CN104479281A - High-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material - Google Patents
High-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material Download PDFInfo
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- CN104479281A CN104479281A CN201410749836.1A CN201410749836A CN104479281A CN 104479281 A CN104479281 A CN 104479281A CN 201410749836 A CN201410749836 A CN 201410749836A CN 104479281 A CN104479281 A CN 104479281A
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Abstract
The invention relates to a high-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material, belonging to the technical field of high polymer materials. The alloy material is prepared from ABS, polyphenylether, polycarbonate, a flame retardant, a toughening compatilizer and other assistants. The PC and ABS alloy enhance the shock strength, wear resistance, corrosion resistance and heat resistance of the material, and improve the heat stability and electric insulativity and flame retardancy of the material. The environment-friendly organic flame retardant is added to ensure the impact resistance of the product and enhance the flame retardancy of the material. The PPO and PC materials have flame retardancy, thereby lowering the addition amount of the flame retardant on the premise of achieving the high-flame-retardancy effect. The high-efficiency antioxidant is added to postpone the aging of the product, so that the product can adapt to various environments and can be normally used under severe conditions.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of method of production of high-impact environment-friendly flame-resistant ABS alloy material.
Background technology
ABS material has excellent chemical resistant properties, mechanical property, excellent processing characteristics, is therefore widely used in the industries such as automobile, household electrical appliances, aviation, boats and ships.Along with product is to the continuous demand of material, modified ABS is also more and more commercially to be occurred.The characteristics such as but ABS material self is because of poor fire, heat-resistant stability is not high, and wear resistant corrosion resistant is not strong, electrical insulating property difference, limit the scope that it uses.According to above deficiency, we carry out study on the modification to ABS material.
PC has higher erosion-resisting characteristics, and dimensional stability is high, wear-resisting, corrosion-resistant; PPO high comprehensive performance, water-absorbent is little, outstanding electrical insulating property and water tolerance, dielectric properties occupy plastics first place, there is higher thermostability and flame retardant resistance simultaneously, therefore research preparation ABS, PC, PPO alloy fire retardant material, can increase substantially properties of materials, expand the range of application of material.Simultaneously in order to corresponding European Union requirements, we study fire retardant, develop to meet European Union RoHS and require and the environment friendly flame-proof ABS material reaching V0 grade.
Summary of the invention
For prior art Problems existing, the object of the invention is to design the technical scheme providing a kind of high-impact flame-proof ABS alloy material, this material has excellent mechanical property, high-impact, high abrasion, high flame retardant, the advantages such as good corrosion resistance.
Described a kind of high-impact flame-proof ABS alloy material, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 25 ~ 60 parts, polyphenylene oxide 8 ~ 40 parts, polycarbonate 10 ~ 35 parts, fire retardant 10 ~ 30 parts, toughness reinforcing compatilizer 5 ~ 20 parts and other auxiliary agent 0.5 ~ 5 part.
Described a kind of high-impact flame-proof ABS alloy material, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 35 ~ 50 parts, polyphenylene oxide 10 ~ 30 parts, polycarbonate 15 ~ 30 parts, fire retardant 12 ~ 25 parts, toughness reinforcing compatilizer 8 ~ 15 parts, other auxiliary agent 1 ~ 3 part.
Described a kind of high-impact flame-proof ABS alloy material, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 38 ~ 46 parts, polyphenylene oxide 15 ~ 25 parts, polycarbonate 20 ~ 25 parts, fire retardant 18 ~ 22 parts, toughness reinforcing compatilizer 9 ~ 12 parts, other auxiliary agent 1.5 ~ 2.5 parts.
Described a kind of high-impact flame-proof ABS alloy material, is characterized in that described fire retardant comprises environmental protection level halogen flame and fire retarding synergist, and described environmental protection level halogen flame is brominated triazine, and described fire retarding synergist is antimonous oxide.
Described a kind of high-impact flame-proof ABS alloy material, is characterized in that described toughness reinforcing compatilizer is more than one materials in Zelan 338, GPM450C, SAG001, GPM400 and SAG002.
Described a kind of high-impact flame-proof ABS alloy material, it is characterized in that other described auxiliary agent comprises oxidation inhibitor and processing aid, described oxidation inhibitor is β (3, 5-di-tert-butyl-hydroxy phenyl) propionate, β (3, 5-di-t-butyl-4 hydroxy phenyl) propionic acid octadecyl alcohol ester, 2, 2-sulfo--bis-(4-methyl-6-tert-butylphenol), three (2, 4-DI-tert-butylphenol compounds) more than one materials in phosphorous acid ester and two stearyl alcohol pentaerythritol diphosphites, described processing aid is PETS, N, more than one materials in N '-ethylene bis stearamide.
The present invention compared with prior art, tool has the following advantages and excellent effect: 1) first the present invention by PC and ABS, improve the shock strength of material, wear resistant corrosion resistant, improve the thermotolerance of material simultaneously, PPO material is added again in above alloy, promote further the property of material, thermostability and the insulativity of material are improved, and improve the flame retardant resistance of material simultaneously; 2) secondly the present invention is by the interpolation of environmental protection organic fire-retardant, and ensure that the erosion-resisting characteristics of product, improve the flame retardant resistance of material simultaneously, the present invention carries flame retardant resistance because of PPO and PC material, reduces the addition of fire retardant, also can reach the effect of high flame retardant; 3) the present invention has been added into high-efficiency anti-oxidant, has delayed the aging of product, makes product can adapt to various environment, normally can use under harsh condition.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.The present invention's number used is weight part.
Embodiment 1
1. get acrylonitrile-butadiene-styrene copolymer 40 parts, polyphenylene oxide 20 parts, polycarbonate 20 parts, after toughness reinforcing compatilizer 8 parts mixing, mix and blend 5-10min is stand-by, and described toughness reinforcing compatilizer comprises Zelan 338 4 parts and SAG001:4 part;
2. in the compound handled well, add fire retardant 10 parts and other auxiliary agent 2 parts, high-speed mixing 5-10min, described fire retardant comprises brominated triazine 5 parts and antimonous oxide 5 parts, other described auxiliary agent comprises β (3,5-di-tert-butyl-hydroxy phenyl) propionate 0.5 part, 2,2-sulfo--bis-(4-methyl-6-tert-butylphenol) 0.5 part, three (2,4-DTBP) phosphorous acid ester 0.5 part and PETS0.5 part;
3. by twin screw extruder, added by the above-mentioned mixture mixed, extrude tie rod from major ingredient mouth, cooling, air-dry, then pelletizing, makes modified ABS/PC/PPO alloy fire retardant material.
Embodiment 2
1. get acrylonitrile-butadiene-styrene copolymer 35 parts, polyphenylene oxide 25 parts, polycarbonate 15 parts, after toughness reinforcing compatilizer 5 parts mixing, mix and blend 5-10min is stand-by, and described toughness reinforcing compatilizer comprises GPM400:2 part and SAG002:3 part;
2. in the compound handled well, add fire retardant 15 parts and other auxiliary agent 5 parts, high-speed mixing 5-10min, described fire retardant comprises brominated triazine 12 parts and antimonous oxide 3 parts, other described auxiliary agent is β (3,5-di-t-butyl-4 hydroxy phenyl) propionic acid octadecyl alcohol ester 2 parts, two stearyl alcohol pentaerythritol diphosphites 2 parts and N, N '-ethylene bis stearamide 1 part;
3. by twin screw extruder, added by the above-mentioned mixture mixed, extrude tie rod from major ingredient mouth, cooling, air-dry, then pelletizing, makes modified ABS/PC/PPO alloy fire retardant material.
Embodiment 3
1. get acrylonitrile-butadiene-styrene copolymer 25 parts, polyphenylene oxide 30 parts, polycarbonate 12 parts, after toughness reinforcing compatilizer 20 parts mixing, mix and blend 5-10min is stand-by, and described toughness reinforcing compatilizer comprises GPM450C:10 part and SAG001:10 part
2. in the compound handled well, add fire retardant 12 parts and other auxiliary agent 1 part, high-speed mixing 5-10min, described fire retardant comprises brominated triazine 10 parts and antimonous oxide 2 parts, other described auxiliary agent comprises β (3,5-di-t-butyl-4 hydroxy phenyl) propionic acid octadecyl alcohol ester 0.2 part, 2,2-sulfo--bis-(4-methyl-6-tert-butylphenol) 0.4 part, three (2,4-DI-tert-butylphenol compounds) phosphorous acid ester 0.4 part and N, N '-ethylene bis stearamide 0.2 part;
3. by twin screw extruder, added by the above-mentioned mixture mixed, extrude tie rod from major ingredient mouth, cooling, air-dry, then pelletizing, makes modified ABS/PC/PPO alloy fire retardant material.
Embodiment 4
1. get acrylonitrile-butadiene-styrene copolymer 60 parts, polyphenylene oxide 10 parts, polycarbonate 10 parts, after toughness reinforcing compatilizer 9.5 parts mixing, mix and blend 5-10min is stand-by, and described toughness reinforcing compatilizer is Zelan 338 4.5 parts, GPM400:3 part and SAG001:2 part
2. in the compound handled well, add fire retardant 10 parts and other auxiliary agent 0.5 part, high-speed mixing 5-10min, described fire retardant comprises brominated triazine 9 parts and antimonous oxide 1 part, other described auxiliary agent comprises β (3,5-di-tert-butyl-hydroxy phenyl) propionate 0.1 part, 2,2-sulfo--bis-(4-methyl-6-tert-butylphenol) 0.1 part, three (2,4-DTBP) phosphorous acid ester 0.1 part and PETS0.2 part;
3. by twin screw extruder, added by the above-mentioned mixture mixed, extrude tie rod from major ingredient mouth, cooling, air-dry, then pelletizing, makes modified ABS/PC/PPO alloy fire retardant material.
Following table 1 shows embodiment 1 and adds the contrasting datas such as the physical property of the material that different ratios composition obtains to embodiment 4: comparative example is acrylonitrile-butadiene-styrene copolymer.
Table 1 embodiment correlation data
By above experimental verification, material of the present invention and acrylonitrile-butadiene-styrene copolymer are (compared with ABS starting material, physical property aspect is greatly improved, and meets the requirements such as high strength, high rigidity, high flame retardant, high heat resistance, has met the requirement of premium quality product.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (6)
1. a high-impact flame-proof ABS alloy material, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 25 ~ 60 parts, polyphenylene oxide 8 ~ 40 parts, polycarbonate 10 ~ 35 parts, fire retardant 10 ~ 30 parts, toughness reinforcing compatilizer 5 ~ 20 parts and other auxiliary agent 0.5 ~ 5 part.
2. a kind of high-impact flame-proof ABS alloy material as claimed in claim 1, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 35 ~ 50 parts, polyphenylene oxide 10 ~ 30 parts, polycarbonate 15 ~ 30 parts, fire retardant 12 ~ 25 parts, toughness reinforcing compatilizer 8 ~ 15 parts, other auxiliary agent 1 ~ 3 part.
3. a kind of high-impact flame-proof ABS alloy material as claimed in claim 1, is characterized in that being made up of the raw material of following portions by weight:
Acrylonitrile-butadiene-styrene copolymer 38 ~ 46 parts, polyphenylene oxide 15 ~ 25 parts, polycarbonate 20 ~ 25 parts, fire retardant 18 ~ 22 parts, toughness reinforcing compatilizer 9 ~ 12 parts, other auxiliary agent 1.5 ~ 2.5 parts.
4. a kind of high-impact flame-proof ABS alloy material as described in claim 1,2 or 3, it is characterized in that described fire retardant comprises environmental protection level halogen flame and fire retarding synergist, described environmental protection level halogen flame is brominated triazine, and described fire retarding synergist is antimonous oxide.
5. a kind of high-impact flame-proof ABS alloy material as described in claim 1,2 or 3, is characterized in that described toughness reinforcing compatilizer is more than one materials in Zelan 338, GPM450C, SAG001, GPM400 and SAG002.
6. as claim 1, a kind of high-impact flame-proof ABS alloy material described in 2 or 3, it is characterized in that other described auxiliary agent comprises oxidation inhibitor and processing aid, described oxidation inhibitor is β (3, 5-di-tert-butyl-hydroxy phenyl) propionate, β (3, 5-di-t-butyl-4 hydroxy phenyl) propionic acid octadecyl alcohol ester, 2, 2-sulfo--bis-(4-methyl-6-tert-butylphenol), three (2, 4-DI-tert-butylphenol compounds) more than one materials in phosphorous acid ester and two stearyl alcohol pentaerythritol diphosphites, described processing aid is PETS, N, more than one materials in N '-ethylene bis stearamide.
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| CN201410749836.1A CN104479281A (en) | 2014-12-10 | 2014-12-10 | High-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788885A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin |
| CN105647156A (en) * | 2016-03-07 | 2016-06-08 | 苏州莱特复合材料有限公司 | PPO alloy and preparation method thereof |
| CN106751664A (en) * | 2016-12-14 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of wear resistant and impact resistant thermoplastic compounds and preparation method thereof |
| CN108794968A (en) * | 2018-04-23 | 2018-11-13 | 杭州金州高分子科技有限公司 | A kind of high-strength anti-flaming ABS alloy material and preparation method thereof |
| CN109385063A (en) * | 2018-09-30 | 2019-02-26 | 金旸（厦门）新材料科技有限公司 | A kind of wear-resisting PC/ASA alloy material and preparation method thereof |
| CN110511528A (en) * | 2019-08-23 | 2019-11-29 | 苏州九维电气制造有限公司 | A kind of ABS cable sheath material and its processing technology |
-
2014
- 2014-12-10 CN CN201410749836.1A patent/CN104479281A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788885A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Flame-retardant heat-resistant wear-resistant antistatic ABS (acrylonitrile-butadiene-styrene) modified resin |
| CN105647156A (en) * | 2016-03-07 | 2016-06-08 | 苏州莱特复合材料有限公司 | PPO alloy and preparation method thereof |
| CN106751664A (en) * | 2016-12-14 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of wear resistant and impact resistant thermoplastic compounds and preparation method thereof |
| CN108794968A (en) * | 2018-04-23 | 2018-11-13 | 杭州金州高分子科技有限公司 | A kind of high-strength anti-flaming ABS alloy material and preparation method thereof |
| CN108794968B (en) * | 2018-04-23 | 2020-12-29 | 杭州金州高分子科技有限公司 | High-strength flame-retardant ABS (acrylonitrile-butadiene-styrene) alloy material and preparation method thereof |
| CN109385063A (en) * | 2018-09-30 | 2019-02-26 | 金旸（厦门）新材料科技有限公司 | A kind of wear-resisting PC/ASA alloy material and preparation method thereof |
| CN110511528A (en) * | 2019-08-23 | 2019-11-29 | 苏州九维电气制造有限公司 | A kind of ABS cable sheath material and its processing technology |
| CN110511528B (en) * | 2019-08-23 | 2022-04-05 | 苏州九维电气制造有限公司 | ABS cable sheath material and processing technology thereof |
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Application publication date: 20150401 |