CN104804366A - ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property - Google Patents
ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property Download PDFInfo
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- CN104804366A CN104804366A CN201510244793.6A CN201510244793A CN104804366A CN 104804366 A CN104804366 A CN 104804366A CN 201510244793 A CN201510244793 A CN 201510244793A CN 104804366 A CN104804366 A CN 104804366A
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Abstract
The invention relates to ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property. The ABS modified resin comprises the following components of ABS resin, aromatic polyimide fibers, diazo diphenylamine paraformaldehyde condensation product, a polyisocyanate block, silicone-modified polyurethane resin, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydroquinoline, styryl pyridine dimethyl sulfate salts, isobutyraldehyde, a curing agent, dimethoxy dipropylene glycol, polyvinyl butanol, an antistatic agent, zinc ferrite, 4-tert-Butylcyclohexanone, cyclododecanone, barium sulfate, 1,2,3,4-cyclopentanetetracarboxylic acid and deionized water. The ABS modified resin disclosed by the invention has the characteristics of high hardness, flame retardance and antistatic property.
Description
Technical field
The present invention relates to a kind of high rigidity flame-retardant and antistatic ABS modified resin.
Background technology
ABS resin plastic cement is that current output is maximum, most widely used polymkeric substance.It has good physical and mechanical property, and shock strength is higher, and chemical stability, electrical property are good, and finished product processing, machining property are good, and water-fast, inorganic salt, soda acid, be a kind of can the engineering materials of widespread use.But current ABS resin plastic cement still exists, and intensity is low, abrasion-resistant surface is poor, flame-proof heat-resistant performance is strong under extreme case, the shortcoming of surface gloss difference.Simultaneously ABS resin is very easily producing accumulation of static electricity with during other surface contact friction, and cause dust suction, electric shock, electric discharge sparking, can cause precision instrument distortion, electronic component short circuit scraps, the accidents such as fire explosion, bring heavy losses to industrial production and scientific research.
Summary of the invention
In order to overcome above-mentioned shortcoming, the present invention by the following technical solutions: a kind of high rigidity flame-retardant and antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Isobutyric aldehyde 2-8 part
Solidifying agent 8-12 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Static inhibitor 7-15 part
Zinc ferrite 8-10 part
4-tbutylcyclohexanone 0.2-0.5 part
Cyclododecanone 0.2-0.5 part
Barium sulfate 10-15 part
1,2,3,4-pentamethylene tetracarboxylic acid 8-16 parts
Deionized water 10-20 part;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Pentachlorophenol zinc 20-30 part,
Three normal-butyl tin acetate 15-18 parts,
N-phenylsalicylamide 10-12 part,
Sulfatobetaine 15-20 part,
Polyvinyl alcohol 10-50 part,
Citric acid 2-5 part,
Pyridine oleate of mercury 3-4 part,
Organosilicon 1-2 part,
SCJ-877 8-10 part,
Magnesium chloride 5-10 part,
Cellulose acetate butyrate 0.2-1.2 part,
Sodium polyacrylate 0.5-1.8 part.
Preferably, described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.
The particle diameter of described magnesium chloride is about 110-150 order.
Beneficial effect of the present invention:
1, polyimide fiber, between diazonium pentanoic poly-formaldehyde condensate, polymeric polyisocyanate block thing, organic silicon modified polyurethane resin four kinds of materials produce synergy, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 63%.
2, barium sulfate, stibazole methyl-sulfate salt composite, significantly promote the wear resistance of plastic surface, make surface of plastic products not easily occur cut.
3,6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline, isobutyric aldehyde, dimethyl ether, polyvinyl alcohol contracting butanols, 1,2,3,4-pentamethylene tetracarboxylic acid, cyclododecanone, the composite of 4-tbutylcyclohexanone create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, pentachlorophenol zinc, three normal-butyl tin acetates, N-phenylsalicylamide, sulfatobetaine, pyridine oleate of mercury, SCJ-877, cellulose acetate butyrate, the composite of sodium polyacrylate creates synergistic effect, adds in ABS resin and effectively serves anlistatig effect.
5, fire-retardant, antistatic, high strength, the useful performance such as wear-resisting are integrated in one by modified ABS resin of the present invention, can be widely applied to the industrial scientific such as precision instrument, electronic component every field, and production cost are low, have a extensive future.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of high rigidity flame-retardant and antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polyimide fiber 8 parts
To diazonium pentanoic poly-formaldehyde condensate 15 parts
Polymeric polyisocyanate block thing 5 parts
Organic silicon modified polyurethane resin 15 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10 parts
Stibazole methyl-sulfate salt 3 parts
Isobutyric aldehyde 2 parts
8 parts, solidifying agent
Dimethyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
7 parts, static inhibitor
Zinc ferrite 8 parts
4-tbutylcyclohexanone 0.2 part
Cyclododecanone 0.2 part
10 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 8 parts
Deionized water 10 parts;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
20 parts, pentachlorophenol zinc,
Three normal-butyl tin acetates 15 parts,
N-phenylsalicylamide 10 parts,
Sulfatobetaine 15 parts,
Polyvinyl alcohol 10 parts,
Citric acid 2 parts,
Pyridine oleate of mercury 3 parts,
Organosilicon 1 part,
SCJ-877 8 parts,
5 parts, magnesium chloride,
Cellulose acetate butyrate 0.2 part,
Sodium polyacrylate 0.5-part.
Embodiment 2:
A kind of high rigidity flame-retardant and antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 100 parts
Polyimide fiber 20 parts
To diazonium pentanoic poly-formaldehyde condensate 30 parts
Polymeric polyisocyanate block thing 15 parts
Organic silicon modified polyurethane resin 25 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 20 parts
Stibazole methyl-sulfate salt 6 parts
Isobutyric aldehyde 8 parts
12 parts, solidifying agent
Dimethyl ether 4 parts
4 parts, polyvinyl alcohol contracting butanols
15 parts, static inhibitor
N-Methyl pyrrolidone 4 parts
Zinc ferrite 10 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 10 parts
4-tbutylcyclohexanone 0.5 part
Cyclododecanone 0.5 part
Gamma-butyrolactone 5 parts
15 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 16 parts
Deionized water 20 parts;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
30 parts, pentachlorophenol zinc,
Three normal-butyl tin acetates 18 parts,
N-phenylsalicylamide 12 parts,
Sulfatobetaine 20 parts,
Polyvinyl alcohol 50 parts,
Citric acid 5 parts,
Pyridine oleate of mercury 4 parts,
Organosilicon 2 parts,
SCJ-877 10 parts,
10 parts, magnesium chloride,
Cellulose acetate butyrate 1.2 parts,
Sodium polyacrylate 1.8 parts.
Embodiment 3:
A kind of high rigidity flame-retardant and antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polyimide fiber 10 parts
To diazonium pentanoic poly-formaldehyde condensate 20 parts
Polymeric polyisocyanate block thing 10 parts
Organic silicon modified polyurethane resin 20 parts
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 15 parts
Stibazole methyl-sulfate salt 5 parts
Isobutyric aldehyde 6 parts
10 parts, solidifying agent
Dimethyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
10 parts, static inhibitor
N-Methyl pyrrolidone 2 parts
Zinc ferrite 9 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 9 parts
4-tbutylcyclohexanone 0.3 part
Cyclododecanone 0.4 part
Gamma-butyrolactone 3 parts
12 parts, barium sulfate
1,2,3,4-pentamethylene tetracarboxylic acid 10 parts
Deionized water 15 parts;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
25 parts, pentachlorophenol zinc,
Three normal-butyl tin acetates 16 parts,
N-phenylsalicylamide 11 parts,
Sulfatobetaine 18 parts,
Polyvinyl alcohol 30 parts,
Citric acid 3 parts,
Pyridine oleate of mercury 3.5 parts,
Organosilicon 1.5 parts,
SCJ-877 9 parts,
8 parts, magnesium chloride,
Cellulose acetate butyrate 0.8 part,
Sodium polyacrylate 0.9 part.
Solidifying agent described in above-described embodiment 1-3 is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
Claims (3)
1. a high rigidity flame-retardant and antistatic ABS modified resin, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Isobutyric aldehyde 2-8 part
Solidifying agent 8-12 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Static inhibitor 7-15 part
Zinc ferrite 8-10 part
4-tbutylcyclohexanone 0.2-0.5 part
Cyclododecanone 0.2-0.5 part
Barium sulfate 10-15 part
1,2,3,4-pentamethylene tetracarboxylic acid 8-16 parts
Deionized water 10-20 part;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Pentachlorophenol zinc 20-30 part,
Three normal-butyl tin acetate 15-18 parts,
N-phenylsalicylamide 10-12 part,
Sulfatobetaine 15-20 part,
Polyvinyl alcohol 10-50 part,
Citric acid 2-5 part,
Pyridine oleate of mercury 3-4 part,
Organosilicon 1-2 part,
SCJ-877 8-10 part,
Magnesium chloride 5-10 part,
Cellulose acetate butyrate 0.2-1.2 part,
Sodium polyacrylate 0.5-1.8 part.
2. high rigidity flame-retardant and antistatic ABS modified resin according to claim 1, is characterized in that: described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
3. high rigidity flame-retardant and antistatic ABS modified resin according to claim 1, is characterized in that: the particle diameter of described magnesium chloride is about 110-150 order.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244793.6A CN104804366A (en) | 2015-05-14 | 2015-05-14 | ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244793.6A CN104804366A (en) | 2015-05-14 | 2015-05-14 | ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property |
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| CN104804366A true CN104804366A (en) | 2015-07-29 |
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| CN201510244793.6A Pending CN104804366A (en) | 2015-05-14 | 2015-05-14 | ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778391A (en) * | 2015-12-18 | 2016-07-20 | 北京理工大学 | Flame-retardant and antistatic material for shell of handheld Raman spectrometer |
| CN106519552A (en) * | 2016-11-22 | 2017-03-22 | 南京悠谷知识产权服务有限公司 | Dustproof antistatic high molecular material and preparation method thereof |
| US10640614B2 (en) | 2016-07-28 | 2020-05-05 | 3M Innovative Properties Company | Segmented silicone polyamide block copolymers and articles containing the same |
| US10865330B2 (en) | 2016-07-28 | 2020-12-15 | 3M Innovative Properties Company | Segmented silicone polyamide block copolymers and articles containing the same |
-
2015
- 2015-05-14 CN CN201510244793.6A patent/CN104804366A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778391A (en) * | 2015-12-18 | 2016-07-20 | 北京理工大学 | Flame-retardant and antistatic material for shell of handheld Raman spectrometer |
| CN105778391B (en) * | 2015-12-18 | 2018-03-02 | 北京理工大学 | A kind of handheld Raman spectrometer housing flame-retardant and anti-static material |
| US10640614B2 (en) | 2016-07-28 | 2020-05-05 | 3M Innovative Properties Company | Segmented silicone polyamide block copolymers and articles containing the same |
| US10865330B2 (en) | 2016-07-28 | 2020-12-15 | 3M Innovative Properties Company | Segmented silicone polyamide block copolymers and articles containing the same |
| CN106519552A (en) * | 2016-11-22 | 2017-03-22 | 南京悠谷知识产权服务有限公司 | Dustproof antistatic high molecular material and preparation method thereof |
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Application publication date: 20150729 |
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