CN102675748A - Formula of weather-resistant polypropylene - Google Patents
Formula of weather-resistant polypropylene Download PDFInfo
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- CN102675748A CN102675748A CN2012101588670A CN201210158867A CN102675748A CN 102675748 A CN102675748 A CN 102675748A CN 2012101588670 A CN2012101588670 A CN 2012101588670A CN 201210158867 A CN201210158867 A CN 201210158867A CN 102675748 A CN102675748 A CN 102675748A
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Abstract
The invention disclose a formula of weather-resistant polypropylene, which comprises polypropylene, a filler, an antiaging agent, a photostabilizer, an antistatic agent and a plasticizer, wherein the filler is calcium sulfate, the antiaging agent is dilauryl thiodipropionate, the photostabilizer is titanium dioxide, the antistatic agent is calcium phosphate, and the plasticizer is dibutyl phthalate. According to the formula, the weather-resistant polypropylene has the advantages of favorable ultraviolet resistance, favorable oxidation resistance, high plasticity, strong mechanical properties and the like.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of weather-proof polypropylene.
Background technology
In recent years, along with the raising of Vestolen PP 7052 production technique, the improvement of polymerization technique, high-flowability polypropylene Products Development and application obtain remarkable progress; Weather-proof polypropylene has advantages such as good processing characteristics, mechanical property, weather resistance and resistance toheat.The Vestolen PP 7052 injection-molded item is used widely in fields such as packing, transportation, household electrical appliances, automobile, offices.
Polypropylene product is divided into homopolymerization type and copoly type, and copoly type is divided into block copolymerization type and random copolymerization again.When the high workability HOPP receives low-temperature impact, poor toughness, big, the easy buckling deformation of product of molding shrinkage, but its good fluidity, tensile strength, flexural strength height; The high workability COPP has improved low-temperature impact property, has snappiness preferably, has higher flow rate and the physicals of applauding, and makes the design of baroque large thin-wall injection-molded item become feasible; And can shorten the process-cycle in process of production, reduce processing temperature, injection pressure and energy consumption; Having processing can be good, punch die reaches advantages such as the product buckling deformation is few easily; Comparatively speaking, the flowability of COPP is slightly poorer than HOPP, and tensile strength, flexural strength are not as high workability HOPP height.
A lot of polypropylene products all have various situation to occur in use, as fade, situation such as oxidation, deliquescing occur, greatly reduce the attractive in appearance of household electronic products, and shortened work-ing life.Therefore, a kind of weather-proof polypropylene product is our urgent problem.
Summary of the invention
The object of the present invention is to provide the prescription of a kind of antiultraviolet, anti-oxidant, plasticity good, mechanical property is strong weather-proof polypropylene.
Technical scheme of the present invention is; A kind of prescription of weather-proof polypropylene comprises Vestolen PP 7052, weighting agent, inhibitor, photostabilizer, static inhibitor, softening agent, and described weighting agent is a calcium sulfate; The thio-2 acid silicone grease in February that inhibitor is; Photostabilizer is a titanium oxide, and static inhibitor is a calcium phosphate, and softening agent is a Witcizer 300.
In preferred embodiment of the present invention; Each composition weight percent of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 75%-85%; Calcium sulfate accounts for 10%-15%, and thio-2 acid silicone grease in February accounts for 0.5%-1%, and titanium oxide accounts for 1%-1.5%; Calcium phosphate accounts for 1.5%-2.5%, and Witcizer 300 accounts for 2%-5%.
In preferred embodiment of the present invention, each composition proportion of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 78%, and calcium sulfate accounts for 14%, and thio-2 acid silicone grease in February accounts for 0.7%, and titanium oxide accounts for 1.2%, and calcium phosphate accounts for 2.1%, and Witcizer 300 accounts for 4%.
According to the invention is a kind of prescription of weather-proof polypropylene, makes the weather-proof polypropylene that makes have antiultraviolet, anti-oxidant, effect such as plasticity good, mechanical property is strong.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of weather-proof polypropylene; Comprise Vestolen PP 7052, weighting agent, inhibitor, photostabilizer, static inhibitor, softening agent; Described weighting agent is a calcium sulfate, the thio-2 acid silicone grease in February that inhibitor is, and photostabilizer is a titanium oxide; Static inhibitor is a calcium phosphate, and softening agent is a Witcizer 300.
Further, each composition weight percent of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 75%-85%, and calcium sulfate accounts for 10%-15%; Thio-2 acid silicone grease in February accounts for 0.5%-1%; Titanium oxide accounts for 1%-1.5%, and calcium phosphate accounts for 1.5%-2.5%, and Witcizer 300 accounts for 2%-5%.
Further, each composition proportion of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 78%, and calcium sulfate accounts for 14%, and thio-2 acid silicone grease in February accounts for 0.7%, and titanium oxide accounts for 1.2%, and calcium phosphate accounts for 2.1%, and Witcizer 300 accounts for 4%.
Wherein, the physicals of this weather-proof polypropylene is through following testing method and test condition: placed 24 hours 23 ℃ of probe temperatures, 50 ℃ of relative humidity in room temperature.Table specific as follows:
Test event | Unit | Testing method | Measured data |
Solubility exponent | g/10min | D1238 | 3 |
Density | g/cm3 | D792 | 0.995 |
Notched Izod impact strength | J/M | D256 | 189 |
Bending strength | mpa | D790 | 23.4 |
Modulus in flexure | mpa | D790 | 1100.64 |
Tensile strength | mpa | D638 | 27.5 |
Elongation at break | % | D638 | 798.66 |
Can debug according to different ratios according to different demands, thereby reach different results of use.This product is applicable to all kinds of outdoor products, like Mosquito killer lamp, and products such as outdoor billboard.
According to the invention is a kind of prescription of weather-proof polypropylene, makes the weather-proof polypropylene that makes have antiultraviolet, anti-oxidant, effect such as plasticity good, mechanical property is strong.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of a weather-proof polypropylene; It is characterized in that: comprise Vestolen PP 7052, weighting agent, inhibitor, photostabilizer, static inhibitor, softening agent; Described weighting agent is a calcium sulfate, the thio-2 acid silicone grease in February that inhibitor is, and photostabilizer is a titanium oxide; Static inhibitor is a calcium phosphate, and softening agent is a Witcizer 300.
2. the prescription of weather-proof polypropylene according to claim 1; It is characterized in that: each composition weight percent of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 75%-85%; Calcium sulfate accounts for 10%-15%, and thio-2 acid silicone grease in February accounts for 0.5%-1%, and titanium oxide accounts for 1%-1.5%; Calcium phosphate accounts for 1.5%-2.5%, and Witcizer 300 accounts for 2%-5%.
3. the prescription of weather-proof polypropylene according to claim 2; It is characterized in that: each composition proportion of the prescription of described weather-proof polypropylene is that Vestolen PP 7052 accounts for 78%; Calcium sulfate accounts for 14%, and thio-2 acid silicone grease in February accounts for 0.7%, and titanium oxide accounts for 1.2%; Calcium phosphate accounts for 2.1%, and Witcizer 300 accounts for 4%.
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CN2012101588670A CN102675748A (en) | 2012-05-22 | 2012-05-22 | Formula of weather-resistant polypropylene |
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CN2012101588670A CN102675748A (en) | 2012-05-22 | 2012-05-22 | Formula of weather-resistant polypropylene |
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CN2012101588670A Pending CN102675748A (en) | 2012-05-22 | 2012-05-22 | Formula of weather-resistant polypropylene |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104562282A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Fishing net thread suitable for being used in seawater |
CN105419103A (en) * | 2015-12-29 | 2016-03-23 | 上海瀚氏模具成型有限公司 | Anti-ageing enhanced PP plastic and preparation method therefor |
CN105774147A (en) * | 2016-03-21 | 2016-07-20 | 林云权 | Anti-aging polypropylene sound absorption cotton and process for preparing same |
CN106574089A (en) * | 2014-04-02 | 2017-04-19 | Sabic环球技术有限责任公司 | Polymer composition having low sensory impression of smell |
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CN1780606A (en) * | 2003-02-28 | 2006-05-31 | 萨尔格莱尼克斯创新公司 | Fibrate tablet and method for the production thereof |
CN101870784A (en) * | 2010-03-29 | 2010-10-27 | 金发科技股份有限公司 | Impact resisting weather-proof polypropylene and preparation method thereof |
CN102336969A (en) * | 2011-09-20 | 2012-02-01 | 上海金发科技发展有限公司 | Glass-fiber reinforced polypropylene material used for communication connector box and preparation method of glass-fiber reinforced polypropylene material |
-
2012
- 2012-05-22 CN CN2012101588670A patent/CN102675748A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1780606A (en) * | 2003-02-28 | 2006-05-31 | 萨尔格莱尼克斯创新公司 | Fibrate tablet and method for the production thereof |
CN101870784A (en) * | 2010-03-29 | 2010-10-27 | 金发科技股份有限公司 | Impact resisting weather-proof polypropylene and preparation method thereof |
CN102336969A (en) * | 2011-09-20 | 2012-02-01 | 上海金发科技发展有限公司 | Glass-fiber reinforced polypropylene material used for communication connector box and preparation method of glass-fiber reinforced polypropylene material |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106574089A (en) * | 2014-04-02 | 2017-04-19 | Sabic环球技术有限责任公司 | Polymer composition having low sensory impression of smell |
CN106574089B (en) * | 2014-04-02 | 2020-03-03 | Sabic环球技术有限责任公司 | Polymer composition with low olfactory sensory impression |
CN104562282A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Fishing net thread suitable for being used in seawater |
CN105419103A (en) * | 2015-12-29 | 2016-03-23 | 上海瀚氏模具成型有限公司 | Anti-ageing enhanced PP plastic and preparation method therefor |
CN105774147A (en) * | 2016-03-21 | 2016-07-20 | 林云权 | Anti-aging polypropylene sound absorption cotton and process for preparing same |
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Application publication date: 20120919 |