CN104788885A - Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin - Google Patents
Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin Download PDFInfo
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- CN104788885A CN104788885A CN201510244951.8A CN201510244951A CN104788885A CN 104788885 A CN104788885 A CN 104788885A CN 201510244951 A CN201510244951 A CN 201510244951A CN 104788885 A CN104788885 A CN 104788885A
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Abstract
the invention relates to a high-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic which comprises an ABS resin, polyimide fiber, p-diazodiphenylamine polyformaldehyde condensate, polyisocyanate block polymer, an organosilicon modified polyurethane resin, trimethyl hexamethylenediamine, dimethyl stilbazole sulfate, lauraldehyde, a curing agent, propanediol monobutyl ether, polyvinyl alcohol butanol, cadmium sulfoselenide, N-methylpyrrolidone, pucherite isoindoline ketone pigment, methyl tert-butyl ketone, cyclopentanone, 3-methoxy butylacetate, calcium carbonate, N-isopropyl-N'-phenyl p-phenylenediamine and deionized water. The ABS modified resin has the characteristics of high hardness, flame retardancy, heat resistance and static resistance.
Description
Technical field
The present invention relates to a kind of Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin.
Background technology
ABS resin plastic cement is that current output is maximum, most widely used polymkeric substance.It has good physical and mechanical property, and shock strength is higher, and chemical stability, electrical property are good, and finished product processing, machining property are good, and water-fast, inorganic salt, soda acid, be a kind of can the engineering materials of widespread use.But current ABS resin plastic cement still exists, and intensity is low, abrasion-resistant surface is poor, flame-proof heat-resistant performance is strong under extreme case, the shortcoming of surface gloss difference.Simultaneously ABS resin is very easily producing accumulation of static electricity with during other surface contact friction, and cause dust suction, electric shock, electric discharge sparking, can cause precision instrument distortion, electronic component short circuit scraps, the accidents such as fire explosion, bring heavy losses to industrial production and scientific research.
Summary of the invention
In order to overcome above-mentioned deficiency, the present invention by the following technical solutions: a kind of Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
Trimethylhexamethylenediamine 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Lauric aldehyde 2-8 part
Solidifying agent 8-12 part
Propylene glycol monobutyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Static inhibitor 7-15 part
Pucherite 8-10 part
Methyl-tert .-butyl ketone 0.2-0.5 part
Cyclopentanone 0.2-0.5 part
Calcium carbonate 10-15 part
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8-16 part
Deionized water 10-20 part.
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Hexamethylene 20-30 part,
1-hydroxyl-2-pyridine sulphur copper 15-18 part,
Tetra isopropyl metatitanic acid 10-12 part,
Sulfatobetaine 15-20 part,
Polyvinyl alcohol 10-50 part,
Citric acid 2-5 part,
Isothiazolinone 3-4 part,
White carbon black 1-2 part,
SCJ-2000 8-10 part,
Wilkinite 5-10 part,
Cellulose acetate butyrate 0.2-1.2 part,
Sodium polyacrylate 0.5-1.8 part.
Preferably, described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.
The particle diameter of described white carbon black is about 110-150 order.
Beneficial effect of the present invention:
1, polyimide fiber, between diazonium pentanoic poly-formaldehyde condensate, polymeric polyisocyanate block thing three kinds of materials produce synergy, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 63%.
2, calcium carbonate, organic silicon modified polyurethane resin, stibazole methyl-sulfate salt composite, significantly promote the wear resistance of plastic surface, make surface of plastic products not easily occur cut.
3, trimethylhexamethylenediamine, lauric aldehyde, propylene glycol monobutyl ether, polyvinyl alcohol contracting butanols, N-sec.-propyl-N '-diphenyl-para-phenylene diamine, cyclopentanone, the composite of methyl-tert .-butyl ketone create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, hexamethylene, 1-hydroxyl-2-pyridine sulphur copper, tetra isopropyl metatitanic acid, sulfatobetaine, isothiazolinone, SCJ-877, cellulose acetate butyrate, the composite of sodium polyacrylate creates synergistic effect, adds in ABS resin and effectively serves anlistatig effect.
5, fire-retardant, antistatic, high strength, the useful performance such as wear-resisting are integrated in one by modified ABS resin of the present invention, can be widely applied to the industrial scientific such as precision instrument, electronic component every field, and production cost are low, have a extensive future.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polyimide fiber 8 parts
To diazonium pentanoic poly-formaldehyde condensate 15 parts
Polymeric polyisocyanate block thing 5 parts
Organic silicon modified polyurethane resin 15 parts
Trimethylhexamethylenediamine 10 parts
Stibazole methyl-sulfate salt 3 parts
Lauric aldehyde 2 parts
8 parts, solidifying agent
Propylene glycol monobutyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
7 parts, static inhibitor
Pucherite 8 parts
Methyl-tert .-butyl ketone 0.2 part
Cyclopentanone 0.2 part
10 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8 parts
Deionized water 10 parts.
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Hexamethylene 20 parts,
1-hydroxyl-2-pyridine sulphur copper 15 parts,
Tetra isopropyl metatitanic acid 10 parts,
Sulfatobetaine 15 parts,
Polyvinyl alcohol 10 parts,
Citric acid 2 parts,
Isothiazolinone 3 parts,
White carbon black 1 part,
SCJ-2000 8 parts,
Wilkinite 5 parts,
Cellulose acetate butyrate 0.2 part,
Sodium polyacrylate 0.5 part.
Embodiment 2:
A kind of Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 100 parts
Polyimide fiber 20 parts
To diazonium pentanoic poly-formaldehyde condensate 30 parts
Polymeric polyisocyanate block thing 15 parts
Organic silicon modified polyurethane resin 25 parts
Trimethylhexamethylenediamine 20 parts
Stibazole methyl-sulfate salt 6 parts
Lauric aldehyde 8 parts
12 parts, solidifying agent
Propylene glycol monobutyl ether 4 parts
4 parts, polyvinyl alcohol contracting butanols
15 parts, static inhibitor
Pucherite 10 parts
Methyl-tert .-butyl ketone 0.5 part
Cyclopentanone 0.5 part
15 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 16 parts
Deionized water 20 parts.
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Hexamethylene 30 parts,
1-hydroxyl-2-pyridine sulphur copper 18 parts,
Tetra isopropyl metatitanic acid 12 parts,
Sulfatobetaine 20 parts,
Polyvinyl alcohol 50 parts,
Citric acid 5 parts,
Isothiazolinone 4 parts,
White carbon black 2 parts,
SCJ-2000 10 parts,
Wilkinite 10 parts,
Cellulose acetate butyrate 1.2 parts,
Sodium polyacrylate 1.8 parts.
Embodiment 3:
A kind of Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polyimide fiber 10 parts
To diazonium pentanoic poly-formaldehyde condensate 20 parts
Polymeric polyisocyanate block thing 10 parts
Organic silicon modified polyurethane resin 20 parts
Trimethylhexamethylenediamine 15 parts
Stibazole methyl-sulfate salt 5 parts
Lauric aldehyde 6 parts
10 parts, solidifying agent
Propylene glycol monobutyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
10 parts, static inhibitor
Pucherite 9 parts
Methyl-tert .-butyl ketone 0.3 part
Cyclopentanone 0.4 part
12 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 10 parts
Deionized water 15 parts.
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Hexamethylene 25 parts,
1-hydroxyl-2-pyridine sulphur copper 16 parts,
Tetra isopropyl metatitanic acid 16 parts,
Sulfatobetaine 18 parts,
Polyvinyl alcohol 30 parts,
Citric acid 4 parts,
Isothiazolinone 3.5 parts,
White carbon black 1.5 parts,
SCJ-2000 89 parts,
Wilkinite 58 parts,
Cellulose acetate butyrate 0.8 part,
Sodium polyacrylate 1.2 parts.
Solidifying agent described in above-described embodiment 1-3 is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.
Claims (3)
1. a Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
Trimethylhexamethylenediamine 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Lauric aldehyde 2-8 part
Solidifying agent 8-12 part
Propylene glycol monobutyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Static inhibitor 7-15 part
Pucherite 8-10 part
Methyl-tert .-butyl ketone 0.2-0.5 part
Cyclopentanone 0.2-0.5 part
Calcium carbonate 10-15 part
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8-16 part
Deionized water 10-20 part;
Described static inhibitor comprises the raw material of the following meter of mark by weight:
Hexamethylene 20-30 part,
1-hydroxyl-2-pyridine sulphur copper 15-18 part,
Tetra isopropyl metatitanic acid 10-12 part,
Sulfatobetaine 15-20 part,
Polyvinyl alcohol 10-50 part,
Citric acid 2-5 part,
Isothiazolinone 3-4 part,
White carbon black 1-2 part,
SCJ-2000 8-10 part,
Wilkinite 5-10 part,
Cellulose acetate butyrate 0.2-1.2 part,
Sodium polyacrylate 0.5-1.8 part.
2. Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin according to claim 1, is characterized in that: described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
3. Flame-retardant heat-resistant wear-resistant antistatic ABS modified resin according to claim 1, is characterized in that: the particle diameter of described white carbon black is about 110-150 order.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244951.8A CN104788885A (en) | 2015-05-14 | 2015-05-14 | Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510244951.8A CN104788885A (en) | 2015-05-14 | 2015-05-14 | Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin |
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| CN104788885A true CN104788885A (en) | 2015-07-22 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107663379A (en) * | 2017-10-24 | 2018-02-06 | 蚌埠隆华压铸机有限公司 | Die casting machine Special wear-resistant anti-static material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
| CN103923431A (en) * | 2014-03-18 | 2014-07-16 | 江苏中利电子信息科技有限公司 | Plastic material with metallic appearance and preparation method thereof |
| CN104479281A (en) * | 2014-12-10 | 2015-04-01 | 杭州金州高分子科技有限公司 | High-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material |
-
2015
- 2015-05-14 CN CN201510244951.8A patent/CN104788885A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
| CN103923431A (en) * | 2014-03-18 | 2014-07-16 | 江苏中利电子信息科技有限公司 | Plastic material with metallic appearance and preparation method thereof |
| CN104479281A (en) * | 2014-12-10 | 2015-04-01 | 杭州金州高分子科技有限公司 | High-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107663379A (en) * | 2017-10-24 | 2018-02-06 | 蚌埠隆华压铸机有限公司 | Die casting machine Special wear-resistant anti-static material |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150722 |
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| RJ01 | Rejection of invention patent application after publication |