CN102675816A - Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) - Google Patents
Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) Download PDFInfo
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- CN102675816A CN102675816A CN2012101590350A CN201210159035A CN102675816A CN 102675816 A CN102675816 A CN 102675816A CN 2012101590350 A CN2012101590350 A CN 2012101590350A CN 201210159035 A CN201210159035 A CN 201210159035A CN 102675816 A CN102675816 A CN 102675816A
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Abstract
The invention discloses a formula of heat-resistant ABS (acrylonitrile-butadiene-styrene), which comprises ABS 121H, an antioxidant, a toughener, a heat resisting agent and an assistant, wherein the antioxidant is thiodipropionate, the toughener is polysulfide rubber, the heat resisting agent is polyimide, and the assistant is chlorinated polyethylene. The heat-resistant ABS is prepared from the following components in percentage by weight: 64.5-66% of ABS 121H, 0.2-0.3% of thiodipropionate, 9-10% of polysulfide rubber, 24.7-25% of polyimide and 0.1-0.2% of chlorinated polyethylene. The heat-resistant ABS has the advantages of shock resistance, favorable mechanical properties, higher toughness, high heat resistance and high chemical resistance.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of heat-proof ABS.
Background technology
ABS is the general thermoplastic engineering plastic that grows up 1940's; It is the very outstanding plastics variety of a comprehensive mechanical property; Not only have favorable rigidity, hardness and processing fluidity, and have the H.T. characteristics, can injection moulding, extrude or thermoforming.All with injection molding forming method processing, the advantage of ABS resin is impact-resistance, sound insulation property, scratch-resistant to most of trolley part, and thermotolerance is better, and is more attractive in appearance than PP, especially at horizontal impact-resistance and the comparatively strict parts of use temperature.ABS resin is to use in the automobile to be only second to Polyurethane and polyacrylic the third-largest resin.ABS resin can be used for Che Nei and car outer enclosure, widgets such as bearing circle, oil guide pipe and handle and button, radiator grill and lampshade etc. before the car outside comprises.ABS resin is processed easily; Finish size stability and surface luster are good; Easily application, painted can also be carried out metallize, plating, welding and suitability for secondary processing such as bonding, can be widely used in field of electronics; Comprise various offices and consumer electronics/electrical equipment, office electrical equipment comprises electronic data processing machine, office equipment.In electronic apparatus market, ABS resin will keep its status in requiring fire-retardant and high heat-stable electronics/electrical equipment market in recent years, fire-retardant and high heat-proof ABS resin with the competition of engineering plastic alloys such as ABS/PC in have remarkable advantages.ABS resin has in the daily necessities field widely to be used, and such as building materials tubing, sheet material or sheet material, has been replaced a part by the more cheap polyvinyl chloride resin of price in recent years.ABS resin is used for and the relevant field of building, and wherein extrusion sheet is used for sanitary apparatus such as bath box, swimming pool lining etc., the tubing of injection moulding and pipe fitting in addition, the produced in small quantities extrusion moulding
Telephone cablePipeline.The AIE Asia-Pacific is international immediately following material market trend; Be devoted to the exploitation and the popularization of ABS material; Release a series of ABS automotive materials with excellent over-all properties and technology performance; The many new A BS matrix materials of exploitation place are like impact, flame retardant resistance, outward appearance, painted etc., for final user's use provides omnidistance support and helps and constantly provide new solution.
Summary of the invention
The object of the present invention is to provide to have shock-resistantly, mechanical property is superior, enhanced toughness, the prescription of a kind of heat-proof ABS of the high and chemical proofing effect of thermotolerance.
Technical scheme of the present invention is: a kind of prescription of heat-proof ABS, comprise ABS121H, oxidation inhibitor, toughner, heat-resistant agent and auxiliary agent, and said oxidation inhibitor is the thio-2 acid dibasic acid esters; Toughner is thiorubber, and heat-resistant agent is a polyimide, and auxiliary agent is a chlorinatedpolyethylene; Each composition weight proportion is that ABS121H accounts for 64.5%-66%, and the thio-2 acid dibasic acid esters accounts for 0.2%-0.3%, and thiorubber accounts for 9%-10%; Polyimide accounts for 24.7%-25%, and chlorinatedpolyethylene accounts for 0.1%-0.2%.
In preferred embodiment of the present invention, said chlorinatedpolyethylene comprises
ResinType chlorinatedpolyethylene and elastomeric-type chlorinatedpolyethylene.
In preferred embodiment of the present invention, each composition weight proportion of the prescription of said heat-proof ABS is that ABS121H accounts for 65.5%, and the thio-2 acid dibasic acid esters accounts for 0.26%, and thiorubber accounts for 9.2%, and polyimide accounts for 24.9%, and chlorinatedpolyethylene accounts for 0.14%.
The prescription of a kind of heat-proof ABS of the present invention has shock-resistantly, and mechanical property is superior, enhanced toughness, the effect of the high and chemical proofing of thermotolerance.
Embodiment
Below in conjunction with preferred embodiment of the present invention is set forth in detail, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
In one embodiment, a kind of prescription of heat-proof ABS comprises ABS121H, oxidation inhibitor, toughner, heat-resistant agent and auxiliary agent, and said oxidation inhibitor is the thio-2 acid dibasic acid esters; Toughner is thiorubber, and heat-resistant agent is a polyimide, and auxiliary agent is a chlorinatedpolyethylene; Each composition weight proportion is that ABS121H accounts for 64.5%-66%, and the thio-2 acid dibasic acid esters accounts for 0.2%-0.3%, and thiorubber accounts for 9%-10%; Polyimide accounts for 24.7%-25%, and chlorinatedpolyethylene accounts for 0.1%-0.2%, and said chlorinatedpolyethylene comprises
ResinType chlorinatedpolyethylene and elastomeric-type chlorinatedpolyethylene.
Further specify, sample test is to place 24 hours in the sample chamber, and the sample chamber temperature remains on 23 ℃, and relative humidity is under 50 ℃:
| Test event | Unit | Testing method | Measured data |
| Dissolve index | g/10min | D1238 | ? |
| Density | g/cm3 | D792 | 1.059 |
| Notched Izod impact strength | J/M | D256 | 120 |
| Bending strength | mpa | D790 | 62.56 |
| The bending amount of touching | mpa | D790 | 2429.45 |
| Tensile strength | mpa | D638 | 43.21 |
| Elongation at break | % | D638 | 17.75 |
Each composition weight proportion of the prescription of said heat-proof ABS is that ABS121H accounts for 65.5%, and the thio-2 acid dibasic acid esters accounts for 0.26%, and thiorubber accounts for 9.2%, and polyimide accounts for 24.9%; Chlorinatedpolyethylene accounts for 0.14%, can debug according to different ratios according to different demands, thereby reach different results of use, and that ABS121H has is shock-resistant; It is superior that the thio-2 acid dibasic acid esters has mechanical property, and thiorubber has enhanced toughness, and polyimide has the thermotolerance height; And chlorinatedpolyethylene has the effect of chemical proofing, and the present invention provides a kind of prescription of heat-proof ABS, has shock-resistant; Mechanical property is superior, enhanced toughness, the effect of thermotolerance height and chemical proofing.
Embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed, and variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of a heat-proof ABS, it is characterized in that: comprise ABS121H, oxidation inhibitor, toughner, heat-resistant agent and auxiliary agent, said oxidation inhibitor is the thio-2 acid dibasic acid esters; Toughner is thiorubber, and heat-resistant agent is a polyimide, and auxiliary agent is a chlorinatedpolyethylene; Each composition weight proportion is that ABS121H accounts for 64.5%-66%, and the thio-2 acid dibasic acid esters accounts for 0.2%-0.3%, and thiorubber accounts for 9%-10%; Polyimide accounts for 24.7%-25%, and chlorinatedpolyethylene accounts for 0.1%-0.2%.
2. the prescription of heat-proof ABS according to claim 1, it is characterized in that: said chlorinatedpolyethylene comprises resin type chlorinatedpolyethylene and elastomeric-type chlorinatedpolyethylene.
3. the prescription of heat-proof ABS according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said heat-proof ABS is that ABS121H accounts for 65.5%, and the thio-2 acid dibasic acid esters accounts for 0.26%, and thiorubber accounts for 9.2%; Polyimide accounts for 24.9%, and chlorinatedpolyethylene accounts for 0.14%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101590350A CN102675816A (en) | 2012-05-22 | 2012-05-22 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101590350A CN102675816A (en) | 2012-05-22 | 2012-05-22 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
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| CN102675816A true CN102675816A (en) | 2012-09-19 |
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| CN2012101590350A Pending CN102675816A (en) | 2012-05-22 | 2012-05-22 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774419A (en) * | 2015-03-25 | 2015-07-15 | 黄山安达尔塑业有限公司 | Heat-resistant stable ABS material and preparation method thereof |
| CN104774418A (en) * | 2015-03-25 | 2015-07-15 | 黄山安达尔塑业有限公司 | Cold-resistant stable ABS material and preparation method thereof |
| CN104774421A (en) * | 2015-04-28 | 2015-07-15 | 李凤燕 | High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic |
| CN104788883A (en) * | 2015-04-28 | 2015-07-22 | 李凤燕 | High-hardness and high-gloss heat and flame resistant ABS plastic |
| CN104945828A (en) * | 2015-05-25 | 2015-09-30 | 孙慧霞 | Board used for drawing spray |
| CN104945829A (en) * | 2015-05-25 | 2015-09-30 | 孙慧霞 | ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray |
| CN105504658A (en) * | 2016-01-07 | 2016-04-20 | 苏州法斯特信息科技有限公司 | Solvent-resistant ABS composite material and preparing method thereof |
| CN107903574A (en) * | 2017-12-27 | 2018-04-13 | 苏州康姆普机械有限公司 | A kind of high-low temperature resistant anti-aging harness |
| CN108676312A (en) * | 2018-04-09 | 2018-10-19 | 南通德瑞森复合材料有限公司 | A kind of cable glass fiber reinforced plastic sheath material and preparation method thereof |
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| CN101659778A (en) * | 2008-10-23 | 2010-03-03 | 青岛科技大学 | Expanded halogen-free flame-retardant ABS compound material |
| CN101831136A (en) * | 2010-04-21 | 2010-09-15 | 深圳市科聚新材料有限公司 | High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof |
| CN102153832A (en) * | 2011-01-27 | 2011-08-17 | 佛山市南海东方塑料制品有限公司 | Processing technology of bromine-containing antiflaming acrylonitrile butadiene styrene (ABS) plastic with stable color |
| CN102391608A (en) * | 2011-10-18 | 2012-03-28 | 金发科技股份有限公司 | Ultrahigh heat-resistant and flame-retardant ABS (acrylonitrile butadiene styrene) composition and preparation method thereof |
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2012
- 2012-05-22 CN CN2012101590350A patent/CN102675816A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101659778A (en) * | 2008-10-23 | 2010-03-03 | 青岛科技大学 | Expanded halogen-free flame-retardant ABS compound material |
| CN101831136A (en) * | 2010-04-21 | 2010-09-15 | 深圳市科聚新材料有限公司 | High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof |
| CN102153832A (en) * | 2011-01-27 | 2011-08-17 | 佛山市南海东方塑料制品有限公司 | Processing technology of bromine-containing antiflaming acrylonitrile butadiene styrene (ABS) plastic with stable color |
| CN102391608A (en) * | 2011-10-18 | 2012-03-28 | 金发科技股份有限公司 | Ultrahigh heat-resistant and flame-retardant ABS (acrylonitrile butadiene styrene) composition and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774419A (en) * | 2015-03-25 | 2015-07-15 | 黄山安达尔塑业有限公司 | Heat-resistant stable ABS material and preparation method thereof |
| CN104774418A (en) * | 2015-03-25 | 2015-07-15 | 黄山安达尔塑业有限公司 | Cold-resistant stable ABS material and preparation method thereof |
| CN104774421A (en) * | 2015-04-28 | 2015-07-15 | 李凤燕 | High-glossiness flame-retardant heat-resistant wear-resistant ABS (acrylonitrile-butadiene-styrene) plastic |
| CN104788883A (en) * | 2015-04-28 | 2015-07-22 | 李凤燕 | High-hardness and high-gloss heat and flame resistant ABS plastic |
| CN104945828A (en) * | 2015-05-25 | 2015-09-30 | 孙慧霞 | Board used for drawing spray |
| CN104945829A (en) * | 2015-05-25 | 2015-09-30 | 孙慧霞 | ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray |
| CN105504658A (en) * | 2016-01-07 | 2016-04-20 | 苏州法斯特信息科技有限公司 | Solvent-resistant ABS composite material and preparing method thereof |
| CN105504658B (en) * | 2016-01-07 | 2017-11-14 | 罗仙花 | A kind of solvent resistance ABS composite material and preparation method thereof |
| CN107903574A (en) * | 2017-12-27 | 2018-04-13 | 苏州康姆普机械有限公司 | A kind of high-low temperature resistant anti-aging harness |
| CN108676312A (en) * | 2018-04-09 | 2018-10-19 | 南通德瑞森复合材料有限公司 | A kind of cable glass fiber reinforced plastic sheath material and preparation method thereof |
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Application publication date: 20120919 |