CN104945828A - Board used for drawing spray - Google Patents
Board used for drawing spray Download PDFInfo
- Publication number
- CN104945828A CN104945828A CN201510269702.4A CN201510269702A CN104945828A CN 104945828 A CN104945828 A CN 104945828A CN 201510269702 A CN201510269702 A CN 201510269702A CN 104945828 A CN104945828 A CN 104945828A
- Authority
- CN
- China
- Prior art keywords
- parts
- sheet material
- naphthol
- pigment
- board used
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007921 spray Substances 0.000 title abstract 3
- 239000000049 pigment Substances 0.000 claims abstract description 15
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 10
- ZVYGIPWYVVJFRW-UHFFFAOYSA-N 3-methylbutyl prop-2-enoate Chemical compound CC(C)CCOC(=O)C=C ZVYGIPWYVVJFRW-UHFFFAOYSA-N 0.000 claims abstract description 7
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims abstract description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004793 Polystyrene Substances 0.000 claims abstract description 7
- 229910001308 Zinc ferrite Inorganic materials 0.000 claims abstract description 7
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims abstract description 7
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims abstract description 7
- CACRRXGTWZXOAU-UHFFFAOYSA-N octadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCCCS(O)(=O)=O CACRRXGTWZXOAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 7
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 7
- 229920002223 polystyrene Polymers 0.000 claims abstract description 7
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 claims abstract description 7
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 17
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 8
- PJKVFARRVXDXAD-UHFFFAOYSA-N 2-naphthaldehyde Chemical compound C1=CC=CC2=CC(C=O)=CC=C21 PJKVFARRVXDXAD-UHFFFAOYSA-N 0.000 claims description 6
- ZUQOBHTUMCEQBG-UHFFFAOYSA-N 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N)=CC=C(S(O)(=O)=O)C2=C1 ZUQOBHTUMCEQBG-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 abstract 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract 2
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 abstract 1
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 abstract 1
- 229950011260 betanaphthol Drugs 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- -1 ABS compound Chemical class 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a board used for drawing spray. The board comprises the following components: ABS (acrylonitrile butadiene styrene copolymers) resin, polystyrene, acrylic acid isoamyl ester, a polyisocyanate block copolymer, diisooctyl phthalate, 1-isoindoline, diethylenetriamine, nitrilotriacetic acid, dipropyleneglycol dimethyl ether, polyvinyl butyral, aluminium isopropoxide, N-methyl pyrrolidone, zinc ferrite, a diketopyrrolopyrrole pigment, octadecyl sulfonate, 2-naphthol, barium sulfate, 1-amino-8-naphthol-4,6-disulphonic acid and deionized water. The board used for drawing spray has high hardness, high surface metal luster wear resistance and the characteristics of flame retardance and heat resistance.
Description
Technical field
The present invention relates to a kind of drawing spraying sheet material, belong to art decoration field.
Background technology
Now, no matter be interior decoration or outdoor advertising panel, all widely use ABS compound resin sheet material, it has, and good material is frivolous, water-fast, the feature of inorganic salt, soda acid, and preparation technology is simple, and therefore production and application amount is huge.But current sheet material shock strength is higher, electrical property is good, finished product processing, machining property are good, and, be a kind of can the engineering materials of widespread use.But current ABS resin sheet material still exists, and intensity is low, poor toughness, abrasion-resistant surface are poor, flame-proof heat-resistant performance is not strong, the shortcoming of surface gloss and tint permanence difference.
Summary of the invention
In order to overcome the deficiency of existing sheet material, the invention provides a kind of drawing spraying sheet material, being grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polystyrene 8-20 part
Isoamyl acrylate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Dimixo-octyl phthalate 15-25 part
1 amino 8 naphthol 4,6 disulfonic acid 8-16 part
1-isoindolinone 10-20 part
Diethylenetriamine 3-6 part
Nitrilotriacetic acid 2-8 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Aluminum isopropylate 7-15 part
N-Methyl pyrrolidone 1-4 part
Zinc ferrite 8-10 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-10 part
Octadecyl sulfonic acid salt 0.2-0.5 part
Beta naphthal 0.2-0.5 part
Barium sulfate 10-15 part
Deionized water 10-20 part.
Preferably, the thickness of described sheet material is about 15-50mm.
Beneficial effect of the present invention:
1, produce synergy between polystyrene, isoamyl acrylate, polymeric polyisocyanate block thing, dimixo-octyl phthalate four kinds of materials, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 68%.
2, barium sulfate, diethylenetriamine composite, significantly promote the wear resistance of plastic surface, make plate surface not easily occur cut.
3,1-isoindolinone, nitrilotriacetic acid, dimethyl ether, polyvinyl alcohol contracting butanols, 1-amino-8-naphthol-4,6-disulfonic acid, beta naphthal, the composite of octadecyl sulfonic acid salt create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, aluminum isopropylate, adding of zinc ferrite make plate surface have metalluster, adding of diketo pyrrolo-pyrrole pigment(DPP pigment), N-Methyl pyrrolidone makes the tack of plate surface pigment, coating, consistency significantly strengthens, and long-time pigment can not fade.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polystyrene 8 parts
Isoamyl acrylate 15 parts
Polymeric polyisocyanate block thing 5 parts
Dimixo-octyl phthalate 15 parts
1 amino 8 naphthol 4,6 disulfonic acid 8 parts
1-isoindolinone 10 parts
Diethylenetriamine 3 parts
Nitrilotriacetic acid 2 parts
Dimethyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
Aluminum isopropylate 7 parts
N-Methyl pyrrolidone 1 part
Zinc ferrite 8 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8 parts
Octadecyl sulfonic acid salt 0.2 part
Beta naphthal 0.2 part
10 parts, barium sulfate
Deionized water 10 parts.
The sheet metal thickness of embodiment 1 is 15mm.
Embodiment 2:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polystyrene 16 parts
Isoamyl acrylate 20 parts
Polymeric polyisocyanate block thing 10 parts
Dimixo-octyl phthalate 20 parts
1 amino 8 naphthol 4,6 disulfonic acid 12 parts
1-isoindolinone 15 parts
Diethylenetriamine 4 parts
Nitrilotriacetic acid 6 parts
Dimethyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
Aluminum isopropylate 12 parts
N-Methyl pyrrolidone 3 parts
Zinc ferrite 9 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 9 parts
Octadecyl sulfonic acid salt 0.3 part
Beta naphthal 0.4 part
12 parts, barium sulfate
Deionized water 15 parts.
The sheet metal thickness of embodiment 2 is 30mm.
Embodiment 3:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 100 parts
Polystyrene 20 parts
Isoamyl acrylate 30 parts
Polymeric polyisocyanate block thing 15 parts
Dimixo-octyl phthalate 25 parts
1 amino 8 naphthol 4,6 disulfonic acid 16 parts
1-isoindolinone 20 parts
Diethylenetriamine 6 parts
Nitrilotriacetic acid 8 parts
Dimethyl ether 4 parts
4 parts, polyvinyl alcohol contracting butanols
Aluminum isopropylate 15 parts
N-Methyl pyrrolidone 4 parts
Zinc ferrite 10 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 10 parts
Octadecyl sulfonic acid salt 0.5 part
Beta naphthal 0.5 part
15 parts, barium sulfate
Deionized water 20 parts.
The sheet metal thickness of embodiment 3 is 50mm.
Claims (2)
1. a drawing spraying sheet material, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-100 part
Polystyrene 8-20 part
Isoamyl acrylate 15-30 part
Polymeric polyisocyanate block thing 5-15 part
Dimixo-octyl phthalate 15-25 part
1 amino 8 naphthol 4,6 disulfonic acid 8-16 part
1-isoindolinone 10-20 part
Diethylenetriamine 3-6 part
Nitrilotriacetic acid 2-8 part
Dimethyl ether 1-4 part
Polyvinyl alcohol contracting butanols 1-4 part
Aluminum isopropylate 7-15 part
N-Methyl pyrrolidone 1-4 part
Zinc ferrite 8-10 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-10 part
Octadecyl sulfonic acid salt 0.2-0.5 part
Beta naphthal 0.2-0.5 part
Barium sulfate 10-15 part
Deionized water 10-20 part.
2. drawing spraying sheet material according to claim 1, is characterized in that: the thickness of described sheet material is about 15-50mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269702.4A CN104945828A (en) | 2015-05-25 | 2015-05-25 | Board used for drawing spray |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269702.4A CN104945828A (en) | 2015-05-25 | 2015-05-25 | Board used for drawing spray |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104945828A true CN104945828A (en) | 2015-09-30 |
Family
ID=54160925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510269702.4A Pending CN104945828A (en) | 2015-05-25 | 2015-05-25 | Board used for drawing spray |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104945828A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
-
2015
- 2015-05-25 CN CN201510269702.4A patent/CN104945828A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151209 Address after: 457000, No. 249 west section of the Yellow River Road, Hualong District, Henan, Puyang Applicant after: Puyang Vocational Technology College Address before: 457000 west section of the Yellow River Road, Henan, Puyang Province, Puyang Vocational and Technical College Applicant before: Sun Huixia |
|
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150930 |
|
| RJ01 | Rejection of invention patent application after publication |