preparation method of the water-soluble silicon element fertilizer containing organosilicon, is as follows:
Step 1 prepares raw material:Proportionally prepare water-soluble silicon Element Solution, modified methyl trisiloxanes organosilicon and
Coupling agent;
Step 2, premix:Modified methyl trisiloxanes organosilicon and coupling agent are uniformly mixed with the rotating speed of 750rpm, obtained
To the first mixture;
Step 3, it is mixed eventually:First mixture is stirred evenly with water-soluble silicon Element Solution with the rotating speed of 120rpm, uniformly
Compounding, obtains finished product.
Comparative example 1
Using common siliceous fertilizer as a comparison case 1.
The application product of 2 gram weights is put into A measuring cups;Take the common siliceous fertilizer of 2 gram weights to be put into B measuring cups, respectively in A and
200 milliliters of clear water is respectively poured into two measuring cups of B, is won two panels wild cabbage leaf in wild cabbage field at random, is placed into testing stand, respectively
With a glass bar in two measuring cups of A and B, a drop is dripped in dish leaf after respectively dipping in solution, is observed and recorded.
It observes that the solution of A measuring cups is spread rapidly in wild cabbage leaf, solution is uniformly being distributed within a large range,
And, there is good wellability at the back side that solution can be penetrated into wild cabbage leaf;The solution of B measuring cups does not become in wild cabbage leaf
Change or motionless, the not any diffusion effect and effect of impregnation of drops.
This shows that the product of the application has unique autgmentability and wellability, and leaf can be uniformly distributed and penetrate into blade
Inside piece, promotes element silicon quickly to absorb, improve the effective rate of utilization of element silicon.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (5)
1. a kind of water-soluble silicon element fertilizer containing organosilicon, which is characterized in that include the raw material of following parts by weight:Water-soluble silicon
0.1-0.3 parts of 7.5-8.7 parts of Element Solution, 1-1.7 parts of modified methyl trisiloxanes organosilicon and coupling agent, three silicon of modified methyl
Oxygen alkane organosilicon is that the silicon oxygen bond of the macromolecule organic silicon molecular resin chain is carried out chain rupture modification and obtained.
2. the water-soluble silicon element fertilizer according to claim 1 containing organosilicon, which is characterized in that the modified methyl three
The structural formula of siloxanes organosilicon is
3. the water-soluble silicon element fertilizer according to claim 1 containing organosilicon, which is characterized in that the water-soluble silicon member
Plain solution is that the silica of 85% or more purity is persistently calcined 4-6 hours under 1900-2100 degrees Celsius, by the dioxy of gasification
It is dissolved in the water to obtain after SiClx separation condensation, the mass fraction of silica in the solution is 22-26%.
4. a kind of preparation method of the water-soluble silicon element fertilizer as described in any one of claims 1-3 containing organosilicon, feature
It is, is as follows:
Step 1 prepares raw material:Proportionally prepare water-soluble silicon Element Solution, modified methyl trisiloxanes organosilicon and coupling
Agent;
Step 2, premix:Modified methyl trisiloxanes organosilicon and coupling agent are uniformly mixed, the first mixture is obtained;
Step 3, it is mixed eventually:First mixture and water-soluble silicon Element Solution are slowly stirred uniformly, uniformly compounds, obtains finished product.
5. the preparation method of the water-soluble silicon element fertilizer according to claim 4 containing organosilicon, which is characterized in that described
The mixing velocity of premix is 600-750rpm, and mixed mixing velocity is 90-120rpm eventually.
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Citations (6)
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CN101011062A (en) * | 2007-02-06 | 2007-08-08 | 张家港市骏博化工有限公司 | Organosilicon pesticide booster and preparing method thereof |
CN101402753A (en) * | 2008-10-31 | 2009-04-08 | 浙江七色鹿色母粒有限公司 | Begin-color flame-proof antistatic polyolefin master batch |
CN104772074A (en) * | 2015-04-22 | 2015-07-15 | 浙江润禾有机硅新材料有限公司 | Hydrolysis-resistant organosilicon surface active agent and preparation method thereof |
CN104844343A (en) * | 2015-04-17 | 2015-08-19 | 邹健 | Ecological organic fertilizer and preparation method thereof |
CN107244993A (en) * | 2017-04-26 | 2017-10-13 | 上海联业农业科技有限公司 | Rhamnolipid siliceous fertilizer and preparation method thereof |
CN107926974A (en) * | 2017-11-21 | 2018-04-20 | 浙江世佳科技有限公司 | Polyether-modified heptamethyltrisiloxane organosilicon is used to prepare the purposes of the pesticide of prevention crop pest |
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2018
- 2018-06-12 CN CN201810619504.XA patent/CN108530187A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101011062A (en) * | 2007-02-06 | 2007-08-08 | 张家港市骏博化工有限公司 | Organosilicon pesticide booster and preparing method thereof |
CN101402753A (en) * | 2008-10-31 | 2009-04-08 | 浙江七色鹿色母粒有限公司 | Begin-color flame-proof antistatic polyolefin master batch |
CN104844343A (en) * | 2015-04-17 | 2015-08-19 | 邹健 | Ecological organic fertilizer and preparation method thereof |
CN104772074A (en) * | 2015-04-22 | 2015-07-15 | 浙江润禾有机硅新材料有限公司 | Hydrolysis-resistant organosilicon surface active agent and preparation method thereof |
CN107244993A (en) * | 2017-04-26 | 2017-10-13 | 上海联业农业科技有限公司 | Rhamnolipid siliceous fertilizer and preparation method thereof |
CN107926974A (en) * | 2017-11-21 | 2018-04-20 | 浙江世佳科技有限公司 | Polyether-modified heptamethyltrisiloxane organosilicon is used to prepare the purposes of the pesticide of prevention crop pest |
Non-Patent Citations (3)
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Application publication date: 20180914 |