CN105419137A - Anti-corrosion flame-retardation environmental protection high-hardness plastic - Google Patents

Anti-corrosion flame-retardation environmental protection high-hardness plastic Download PDF

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CN105419137A
CN105419137A CN201511014143.9A CN201511014143A CN105419137A CN 105419137 A CN105419137 A CN 105419137A CN 201511014143 A CN201511014143 A CN 201511014143A CN 105419137 A CN105419137 A CN 105419137A
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parts
environmental protection
plastic
carbon black
rubber
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王威淞
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/16Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286Chlorinated polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/022 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses anti-corrosion flame-retardation environmental protection high-hardness plastic. The provided plastic is divided into an internal layer and an external layer. The provided plastic is characterized in that the external layer plastic pipe is composed of the following raw materials, by weight, 15-25 parts of chlorinated polyethylene rubber, 1-3 parts of short fiber, 0.3-0.5 part of trioctyl trimellitate, 6 parts of modified starch glue, 16-18 parts of polystyrene, 5-7 parts of carbon black, 3-5 parts of white carbon black, 0.5-0.8 part of corrosion inhibitor, 2-3 parts of paraffin and 3-5 parts of talcum powder. the external layer plastic pipe employs the components of modified starch glue, carbon black and the like, the wear resistance of plastic is raised, the operation mechanical property is good, and the corrosion inhibitor is employed for complex formulation preparation of high-efficiency and environmental protection plastic and applied to a natural rubber system, the corrosion resistance of the material is raised. The inner layer glass fiber pipe has aging resistance and wear resistance, and has good chemical stability. The inner layer is made of materials of glass fibers with a high intensity or the like, the intensity and the stiffness of the plastic pipe are enhanced, the high-temperature bearing performance is raised, and good shock resistance is achieved.

Description

A kind of high rigidity plastics of anticorrosive flame-proof environmental protection
Technical field
The present invention relates to plastic material field, be specifically related to a kind of high rigidity plastics of anticorrosive flame-proof environmental protection.
Background technology
Plastics tubing kind is a lot, is divided into thermoplastic pipes and the large class of thermosetting resin pipe two.Belong to thermoplastic and have polyvinyl chloride pipe, polyethylene tube, polypropylene tube, polyoxymethylene pipe etc.; Belong to heat cured and have phenola plastics pipe etc.The major advantage of plastics tubing is that corrosion resisting property is good, quality light, convenient formation, handling ease, shortcoming are that intensity is lower, poor heat resistance.The Young's modulus of plastics is between rubber and fiber, and certain deformation occurs stressed energy.Soft plastics is close to rubber, and duroplasts is close to fiber.The plastics definition of narrow sense refers to resin (or using monomer direct polymerization in the course of processing) for main component, with additives such as softening agent, weighting agent, lubricant, tinting materials for ancillary component, and the material of energy flowing forming in the course of processing.Plastics are the macromolecular compound of synthesis, freely can change body styles.Plastics are the materials utilizing raw material monomer to be polymerized with synthesis or condensation reaction.
Organic phosphorus flame retardant is the good fire retardant of a kind of flame retardant properties, and it has fire-retardant plasticising dual-use function, can replace halogenation flame retardant, make fire-retardant realize completely non-halogen, but its physical and mechanical properties on polymkeric substance impact larger.The mechanical property of polymeric matrix, gas barrier property and solvent resistance can be improved.
Along with people are to environmental protection and the raising to material performance requirement, plastic material is required to have good resistance to electrical insulating property and safety and environmental protection performance, the index request of its thermotolerance, ageing-resistant, flame retardant resistance, also in raising, develops the comfortable plastic material processed of novel effective, eco-friendly flame-proof abrasion-resistant and has great importance.
Nylon66 fiber is that the fusing point of polyamide resin is higher, there is good physical and mechanical property and ageing resistance, wear resistance and self lubricity, but it is higher owing to self there is water-intake rate, can moisture in Long-term absorption air, thus cause physical property to change, especially, in the environment of long-term continuous high temperature high humidity, this shortcoming has become and cannot receive, and must significantly be improved.Produce from synthetic resins, plastics machinery and plastics, the growth momentum that China Plastics Industry is powerful, existing plastics tubing is generally simple plastics tubing, its strength ratio is lower, and this plastics tubing large, the pipeline of the coefficient of expansion is easily softening and yielding under given conditions, not easily widespread use.
Summary of the invention
The object of the present invention is to provide a kind of high rigidity plastics of anticorrosive flame-proof environmental protection.
The technical scheme that the present invention takes is:
High rigidity plastics for anticorrosive flame-proof environmental protection, be divided into inside and outside two-layer, it is characterized in that, raw material is composed as follows according to weight part:
Outer layer plastic tube: chlorinated polyethylene rubber 15-25 part, staple fibre 1-3 part, trioctyl trimellitate 0.3-0.5 part, modified starch adhesive-6 parts, polystyrene 16-18 part, carbon black 5-7 part, white carbon black 3-5 part, corrosion inhibitor 0.5-0.8 part, paraffin 2-3 part, talcum powder 3-5 part;
Inner layer glass fibre pipe: nylon66 fiber 20-25 part, glass wool 10-12 part, Halogen alkali-free glass fiber 12-14 part, environmental protection fire retarding agent 2-4 part, Vulcanization accelerator TMTD 0.2-0.5 part, stearic acid 0.2-0.3 part, antioxidant 0.6-0.8 part;
Modified starch adhesive in described outer layer plastic tube is the mixed rubber be made up of according to 2:1:1 terpolymer EP rubber, styrene-butadiene rubber(SBR) containing 3-5%LH-C96 vulcanizing agent.
Further, described corrosion inhibitor is the mixture that glyceryl monostearate and Sorbitol Powder form according to 2:3.
Further, described environmental protection fire retarding agent to be mass ratio be 1: 1 organo montmorillonite and triaryl phosphate be polymerized.
Beneficial effect of the present invention is:
The compositions such as outer layer plastic tube modified starch adhesive of the present invention and carbon black, improve the wear resistance of plastics, operate machine functional, adopt that corrosion inhibitor composite preparation is efficient, environment-friendly type plastic, and apply it in natural rubber system, improve the erosion resistance of material; It is good that inner layer glass fibre pipe has the chemical stability such as ageing resistance, wear resistance, and internal layer have employed that the materials such as the higher glass fibre of intensity make, and enhances the strength and stiffness of plastics tubing, improves its high-temperature bearing performance, have good shock resistance.
Embodiment
Embodiment 1
High rigidity plastics for anticorrosive flame-proof environmental protection, be divided into inside and outside two-layer, it is characterized in that, raw material is composed as follows according to weight part:
Outer layer plastic tube: chlorinated polyethylene rubber 15 parts, 1 part, staple fibre, trioctyl trimellitate 0.3 part, modified starch adhesive 6 parts, polystyrene 16 parts, carbon black 5 parts, white carbon black 3 parts, corrosion inhibitor 0.5 part, 2 parts, paraffin, talcum powder 3 parts;
Inner layer glass fibre pipe: nylon66 fiber 25 parts, glass wool 12 parts, Halogen alkali-free glass fiber 14 parts, environmental protection fire retarding agent 4 parts, Vulcanization accelerator TMTD 0.5 part, stearic acid 0.3 part, antioxidant 0.8 part;
Modified starch adhesive in described outer layer plastic tube is the mixed rubber be made up of according to 2:1:1 terpolymer EP rubber, styrene-butadiene rubber(SBR) containing 3-5%LH-C96 vulcanizing agent.
Further, described corrosion inhibitor is the mixture that glyceryl monostearate and Sorbitol Powder form according to 2:3.
Further, described environmental protection fire retarding agent to be mass ratio be 1: 1 organo montmorillonite and triaryl phosphate be polymerized.
Embodiment 2
High rigidity plastics for anticorrosive flame-proof environmental protection, be divided into inside and outside two-layer, it is characterized in that, raw material is composed as follows according to weight part:
Outer layer plastic tube: chlorinated polyethylene rubber 25 parts, 3 parts, staple fibre, trioctyl trimellitate 0.5 part, modified starch adhesive 6 parts, polystyrene 18 parts, carbon black 7 parts, white carbon black 5 parts, corrosion inhibitor 0.8 part, 3 parts, paraffin, talcum powder 5 parts;
Inner layer glass fibre pipe: nylon66 fiber 20 parts, glass wool 10 parts, Halogen alkali-free glass fiber 12 parts, environmental protection fire retarding agent 2 parts, Vulcanization accelerator TMTD 0.2 part, stearic acid 0.2 part, antioxidant 0.6 part;
Modified starch adhesive in described outer layer plastic tube is the mixed rubber be made up of according to 2:1:1 terpolymer EP rubber, styrene-butadiene rubber(SBR) containing 3-5%LH-C96 vulcanizing agent.
Further, described corrosion inhibitor is the mixture that glyceryl monostearate and Sorbitol Powder form according to 2:3.
Further, described environmental protection fire retarding agent to be mass ratio be 1: 1 organo montmorillonite and triaryl phosphate be polymerized.

Claims (3)

1. high rigidity plastics for anticorrosive flame-proof environmental protection, be divided into inside and outside two-layer, it is characterized in that, raw material is composed as follows according to weight part:
Outer layer plastic tube: chlorinated polyethylene rubber 15-25 part, staple fibre 1-3 part, trioctyl trimellitate 0.3-0.5 part, modified starch adhesive-6 parts, polystyrene 16-18 part, carbon black 5-7 part, white carbon black 3-5 part, corrosion inhibitor 0.5-0.8 part, paraffin 2-3 part, talcum powder 3-5 part;
Inner layer glass fibre pipe: nylon66 fiber 20-25 part, glass wool 10-12 part, Halogen alkali-free glass fiber 12-14 part, environmental protection fire retarding agent 2-4 part, Vulcanization accelerator TMTD 0.2-0.5 part, stearic acid 0.2-0.3 part, antioxidant 0.6-0.8 part;
Modified starch adhesive in described outer layer plastic tube is the mixed rubber be made up of according to 2:1:1 terpolymer EP rubber, styrene-butadiene rubber(SBR) containing 3-5%LH-C96 vulcanizing agent.
2. the high rigidity plastics of a kind of anticorrosive flame-proof environmental protection according to claim 1, is characterized in that, described corrosion inhibitor is the mixture that glyceryl monostearate and Sorbitol Powder form according to 2:3.
3. the high rigidity plastics of a kind of anticorrosive flame-proof environmental protection according to claim 1, is characterized in that, described environmental protection fire retarding agent to be mass ratio be 1: 1 organo montmorillonite and triaryl phosphate be polymerized.
CN201511014143.9A 2015-12-31 2015-12-31 Anti-corrosion flame-retardation environmental protection high-hardness plastic Pending CN105419137A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329609A (en) * 2018-02-27 2018-07-27 合肥择浚电气设备有限公司 A kind of high-strength Antistatic insulating material of heat-proof combustion-resistant and preparation method thereof
CN109535512A (en) * 2018-10-31 2019-03-29 安徽春辉仪表线缆集团有限公司 A kind of instrument cable flame-proof abrasion-resistant styrene-butadiene rubber composite material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329609A (en) * 2018-02-27 2018-07-27 合肥择浚电气设备有限公司 A kind of high-strength Antistatic insulating material of heat-proof combustion-resistant and preparation method thereof
CN109535512A (en) * 2018-10-31 2019-03-29 安徽春辉仪表线缆集团有限公司 A kind of instrument cable flame-proof abrasion-resistant styrene-butadiene rubber composite material

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Application publication date: 20160323