CN101130617B - ABS composite material - Google Patents
ABS composite material Download PDFInfo
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- CN101130617B CN101130617B CN200610037194A CN200610037194A CN101130617B CN 101130617 B CN101130617 B CN 101130617B CN 200610037194 A CN200610037194 A CN 200610037194A CN 200610037194 A CN200610037194 A CN 200610037194A CN 101130617 B CN101130617 B CN 101130617B
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- abs
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- fire retardant
- matrix material
- coupling agent
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Abstract
The invention discloses an ABS composite material, which comprises the following parts: 45-65% ABS, 5-20% glass fiber, 5-10% compatible agent, 1-5% toughening agent, 15-21% bromine-system fire retardant, 5-7% antimony-system fire retardant, 0. 1-0. 5% anti-oxidant, 0. 05-0. 3% manufacturing stabilizer and 0. 05-0. 2% coupler, wherein the ABS composite material adopts the method to add glass fiberinto ABS to improve hardness of the composite material, which satisfies the need of surface hardness for partially special product. The invention modifies the flame resistance, which can prepare the ABS composite material with high flame resistant grade and surface hardness.
Description
Technical field
The present invention relates to polymer Ji Intraoperative field, particularly relate to a kind of macromolecular material.
Background technology
ABS is vinyl cyanide, divinyl, cinnamic multipolymer, has good comprehensive performances: good chemical resistance and processing fluidity and superior heat resistance, toughness, impact property and rigidity, so be widely used in the component of making various machineries, plant and instrument, reach the shell of electrical equipment, instrument.But the surface hardness of ABS is relatively low, and goods can not satisfy the requirement with high surface hardness of part goods easily by scratch, needs further goods to be carried out post-treatment such as spray paint or gloss oil and handles, and production cost is also higher.
Summary of the invention
In view of above problem, the object of the present invention is to provide a kind of ABS matrix material, this ABS composite material surface hardness can reach 1H, has satisfied the requirement of part specialty products to surface hardness.
For achieving the above object, the invention provides a kind of ABS matrix material, it mainly comprises following composition, is expressed as with parts by weight:
ABS 45～65；
Glass fibre 5～20;
Compatilizer 5～10;
Toughner 1～5;
Bromide fire retardant 15～21;
Sb system fire retardant 5～7;
Oxidation inhibitor 0.1～0.5;
Processing stabilizers 0.05～0.3;
Coupling agent 0.05～0.2.
Wherein, described compatible agent can be ABS-g-MAH or PP-g-MAH etc.
Described toughner can be MBS (MBS), SBS-g-MAH, EPDM-g-MAH etc.
Described bromide fire retardant can be brominated polycarbonate, tetrabromo-bisphenol, tetrabromobisphenol a polycarbonate oligopolymer, hexabromocyclododecane or TDE etc.
Described Sb system fire retardant can be antimonous oxide, antimony peroxide or sodium antimonate etc.
Described oxidation inhibitor can be oxidation inhibitor 2921 or antioxidant 1010 etc.
Described processing stabilizers can be phosphoric acid ester, phosphorous acid ester etc.
Described coupling agent is preferably the mixture of silane coupling agent and titanate coupling agent, and wherein said both quality optimization is 1: 1.
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 65；
Glass fibre 5;
PP-g-MAH 5；
MBS 1；
TDE 18;
Antimonous oxide 6;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.05.
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 53；
Glass fibre 10;
PP-g-MAH 10；
MBS 3；
TDE 18;
Antimonous oxide 6;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.1.
Preferably, a kind of ABS matrix material provided by the invention, its component is expressed as with parts by weight:
ABS 45；
Glass fibre 20;
PP-g-MAH 10；
MBS 5；
TDE 15;
Antimonous oxide 5;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.2.
Total the above, ABS matrix material provided by the invention, it adopts the method for adding glass fibre in ABS, to improve the hardness of this matrix material, thereby satisfy the demand of part exotic materials product team surface hardness, simultaneously, this method has also been carried out flame-retardant modified to ABS, prepares a kind of ABS matrix material of flame retardant grade high surface hardness.
Embodiment
Embodiment 1
Take by weighing following material in proportion:
ABS 65；
Glass fibre 5;
PP-g-MAH 5；
MBS 1；
TDE 18;
Antimonous oxide 6;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.05.
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result is more as shown in table 1 with the preceding ABS raw material correlated performance of improvement:
Performance relatively between table 1: embodiment 1 gained finished product and the ABS raw material
| Project | Testing standard | The ABS raw material | The ABS matrix material |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 6.8 |
| Surface hardness | GB/T6739-1996 | HB | 1H |
| Burning rank (3mm) | UL94 | Non-fire-retardant | V-0 |
Embodiment 2
Take by weighing following material in proportion:
ABS 53；
Glass fibre 10;
PP-g-MAH 10；
MBS 3；
TDE 18;
Antimonous oxide 6;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.1.
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result is more as shown in table 2 with the preceding ABS raw material correlated performance of improvement:
Performance relatively between table 2: embodiment 2 gained finished products and the ABS raw material
| Project | Testing standard | The ABS raw material | The ABS matrix material |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 7.9 |
| Surface hardness | GB/T6739-1996 | HB | 1H |
| Burning rank (3mm) | UL94 | Non-fire-retardant | V-0 |
Embodiment 3
Take by weighing following material in proportion:
ABS 45；
Glass fibre 20;
PP-g-MAH 10；
MBS 5；
TDE 15;
Antimonous oxide 5;
Antioxidant 1010 0.4;
Phosphorous acid ester 0.2;
Coupling agent 0.2.
Again this blend composition is passed through mixing granulator in the forcing machine, the gained mixing granulator is made finished product through injection molding, tests its performance then, and its result is more as shown in table 3 with the preceding ABS raw material correlated performance of improvement:
Performance relatively between table 3: embodiment 3 gained finished products and the ABS raw material
| Project | Testing standard | The ABS raw material | The ABS matrix material |
| Notched Izod impact strength (KJ/m 2) | GB/T1843-1996 | 12.5 | 6.1 |
| Surface hardness | GB/T6739-1996 | HB | 2H |
| Burning rank (3mm) | UL94 | Non-fire-retardant | V-0 |
The above; only be the preferable feasible embodiment of the present invention; can not therefore promptly limit to interest field of the present invention; concerning being familiar with those of ordinary skill in the art; such as use technical scheme of the present invention and technical conceive to make other various corresponding changes and distortion, and all these changes and distortion all should belong within the protection domain of claim of the present invention.
Claims (4)
1. an ABS matrix material is characterized in that, mainly comprises following composition, is expressed as with parts by weight:
ABS 45～65；
Glass fibre 5～20;
Compatilizer 5～10;
Toughner 1～5;
Bromide fire retardant 15～21;
Sb system fire retardant 5～7;
Oxidation inhibitor 0.1～0.5;
Processing stabilizers 0.05～0.3;
Coupling agent 0.05～0.2;
Wherein, described compatilizer is ABS-g-MAH or PP-g-MAH; Described toughner is MBS (MBS), SBS-g-MAH, EPDM-g-MAH; Described bromide fire retardant is brominated polycarbonate, tetrabromo-bisphenol, tetrabromobisphenol a polycarbonate oligopolymer, hexabromocyclododecane or TDE; Described Sb system fire retardant is antimonous oxide, antimony peroxide or sodium antimonate.
2. ABS matrix material according to claim 1 is characterized in that, described oxidation inhibitor is oxidation inhibitor 2921 or antioxidant 1010.
3. ABS matrix material according to claim 1 is characterized in that, described processing stabilizers is phosphoric acid ester, phosphorous acid ester.
4. ABS matrix material according to claim 1 is characterized in that, described coupling agent is the mixture of silane coupling agent and titanate coupling agent, and wherein said both mass ratio is 1: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610037194A CN101130617B (en) | 2006-08-25 | 2006-08-25 | ABS composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610037194A CN101130617B (en) | 2006-08-25 | 2006-08-25 | ABS composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101130617A CN101130617A (en) | 2008-02-27 |
| CN101130617B true CN101130617B (en) | 2010-05-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610037194A Expired - Fee Related CN101130617B (en) | 2006-08-25 | 2006-08-25 | ABS composite material |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532789A (en) * | 2010-12-27 | 2012-07-04 | 重庆工商大学 | Glass fiber-reinforced flame-retardant antistatic ABS (Acrylonitrile Butadiene Styrene) plastic formula for treating oil |
| CN102127285A (en) * | 2011-01-30 | 2011-07-20 | 江苏金发科技新材料有限公司 | Flame-retarding reinforced acrylonitrile-butadiene-styrene (ABS) composite material and preparation method thereof |
| CN102234407B (en) * | 2011-05-06 | 2013-03-20 | 深圳市兴盛迪新材料有限公司 | Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof |
| CN102993621B (en) * | 2011-09-13 | 2015-09-30 | 黑龙江鑫达企业集团有限公司 | A kind of HI high impact, high-heat-resisting glass-fiber strengthen flame-retardant ABS compound material and preparation technology thereof |
| CN103265787A (en) * | 2013-05-28 | 2013-08-28 | 杭州金州高分子科技有限公司 | Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance |
| CN103509312A (en) * | 2013-09-11 | 2014-01-15 | 青岛颐世保塑料有限公司 | Flame retardant ABS material |
| CN103724922B (en) * | 2013-12-09 | 2016-09-14 | 天津金发新材料有限公司 | A kind of low abnormal smells from the patient fiber glass reinforced ABS compositions and preparation method thereof |
| CN105086337A (en) * | 2015-09-01 | 2015-11-25 | 深圳市兴邦盛塑胶原料有限公司 | Flame-retarding enhanced ABS composition and preparation method thereof |
| CN105949705A (en) * | 2016-07-11 | 2016-09-21 | 新昌县绿泰塑胶有限公司 | Acrylonitrile-butadiene-styrene (ABS) material |
| CN109679270A (en) * | 2018-11-21 | 2019-04-26 | 苏州市同发塑业有限公司 | A kind of ABS composite material and preparation method thereof of fire-retardant dumb light |
-
2006
- 2006-08-25 CN CN200610037194A patent/CN101130617B/en not_active Expired - Fee Related
Non-Patent Citations (9)
| Title |
|---|
| JP平4-153246A 1992.05.26 |
| JP昭63-278951A 1988.11.16 |
| JP昭64-31848A 1989.02.02 |
| 孙凌刚，周政懋，李响，吕景林.阻燃剂十溴二苯乙烷的合成与应用.塑料33 1.2004,33(1),62. |
| 孙凌刚,周政懋,李响,吕景林.阻燃剂十溴二苯乙烷的合成与应用.塑料33 1.2004,33(1),62. * |
| 肖望东.阻燃ABS及其耐性性研究.工程塑料应用32 11.2004,32(11),14-16. |
| 肖望东.阻燃ABS及其耐性性研究.工程塑料应用32 11.2004,32(11),14-16. * |
| 金敏善，张文华，陈光岩.玻纤增强ABS复合材料的研究.塑料科技 163.2004,(163),1-4. |
| 金敏善,张文华,陈光岩.玻纤增强ABS复合材料的研究.塑料科技 163.2004,(163),1-4. * |
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| CN101130617A (en) | 2008-02-27 |
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