CN105440503A - Flame-retardant PVC waterproof coiled material - Google Patents
Flame-retardant PVC waterproof coiled material Download PDFInfo
- Publication number
- CN105440503A CN105440503A CN201511013936.9A CN201511013936A CN105440503A CN 105440503 A CN105440503 A CN 105440503A CN 201511013936 A CN201511013936 A CN 201511013936A CN 105440503 A CN105440503 A CN 105440503A
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- parts
- coiled material
- flame
- reinforcing filler
- plasticized starch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant PVC waterproof coiled material. The coiled material comprises the following raw materials in parts by weight: 30-40 parts of PVC resin, 10-12 parts of ABS resin, 6-8 parts of thermoplastic polyurethane TPU, 6-8 parts of plasticized starch, 1.2-1.5 parts of a non-ionic surfactant HDC-201, 2-3 parts of an antioxidant, 5-7 parts of polyethylene glass fiber, 4-6 parts of a reinforcing filler, 2-3 parts of stearic acid, 3-5 parts of a flame retardant, 2-4 parts of ethyltriphenylphosphonium bromide. The PVC/ABS coiled material prepared by the formula is balanced in mechanical properties of toughness, hardness and rigidity; the bending strength can reach up to 70 MPa or above; the impact strength is high; through the synergistic effect of the antioxidant and the low-smoke flame retardant, the heat resistance and the flame retardancy of the coiled material are remarkably improved; the highest 0.45 MPa load heat distortion temperature can reach up to 86 DEG C or above; through the addition of plasticized starch, polyethylene glass fiber and the reinforcing filler, the mechanical property, the impact strength and the temperature resistance are fused, so that the comprehensive performance of the coiled material is improved, and the coiled material is high in mobility, good in appearance and excellent in combination property.
Description
Technical field
The invention belongs to web material technical field, be specifically related to a kind of flame-proof PVC waterproof roll.
Background technology
Trevira internal reinforcing type polyvinyl chloride (PVC) waterproof roll is a kind of thermoplastic PVC roll material, this coiled material is using dacron fabric as stiffening web, by special extrusion coating methods technique, make the polymer coiled material that the two-sided polyvinyl chloride plastic bed of material and middle polyester stiffening web are combined into one and are formed.The polyvinyl chloride plastic bed of material of formula advanced person combines with cancellated dacron fabric, makes coiled material have splendid dimensional stability and lower thermal expansivity.Lifting coiled material is directly exposed to the long-term behaviour in physical environment.
ABS resin is one of five large synthetic resins, its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties, also there is the features such as easy processing, product size is stable, surface luster property is good, PC/ABS is polycarbonate and acrylonitrile-butadiene-styrene copolymer and mixture, it is the thermoplastic plastic rubber by polycarbonate (PC) and ABS resin (ABS) coiled material, combine the excellent specific property of bi-material, can be widely used on automotive interior parts, Business Machine, the communication apparatus, electrical home appliances and set lights.
But the exhaust gas volumn of existing PVC/ABS coiled material is large, poor heat stability, poor fluidity, during injection moulding, easy frictional heat causes degraded jaundice, has a strong impact on product appearance and use properties.Therefore, how to produce a kind of flame-proof PVC waterproof roll, have important practical significance.
Summary of the invention
The object of the invention is for deficiency of the prior art, a kind of flame-proof PVC waterproof roll is provided.
The technical scheme that the present invention takes is:
A kind of flame-proof PVC waterproof roll, feed components is composed as follows according to weight fraction:
Polyvinyl chloride resin 30-40 part, ABS resin 10-12 part, thermoplastic polyurethane TPU6-8 part, plasticized starch 6-8 part, nonionic surface active agent HDC-2011.2-1.5 part, oxidation inhibitor 2-3 part, polyethylene-glass fibre 5-7 part, reinforcing filler 4-6 part, stearic acid 2-3 part, fire retardant 3-5 part, Ethyltriphenylphosphonium brimide 2-4 part;
Described oxidation inhibitor is the mixture that phosphite antioxidant JC-242 and oxidation inhibitor DNP form according to weight ratio 1:1;
The mixture that described low-smoke and flame retardant agent is clorafin, hexabromo ring tridecane and molybdenum oxide form according to weight ratio 3:2:2.
Further, described reinforcing filler be maleic anhydride graft, silicone powder and titanium dioxide according to weight ratio 2:2:3 waterproof roll, feed components is composed as follows according to weight fraction:
Polyvinyl chloride resin 30-40 part, ABS resin 10-12 part, thermoplastic polyurethane TPU6-8 part, plasticized starch 6-8 part, nonionic surface active agent HDC-2011.2-1.5 part, oxidation inhibitor 2-3 part, polyethylene-glass fibre 5-7 part, reinforcing filler 4-6 part, stearic acid 2-3 part, fire retardant 3-5 part, Ethyltriphenylphosphonium brimide 2-4 part;
Described oxidation inhibitor is the mixture that phosphite antioxidant JC-242 and oxidation inhibitor DNP form according to weight ratio 1:1;
The mixture that described low-smoke and flame retardant agent is clorafin, hexabromo ring tridecane and molybdenum oxide form according to weight ratio 3:2:2.
Further, described reinforcing filler is that maleic anhydride graft, silicone powder and titanium dioxide are according to weight ratio 2:2:3
Described oxidation inhibitor is the mixture that phosphite antioxidant JC-242 and oxidation inhibitor DNP form according to weight ratio 1:1;
The mixture that described low-smoke and flame retardant agent is clorafin, hexabromo ring tridecane and molybdenum oxide form according to weight ratio 3:2:2.
Further, described reinforcing filler is the mixture that maleic anhydride graft, silicone powder and titanium dioxide form according to weight ratio 2:2:3.
Further, the described reinforcing filler plasticized starch that to be plasticized starch be containing 4-5% magnesium hydroxide.
Embodiment 2
A kind of flame-proof PVC waterproof roll, feed components is composed as follows according to weight fraction:
Polyvinyl chloride resin 40 parts, ABS resin 12 parts, thermoplastic polyurethane TPU8 part, plasticized starch 8 parts, nonionic surface active agent HDC-2011.5 part, 3 parts, oxidation inhibitor, polyethylene-glass fibre 7 parts, reinforcing filler 6 parts, stearic acid 3 parts, fire retardant 5 parts, Ethyltriphenylphosphonium brimide 4 parts;
Described oxidation inhibitor is the mixture that phosphite antioxidant JC-242 and oxidation inhibitor DNP form according to weight ratio 1:1;
The mixture that described low-smoke and flame retardant agent is clorafin, hexabromo ring tridecane and molybdenum oxide form according to weight ratio 3:2:2.
Further, described reinforcing filler is the mixture that maleic anhydride graft, silicone powder and titanium dioxide form according to weight ratio 2:2:3.
Further, the described reinforcing filler plasticized starch that to be plasticized starch be containing 4-5% magnesium hydroxide.
Claims (3)
1. a flame-proof PVC waterproof roll, is characterized in that, feed components is composed as follows according to weight fraction:
Polyvinyl chloride resin 30-40 part, ABS resin 10-12 part, thermoplastic polyurethane TPU6-8 part, plasticized starch 6-8 part, nonionic surface active agent HDC-2011.2-1.5 part, oxidation inhibitor 2-3 part, polyethylene-glass fibre 5-7 part, reinforcing filler 4-6 part, stearic acid 2-3 part, fire retardant 3-5 part, Ethyltriphenylphosphonium brimide 2-4 part;
Described oxidation inhibitor is the mixture that phosphite antioxidant JC-242 and oxidation inhibitor DNP form according to weight ratio 1:1;
The mixture that described low-smoke and flame retardant agent is clorafin, hexabromo ring tridecane and molybdenum oxide form according to weight ratio 3:2:2.
2. a kind of flame-proof PVC waterproof roll according to claim 1, is characterized in that, described reinforcing filler is the mixture that maleic anhydride graft, silicone powder and titanium dioxide form according to weight ratio 2:2:3.
3. a kind of flame-proof PVC waterproof roll according to claim 1, is characterized in that, the described reinforcing filler plasticized starch that to be plasticized starch be containing 4-5% magnesium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511013936.9A CN105440503A (en) | 2015-12-31 | 2015-12-31 | Flame-retardant PVC waterproof coiled material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511013936.9A CN105440503A (en) | 2015-12-31 | 2015-12-31 | Flame-retardant PVC waterproof coiled material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105440503A true CN105440503A (en) | 2016-03-30 |
Family
ID=55551172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511013936.9A Pending CN105440503A (en) | 2015-12-31 | 2015-12-31 | Flame-retardant PVC waterproof coiled material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105440503A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192323A (en) * | 2017-12-11 | 2018-06-22 | 浙江金华天开电子材料有限公司 | A kind of wear-resisting PVC coiled material and preparation method thereof |
| CN109181159A (en) * | 2018-08-27 | 2019-01-11 | 潍坊天元防水材料股份有限公司 | A kind of flame retardant type PVC waterproof roll and preparation method thereof |
| CN110539534A (en) * | 2018-05-29 | 2019-12-06 | 山东金顶防水技术股份有限公司 | Root-puncture-resistant PVC waterproof coiled material and preparation method thereof |
| CN112759889A (en) * | 2021-01-22 | 2021-05-07 | 王聪 | Modified waterproof coiled material and preparation method thereof |
-
2015
- 2015-12-31 CN CN201511013936.9A patent/CN105440503A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192323A (en) * | 2017-12-11 | 2018-06-22 | 浙江金华天开电子材料有限公司 | A kind of wear-resisting PVC coiled material and preparation method thereof |
| CN110539534A (en) * | 2018-05-29 | 2019-12-06 | 山东金顶防水技术股份有限公司 | Root-puncture-resistant PVC waterproof coiled material and preparation method thereof |
| CN109181159A (en) * | 2018-08-27 | 2019-01-11 | 潍坊天元防水材料股份有限公司 | A kind of flame retardant type PVC waterproof roll and preparation method thereof |
| CN112759889A (en) * | 2021-01-22 | 2021-05-07 | 王聪 | Modified waterproof coiled material and preparation method thereof |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160330 |
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| WD01 | Invention patent application deemed withdrawn after publication |