CN101113225A - ABS composite material - Google Patents
ABS composite material Download PDFInfo
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- CN101113225A CN101113225A CNA2006100368216A CN200610036821A CN101113225A CN 101113225 A CN101113225 A CN 101113225A CN A2006100368216 A CNA2006100368216 A CN A2006100368216A CN 200610036821 A CN200610036821 A CN 200610036821A CN 101113225 A CN101113225 A CN 101113225A
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- abs
- mah
- matrix material
- coupling agent
- oxidation inhibitor
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Abstract
An ABS composite material mainly comprises the components that are expressed by weight portion like: ABS 65-89 portions, glass fiber 5-20 portions, compatilizer 5-10 portions, toughener 1-5 portions, antioxidant 0.1-0.5 portion and resin acceptor 0.05-0.2 portion. The ABS composite material can increase the surface hardness of the ABS by adding the glass fiber so as to meet the requirements concerning the surface hardness by special products. Besides, the toughener that is specially used in the ABS is used in the material, resulting in improving the surface hardness of the ABS without causing toboggan of the toughness of the ABS. Therefore, the ABS composite material provided by the invention has outstanding comprehensive performance, wide application scope and good economic benefits.
Description
Technical field
The present invention relates to polymer Ji Intraoperative field, particularly relate to a kind of macromolecular material.
Background technology
ABS is vinyl cyanide, divinyl, cinnamic multipolymer, has good comprehensive performances: good chemical resistance and processing fluidity and superior heat resistance, toughness, impact property and rigidity, so be widely used in the component of making various machineries, plant and instrument, in addition, ABS also is widely used in making the panel of electric equipment products, in order to keep permanent aesthetic appearance, its surface hardness has been proposed new requirement, and the surface hardness of ABS is relatively low, goods can not satisfy the part product requirements easily by scratch.Therefore, be necessary very much to research and develop a kind of ABS matrix material of high rigidity.
Summary of the invention
In view of above problem, the object of the present invention is to provide a kind of ABS matrix material, this material is in the surface hardness of having improved ABS, and toughness can sharply not descend, and makes it can satisfy the demand of part specialty products.
For achieving the above object, a kind of ABS matrix material provided by the invention, it mainly comprises following component, is expressed as with parts by weight:
ABS 65～89
Glass fibre 5～20
Compatilizer 5～10
Toughner 1～5
Oxidation inhibitor 0.1～0.5
Coupling agent 0.05～0.2
Wherein, described compatible agent can be ABS-g-MAH, SBS-g-MAH, PP-g-MAH or EPDM-g-MAH etc.
Described toughner can be ACR (methacrylic ester-acrylate copolymer), MBS (basic methyl acrylate-butadiene-styrene copolymer), MMB (methyl methacrylate butadi ene copolymer) or ASA (acrylonitrile-styrene-acrylic ester copolymer) etc.
Described oxidation inhibitor can be antioxidant 1010, oxidation inhibitor 2921, antioxidant 1076 etc.
Described coupling agent is preferably silane coupling agent and titanate coupling agent with mass ratio blend in 1: 1.
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 89
Glass fibre 5
PP-g-MAH 5
MBS 1
Oxidation inhibitor 2,921 0.5
Coupling agent 0.05
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 77
Glass fibre 10
PP-g-MAH 10
MBS 3
Oxidation inhibitor 2,921 0.4
Coupling agent 0.1
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 65
Glass fibre 20
PP-g-MAH 10
MBS 5
Oxidation inhibitor 2,921 0.3
Coupling agent 0.2
So as seen, a kind of ABS matrix material provided by the invention, it is by adopting the method for adding glass fibre, improve the surface hardness of ABS, so that it can satisfy the requirement of part specialty products to surface hardness, in addition, this material has been used the toughner of ABS special use simultaneously, when improving the ABS surface hardness, can not cause the toughness of ABS sharply to descend.Therefore, this ABS matrix material provided by the invention, its over-all properties is superior, and applied range has good economic benefits.
Embodiment
Embodiment 1
Take by weighing following material in proportion:
ABS 89
Glass fibre 5
PP-g-MAH 5
MBS 1
Oxidation inhibitor 2,921 0.5
Coupling agent 0.05
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result and the contrast of ABS raw material are as shown in table 1:
Table 1: embodiment 1 gained finished product result and the contrast of ABS raw material
| Project | Testing standard | The ABS raw material | Finished product |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 8.3 |
| Surface hardness | GB/T6739-1996 | HB | 1H |
Embodiment 2
Take by weighing following material in proportion:
ABS 77
Glass fibre 10
PP-g-MAH 10
MBS 3
Oxidation inhibitor 2,921 0.4
Coupling agent 0.1
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result and the contrast of ABS raw material are as shown in table 2:
Table 2: embodiment 2 gained finished product results and the contrast of ABS raw material
| Project | Testing standard | The ABS raw material | Finished product |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 8.0 |
| Surface hardness | GB/T6739-1996 | HB | 1H |
Embodiment 3
Take by weighing following material in proportion:
ABS 65
Glass fibre 20
PP-g-MAH 10
MBS 5
Oxidation inhibitor 2,921 0.3
Coupling agent 0.2
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result and the contrast of ABS raw material are as shown in table 3:
Table 3: embodiment 3 gained finished product results and the contrast of ABS raw material
| Project | Testing standard | The ABS raw material | Finished product |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 7.5 |
| Surface hardness | GB/T6739-1996 | HB | 1H |
The above; only be the preferable feasible embodiment of the present invention; can not therefore promptly limit to interest field of the present invention; concerning being familiar with those of ordinary skill in the art; such as use technical scheme of the present invention and technical conceive to make other various corresponding changes and distortion, and all these changes and distortion all should belong within the protection domain of claim of the present invention.
Claims (8)
1. an ABS matrix material is characterized in that, mainly comprises following component, is expressed as with parts by weight:
ABS 65～89
Glass fibre 5～20
Compatilizer 5～10
Toughner 1～5
Oxidation inhibitor 0.1～0.5
Coupling agent 0.05～0.2
2. a kind of ABS matrix material according to claim 1 is characterized in that described compatilizer can be ABS-g-MAH, SBS-g-MAH, PP-g-MAH or EPDM-g-MAH etc.
3. a kind of ABS matrix material according to claim 1, it is characterized in that described toughner can be ACR (methacrylic ester-acrylate copolymer), MBS (MBS), MMB (methyl methacrylate butadi ene copolymer) or ASA (acrylonitrile-styrene-acrylic ester copolymer) etc.
4. a kind of ABS matrix material according to claim 1 is characterized in that described oxidation inhibitor can be antioxidant 1010, oxidation inhibitor 2921, antioxidant 1076 etc.
5. a kind of ABS matrix material according to claim 1 is characterized in that, described coupling agent is preferably silane coupling agent and titanate coupling agent with mass ratio blend in 1: 1.
6. according to any described a kind of ABS matrix material of claim 1-5, it is characterized in that its screening formulation is expressed as with parts by weight:
ABS 89
Glass fibre 5
PP-g-MAH 5
MBS 1
Oxidation inhibitor 292 10.5
Coupling agent 0.05
7. according to any described a kind of ABS matrix material of claim 1-5, it is characterized in that its screening formulation is expressed as with parts by weight:
ABS 77
Glass fibre 10
PP-g-MAH 10
MBS 3
Oxidation inhibitor 2,921 0.4
Coupling agent 0.1
8. according to any described a kind of ABS matrix material of claim 1-5, it is characterized in that its screening formulation is expressed as with parts by weight:
ABS 65
Glass fibre 20
PP-g-MAH 10
MBS 5
Oxidation inhibitor 2,921 0.3
Coupling agent 0.2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100368216A CN101113225A (en) | 2006-07-28 | 2006-07-28 | ABS composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100368216A CN101113225A (en) | 2006-07-28 | 2006-07-28 | ABS composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101113225A true CN101113225A (en) | 2008-01-30 |
Family
ID=39021762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006100368216A Pending CN101113225A (en) | 2006-07-28 | 2006-07-28 | ABS composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN101113225A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190855A (en) * | 2011-05-31 | 2011-09-21 | 王剑伟 | Formula and manufacture process for ABS (acrylonitrile-butadiene-styrene copolymer) antibacterial board |
| CN102276955A (en) * | 2011-07-18 | 2011-12-14 | 余姚市中发工程塑料有限公司 | Antistatic glass fiber reinforcement ABS (acrylonitrile butadiene styrene) composite material |
| CN102432977A (en) * | 2011-10-17 | 2012-05-02 | 重庆文理学院 | Modified ABS special material and preparation method thereof |
| CN102504471A (en) * | 2011-12-02 | 2012-06-20 | 四川长虹电器股份有限公司 | ABS (acrylonitrile-butadiene-styrene)/fiberglass composite material and preparation method thereof |
| CN101747639B (en) * | 2008-12-12 | 2012-12-12 | 比亚迪股份有限公司 | Wood plastic composite composition, wood plastic composite and preparation method thereof |
| CN103265787A (en) * | 2013-05-28 | 2013-08-28 | 杭州金州高分子科技有限公司 | Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance |
| CN103509310A (en) * | 2012-06-28 | 2014-01-15 | 常州市同裕塑件有限公司 | Plastic cutting ring |
| CN104135297A (en) * | 2014-07-11 | 2014-11-05 | 浙江明磊工具实业有限公司 | Radio |
| CN104479277A (en) * | 2014-11-13 | 2015-04-01 | 苏州威尔德工贸有限公司 | ABS composite material for plastic toys and preparation method thereof |
| CN105566839A (en) * | 2016-02-01 | 2016-05-11 | 佳易容相容剂江苏有限公司 | High-performance anti-aging ABS/GF composite material and preparation method thereof |
| CN105860420A (en) * | 2016-05-31 | 2016-08-17 | 苏州市奎克力电子科技有限公司 | Conductive antiaging ABS (acrylonitrile-butadiene-styrene) composite plastic and preparation method thereof |
| CN106418997A (en) * | 2016-08-31 | 2017-02-22 | 杭州维丽杰旅行用品有限公司 | Locatable high-strength wear-resistant and super-tough hard box |
| CN106633604A (en) * | 2016-12-25 | 2017-05-10 | 合肥会通新材料有限公司 | Low-shrinkage ABS composite for solving problem of abnormal sound and preparation method thereof |
-
2006
- 2006-07-28 CN CNA2006100368216A patent/CN101113225A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747639B (en) * | 2008-12-12 | 2012-12-12 | 比亚迪股份有限公司 | Wood plastic composite composition, wood plastic composite and preparation method thereof |
| CN102190855A (en) * | 2011-05-31 | 2011-09-21 | 王剑伟 | Formula and manufacture process for ABS (acrylonitrile-butadiene-styrene copolymer) antibacterial board |
| CN102276955A (en) * | 2011-07-18 | 2011-12-14 | 余姚市中发工程塑料有限公司 | Antistatic glass fiber reinforcement ABS (acrylonitrile butadiene styrene) composite material |
| CN102276955B (en) * | 2011-07-18 | 2013-04-24 | 余姚市中发工程塑料有限公司 | Antistatic glass fiber reinforcement ABS (acrylonitrile butadiene styrene) composite material |
| CN102432977A (en) * | 2011-10-17 | 2012-05-02 | 重庆文理学院 | Modified ABS special material and preparation method thereof |
| CN102432977B (en) * | 2011-10-17 | 2014-04-02 | 重庆文理学院 | Modified ABS special material and preparation method thereof |
| CN102504471B (en) * | 2011-12-02 | 2014-04-02 | 四川长虹电器股份有限公司 | ABS (acrylonitrile-butadiene-styrene)/fiberglass composite material and preparation method thereof |
| CN102504471A (en) * | 2011-12-02 | 2012-06-20 | 四川长虹电器股份有限公司 | ABS (acrylonitrile-butadiene-styrene)/fiberglass composite material and preparation method thereof |
| CN103509310A (en) * | 2012-06-28 | 2014-01-15 | 常州市同裕塑件有限公司 | Plastic cutting ring |
| CN103265787A (en) * | 2013-05-28 | 2013-08-28 | 杭州金州高分子科技有限公司 | Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance |
| CN104135297A (en) * | 2014-07-11 | 2014-11-05 | 浙江明磊工具实业有限公司 | Radio |
| CN104135297B (en) * | 2014-07-11 | 2016-09-21 | 浙江明磊工具实业有限公司 | A kind of radio |
| CN104479277A (en) * | 2014-11-13 | 2015-04-01 | 苏州威尔德工贸有限公司 | ABS composite material for plastic toys and preparation method thereof |
| CN105566839A (en) * | 2016-02-01 | 2016-05-11 | 佳易容相容剂江苏有限公司 | High-performance anti-aging ABS/GF composite material and preparation method thereof |
| CN105566839B (en) * | 2016-02-01 | 2018-04-17 | 佳易容相容剂江苏有限公司 | A kind of high-performance anti-aging ABS/GF composite materials and preparation method thereof |
| CN105860420A (en) * | 2016-05-31 | 2016-08-17 | 苏州市奎克力电子科技有限公司 | Conductive antiaging ABS (acrylonitrile-butadiene-styrene) composite plastic and preparation method thereof |
| CN105860420B (en) * | 2016-05-31 | 2018-02-02 | 合肥圆融新材料有限公司 | A kind of conductive anti-aging ABS composite plastics and preparation method thereof |
| CN106418997A (en) * | 2016-08-31 | 2017-02-22 | 杭州维丽杰旅行用品有限公司 | Locatable high-strength wear-resistant and super-tough hard box |
| CN106633604A (en) * | 2016-12-25 | 2017-05-10 | 合肥会通新材料有限公司 | Low-shrinkage ABS composite for solving problem of abnormal sound and preparation method thereof |
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