CN105038096A - White high-brightness weather-proof material containing ABS resin and preparation method of white high-brightness weather-proof material - Google Patents
White high-brightness weather-proof material containing ABS resin and preparation method of white high-brightness weather-proof material Download PDFInfo
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- CN105038096A CN105038096A CN201510570275.3A CN201510570275A CN105038096A CN 105038096 A CN105038096 A CN 105038096A CN 201510570275 A CN201510570275 A CN 201510570275A CN 105038096 A CN105038096 A CN 105038096A
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Abstract
The invention discloses a white high-brightness weather-proof material containing ABS resin and a preparation method of the white high-brightness weather-proof material. The material is formed by mixing the ABS resin, a mixture of the ABS resin, SAN resin, a whitening agent, a surface brightening agent, a lubricating agent, antioxidant, light stabilizer, ultraviolet light absorber and a processing agent. According to the white high-brightness weather-proof material containing the ABS resin, on the basis that the good mechanical performance, chemical performance and processing performance of original resin are reserved, through the coordination of the components, the weather-proof performance of the resin is greatly improved, the high surface brightness of the material is achieved, and perception is good. The production process is simple, cost is low, and the white high-brightness weather-proof material can be widely applied to the fields of electronic and electrical appliances, automobile instruments, household appliances and the like.
Description
Technical field
The invention belongs to Material Field, be specifically related to a kind of high light weatherable materials of white containing ABS resin and preparation method thereof.
Background technology
Existing ABS resin is acrylonitrile-butadiene-styrene copolymer, this resin material has good surface luster and chemical proofing, there is tough and tensile, that matter is hard mechanical property and good processibility, thus be widely used in the fields such as electrical equipment, automobile, machinery.But there is double bond in the molecular structure of ABS resin, thus cause the weathering resistance of resin material poor.
Summary of the invention
The object of the invention is the defect existed for ABS resin, resin material providing a kind of high light weather-proof and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of high light weatherable materials of white containing ABS resin, this material is mixed by ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid, and the mass ratio of each component is followed successively by 30 ~ 90:1 ~ 35:1 ~ 15:1 ~ 15:0.1 ~ 8:0.1 ~ 9:0.1 ~ 7:0.1 ~ 9:0.1 ~ 8; Wherein, described ABS resin mixture is the mixture that ABS resin and acrylonitrile-styrene-acrylic terpolymer and/or methyl methacrylate-divinyl-Pei grafted ethylene copolymer carry out being mixed to form.
In some preferred embodiments: the mass ratio of ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid is followed successively by 65 ~ 85:5 ~ 15:1 ~ 3:3 ~ 8:0.4 ~ 0.8:0.8 ~ 1.6:0.4 ~ 0.8:0.3 ~ 0.9:0.5 ~ 1.
In technical solution of the present invention, in described ABS resin mixture, the content of ABS resin is 40 ~ 60%.
SAN resin described in technical solution of the present invention its melting index under 200 DEG C of conditions is greater than 8g/10min.
Oxidation inhibitor described in technical solution of the present invention is one in irgasfos 168 and antioxidant 1076 or two kinds; Described photostabilizer is hindered amine light stabilizer, and preferred light stablizer is one or more in photostabilizer 770, photostabilizer 622 and photostabilizer 744.
Whitening agent described in technical solution of the present invention is the mixture of titanium dioxide and white dyes, and the mass ratio of titanium dioxide and white dyes is 8 ~ 9:1 ~ 2; Described finishing agent is EVA wax or brightening agent 806; Described lubricant is one or more in EB-FF, PE wax, stearic acid amide, methylene bis stearylamide and ethylene bis stearic acid amide.
UV light absorber described in technical solution of the present invention is the one in UV light absorber UVP, preferred UVP-328.
Processing aid described in technical solution of the present invention is the mixture of one or several in fatty acid amide, silicone oil, white mineral oil, silicone mixture, ethylene bis stearic acid amide.
In technical solution of the present invention, preferred ABS resin is ABS757 resin, and SAN resin is SAN335T resin, and titanium dioxide is titanium dioxide R350.
A preparation method for the above-mentioned high light weatherable materials of white containing ABS resin, the method comprises the steps:
(1) take ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid in mass ratio, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
Twin screw extruder length-to-diameter ratio described in aforesaid method is 36 ~ 44, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 170 ~ 230 DEG C, and screw speed controls at 100 ~ 500 revs/min.
In aforesaid method: ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid mix, and the mass ratio of each component is followed successively by 30 ~ 90:1 ~ 35:1 ~ 15:1 ~ 15:0.1 ~ 8:0.1 ~ 9:0.1 ~ 7:0.1 ~ 9:0.1 ~ 8; Wherein, described ABS resin mixture is the mixture that ABS resin and acrylonitrile-styrene-acrylic terpolymer and/or methyl methacrylate-divinyl-Pei grafted ethylene copolymer carry out being mixed to form.
In aforesaid method preferably: the mass ratio of ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid is followed successively by 65 ~ 85:5 ~ 15:1 ~ 3:3 ~ 8:0.4 ~ 0.8:0.8 ~ 1.6:0.4 ~ 0.8:0.3 ~ 0.9:0.5 ~ 1.
Beneficial effect of the present invention:
The inventive method has selected ABS resin of specific consumption and composition thereof, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid, by the synergy between these components, the product prepared is made to have good weathering resistance, impart the surface brightness that material is higher, perception is good.In addition production technique of the present invention is simple, and cost is low, can be widely used in the fields such as electronic apparatus, gas car instrument, household electrical appliances.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited thereto:
SAN335T resin described in embodiment 1 ~ 12 its melting index under 200 DEG C of conditions is all greater than 8g/10min.
Various raw material in embodiment 1 ~ 12 and auxiliary agent are commercially available general commodity.
Embodiment 1 ~ 3
Raw material used in table 1 embodiment 1 ~ 3 and each amounts of components
Implement the preparation method of 1-3:
(1) by taking ABS resin, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid in table 1, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
Wherein, described twin screw extruder length-to-diameter ratio is 40, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 170 ~ 190 DEG C, and screw speed controls at 100 revs/min.
Embodiment 4 ~ 6
Raw material used in table 2 embodiment 4 ~ 6 and each amounts of components
Preparation method:
(1) by taking ABS resin mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid in table 2, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
Twin screw extruder length-to-diameter ratio described in aforesaid method is 40, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 190 ~ 200 DEG C, and screw speed controls at 200 revs/min.
Raw material used in table 3 embodiment 7 ~ 9 and each amounts of components
Preparation method:
(1) take ABS resin mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid by table 3, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
Twin screw extruder length-to-diameter ratio described in aforesaid method is 36 ~ 44, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 200 ~ 210 DEG C, and screw speed controls at 300 revs/min.
Raw material used in table 4 embodiment 10 ~ 12 and each amounts of components
Preparation method:
(1) take ABS resin mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid by table 4, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
Twin screw extruder length-to-diameter ratio described in aforesaid method is 40, and with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 200 ~ 210 DEG C, and screw speed controls at 500 revs/min.
Performance Detection:
Radial-boom impact tester: XJU-5.5 type, Chengde Jinjian Testing Instrument Co., Ltd.;
The proofing box of Ci5000 xenon lamp artificial climate, ATLAS company of the U.S..
Test method and condition
(1) natural climate weathering test, carries out natural climate weathering test, exposed location Shuande according to GB/T3681-2000 " plastics weather exposure test method ", sample towards south, angle at 45 ° with horizontal plane.
(2) artificial climate aging of xenon lamp test, artificial climate aging of xenon lamp test is carried out according to GB/T16422.2-1999 " plastics laboratory light source test method second section: xenon arc lamp ", test conditions: light source is water-cooled xenon lamp (5kW ~ 14kW), irradiance (340nm): 0.5W/m
2nm, black standard temperature: (65 ± 2) DEG C, relative humidity: (65 ± 5) %, rainfall cycle 18min/102min (water spraying time/not spray cycle time).
The Izod notched impact strength of the aging front and back of ABS is detected by GB/T1843-1996 " plastics izodtest method ".
Result is as table 1-1, table 1-2; Table 2-1, table 2-2; Table 3-1, table 3-2; Table 4-1, table 4-2.
Table 1-1
Table 1-2
Table 2-1
Table 2-2
Table 3-1
Table 3-2
Table 4-1
Table 4-2
In addition, also the sample that embodiment 1 ~ 12 prepares has been carried out the test of tensile strength, elongation at break, flexural strength, modulus in flexure, melting index and surface smoothness, concrete table with test results 5 is as follows: table 5
| Test item | Detect foundation | Detected result |
| Tensile strength (MPa) | GB/T1040-2006 | 42.68～43.59 |
| Elongation at break (%) | GB/T1040-2006 | 15.21～16.32 |
| Flexural strength (MPa) | GB/T9341-2008 | 45.16～48.32 |
| Modulus in flexure (Gpa) | GB/T9341-2008 | 1622.86～1635.29 |
| Melting index (g/10min) | GB/T3682-2008 | 2.2～3.1 |
| Surface smoothness | Range estimation | Gao Guang |
Claims (10)
1. the high light weatherable materials of white containing ABS resin, it is characterized in that this material is mixed by ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid, the mass ratio of each component is followed successively by 30 ~ 90:1 ~ 35:1 ~ 15:1 ~ 15:0.1 ~ 8:0.1 ~ 9:0.1 ~ 7:0.1 ~ 9:0.1 ~ 8; Wherein, described ABS resin mixture is the mixture that ABS resin and acrylonitrile-styrene-acrylic terpolymer and/or methyl methacrylate-divinyl-Pei grafted ethylene copolymer carry out being mixed to form.
2. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: the mass ratio of ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid is followed successively by 65 ~ 85:5 ~ 15:1 ~ 3:3 ~ 8:0.4 ~ 0.8:0.8 ~ 1.6:0.4 ~ 0.8:0.3 ~ 0.9:0.5 ~ 1.
3. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: in ABS resin mixture, the content of ABS resin is 40 ~ 60%.
4. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: described SAN resin its melting index under 200 DEG C of conditions is greater than 8g/10min.
5. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: described oxidation inhibitor is one in irgasfos 168 and antioxidant 1076 or two kinds; Described photostabilizer is hindered amine light stabilizer, and preferred light stablizer is one or more in photostabilizer 770, photostabilizer 622 and photostabilizer 744.
6. the high light weatherable materials of white containing ABS resin according to claim 1, it is characterized in that: described whitening agent is the mixture of titanium dioxide and white dyes, and the mass ratio of titanium dioxide and white dyes is 8 ~ 9:1 ~ 2; Described finishing agent is EVA wax or brightening agent 806; Described lubricant is one or more in EB-FF, PE wax, stearic acid amide, methylene bis stearylamide and ethylene bis stearic acid amide.
7. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: described UV light absorber is the one in UV light absorber UVP, preferred UVP-328.
8. the high light weatherable materials of white containing ABS resin according to claim 1, is characterized in that: described processing aid is the mixture of one or several in fatty acid amide, silicone oil, white mineral oil, silicone mixture, ethylene bis stearic acid amide.
9. a preparation method for the high light weatherable materials of white containing ABS resin described in any one of claim 1-8, is characterized in that: the method comprises the steps:
(1) take ABS resin or its mixture, SAN resin, whitening agent, finishing agent, lubricant, oxidation inhibitor, photostabilizer, UV light absorber and processing aid in mass ratio, after taking, each component is stirred in high-speed mixer fully mixing;
(2) above-mentioned blend is sent in twin screw extruder, through the shearing of screw rod, mixing and conveying, material is able to abundant fusing, mixing, then through extruding, granulation, after dry, packaging becomes finished product.
10. the preparation method of the high light weatherable materials of white containing ABS resin according to claim 9, it is characterized in that: described twin screw extruder length-to-diameter ratio is 36 ~ 44, with accurate temperature controller device and vacuum extractor, wherein extruder temperature controls at 170 ~ 230 DEG C, and screw speed controls at 100 ~ 500 revs/min.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084625A (en) * | 2016-07-29 | 2016-11-09 | 广东壹豪新材料科技股份有限公司 | A kind of weather-proof exempting from sprays high-light ABS |
| CN108250661A (en) * | 2018-01-02 | 2018-07-06 | 合肥永健工贸有限公司 | A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof |
| CN109705514A (en) * | 2018-12-17 | 2019-05-03 | 会通新材料股份有限公司 | A kind of automobile-used ABS material of high fondant-strength and preparation method thereof |
| CN113337067A (en) * | 2021-06-07 | 2021-09-03 | 广东锦湖日丽高分子材料有限公司 | High-weather-resistance high-impact-resistance ABS resin and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100358235B1 (en) * | 1998-12-08 | 2003-02-19 | 주식회사 엘지화학 | Manufacturing method of heat resistant thermoplastic resin excellent in gloss |
| CN103044851A (en) * | 2013-01-21 | 2013-04-17 | 山东大学 | High-gloss ABS (acrylonitrile-butadiene-styrene) alloy and method for preparing same from matte ABS |
| US20130230711A1 (en) * | 2010-11-08 | 2013-09-05 | Lg Hausys, Ltd. | Abs resin composition capable of maintaining high glossiness in thermoforming and abs sheet using same |
| CN103740038A (en) * | 2013-12-12 | 2014-04-23 | 连云港海水化工有限公司 | High-glossiness halogen-free flame-retardant ABS material and preparation method thereof |
-
2015
- 2015-09-02 CN CN201510570275.3A patent/CN105038096A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100358235B1 (en) * | 1998-12-08 | 2003-02-19 | 주식회사 엘지화학 | Manufacturing method of heat resistant thermoplastic resin excellent in gloss |
| US20130230711A1 (en) * | 2010-11-08 | 2013-09-05 | Lg Hausys, Ltd. | Abs resin composition capable of maintaining high glossiness in thermoforming and abs sheet using same |
| CN103044851A (en) * | 2013-01-21 | 2013-04-17 | 山东大学 | High-gloss ABS (acrylonitrile-butadiene-styrene) alloy and method for preparing same from matte ABS |
| CN103740038A (en) * | 2013-12-12 | 2014-04-23 | 连云港海水化工有限公司 | High-glossiness halogen-free flame-retardant ABS material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084625A (en) * | 2016-07-29 | 2016-11-09 | 广东壹豪新材料科技股份有限公司 | A kind of weather-proof exempting from sprays high-light ABS |
| CN108250661A (en) * | 2018-01-02 | 2018-07-06 | 合肥永健工贸有限公司 | A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof |
| CN109705514A (en) * | 2018-12-17 | 2019-05-03 | 会通新材料股份有限公司 | A kind of automobile-used ABS material of high fondant-strength and preparation method thereof |
| CN113337067A (en) * | 2021-06-07 | 2021-09-03 | 广东锦湖日丽高分子材料有限公司 | High-weather-resistance high-impact-resistance ABS resin and preparation method and application thereof |
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Effective date of registration: 20170809 Address after: 222000 Jiangsu Province, Lianyungang City Lianyun District Banqiao Industrial Park, Xianghe Road No. 8 Applicant after: Lianyungang Engineering Investment Group Li Hai Chemical Co., Ltd. Address before: Banqiao Industrial Park in Jiangsu Province, Lianyungang City Lianyun District 222046 longitudinal road four Southeast Applicant before: Lianyungang Sea Water Chemical Co., Ltd. |
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