CN104945829A - ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray - Google Patents
ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray Download PDFInfo
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- CN104945829A CN104945829A CN201510269733.XA CN201510269733A CN104945829A CN 104945829 A CN104945829 A CN 104945829A CN 201510269733 A CN201510269733 A CN 201510269733A CN 104945829 A CN104945829 A CN 104945829A
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- parts
- resin composite
- abs resin
- abs
- acid
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 19
- 239000000805 composite resin Substances 0.000 title claims abstract description 8
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title abstract 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract 4
- 239000007921 spray Substances 0.000 title abstract 3
- 229920006026 co-polymeric resin Polymers 0.000 title abstract 2
- 239000000049 pigment Substances 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004793 Polystyrene Substances 0.000 claims abstract description 7
- 229910001308 Zinc ferrite Inorganic materials 0.000 claims abstract description 7
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims abstract description 7
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 claims abstract description 7
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims abstract description 7
- CACRRXGTWZXOAU-UHFFFAOYSA-N octadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCCCS(O)(=O)=O CACRRXGTWZXOAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002223 polystyrene Polymers 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 7
- APRRQJCCBSJQOQ-UHFFFAOYSA-N 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N)=CC(S(O)(=O)=O)=CC2=C1 APRRQJCCBSJQOQ-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229960001860 salicylate Drugs 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 abstract 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 abstract 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 abstract 1
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 abstract 1
- PMGCQNGBLMMXEW-UHFFFAOYSA-N Isoamyl salicylate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1O PMGCQNGBLMMXEW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 abstract 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to an ABS (acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray. The ABS resin composite board comprises the following components: ABS resin, polystyrene, isoamyl salicylate, hydroxyl-terminated polyacrylate, diisooctyl phthalate, phthalimide, 2-acrylamido-2-methylpropanesulfonic acid, nitrilotriacetic acid, dipropyleneglycol dimethyl ether, polyvinyl butyral, pseudo-boehmite powder, N-methyl pyrrolidone, zinc ferrite, a diketopyrrolopyrrole pigment, octadecyl sulfonate, naphthalenediol, titanium dioxide, 1-amino-8-naphthol-3,6-disulphonic acid and deionized water. The board used for drawing spray has high hardness, high surface metal luster wear resistance and the characteristics of flame retardance and heat resistance.
Description
Technical field
The present invention relates to a kind of drawing spraying ABS resin composite sheet, belong to art decoration field.
Background technology
Now, no matter be interior decoration or outdoor advertising panel, all widely use ABS compound resin sheet material, it has, and good material is frivolous, water-fast, the feature of inorganic salt, soda acid, and preparation technology is simple, and therefore production and application amount is huge.But current sheet material shock strength is higher, electrical property is good, finished product processing, machining property are good, and, be a kind of can the engineering materials of widespread use.But current ABS resin sheet material still exists, and intensity is low, poor toughness, abrasion-resistant surface are poor, flame-proof heat-resistant performance is not strong, the shortcoming of surface gloss and tint permanence difference.
Summary of the invention
In order to overcome the deficiency of existing sheet material, the invention provides a kind of drawing spraying ABS resin composite sheet, being grouped into by the one-tenth of following weight parts:
ABS resin 80-120 part
Polystyrene 8-30 part
Salicylate Isomyl 15-30 part
Hydroxy terminated polypropylene acid esters 5-15 part
Dimixo-octyl phthalate 15-25 part
1-amino-8-naphthol-3,6-disulfonic acid 8-18 part
Phthalic imidine 10-20 part
2-acrylamide-2-methyl propane sulfonic 3-6 part
Nitrilotriacetic acid 2-8 part
Dimethyl ether 1-6 part
Polyvinyl alcohol contracting butanols 1-6 part
Pseudo-boehmite powder 7-15 part
N-Methyl pyrrolidone 1-8 part
Zinc ferrite 8-12 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-14 part
Octadecyl sulfonic acid salt 0.2-0.8 part
Naphthalenediol 0.2-0.8 part
Titanium dioxide 10-16 part
Deionized water 10-20 part.
Preferably, the thickness of described sheet material is about 20-60mm.
Beneficial effect of the present invention:
1, produce synergy between polystyrene, Salicylate Isomyl, hydroxy terminated polypropylene acid esters, dimixo-octyl phthalate four kinds of materials, drastically increase hardness and the resistance to bending of plastic surface, wherein the more common ABS plastic of intensity improves 68%.
2, titanium dioxide, 2-acrylamide-2-methyl propane sulfonic composite, significantly promote the wear resistance of plastic surface, make plate surface not easily occur cut.
3, phthalic imidine, nitrilotriacetic acid, dimethyl ether, polyvinyl alcohol contracting butanols, 1-amino-8-naphthol-3,6-disulfonic acid, naphthalenediol, the composite of octadecyl sulfonic acid salt create synergistic effect, improve the flame-proof heat-resistant performance of plastic cement greatly.
4, pseudo-boehmite powder, adding of zinc ferrite plate surface is made to have metalluster, adding of diketo pyrrolo-pyrrole pigment(DPP pigment), N-Methyl pyrrolidone makes the tack of plate surface pigment, coating, consistency significantly strengthens, and long-time pigment can not fade.
Embodiment
Below by embodiment, the present invention is described in detail, should be understood that, these embodiments only can be used for explaining the present invention and can not being used for explaining limitation of the present invention.
Embodiment 1:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 80 parts
Polystyrene 8 parts
Salicylate Isomyl 15 parts
Hydroxy terminated polypropylene acid esters 5 parts
Dimixo-octyl phthalate 15 parts
1-amino-8-naphthol-3,6-disulfonic acid 8 parts
Phthalic imidine 10 parts
2-acrylamide-2-methyl propane sulfonic 3 parts
Nitrilotriacetic acid 2 parts
Dimethyl ether 1 part
1 part, polyvinyl alcohol contracting butanols
7 parts, pseudo-boehmite powder
N-Methyl pyrrolidone 1 part
Zinc ferrite 8 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8 parts
Octadecyl sulfonic acid salt 0.2 part
Naphthalenediol 0.2 part
Titanium dioxide 10 parts
Deionized water 10 parts.
The sheet metal thickness of embodiment 1 is 20mm.
Embodiment 2:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 90 parts
Polystyrene 16 parts
Salicylate Isomyl 20 parts
Hydroxy terminated polypropylene acid esters 10 parts
Dimixo-octyl phthalate 20 parts
1-amino-8-naphthol-3,6-disulfonic acid 12 parts
Phthalic imidine 15 parts
2-acrylamide-2-methyl propane sulfonic 4 parts
Nitrilotriacetic acid 6 parts
Dimethyl ether 2 parts
3 parts, polyvinyl alcohol contracting butanols
12 parts, pseudo-boehmite powder
N-Methyl pyrrolidone 3 parts
Zinc ferrite 9 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 9 parts
Octadecyl sulfonic acid salt 0.3 part
Naphthalenediol 0.4 part
Titanium dioxide 12 parts
Deionized water 15 parts.
The sheet metal thickness of embodiment 2 is 40mm.
Embodiment 3:
A kind of drawing spraying sheet material, is grouped into by the one-tenth of following weight parts:
ABS resin 120 parts
Polystyrene 30 parts
Salicylate Isomyl 30 parts
Hydroxy terminated polypropylene acid esters 15 parts
Dimixo-octyl phthalate 25 parts
1-amino-8-naphthol-3,6-disulfonic acid 18 parts
Phthalic imidine 20 parts
2-acrylamide-2-methyl propane sulfonic 6 parts
Nitrilotriacetic acid 8 parts
Dimethyl ether 6 parts
6 parts, polyvinyl alcohol contracting butanols
15 parts, pseudo-boehmite powder
N-Methyl pyrrolidone 8 parts
Zinc ferrite 12 parts
Diketo pyrrolo-pyrrole pigment(DPP pigment) 14 parts
Octadecyl sulfonic acid salt 0.8 part
Naphthalenediol 0.8 part
Titanium dioxide 16 parts
Deionized water 20 parts.
The sheet metal thickness of embodiment 3 is 60mm.
Claims (2)
1. a drawing spraying ABS resin composite sheet, is characterized in that: be grouped into by the one-tenth of following weight parts:
ABS resin 80-120 part
Polystyrene 8-30 part
Salicylate Isomyl 15-30 part
Hydroxy terminated polypropylene acid esters 5-15 part
Dimixo-octyl phthalate 15-25 part
1-amino-8-naphthol-3,6-disulfonic acid 8-18 part
Phthalic imidine 10-20 part
2-acrylamide-2-methyl propane sulfonic 3-6 part
Nitrilotriacetic acid 2-8 part
Dimethyl ether 1-6 part
Polyvinyl alcohol contracting butanols 1-6 part
Pseudo-boehmite powder 7-15 part
N-Methyl pyrrolidone 1-8 part
Zinc ferrite 8-12 part
Diketo pyrrolo-pyrrole pigment(DPP pigment) 8-14 part
Octadecyl sulfonic acid salt 0.2-0.8 part
Naphthalenediol 0.2-0.8 part
Titanium dioxide 10-16 part
Deionized water 10-20 part.
2. drawing spraying ABS resin composite sheet according to claim 1, is characterized in that: the thickness of described sheet material is about 20-60mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269733.XA CN104945829A (en) | 2015-05-25 | 2015-05-25 | ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269733.XA CN104945829A (en) | 2015-05-25 | 2015-05-25 | ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104945829A true CN104945829A (en) | 2015-09-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510269733.XA Pending CN104945829A (en) | 2015-05-25 | 2015-05-25 | ABS (Acrylonitrile butadiene styrene copolymer) resin composite board used for drawing spray |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104945829A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
-
2015
- 2015-05-25 CN CN201510269733.XA patent/CN104945829A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1562623A (en) * | 2004-03-23 | 2005-01-12 | 孙建宁 | Flame-retardant antistatic high-strength and high-toughness polyvinyl chloride composite pipe and preparation method thereof |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151209 Address after: 457000, No. 249 west section of the Yellow River Road, Hualong District, Henan, Puyang Applicant after: Puyang Vocational Technology College Address before: 457000 west section of the Yellow River Road, Henan, Puyang Province, Puyang Vocational and Technical College Applicant before: Sun Huixia |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150930 |