CN103265787A - Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance - Google Patents
Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance Download PDFInfo
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- CN103265787A CN103265787A CN2013102036728A CN201310203672A CN103265787A CN 103265787 A CN103265787 A CN 103265787A CN 2013102036728 A CN2013102036728 A CN 2013102036728A CN 201310203672 A CN201310203672 A CN 201310203672A CN 103265787 A CN103265787 A CN 103265787A
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Abstract
The invention discloses a glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance and belongs to the technical field of high molecular materials. The ABS material consists of the following components: ABS, glass fibers, a compatilizer, a toughening agent, a heat resisting agent, an antioxidant and a processing aid. Compared with the prior art, the ABS material has the following advantages and beneficial effects: (1) the high-efficiency ABS heat resisting agent is adopted, the effect of compatibility with an ABS base material is good, the properties are enhanced remarkably, the heat-resisting temperature of the unmodified ABS material is about 80 DEG C and the heat-resisting temperature of the modified ABS material achieves over 100 DEG C; (2) by the composition of the glass fibers, the heat resistance of the ABS material is enhanced further, so that the heat-resisting temperature of the modified ABS material achieves over 150 DEG C, also, the strength of the material is enhanced and the application field of products is expanded; and (3) the ABS material with high heat resistance and high strength has high rigidity and meanwhile retains certain toughness, so that the application field is expanded further; and the ABS material conforms to national environment protection requirements.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of high-heat-resisting glass-fiber reinforced ABS material.
Background technology
The ABS material has the processing characteristics of excellent chemical resistant properties, mechanical property, excellence, therefore is widely used in industries such as automobile, household electrical appliances, aviation, boats and ships.Along with the continuous demand of product to material, modified ABS also gets more and more and occurs in market.But because there is the defective of poor heat resistance in ABS self, general use temperature can only reach about 80～90 ℃, thereby has limited the Application Areas of ABS.In recent years, along with the development of China's electrical appliance industry, automobile industry and renewal day by day, enlarge thereby introduced a large amount of product lines and scale, these branchs of industry need the ABS resin product of a large amount of high heat resistant types, high strength type, high shock resistance type, high gloss type.And at present, heat-resisting, the high-intensity ABS resin of the domestic ability of not having mass production height, major part or dependence on import.Our company develops the ABS resin product with high strength and high heat resistance requirement by effort.
Summary of the invention
At the problem that prior art exists, the objective of the invention is to design provides a kind of technical scheme with excellent mechanical property and high strength, high heat-resisting modified ABS material.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that being made of following weight proportioning component:
45～75 parts of ABS
10～30 parts of glasses
1～5 part of compatilizer
1～10 part of toughner
5～20 parts of heat-resistant agents
0～2.0 part in oxidation inhibitor
0～2.0 part of processing aid.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that being made of the component of following weight proportioning:
50～70 parts of ABS
15～25 parts of glasses
2～4 parts of compatilizers
2～8 parts of toughner
10～15 parts of heat-resistant agents
0.5～1.5 part in oxidation inhibitor
0.5～1.5 part of processing aid.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that described compatilizer is the phenylethylene-maleic anhydride graft copolymer.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that described toughner is the butadiene type terpolymer.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that described heat-resistant agent is more than one mixtures among N-phenylmaleimide, heat-resistant agent HR-15 and the heat-resistant agent MS-NB.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that described oxidation inhibitor is more than one mixtures among antioxidant 1010, antioxidant 1076, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300 and the oxidation inhibitor DSTP.
Described a kind of high-heat-resisting glass-fiber reinforced ABS material is characterized in that described processing aid is more than one mixtures in stearic acid, Magnesium Stearate and the Palmiticacid.
Various components among the present invention are currently available products, all can buy on market.
The present invention compared with prior art, have following advantage and excellent effect: 1) the present invention has adopted efficient ABS heat-resistant agent, and is compatible with the ABS base-material effective, and performance improves obviously, unmodified heat resisting temperature is about 80 ℃, and the ABS thermotolerance has reached more than 100 ℃ after the modification; 2) compound by glass further improved the thermotolerance of ABS material, and the ABS thermotolerance after the modification has been reached more than 150 ℃, improved the intensity of material simultaneously, enlarged the Application Areas of product; 3) the prepared high heat-resistance high-strength degree ABS material of the present invention, it has higher rigidity, but has also kept certain toughness simultaneously, make Application Areas further enlarge, and this product meets national requirements for environmental protection.
Embodiment
Further specify the present invention below in conjunction with embodiment, the used umber of the present invention is weight part.
It is to change the ABS structure that heat-resistant agent mainly acts on, and improves the softening temperature of ABS, has improved the thermotolerance of material itself; Oxidation inhibitor mainly plays the effect that suppresses and slow down the autoxidation reaction of macromolecular material, prevents that simultaneously polymkeric substance is because of the effect of fading and wearing out of processing or use causes; The adding of processing aid can improve workability, release property and the oilness of material.
Embodiment 1(Comparative Examples 1)
98 parts of ABS, 1 part in oxidation inhibitor (more than one mixtures among antioxidant 1010, antioxidant 1076, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300 and the oxidation inhibitor DSTP), 1 part of processing aid (more than one mixtures in stearic acid, Magnesium Stearate and the Palmiticacid), join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 2(Comparative Examples 2)
1 part of 88 parts of ABS, heat-resistant agent 10 parts of (more than one mixtures among N-phenylmaleimide, heat-resistant agent HR-15 and the heat-resistant agent MS-NB), 1 part in oxidation inhibitor (more than one mixtures among antioxidant 1010, antioxidant 1076, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300 and the oxidation inhibitor DSTP), processing aid (more than one mixtures in stearic acid, Magnesium Stearate and the Palmiticacid), join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 3(Comparative Examples 3)
More than one mixtures among 93 parts of ABS, 5 parts of heat-resistant agents (more than one mixtures among N-phenylmaleimide, heat-resistant agent HR-15 and the heat-resistant agent MS-NB), oxidation inhibitor antioxidant 1010, antioxidant 1076, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300 and the oxidation inhibitor DSTP) 1 part, 1 part of processing aid (more than one mixtures in stearic acid, Magnesium Stearate and the Palmiticacid), join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 4
73 parts of ABS, 10 parts of glasses, 10 parts of N-phenylmaleimides, 1 part of styrene-maleic anhydride copolymer, 1 part of antioxidant 1010,168 1 parts in oxidation inhibitor, 1 part of stearic acid, 3 parts of toughner KT-6, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 5
64 parts of ABS, 20 parts of glasses, 5 parts of heat-resistant agent HR-15,2 parts of styrene-maleic anhydride copolymers, 0.5 part of antioxidant 1076,168 0.5 parts in oxidation inhibitor, 0.5 part of stearic acid, 1 part of Magnesium Stearate, 0.5 part of Palmiticacid, 6 parts of toughner KT-4, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 6
47 parts of ABS, 30 parts of glasses, 15 parts of heat-resistant agent MS-NB, 4 parts of styrene-maleic anhydride copolymers, 1 part of antioxidant 1010,618 1 parts in oxidation inhibitor, 2 parts of Palmiticacid, 10 parts of toughner PS510, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 7
60 parts of ABS, 15 parts of glasses, 8 parts of 7 parts of heat-resistant agent HR-15, heat-resistant agent MS-NB, 2 parts of styrene-maleic anhydride copolymers, 618 2 parts in oxidation inhibitor, 2 parts of Magnesium Stearates, 4 parts of toughner A667, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 8
49 parts of ABS, 25 parts of glasses, 4 parts of N-phenylmaleimides, 4 parts of heat-resistant agent HR-15, heat-resistant agent MS-NB4 part, 5 parts of styrene-maleic anhydride copolymers, 0.5 part of antioxidant 1076,0.5 part of Palmiticacid, 8 parts of toughner KT-6, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Embodiment 9
56 parts of ABS, 20 parts of glasses, 6 parts of 6 parts of heat-resistant agent HR-15, heat-resistant agent MS-NB, 2 parts of styrene-maleic anhydride copolymers, 1 part of antioxidant 1010,1 part of oxidation inhibitor DSTP, 1 part of stearic acid, 1 part of Palmiticacid, 6 parts of toughner A667, join in the high mixer successively, after fully mixing 3-5min, drop into the twin screw extruder mixed melting and extrude, standard test piece processed carries out performance test again.
Above embodiment is carried out physical property measurement, and the result obtains following data:
In sum, material of the present invention is high strength, high heat-resisting ABS material, environmental protection, low toxicity are applicable to commercial scale production, and are applicable to the product material of various high performance requirements.In addition, after the present invention added heat-resistant agent and glass, heat-drawn wire significantly improved.
Claims (7)
1. high-heat-resisting glass-fiber reinforced ABS material is characterized in that being made of following weight proportioning component:
45～75 parts of ABS
10～30 parts of glasses
1～5 part of compatilizer
1～10 part of toughner
5～20 parts of heat-resistant agents
0～2.0 part in oxidation inhibitor
0～2.0 part of processing aid.
2. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 is characterized in that being made of the component of following weight proportioning:
50～70 parts of ABS
15～25 parts of glasses
2～4 parts of compatilizers
2～8 parts of toughner
10～15 parts of heat-resistant agents
0.5～1.5 part in oxidation inhibitor
0.5～1.5 part of processing aid.
3. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 or 2 is characterized in that described compatilizer is the phenylethylene-maleic anhydride graft copolymer.
4. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 or 2 is characterized in that described toughner is the butadiene type terpolymer.
5. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 or 2 is characterized in that described heat-resistant agent is more than one mixtures among N-phenylmaleimide, heat-resistant agent HR-15 and the heat-resistant agent MS-NB.
6. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 or 2 is characterized in that described oxidation inhibitor is more than one mixtures among antioxidant 1010, antioxidant 1076, oxidation inhibitor 168, oxidation inhibitor 618, antioxidant 300 and the oxidation inhibitor DSTP.
7. a kind of high-heat-resisting glass-fiber reinforced ABS material as claimed in claim 1 or 2 is characterized in that described processing aid is more than one mixtures in stearic acid, Magnesium Stearate and the Palmiticacid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013102036728A CN103265787A (en) | 2013-05-28 | 2013-05-28 | Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013102036728A CN103265787A (en) | 2013-05-28 | 2013-05-28 | Glass fiber reinforced ABS (Acrylonitrile Butadiene Styrene) material with high heat resistance |
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| CN103265787A true CN103265787A (en) | 2013-08-28 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104151767A (en) * | 2014-08-12 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Filling modification ABS (Acrylonitrile Butadiene Styrene) material |
| CN105131505A (en) * | 2015-08-31 | 2015-12-09 | 宁波海雨新材料科技有限公司 | Matte-level heat-resistant ABS modified material and preparation method thereof |
| CN105949705A (en) * | 2016-07-11 | 2016-09-21 | 新昌县绿泰塑胶有限公司 | Acrylonitrile-butadiene-styrene (ABS) material |
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| CN101113225A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101130617A (en) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101302323A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Toughened and reinforced ABS material and preparation thereof |
| CN102504471A (en) * | 2011-12-02 | 2012-06-20 | 四川长虹电器股份有限公司 | ABS (acrylonitrile-butadiene-styrene)/fiberglass composite material and preparation method thereof |
| CN102532787A (en) * | 2010-12-28 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | High-heat-resistance high-toughness ABS (acrylonitrile-butadiene-styrene) resin and preparation method thereof |
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| CN101113225A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101130617A (en) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101302323A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Toughened and reinforced ABS material and preparation thereof |
| CN102532787A (en) * | 2010-12-28 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | High-heat-resistance high-toughness ABS (acrylonitrile-butadiene-styrene) resin and preparation method thereof |
| CN102504471A (en) * | 2011-12-02 | 2012-06-20 | 四川长虹电器股份有限公司 | ABS (acrylonitrile-butadiene-styrene)/fiberglass composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104151767A (en) * | 2014-08-12 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Filling modification ABS (Acrylonitrile Butadiene Styrene) material |
| CN105131505A (en) * | 2015-08-31 | 2015-12-09 | 宁波海雨新材料科技有限公司 | Matte-level heat-resistant ABS modified material and preparation method thereof |
| CN105131505B (en) * | 2015-08-31 | 2018-09-21 | 宁波海雨新材料科技有限公司 | A kind of dumb light grade heat-proof ABS modified material and preparation method thereof |
| CN105949705A (en) * | 2016-07-11 | 2016-09-21 | 新昌县绿泰塑胶有限公司 | Acrylonitrile-butadiene-styrene (ABS) material |
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Application publication date: 20130828 |