CN104479277A - ABS composite material for plastic toys and preparation method thereof - Google Patents
ABS composite material for plastic toys and preparation method thereof Download PDFInfo
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- CN104479277A CN104479277A CN201410635928.7A CN201410635928A CN104479277A CN 104479277 A CN104479277 A CN 104479277A CN 201410635928 A CN201410635928 A CN 201410635928A CN 104479277 A CN104479277 A CN 104479277A
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Abstract
The invention provides an ABS composite material for plastic toys, wherein the ABS composite material comprises the following components in parts by weight: 50-80 parts of ABS, 3-8 parts of SBS, 5-20 parts of a composite reinforcing agent, 5-15 parts of a plasticizer, 0.5-2 parts of a lubricant, 0.5-2 parts of an antioxidant, and 2-5 parts of a silane coupling agent, wherein the composite reinforcing agent is prepared by mixing ceramic micro-beads and glass fibers with the weight ratio of 2:1. The invention also discloses a preparation method of the ABS composite material for the plastic toys. The ABS composite material for the plastic toys has relatively good shock-resisting and wear-resisting properties.
Description
Technical field:
The present invention relates to a kind of ABS composite material, particularly relate to a kind of plastic toy ABS composite material and preparation method thereof.
Background technology:
ABS, Chinese acrylonitrile-butadiene-styrene copolymer by name is by vinyl cyanide, and the terpolymer of divinyl and vinylbenzene composition, A represents vinyl cyanide, and B represents divinyl, and S represents vinylbenzene.ABS has excellent electrical property, and surface smoothness is good, dimensional stabilizing, not organic solvent-resistant, is therefore one of plastic material that toy is conventional.The user of plastic toy is infant mostly, unavoidably can be thrown away on the ground, pound on wall or on desktop by infant, be easy to be smashed or grind away, and therefore proposes very high requirement to the shock resistance of toy material and wear resisting property.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of plastic toy ABS composite material, has good shock resistance and wear resisting property.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of plastic toy ABS composite material, it comprises following weight part composition:
Wherein, described composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Preferably, softening agent of the present invention is DOP or DBP.
Preferably, lubricant of the present invention is Zinic stearas or polyethylene wax.
Preferably, oxidation inhibitor of the present invention is antioxidant 1010 or antioxidant 1076.
Preferably, silane coupling agent of the present invention is KH-550 or KH-560.
Another technical problem that the present invention will solve is to provide the preparation method of above-mentioned plastic toy ABS composite material.
For solving the problems of the technologies described above, technical scheme is:
A preparation method for plastic toy ABS composite material, comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, silane coupling agent is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of silane coupling agent while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, softening agent, lubricant, oxidation inhibitor, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Therefore compared with prior art, the present invention has following beneficial effect:
SBS is a kind of plasticized modifier preferably, and it is scattered in ABS, and interface power between ABS is better, effectively can improve the shock resistance of matrix material; Composite fortifier after silane coupler modified can be dispersed in ABS matrix, extraneous Stress transmit can be assigned on glass fibre by ABS, isolated glass fibre is bonded together formation entirety, to resist destruction under extraneous stress and distortion, improve tensile strength and the shock strength of matrix material; Engaging force between ceramic fine bead and ABS matrix is comparatively strong, defines crosslinked preferably, improves the hardness of matrix material, reduce the friction contact area between matrix and external object, therefore significantly improve the wear resisting property of matrix material.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 50 parts, SBS 8 parts, composite fortifier 18 parts, DOP 15 parts, Zinic stearas 2 parts, antioxidant 1010 2 parts, KH-5505 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-550 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-550 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DOP, Zinic stearas, antioxidant 1010, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Embodiment 2
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 80 parts, SBS 3 parts, composite fortifier 9 parts, DBP 5 parts, polyethylene wax 0.5 part, antioxidant 1076 0.5 part, KH-5602 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-560 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-560 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DBP, polyethylene wax, antioxidant 1076, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Embodiment 3
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 70 parts, SBS 7 parts, composite fortifier 5 parts, DOP 12 parts, polyethylene wax 1 part, antioxidant 1076 1 part, KH-5604 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-560 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-560 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DOP, polyethylene wax, antioxidant 1076, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Embodiment 4
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 64 parts, SBS 4 parts, composite fortifier 20 parts, DBP 6 parts, Zinic stearas 1.5 parts, antioxidant 1076 1.5 parts, KH-5603 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-560 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-560 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DBP, Zinic stearas, antioxidant 1076, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Embodiment 5
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 72 parts, SBS 5 parts, composite fortifier 10 parts, DBP 10 parts, Zinic stearas 0.6 part, antioxidant 1010 0.9 part, KH-5602.5 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-560 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-560 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DBP, Zinic stearas, antioxidant 1010, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Embodiment 6
A kind of plastic toy ABS composite material, it comprises following weight part composition: ABS 67 parts, SBS 6 parts, composite fortifier 14 parts, DOP 8 parts, polyethylene wax 0.8 part, antioxidant 1076 0.7 part, KH-5503.5 part; Wherein, composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
Its preparation method comprises the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, KH-550 is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of KH-550 while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, DOP, polyethylene wax, antioxidant 1076, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (6)
1. a plastic toy ABS composite material, is characterized in that: it comprises following weight part composition:
Wherein, described composite fortifier is mixed with the weight ratio of 2:1 by ceramic fine bead and glass fibre.
2. a kind of plastic toy ABS composite material according to claim 1, is characterized in that: described softening agent is DOP or DBP.
3. a kind of plastic toy ABS composite material according to claim 1, is characterized in that: described lubricant is Zinic stearas or polyethylene wax.
4. a kind of plastic toy ABS composite material according to claim 1, is characterized in that: described oxidation inhibitor is antioxidant 1010 or antioxidant 1076.
5. a kind of plastic toy ABS composite material according to claim 1, is characterized in that: described silane coupling agent is KH-550 or KH-560.
6. the preparation method of a kind of plastic toy ABS composite material according to Claims 1 to 5 any one, is characterized in that: comprise the following steps:
(1) by composite fortifier at 100 DEG C dry 3 hours, silane coupling agent is dissolved in ethanolic soln, dried composite fortifier is put into stirrer stir, add the ethanolic soln of silane coupling agent while stirring, stirring is placed in baking oven in 1 hour, at 90 DEG C, drying 3 hours, obtains modification composite fortifier;
(2) ABS, SBS, softening agent, lubricant, oxidation inhibitor, modification composite fortifier are added in high-speed mixer mix 5 minutes, after cooling, obtain compound;
(3) compound is sent into twin screw extruder to extrude, then obtain plastic toy ABS composite material after check rod, granulation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410635928.7A CN104479277A (en) | 2014-11-13 | 2014-11-13 | ABS composite material for plastic toys and preparation method thereof |
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| CN201410635928.7A CN104479277A (en) | 2014-11-13 | 2014-11-13 | ABS composite material for plastic toys and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987649A (en) * | 2015-07-28 | 2015-10-21 | 苏州荣昌复合材料有限公司 | Corrosion-resistant ABS (acrylonitrile butadiene styrene) modified plastic |
| CN106566186A (en) * | 2016-11-10 | 2017-04-19 | 滁州思达机电有限责任公司 | Technology of preparing high-performance distribution box shell from swill-cooked dirty oil |
| CN109651756A (en) * | 2018-12-21 | 2019-04-19 | 天津万塑新材料科技有限公司 | A kind of high-flexibility ABS |
| CN111745886A (en) * | 2020-06-24 | 2020-10-09 | 赣县洪顺工艺厂 | Resin handheld processing technology |
| CN112409745A (en) * | 2020-12-01 | 2021-02-26 | 安徽理工大学 | Pencil surface material |
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| CN101113225A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101130618A (en) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101724220A (en) * | 2009-12-18 | 2010-06-09 | 南京金杉汽车工程塑料有限责任公司 | Heat-resistant abs |
| CN102746606A (en) * | 2012-06-27 | 2012-10-24 | 深圳市科聚新材料有限公司 | Hollow glass bead filling-modified acrylonitrile-butadiene-styrene (ABS) material and preparation method thereof |
| CN103509310A (en) * | 2012-06-28 | 2014-01-15 | 常州市同裕塑件有限公司 | Plastic cutting ring |
| CN103804845A (en) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | High-strength high thermal conductivity ABS master batch and preparation method thereof |
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| CN101113225A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
| CN101130618A (en) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | ABS composite material |
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| CN102746606A (en) * | 2012-06-27 | 2012-10-24 | 深圳市科聚新材料有限公司 | Hollow glass bead filling-modified acrylonitrile-butadiene-styrene (ABS) material and preparation method thereof |
| CN103509310A (en) * | 2012-06-28 | 2014-01-15 | 常州市同裕塑件有限公司 | Plastic cutting ring |
| CN103804845A (en) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | High-strength high thermal conductivity ABS master batch and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987649A (en) * | 2015-07-28 | 2015-10-21 | 苏州荣昌复合材料有限公司 | Corrosion-resistant ABS (acrylonitrile butadiene styrene) modified plastic |
| CN106566186A (en) * | 2016-11-10 | 2017-04-19 | 滁州思达机电有限责任公司 | Technology of preparing high-performance distribution box shell from swill-cooked dirty oil |
| CN109651756A (en) * | 2018-12-21 | 2019-04-19 | 天津万塑新材料科技有限公司 | A kind of high-flexibility ABS |
| CN111745886A (en) * | 2020-06-24 | 2020-10-09 | 赣县洪顺工艺厂 | Resin handheld processing technology |
| CN112409745A (en) * | 2020-12-01 | 2021-02-26 | 安徽理工大学 | Pencil surface material |
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Application publication date: 20150401 |