CN105504411A - Flame-retardant shock-absorbing rubber composite formulation - Google Patents
Flame-retardant shock-absorbing rubber composite formulation Download PDFInfo
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- CN105504411A CN105504411A CN201510819781.1A CN201510819781A CN105504411A CN 105504411 A CN105504411 A CN 105504411A CN 201510819781 A CN201510819781 A CN 201510819781A CN 105504411 A CN105504411 A CN 105504411A
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Abstract
The present invention discloses a flame-retardant shock-absorbing rubber composite formulation, and relates to the field of rubber, the composite formulation consists of the following components by weight: 12-13 parts of chloroprene rubber raw rubber, 8-10 parts of zinc oxide, 13-15 parts of semi-reinforcing furnace black, 7-9 parts of magnesium oxide, 14-16 parts of titanium dioxide, 13-15 parts of white carbon black, 5-7 parts of dioctyl phthalate, 9-12 parts of stearic acid, 4-5 parts of paraffin wax, 12-14 parts of zinc borate, 17-19 parts of dibutyl ester, 3-5 parts of accelerator NA-32, 15-18 parts of zinc oxide, 8-9 parts of a plasticizer, 6-7 parts of sulfur, 3-5parts of polyethylene oxide, 8-9 parts of ethanol, 13-15 parts of cuprous chloride and 8-11 parts of a polyalkylphenol disulfide, a glass fiber composite material prepared by the formulation is light in weight, and excellent in heat aging resistance, tear resistance and flame retardant effect, compared with conventional rubber materials, cold resistance and shelf stability are greatly improved, and the rubber material has good wet and skid resistance performance and excellent traction performance and wear resistance.
Description
Technical field
The present invention relates to rubber materials, be specifically related to a kind of formula of fire-retardant shock-absorbing rubber composite.
Background technology
Along with the enhancing of environmental consciousness, require more and more higher to the safety and environmental protection of used elastomeric material, other sebific ducts such as automobile canister adsorption and desorption flexible pipe are interior glue paracril, the full plastic structure of compound of outer glue chlorosulfonated polyethylene rubber, outer glue chlorosulfonated polyethylene rubber color mostly is grey, black, redness, blueness etc.Mostly current domestic common chloroprene rubber flame-retardant formulations is to use containing halogen containing flame-retardants such as chlorine-based flame retardants, although use this based flame retardant can meet good flame retardant effect, but once presence of fire can produce the poisonous hydrogen halide that is corrosive in a large number, secondary is caused to endanger, the consequence that its harm causes than burning usually is more serious, the life security of serious harm people, chloroprene rubber is the rubber that main raw material carries out α-polymerization and generates by chloroprene, can be used for producing travelling belt, travelling belt, oil resisting rubber hose, the rubber items such as sealing material, also can be used for producing tackiness agent, for metal, timber, the materials such as leather bonding etc., there is good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to ozone, acid and alkali-resistance, simultaneously, in recent years, due to be faced with from external product competition and reduce the needs of production cost, domestic Rubber processing industry recognizes change conventional formulation gradually, increase the significance of oil-extended styrene-butadiene rubber usage ratio, especially along with the increase of China's oil-extended styrene-butadiene rubber resource, more domestic outsize tire enterprises adjust formula one after another, improve oil-extended styrene-butadiene rubber usage ratio, the output of current domestic oil-extended styrene-butadiene rubber can not satisfy the demands far away.
Summary of the invention
Problem to be solved by this invention is to provide material light weight, the fire-retardant shock-absorbing rubber composite that heat-resisting ageing-resisting performance is good.
To achieve these goals, the technical scheme that the present invention takes is the formula of a kind of fire-retardant shock-absorbing rubber composite provided, described composite-material formula is made up of the component of following weight fraction: chloroprene rubber rubber 12-13 part, zinc oxide 8-10 part, semi-reinforcing furnace black 13-15 part, magnesium oxide 7-9 part, titanium dioxide 14-16 part, white carbon black 13-15 part, dioctyl phthalate (DOP) 5-7 part, stearic acid 9-12 part, paraffin 4-5 part, zinc borate 12-14 part, dibutylester 17-19 part, accelerant N A-323-5 part, zinc oxide 15-18 part, softening agent 8-9 part, sulphur 6-7 part, polyethylene oxide 3-5 part, ethanol 8-9 part, cuprous chloride 13-15 part, polyalkylbenzene phenol disulphide 8-11 part.
Preferably, the formula of a kind of fire-retardant shock-absorbing rubber composite according to claim 1, described composite-material formula is made up of the component of following weight fraction: chloroprene rubber rubber 12 parts, 10 parts, zinc oxide, semi-reinforcing furnace black 15 parts, 8 parts, magnesium oxide, titanium dioxide 15 parts, white carbon black 14 parts, dioctyl phthalate (DOP) 6 parts, stearic acid 10 parts, 5 parts, paraffin, zinc borate 13 parts, dibutylester 18 parts, accelerant N A-324 part, 17 parts, zinc oxide, 8 parts, softening agent, 7 parts, sulphur, polyethylene oxide 4 parts, ethanol 9 parts, cuprous chloride 14 parts, polyalkylbenzene phenol disulphide 10 parts.
Preferably, described softening agent is dioctyl phthalate (DOP) or dimixo-octyl phthalate.
Adopt technical scheme of the present invention, the formula of a kind of fire-retardant shock-absorbing rubber composite of the present invention, the glass fiber compound material material light weight that described formula is obtained, heat aging property, tear-resistant performance, flame retardant effect are excellent, and relative to elastomeric material in the past, its winter hardiness and shelf-stable stability also improve a lot, and this kind of elastomeric material has hauling ability and the abrasion resistance properties of good wet-sliding resistant performance and excellence simultaneously.
Embodiment
The technique means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with embodiment, setting forth the present invention further.
Embodiment 1:
A kind of formula of fire-retardant shock-absorbing rubber composite, described composite-material formula is made up of the component of following weight fraction: chloroprene rubber rubber 12 parts, 10 parts, zinc oxide, semi-reinforcing furnace black 15 parts, 8 parts, magnesium oxide, titanium dioxide 15 parts, white carbon black 14 parts, dioctyl phthalate (DOP) 6 parts, stearic acid 10 parts, 5 parts, paraffin, zinc borate 13 parts, dibutylester 18 parts, accelerant N A-324 part, 17 parts, zinc oxide, 8 parts, softening agent, 7 parts, sulphur, polyethylene oxide 4 parts, ethanol 9 parts, cuprous chloride 14 parts, polyalkylbenzene phenol disulphide 10 parts.
Based on above-mentioned, the formula of a kind of fire-retardant shock-absorbing rubber composite of the present invention, the glass fiber compound material material light weight that described formula is obtained, heat aging property, tear-resistant performance, flame retardant effect are excellent, and relative to elastomeric material in the past, its winter hardiness and shelf-stable stability also improve a lot, and this kind of elastomeric material has hauling ability and the abrasion resistance properties of good wet-sliding resistant performance and excellence simultaneously.
Obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.
Claims (3)
1. the formula of a fire-retardant shock-absorbing rubber composite, it is characterized in that, described composite-material formula is made up of the component of following weight fraction: chloroprene rubber rubber 12-13 part, zinc oxide 8-10 part, semi-reinforcing furnace black 13-15 part, magnesium oxide 7-9 part, titanium dioxide 14-16 part, white carbon black 13-15 part, dioctyl phthalate (DOP) 5-7 part, stearic acid 9-12 part, paraffin 4-5 part, zinc borate 12-14 part, dibutylester 17-19 part, accelerant N A-323-5 part, zinc oxide 15-18 part, softening agent 8-9 part, sulphur 6-7 part, polyethylene oxide 3-5 part, ethanol 8-9 part, cuprous chloride 13-15 part, polyalkylbenzene phenol disulphide 8-11 part.
2. the formula of a kind of fire-retardant shock-absorbing rubber composite according to claim 1, it is characterized in that, described composite-material formula is made up of the component of following weight fraction: chloroprene rubber rubber 12 parts, 10 parts, zinc oxide, semi-reinforcing furnace black 15 parts, 8 parts, magnesium oxide, titanium dioxide 15 parts, white carbon black 14 parts, dioctyl phthalate (DOP) 6 parts, stearic acid 10 parts, 5 parts, paraffin, zinc borate 13 parts, dibutylester 18 parts, accelerant N A-324 part, 17 parts, zinc oxide, 8 parts, softening agent, 7 parts, sulphur, polyethylene oxide 4 parts, ethanol 9 parts, cuprous chloride 14 parts, polyalkylbenzene phenol disulphide 10 parts.
3. the formula of a kind of fire-retardant shock-absorbing rubber composite according to claim 1 and 2, it is characterized in that, described softening agent is dioctyl phthalate (DOP) or dimixo-octyl phthalate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510819781.1A CN105504411A (en) | 2015-11-24 | 2015-11-24 | Flame-retardant shock-absorbing rubber composite formulation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510819781.1A CN105504411A (en) | 2015-11-24 | 2015-11-24 | Flame-retardant shock-absorbing rubber composite formulation |
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| CN105504411A true CN105504411A (en) | 2016-04-20 |
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| CN201510819781.1A Pending CN105504411A (en) | 2015-11-24 | 2015-11-24 | Flame-retardant shock-absorbing rubber composite formulation |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106279849A (en) * | 2016-08-16 | 2017-01-04 | 苏州海德新材料科技股份有限公司 | A kind of shock isolating pedestal protection glue |
| CN107141543A (en) * | 2017-06-27 | 2017-09-08 | 苏州菱慧电子科技有限公司 | A kind of high temperature resistant CR sizing materials |
| CN115322463A (en) * | 2022-09-16 | 2022-11-11 | 中策橡胶集团股份有限公司 | Low-heat-generation and anti-fatigue rubber composition and preparation method and application thereof |
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| CN101812193A (en) * | 2009-12-07 | 2010-08-25 | 天津鹏翎胶管股份有限公司 | Formula of environment-friendly flame-retardant chloroprene rubber |
| CN103113639A (en) * | 2012-11-15 | 2013-05-22 | 青岛融鑫源橡胶机械有限公司 | Flame-retardant chloroprene rubber formula |
| CN103881173A (en) * | 2014-03-19 | 2014-06-25 | 安徽嘉木橡塑工业有限公司 | Flame-retardant chloroprene rubber |
| CN104212015A (en) * | 2014-09-29 | 2014-12-17 | 山西德邦橡胶制品有限公司 | Steel wire rope core flame-retardant belt bonding core rubber |
| CN104262726A (en) * | 2014-10-24 | 2015-01-07 | 中国铁道科学研究院 | Flame retardant composition for neoprene and preparation method thereof |
| CN104448409A (en) * | 2013-09-23 | 2015-03-25 | 招远市东晟橡胶制品有限公司 | Rubber |
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2015
- 2015-11-24 CN CN201510819781.1A patent/CN105504411A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812193A (en) * | 2009-12-07 | 2010-08-25 | 天津鹏翎胶管股份有限公司 | Formula of environment-friendly flame-retardant chloroprene rubber |
| CN103113639A (en) * | 2012-11-15 | 2013-05-22 | 青岛融鑫源橡胶机械有限公司 | Flame-retardant chloroprene rubber formula |
| CN104448409A (en) * | 2013-09-23 | 2015-03-25 | 招远市东晟橡胶制品有限公司 | Rubber |
| CN103881173A (en) * | 2014-03-19 | 2014-06-25 | 安徽嘉木橡塑工业有限公司 | Flame-retardant chloroprene rubber |
| CN104212015A (en) * | 2014-09-29 | 2014-12-17 | 山西德邦橡胶制品有限公司 | Steel wire rope core flame-retardant belt bonding core rubber |
| CN104262726A (en) * | 2014-10-24 | 2015-01-07 | 中国铁道科学研究院 | Flame retardant composition for neoprene and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106279849A (en) * | 2016-08-16 | 2017-01-04 | 苏州海德新材料科技股份有限公司 | A kind of shock isolating pedestal protection glue |
| CN107141543A (en) * | 2017-06-27 | 2017-09-08 | 苏州菱慧电子科技有限公司 | A kind of high temperature resistant CR sizing materials |
| CN115322463A (en) * | 2022-09-16 | 2022-11-11 | 中策橡胶集团股份有限公司 | Low-heat-generation and anti-fatigue rubber composition and preparation method and application thereof |
| CN115322463B (en) * | 2022-09-16 | 2023-04-14 | 中策橡胶集团股份有限公司 | Low-heat-generation and anti-fatigue rubber composition and preparation method and application thereof |
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Application publication date: 20160420 |