CN104788883A - High-hardness and high-gloss heat and flame resistant ABS plastic - Google Patents
High-hardness and high-gloss heat and flame resistant ABS plastic Download PDFInfo
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- CN104788883A CN104788883A CN201510205503.7A CN201510205503A CN104788883A CN 104788883 A CN104788883 A CN 104788883A CN 201510205503 A CN201510205503 A CN 201510205503A CN 104788883 A CN104788883 A CN 104788883A
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Abstract
The invention relates to high-hardness and high-gloss heat and flame resistant ABS plastic which comprises the following components: ABS resin, polyimide fiber, a diazo diphenylamine paraformaldehyde condensate, a polyisocyanate block polymer, silicone-modified polyurethane resin, 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline, styryl pyridinealdoximedimethyl sulfate salt, isobutyraldehyde, a curing agent, dipropylene glycol dimethyl ether, polyvinyl butanol, cadmium sulfoselenide, N-methylpyrrolidone, zinc ferrite, diketo-pyrrolo-pyrrole pigment, p-tert-butyl-cyclohexanon, cyclododecanone, gamma butyrolactone, barium sulfate, 1,2,3,4-cyclopentanetetracarboxylic acid, and deionized water. The high-hardness and high-gloss heat and flame resistant ABS plastic is high in hardness, has metallic gloss on the surface only, is high in abrasion resistance, and is heat and flame resisting.
Description
Technical field
The present invention relates to a kind of high-hardness high-light pool flame-proof heat-resistant ABS plastic.
Background technology
ABS resin plastic cement is that current output is maximum, most widely used polymkeric substance.It has good physical and mechanical property, and shock strength is higher, and chemical stability, electrical property are good, and finished product processing, machining property are good, and water-fast, inorganic salt, soda acid, be a kind of can the engineering materials of widespread use.But current ABS resin plastic cement still exists, and intensity is low, abrasion-resistant surface is poor, flame-proof heat-resistant performance is strong under extreme case, the shortcoming of surface gloss difference.
Summary of the invention
To achieve these goals, the present invention is by the following technical solutions: a kind of high-hardness high-light pool flame-proof heat-resistant ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Isobutyric aldehyde 2-8 part
Solidifying agent 8-12 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Cadmium sulfoselenide 7-15 part
N-Methyl pyrrolidone 1-4 part
Zinc ferrite 8-10 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-10 part
4-tbutylcyclohexanone 0.2-0.5 part
Cyclododecanone 0.2-0.5 part
Gamma-butyrolactone 2-5 part
Barium sulfate 10-15 part
1,2,3,4-pentamethylene tetracarboxylic acid 8-16 parts
Deionized water 10-20 part.
Preferably, described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.
Beneficial effect of the present invention:
1, polyimide fiber, between diazonium pentanoic poly-formaldehyde condensate, polymeric polyisocyanate block thing, organic silicon modified polyurethane resin four kinds of materials produce synergy, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 63%.
2, barium sulfate, stibazole methyl-sulfate salt composite, significantly promote the wear resistance of plastic surface, make surface of plastic products not easily occur cut.
3,6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline, isobutyric aldehyde, dimethyl ether, polyvinyl alcohol contracting butanols, 1,2,3,4-pentamethylene tetracarboxylic acid, cyclododecanone, the composite of 4-tbutylcyclohexanone create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, cadmium sulfoselenide, adding of zinc ferrite make plastic surface only have metalluster, adding of diketo pyrrolo-pyrrole pigment(DPP pigment), gamma-butyrolactone, N-Methyl pyrrolidone makes the bright spot of plastic surface, glossiness significantly promotes.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of high-hardness high-light pool flame-proof heat-resistant ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polyimide fiber 8 parts
To diazonium pentanoic poly-formaldehyde condensate 15 parts
Polymeric polyisocyanate block thing 5 parts
Organic silicon modified polyurethane resin 15 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10 parts
Stibazole methyl-sulfate salt 3 parts
Isobutyric aldehyde 2 parts
8 parts, solidifying agent
Dimethyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 7 parts
N-Methyl pyrrolidone 1 part
Zinc ferrite 8 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8 parts
4-tbutylcyclohexanone 0.2 part
Cyclododecanone 0.2 part
Gamma-butyrolactone 2 parts
10 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 8 parts
Deionized water 10 parts.
Embodiment 2:
A kind of high-hardness high-light pool flame-proof heat-resistant ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 100 parts
Polyimide fiber 20 parts
To diazonium pentanoic poly-formaldehyde condensate 30 parts
Polymeric polyisocyanate block thing 15 parts
Organic silicon modified polyurethane resin 25 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 20 parts
Stibazole methyl-sulfate salt 6 parts
Isobutyric aldehyde 8 parts
12 parts, solidifying agent
Dimethyl ether 4 parts
4 parts, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 15 parts
N-Methyl pyrrolidone 4 parts
Zinc ferrite 10 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 10 parts
4-tbutylcyclohexanone 0.5 part
Cyclododecanone 0.5 part
Gamma-butyrolactone 5 parts
15 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 16 parts
Deionized water 20 parts.
Embodiment 3:
A kind of high-hardness high-light pool flame-proof heat-resistant ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polyimide fiber 10 parts
To diazonium pentanoic poly-formaldehyde condensate 20 parts
Polymeric polyisocyanate block thing 10 parts
Organic silicon modified polyurethane resin 20 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 15 parts
Stibazole methyl-sulfate salt 5 parts
Isobutyric aldehyde 6 parts
10 parts, solidifying agent
Dimethyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 10 parts
N-Methyl pyrrolidone 2 parts
Zinc ferrite 9 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 9 parts
4-tbutylcyclohexanone 0.3 part
Cyclododecanone 0.4 part
Gamma-butyrolactone 3 parts
12 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 10 parts
Deionized water 15 parts.
Solidifying agent described in above-described embodiment 1-3 is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
Claims (2)
1. a high-hardness high-light pool flame-proof heat-resistant ABS plastic, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Isobutyric aldehyde 2-8 part
Solidifying agent 8-12 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Cadmium sulfoselenide 7-15 part
N-Methyl pyrrolidone 1-4 part
Zinc ferrite 8-10 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-10 part
4-tbutylcyclohexanone 0.2-0.5 part
Cyclododecanone 0.2-0.5 part
Gamma-butyrolactone 2-5 part
Barium sulfate 10-15 part
1,2,3,4-pentamethylene tetracarboxylic acid 8-16 parts
Deionized water 10-20 part.
2. high-hardness high-light pool according to claim 1 flame-proof heat-resistant ABS plastic, is characterized in that: described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510205503.7A CN104788883A (en) | 2015-04-28 | 2015-04-28 | High-hardness and high-gloss heat and flame resistant ABS plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510205503.7A CN104788883A (en) | 2015-04-28 | 2015-04-28 | High-hardness and high-gloss heat and flame resistant ABS plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104788883A true CN104788883A (en) | 2015-07-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510205503.7A Pending CN104788883A (en) | 2015-04-28 | 2015-04-28 | High-hardness and high-gloss heat and flame resistant ABS plastic |
Country Status (1)
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103232672A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | Modified ABS high temperature resistant high polymer material |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
| CN103740040A (en) * | 2013-12-26 | 2014-04-23 | 苏州市涵信塑业有限公司 | ABS (Acrylonitrile Butadiene Styrene) resin-polyethylene composite modified plastic |
-
2015
- 2015-04-28 CN CN201510205503.7A patent/CN104788883A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103232672A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | Modified ABS high temperature resistant high polymer material |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
| CN103740040A (en) * | 2013-12-26 | 2014-04-23 | 苏州市涵信塑业有限公司 | ABS (Acrylonitrile Butadiene Styrene) resin-polyethylene composite modified plastic |
Non-Patent Citations (3)
| Title |
|---|
| C.赖利: "《食品的金属污染》", 30 September 1986, 轻工业出版社 * |
| 朱骥良等: "《颜料工艺学》", 31 January 2002, 化学工业出版社 * |
| 董川等: "《墨水化学原理及应用》", 30 September 2007, 科学出版社 * |
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Application publication date: 20150722 |
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