CN107083014A - A kind of heat resistant and wear resistant polymer composite - Google Patents
A kind of heat resistant and wear resistant polymer composite Download PDFInfo
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- CN107083014A CN107083014A CN201710359518.8A CN201710359518A CN107083014A CN 107083014 A CN107083014 A CN 107083014A CN 201710359518 A CN201710359518 A CN 201710359518A CN 107083014 A CN107083014 A CN 107083014A
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- polymer composite
- heat resistant
- wear resistant
- resistant polymer
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- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 229920000642 polymer Polymers 0.000 title claims abstract description 12
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005011 phenolic resin Substances 0.000 claims abstract description 14
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000003292 glue Substances 0.000 claims description 10
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical group CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003365 glass fiber Substances 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 4
- 235000013312 flour Nutrition 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses the raw material composition of a kind of heat resistant and wear resistant polymer composite, including following parts by weight：80 100 parts of phenolic resin；10 20 parts of glass fibre；5 15 parts of haydite；58 parts of graphite powder；6 10 parts of silica flour；0.15 0.25 parts of accelerator；8 12 parts of coupling agent；10 15 parts of Nano filling.Added with the combination such as glass fibre, haydite and silica flour in material component proposed by the present invention, the resistance to elevated temperatures and anti-wear performance of material are significantly improved, in the use environment available for very fast friction and circulation friction, service life is improved, cost input is low, is easy to improve the economic benefit of enterprise.
Description
Technical field
The present invention relates to technical field of polymer composite materials, more particularly to a kind of heat resistant and wear resistant macromolecule composite wood
Material.
Background technology
Composite be by two or more organic material of different nature, by method physically or chemically,
Macroscopically composition has the material of new capability.Various materials make up for each other's deficiencies and learn from each other in performance, produce cooperative effect, make composite wood
The combination property of material is better than former composition material and meets a variety of requirements.Wherein high polymer material is because generally having many gold
Belong to the advantage that can not replace with inorganic material and obtain rapid development, the development of modern project technology, to high polymer material
Propose higher requirement, but existing high polymer material is existed and worn no resistance, the shortcomings of resistance to elevated temperatures is poor, especially in material
Use environment is expected for circulation friction or during very fast friction, and the friction high temperature of generation causes high polymer material denaturation, aging, firmly crisp,
Gradually lose the premium properties that high polymer material possesses in itself.
Therefore, in order to solve above-mentioned technical problem, the invention provides a kind of new technology.
The content of the invention
It is an object of the invention to provide a kind of heat resistant and wear resistant polymer composite.
It is of the invention to be for the technical scheme that above-mentioned technological deficiency is used：
A kind of heat resistant and wear resistant polymer composite, includes the raw material composition of following parts by weight：
Further, a diameter of 5-10mm of the haydite.
Further, the accelerator is methylimidazole.
Further, the coupling agent is titanate coupling agent.
Further, the Nano filling is aluminium hydroxide, titanium dioxide, the mixture of calcium carbonate.
Further, using phenolic resin as main body formulated phenolic resin glue, remaining component is placed in glue and stirred
30-55min is impregnated, batch mixing is placed in into progress granulation in comminutor thereafter produces.
The beneficial effects of the invention are as follows：Glass fibre, haydite and silica flour are added with material component proposed by the present invention
Deng combination, hence it is evident that improve the resistance to elevated temperatures and anti-wear performance of material, the use environment available for very fast friction and circulation friction
In, service life is improved, and cost input is low, is easy to improve the economic benefit of enterprise.
Embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, the embodiment
It is only used for explaining the present invention, does not constitute the restriction to protection scope of the present invention.
Embodiment 1
80 parts of phenolic resin；
10 parts of glass fibre；
5 parts of haydite
Wherein, a diameter of 5mm of haydite；
Preparation method：Using phenolic resin as main body formulated phenolic resin glue, remaining component of said ratio is placed in
Stirring dipping 30min in glue, is placed in progress granulation in comminutor by batch mixing thereafter and produces.
Embodiment 2
90 parts of phenolic resin；
15 parts of glass fibre；
10 parts of haydite
Wherein, a diameter of 5mm of haydite；
Preparation method：Using phenolic resin as main body formulated phenolic resin glue, remaining component of said ratio is placed in
Stirring dipping 45min in glue, is placed in progress granulation in comminutor by batch mixing thereafter and produces.
Embodiment 3
100 parts of phenolic resin；
20 parts of glass fibre；
15 parts of haydite
Wherein, a diameter of 10mm of haydite；
Preparation method：Using phenolic resin as main body formulated phenolic resin glue, remaining component of said ratio is placed in
Stirring dipping 55min in glue, is placed in progress granulation in comminutor by batch mixing thereafter and produces.
The beneficial effects of the invention are as follows：Glass fibre, haydite and silica flour are added with material component proposed by the present invention
Deng combination, hence it is evident that improve the resistance to elevated temperatures and anti-wear performance of material, the use environment available for very fast friction and circulation friction
In, service life is improved, and cost input is low, is easy to improve the economic benefit of enterprise.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (6)
1. a kind of heat resistant and wear resistant polymer composite, it is characterised in that：Raw material composition including following parts by weight：
2. a kind of heat resistant and wear resistant polymer composite according to claim 1, it is characterised in that：The haydite it is straight
Footpath is 5-10mm.
3. a kind of heat resistant and wear resistant polymer composite according to claim 1, it is characterised in that：The accelerator is
Methylimidazole.
4. a kind of heat resistant and wear resistant polymer composite according to claim 1, it is characterised in that：The coupling agent is
Titanate coupling agent.
5. a kind of heat resistant and wear resistant polymer composite according to claim 1, it is characterised in that：The Nano filling
For aluminium hydroxide, titanium dioxide, calcium carbonate mixture.
6. a kind of preparation method of heat resistant and wear resistant polymer composite according to claim 1, it is characterised in that：With
Remaining component is placed in stirring dipping 30-55min in glue, thereafter will by phenolic resin as main body formulated phenolic resin glue
Batch mixing is placed in progress granulation in comminutor and produced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710359518.8A CN107083014A (en) | 2017-05-19 | 2017-05-19 | A kind of heat resistant and wear resistant polymer composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710359518.8A CN107083014A (en) | 2017-05-19 | 2017-05-19 | A kind of heat resistant and wear resistant polymer composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107083014A true CN107083014A (en) | 2017-08-22 |
Family
ID=59607559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710359518.8A Pending CN107083014A (en) | 2017-05-19 | 2017-05-19 | A kind of heat resistant and wear resistant polymer composite |
Country Status (1)
| Country | Link |
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| CN (1) | CN107083014A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021490A (en) * | 2018-06-25 | 2018-12-18 | 四川创客知佳科技有限公司 | A kind of high-temperature wear-resistant composite material and preparation method thereof |
| CN109486095A (en) * | 2017-09-13 | 2019-03-19 | 中南大学 | A kind of high-performance abrasion-proof phenolic aldehyde based composites and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830029A (en) * | 2015-06-07 | 2015-08-12 | 安徽华美高分子材料科技有限公司 | High-temperature-resistant and abrasion-resistant high-polymer material |
| CN104877311A (en) * | 2015-06-08 | 2015-09-02 | 安徽美腾特种电缆材料有限公司 | High-temperature-resistant and wear-resistant high-molecular material |
| CN105885345A (en) * | 2016-06-21 | 2016-08-24 | 南通志邦新材料科技有限公司 | High-temperature-resistant wear-resistant high polymer composite material |
| CN106084657A (en) * | 2016-06-18 | 2016-11-09 | 合肥浦尔菲电线科技有限公司 | A kind of heat resistant and wear resistant macromolecular material |
-
2017
- 2017-05-19 CN CN201710359518.8A patent/CN107083014A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830029A (en) * | 2015-06-07 | 2015-08-12 | 安徽华美高分子材料科技有限公司 | High-temperature-resistant and abrasion-resistant high-polymer material |
| CN104877311A (en) * | 2015-06-08 | 2015-09-02 | 安徽美腾特种电缆材料有限公司 | High-temperature-resistant and wear-resistant high-molecular material |
| CN106084657A (en) * | 2016-06-18 | 2016-11-09 | 合肥浦尔菲电线科技有限公司 | A kind of heat resistant and wear resistant macromolecular material |
| CN105885345A (en) * | 2016-06-21 | 2016-08-24 | 南通志邦新材料科技有限公司 | High-temperature-resistant wear-resistant high polymer composite material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486095A (en) * | 2017-09-13 | 2019-03-19 | 中南大学 | A kind of high-performance abrasion-proof phenolic aldehyde based composites and preparation method thereof |
| CN109021490A (en) * | 2018-06-25 | 2018-12-18 | 四川创客知佳科技有限公司 | A kind of high-temperature wear-resistant composite material and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170822 |
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