CN106700465A - High-strength PC/ABS/PP (Polycarbonate/Acrylonitrile Butadiene Styrene/Polypropylene) composite material - Google Patents
High-strength PC/ABS/PP (Polycarbonate/Acrylonitrile Butadiene Styrene/Polypropylene) composite material Download PDFInfo
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Abstract
The invention relates to a high-strength PC/ABS/PP (Polycarbonate/Acrylonitrile Butadiene Styrene/Polypropylene) composite material, belongs to the technical field of materials, and aims to solve the problems that in the prior art, a PC/ABS/PP composite material is low in strength and free of a flame retardant. The high-strength PC/ABS/PP composite material comprises the following components in parts by weight: 20-50 parts of PC, 10-30 parts of ASB, 10-30 parts of PP, 10-20 parts of glass fiber, 5-20 parts of a toughening agent, 5-10 parts of a flame retardant, 3-8 parts of a compatilizer, 5-8 parts of a thermal stabilizer, 0.5-5 parts of an antioxidant, 1-5 parts of a lubricant and 3-5 parts of a coupling agent. Due to addition of the glass fiber in the PC/ABS/PP composite material, the physical properties of the composite material can be improved, particularly the strength of the composite material can be improved, and due to addition of the flame retardant in the composite material, the composite material has very good flame retardancy in addition to high strength.
Description
Technical field
The present invention relates to a kind of high-strength PC/ABS/PP composites, belong to material technology
Field.
Background technology
PC (makrolon) resin is a kind of to integrate firm, hard, tough plastic material
Typical Representative, its outstanding properties show as impact and the transparency is excellent, dimensionally stable
Property is high.Typically it is widely used in some simultaneously desired strength high products high to size requirement
In, such as in household electrical appliance, electronic device.In recent years, domestic and international fiber glass reinforced halogen-free flame retardant
The demand of PC resin also gradually increases, with China's sustained and rapid development of economy, from now on
The fiber glass reinforced halogen-free flame retardant PC resin market demand potential is larger within several years.
The content of the invention
There is provided a kind of with fire-retardant it is an object of the invention to solve defect of the prior art
High-strength PC/ABS/PP the composites of property.
Above-mentioned purpose of the invention can be achieved through the following technical solutions：A kind of high intensity
PC/ABS/PP composites, the composite includes following component and its parts by weight：
PC：20-50 parts, ABS：10-30 parts, PP：10-30 parts, glass fibre：10-20
Part, toughener：5-20 parts, fire retardant：5-10 parts, compatilizer：3-8 parts, heat is steady
Determine agent：5-8 parts, antioxidant：0.5-5 parts, lubricant：1-5 parts, coupling agent：
3-5 parts.
Further, the composite includes following component and its parts by weight：PC：
30-40 parts, ABS：20-30 parts, PP：10-20 parts, glass fibre：12-18 parts,
Toughener：8-15 parts, fire retardant：6-10 parts, compatilizer：3-6 parts, heat stabilizer：
5-8 parts, antioxidant：1-3 parts, lubricant：2-4 parts, coupling agent：3-5 parts.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the PC
Molecular weight is 10000-40000.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the ABS
Middle butadiene content is the 10%-30% of ABS weight.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the glass
The chopped fiber that fiber is a diameter of 8-10mm, length is 3-6mm.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the toughness reinforcing
Agent is high glue powder, POE, GMA or ethylene propylene diene rubber.
In above-mentioned high-strength PC/ABS/PP composites, preferably, described fire-retardant
Agent is potassium phenylsulphonyl benzene sulfonate (KSS), 2,4,5- trichlorines benzene sulfonic acid sodium salt (STB), complete
In fluorine butyl sulfonic acid potassium (PPFBS), three (2,4- dibromo phenyls) phosphate (BPP)
One or more.
In above-mentioned high-strength PC/ABS/PP composites, preferably, described compatible
Agent is EVOH-PPMA Macromolecular Compatibilizers.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the heat is steady
Agent is determined for phenolic thermostabilizers.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the antioxygen
Agent is phenol antioxidant 1010, phosphite antioxidant 168 or phosphorous acid
Esters antioxidant 627A.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the lubricant
It is fatty acid amide lubricant or dimethicone.
In above-mentioned high-strength PC/ABS/PP composites, preferably, the coupling
Agent is silane coupler or titanate coupling agent.
Relative to prior art, the present invention is by the compounding resin in PC, ABS, PP
The physical property of middle addition glass fibre reinforced composion, especially composite is strong
Degree, and fire retardant is with the addition of in the composite, make it that there is pole while high intensity
Good anti-flammability.
Specific embodiment
The following is specific embodiment of the invention, further is made to technical scheme
Description, but the present invention is not limited to these embodiments.
Embodiment 1
A kind of high-strength PC/ABS/PP composites, including following component and its weight portion
Number：PC：30 parts, ABS：20 parts, PP：20 parts, glass fibre：15 parts, increase
Tough dose：15 parts, fire retardant：8 parts, compatilizer：5 parts, heat stabilizer：6 parts, resist
Oxidant：4 parts, lubricant：3 parts, coupling agent：4 parts.
Wherein, the molecular weight of the PC is 20000；Butadiene content in the ABS
It is the 20% of ABS weight；Glass fibre is a diameter of 9mm, length for 5mm's is short
Fiber；The toughener is high glue powder；The fire retardant is potassium phenylsulphonyl benzene sulfonate
(KSS), 2,4,5- trichlorines benzene sulfonic acid sodium salt (STB)；The compatilizer is EVOH-PPMA
Macromolecular Compatibilizer；The heat stabilizer is phenolic thermostabilizers；The antioxidant is
Phenol antioxidant 1010；The lubricant is fatty acid amide lubricant；The coupling
Agent is silane coupler.
The PC/ABS/PP composites of the embodiment have high intensity, and anti-flammability
It is good.
Embodiment 2
A kind of high-strength PC/ABS/PP composites, including following component and its weight portion
Number：PC：20 parts, ABS：30 parts, PP：30 parts, glass fibre：10 parts, increase
Tough dose：20 parts, fire retardant：5 parts, compatilizer：8 parts, heat stabilizer：5 parts, resist
Oxidant：5 parts, lubricant：1 part, coupling agent：5 parts.
Wherein, the molecular weight of the PC is 10000；Butadiene content in the ABS
It is the 30% of ABS weight；The glass fibre is a diameter of 8mm, length is 6mm
Chopped fiber；The toughener is POE, GMA；The fire retardant is perfluoro butyl sulphur
Sour potassium (PPFBS), three (2,4- dibromo phenyls) phosphates (BPP)；The compatilizer
It is EVOH-PPMA Macromolecular Compatibilizers；The heat stabilizer is phenolic thermostabilizers；
The antioxidant is phosphite antioxidant 627A；The lubricant is dimethyl
Silicone oil；The coupling agent is titanate coupling agent.
The PC/ABS/PP composites of the embodiment have high intensity, and anti-flammability
It is good.
Embodiment 3
A kind of high-strength PC/ABS/PP composites, including following component and its weight portion
Number：PC：50 parts, ABS：10 parts, PP：30 parts, glass fibre：10 parts, increase
Tough dose：20 parts, fire retardant：5 parts, compatilizer：8 parts, heat stabilizer：5 parts, resist
Oxidant：5 parts, lubricant：1 part, coupling agent：5 parts.
Wherein, the molecular weight of the PC is 10000；Butadiene content in the ABS
It is the 30% of ABS weight；The glass fibre is a diameter of 10mm, length is 3mm
Chopped fiber；The toughener is POE, GMA；The fire retardant is perfluoro butyl sulphur
Sour potassium (PPFBS), three (2,4- dibromo phenyls) phosphates (BPP)；The compatilizer
It is EVOH-PPMA Macromolecular Compatibilizers；The heat stabilizer is phenolic thermostabilizers；
The antioxidant is phosphite antioxidant 627A；The lubricant is dimethyl
Silicone oil；The coupling agent is titanate coupling agent.
The PC/ABS/PP composites of the embodiment have high intensity, and anti-flammability
It is good.
Specific embodiment described herein is only to the spiritual theory for example of the present invention
It is bright.Those skilled in the art can be to described specific embodiment
Make various modifications or supplement or substituted using similar mode, but without departing from
Spirit of the invention surmounts scope defined in appended claims.
Claims (10)
1. a kind of high-strength PC/ABS/PP composites, it is characterised in that described compound
Material includes following component and its parts by weight：PC：20-50 parts, ABS：10-30 parts,
PP：10-30 parts, glass fibre：10-20 parts, toughener：5-20 parts, fire retardant：5-10
Part, compatilizer：3-8 parts, heat stabilizer：5-8 parts, antioxidant：0.5-5 parts, profit
Lubrication prescription：1-5 parts, coupling agent：3-5 parts.
2. high-strength PC according to claim 1/ABS/PP composites, it is special
Levy and be, the composite includes following component and its parts by weight：PC：30-40 parts,
ABS：20-30 parts, PP：10-20 parts, glass fibre：12-18 parts, toughener：8-15
Part, fire retardant：6-10 parts, compatilizer：3-6 parts, heat stabilizer：It is 5-8 parts, anti-oxidant
Agent：1-3 parts, lubricant：2-4 parts, coupling agent：3-5 parts.
3. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the molecular weight of the PC is 10000-40000, fourth two in the ABS
Alkene content is the 10%-30% of ABS weight.
4. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the glass fibre is short for 3-6mm a diameter of 8-10mm, length
Fiber.
5. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the toughener is high glue powder, POE, GMA or ethylene-propylene-diene monomer
Glue.
6. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the fire retardant is potassium phenylsulphonyl benzene sulfonate (KSS), 2,4,5- trichlorines
Benzene sulfonic acid sodium salt (STB), perfluorobutyl potassium sulfonate (PPFBS), three (2,4- dibromo phenyls)
One or more in phosphate (BPP).
7. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the compatilizer is EVOH-PPMA Macromolecular Compatibilizers.
8. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the heat stabilizer is phenolic thermostabilizers.
9. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the antioxidant is phenol antioxidant 1010, phosphorous acid esters antioxygen
Agent 168 or phosphite antioxidant 627A.
10. high-strength PC according to claim 1 and 2/ABS/PP composites,
Characterized in that, the lubricant is fatty acid amide lubricant or dimethicone, institute
Coupling agent is stated for silane coupler or titanate coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510522728.5A CN106700465A (en) | 2015-08-24 | 2015-08-24 | High-strength PC/ABS/PP (Polycarbonate/Acrylonitrile Butadiene Styrene/Polypropylene) composite material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510522728.5A CN106700465A (en) | 2015-08-24 | 2015-08-24 | High-strength PC/ABS/PP (Polycarbonate/Acrylonitrile Butadiene Styrene/Polypropylene) composite material |
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| CN106700465A true CN106700465A (en) | 2017-05-24 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485226A (en) * | 2018-04-23 | 2018-09-04 | 合肥仁德电子科技有限公司 | A kind of high intensity shock-absorbing composite material for mouse manufacture |
| CN109777064A (en) * | 2017-11-14 | 2019-05-21 | 万华化学集团股份有限公司 | A kind of extrusion grade Polycarbonate alloy material and its preparation method and application |
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| CN102993668A (en) * | 2012-08-22 | 2013-03-27 | 广东威林工程塑料有限公司 | Polycarbonate/acrylonitrile-butadiene-styrene (ABS)/polypropylene ternary alloy material and preparation method thereof |
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| CN103146111A (en) * | 2013-04-04 | 2013-06-12 | 青岛文晟汽车零部件有限公司 | ABS (Acrylonitrile butadiene styrene) alloy material for instrument panels of automobiles |
| CN103540088A (en) * | 2013-09-28 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Acrylonitrile butadiene styrene (ABS) and poly carbonate (PC) composite engineering plastic with high tenacity |
| CN103642168A (en) * | 2013-11-22 | 2014-03-19 | 苏州润佳工程塑料股份有限公司 | Modified ABS material |
| CN104151705A (en) * | 2014-08-12 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Modified polypropylene material |
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2015
- 2015-08-24 CN CN201510522728.5A patent/CN106700465A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102993668A (en) * | 2012-08-22 | 2013-03-27 | 广东威林工程塑料有限公司 | Polycarbonate/acrylonitrile-butadiene-styrene (ABS)/polypropylene ternary alloy material and preparation method thereof |
| CN103059540A (en) * | 2012-12-31 | 2013-04-24 | 安徽科聚新材料有限公司 | PC (Poly Carbonate)/ABS (Acrylonitrile Butadiene S) alloy material and preparation method thereof |
| CN103146111A (en) * | 2013-04-04 | 2013-06-12 | 青岛文晟汽车零部件有限公司 | ABS (Acrylonitrile butadiene styrene) alloy material for instrument panels of automobiles |
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| CN103642168A (en) * | 2013-11-22 | 2014-03-19 | 苏州润佳工程塑料股份有限公司 | Modified ABS material |
| CN104151705A (en) * | 2014-08-12 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Modified polypropylene material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109777064A (en) * | 2017-11-14 | 2019-05-21 | 万华化学集团股份有限公司 | A kind of extrusion grade Polycarbonate alloy material and its preparation method and application |
| CN109777064B (en) * | 2017-11-14 | 2021-07-23 | 万华化学集团股份有限公司 | Extrusion-grade polycarbonate alloy material and preparation method and application thereof |
| CN108485226A (en) * | 2018-04-23 | 2018-09-04 | 合肥仁德电子科技有限公司 | A kind of high intensity shock-absorbing composite material for mouse manufacture |
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Application publication date: 20170524 |