CN104774421A - High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic - Google Patents

High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic Download PDF

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Publication number
CN104774421A
CN104774421A CN201510205349.3A CN201510205349A CN104774421A CN 104774421 A CN104774421 A CN 104774421A CN 201510205349 A CN201510205349 A CN 201510205349A CN 104774421 A CN104774421 A CN 104774421A
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parts
resistant
abs
retardant heat
plastic
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CN201510205349.3A
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Chinese (zh)
Inventor
李凤燕
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Individual
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Individual
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Priority to CN201510205349.3A priority Critical patent/CN104774421A/en
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Abstract

The invention relates to a high-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic which comprises an ABS resin, polyimide fiber, p-diazodiphenylamine polyformaldehyde condensate, polyisocyanate block polymer, an organosilicon modified polyurethane resin, trimethyl hexamethylenediamine, dimethyl stilbazole sulfate, lauraldehyde, a curing agent, propanediol monobutyl ether, polyvinyl alcohol butanol, cadmium sulfoselenide, N-methylpyrrolidone, pucherite isoindoline ketone pigment, methyl tert-butyl ketone, cyclopentanone, 3-methoxy butylacetate, calcium carbonate, N-isopropyl-N'-phenyl p-phenylenediamine and deionized water. The high-glossiness flame-retardant heat-resistant wear-resistant ABS plastic has the characteristics of high hardness, high abrasion resistance, flame retardancy and heat resistance, and has metallic gloss on the surface.

Description

A kind of glazed flame-retardant heat-resistant antifriction ABS plastic
Technical field
The present invention relates to a kind of glazed flame-retardant heat-resistant antifriction ABS plastic.
Background technology
ABS resin plastic cement is that current output is maximum, most widely used polymkeric substance.It has good physical and mechanical property, and shock strength is higher, and chemical stability, electrical property are good, and finished product processing, machining property are good, and water-fast, inorganic salt, soda acid, be a kind of can the engineering materials of widespread use.But current ABS resin plastic cement still exists, and intensity is low, abrasion-resistant surface is poor, flame-proof heat-resistant performance is strong under extreme case, the shortcoming of surface gloss difference.
Summary of the invention
To achieve these goals, the present invention is by the following technical solutions: a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
Trimethylhexamethylenediamine 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Lauric aldehyde 2-8 part
Solidifying agent 8-12 part
Propylene glycol monobutyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Cadmium sulfoselenide 7-15 part
N-Methyl pyrrolidone 1-4 part
Pucherite 8-10 part
Isoindolenone pigments 8-10 part
Methyl-tert .-butyl ketone 0.2-0.5 part
Cyclopentanone 0.2-0.5 part
3-methoxybutyl acetic ester 2-5 part
Calcium carbonate 10-15 part
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8-16 part
Deionized water 10-20 part.
Preferably, described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.
Beneficial effect of the present invention:
1, polyimide fiber, between diazonium pentanoic poly-formaldehyde condensate, polymeric polyisocyanate block thing three kinds of materials produce synergy, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 63%.
2, calcium carbonate, organic silicon modified polyurethane resin, stibazole methyl-sulfate salt composite, significantly promote the wear resistance of plastic surface, make surface of plastic products not easily occur cut.
3, trimethylhexamethylenediamine, lauric aldehyde, propylene glycol monobutyl ether, polyvinyl alcohol contracting butanols, N-sec.-propyl-N '-diphenyl-para-phenylene diamine, cyclopentanone, the composite of methyl-tert .-butyl ketone create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, cadmium sulfoselenide, adding of pucherite make plastic surface only have metalluster, adding of isoindolenone pigments, 3-methoxybutyl acetic ester, N-Methyl pyrrolidone makes the bright spot of plastic surface, glossiness significantly promotes.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of glazed flame-retardant heat-resistant antifriction ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polyimide fiber 8 parts
To diazonium pentanoic poly-formaldehyde condensate 15 parts
Polymeric polyisocyanate block thing 5 parts
Organic silicon modified polyurethane resin 15 parts
Trimethylhexamethylenediamine 10 parts
Stibazole methyl-sulfate salt 3 parts
Lauric aldehyde 2 parts
8 parts, solidifying agent
Propylene glycol monobutyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 7 parts
N-Methyl pyrrolidone 1 part
Pucherite 8 parts
Isoindolenone pigments 8 parts
Methyl-tert .-butyl ketone 0.2 part
Cyclopentanone 0.2 part
3-methoxybutyl acetic ester 2 parts
10 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8 parts
Deionized water 10 parts.
Embodiment 2:
A kind of glazed flame-retardant heat-resistant antifriction ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 100 parts
Polyimide fiber 20 parts
To diazonium pentanoic poly-formaldehyde condensate 30 parts
Polymeric polyisocyanate block thing 15 parts
Organic silicon modified polyurethane resin 25 parts
Trimethylhexamethylenediamine 20 parts
Stibazole methyl-sulfate salt 6 parts
Lauric aldehyde 8 parts
12 parts, solidifying agent
Propylene glycol monobutyl ether 4 parts
4 parts, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 15 parts
N-Methyl pyrrolidone 4 parts
Pucherite 10 parts
Isoindolenone pigments 10 parts
Methyl-tert .-butyl ketone 0.5 part
Cyclopentanone 0.5 part
3-methoxybutyl acetic ester 5 parts
15 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 16 parts
Deionized water 20 parts.
Embodiment 3:
A kind of glazed flame-retardant heat-resistant antifriction ABS plastic, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polyimide fiber 10 parts
To diazonium pentanoic poly-formaldehyde condensate 20 parts
Polymeric polyisocyanate block thing 10 parts
Organic silicon modified polyurethane resin 20 parts
Trimethylhexamethylenediamine 15 parts
Stibazole methyl-sulfate salt 5 parts
Lauric aldehyde 6 parts
10 parts, solidifying agent
Propylene glycol monobutyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
Cadmium sulfoselenide 10 parts
N-Methyl pyrrolidone 2 parts
Pucherite 9 parts
Isoindolenone pigments 9 parts
Methyl-tert .-butyl ketone 0.3 part
Cyclopentanone 0.4 part
3-methoxybutyl acetic ester 3 parts
12 parts, calcium carbonate
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 10 parts
Deionized water 15 parts.
Solidifying agent described in above-described embodiment 1-3 is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof.

Claims (2)

1. a glazed flame-retardant heat-resistant antifriction ABS plastic, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polyimide fiber 8-20 part
To diazonium pentanoic poly-formaldehyde condensate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Organic silicon modified polyurethane resin 15-25 part
Trimethylhexamethylenediamine 10-20 part
Stibazole methyl-sulfate salt 3-6 part
Lauric aldehyde 2-8 part
Solidifying agent 8-12 part
Propylene glycol monobutyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Cadmium sulfoselenide 7-15 part
N-Methyl pyrrolidone 1-4 part
Pucherite 8-10 part
Isoindolenone pigments 8-10 part
Methyl-tert .-butyl ketone 0.2-0.5 part
Cyclopentanone 0.2-0.5 part
3-methoxybutyl acetic ester 2-5 part
Calcium carbonate 10-15 part
N-sec.-propyl-N '-diphenyl-para-phenylene diamine 8-16 part
Deionized water 10-20 part.
2. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, is characterized in that: described solidifying agent is low-molecular-weight polyamide resin, acid anhydrides, boron trifluoride and complex compound thereof etc.
CN201510205349.3A 2015-04-28 2015-04-28 High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic Pending CN104774421A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510205349.3A CN104774421A (en) 2015-04-28 2015-04-28 High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510205349.3A CN104774421A (en) 2015-04-28 2015-04-28 High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic

Publications (1)

Publication Number Publication Date
CN104774421A true CN104774421A (en) 2015-07-15

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CN201510205349.3A Pending CN104774421A (en) 2015-04-28 2015-04-28 High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675816A (en) * 2012-05-22 2012-09-19 苏州新区华士达工程塑胶有限公司 Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene)
CN103232672A (en) * 2013-03-31 2013-08-07 青岛永卓真塑料制品有限公司 Modified ABS high temperature resistant high polymer material
CN103360718A (en) * 2013-07-14 2013-10-23 上海秋橙新材料科技有限公司 Anti-aging ABS-TPU plastic alloy
CN103740040A (en) * 2013-12-26 2014-04-23 苏州市涵信塑业有限公司 ABS (Acrylonitrile Butadiene Styrene) resin-polyethylene composite modified plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675816A (en) * 2012-05-22 2012-09-19 苏州新区华士达工程塑胶有限公司 Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene)
CN103232672A (en) * 2013-03-31 2013-08-07 青岛永卓真塑料制品有限公司 Modified ABS high temperature resistant high polymer material
CN103360718A (en) * 2013-07-14 2013-10-23 上海秋橙新材料科技有限公司 Anti-aging ABS-TPU plastic alloy
CN103740040A (en) * 2013-12-26 2014-04-23 苏州市涵信塑业有限公司 ABS (Acrylonitrile Butadiene Styrene) resin-polyethylene composite modified plastic

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Application publication date: 20150715