CN1047042A - 燃烧烟气的处理方法 - Google Patents
燃烧烟气的处理方法 Download PDFInfo
- Publication number
- CN1047042A CN1047042A CN90102605A CN90102605A CN1047042A CN 1047042 A CN1047042 A CN 1047042A CN 90102605 A CN90102605 A CN 90102605A CN 90102605 A CN90102605 A CN 90102605A CN 1047042 A CN1047042 A CN 1047042A
- Authority
- CN
- China
- Prior art keywords
- flue gas
- compound
- urea
- desulfurization
- inorganic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 25
- 239000007789 gas Substances 0.000 title claims abstract description 18
- 238000003672 processing method Methods 0.000 title claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000003546 flue gas Substances 0.000 claims abstract description 96
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 66
- 230000023556 desulfurization Effects 0.000 claims abstract description 66
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 62
- 150000001875 compounds Chemical class 0.000 claims abstract description 62
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000004202 carbamide Substances 0.000 claims abstract description 43
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 31
- 239000002002 slurry Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 15
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 15
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000007598 dipping method Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 67
- 230000008569 process Effects 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000006253 efflorescence Methods 0.000 abstract description 3
- 206010037844 rash Diseases 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 40
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 37
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 36
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 36
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 24
- 239000003245 coal Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 13
- 235000011941 Tilia x europaea Nutrition 0.000 description 13
- 239000004571 lime Substances 0.000 description 13
- 239000001294 propane Substances 0.000 description 12
- 239000000920 calcium hydroxide Substances 0.000 description 11
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 11
- 239000011575 calcium Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000035484 reaction time Effects 0.000 description 6
- 235000019738 Limestone Nutrition 0.000 description 5
- 238000010531 catalytic reduction reaction Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000006028 limestone Substances 0.000 description 5
- 239000011859 microparticle Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 230000002650 habitual effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000003009 desulfurizing effect Effects 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- ADUFBHYKXMWOSH-UHFFFAOYSA-N [O--].[O--].[Ti+4].[V+5] Chemical compound [O--].[O--].[Ti+4].[V+5] ADUFBHYKXMWOSH-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Weting (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP113941/89 | 1989-05-06 | ||
JP11394189 | 1989-05-06 | ||
JP223682/89 | 1989-08-30 | ||
JP22368289 | 1989-08-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1047042A true CN1047042A (zh) | 1990-11-21 |
Family
ID=26452809
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN90102605A Pending CN1047042A (zh) | 1989-05-06 | 1990-05-05 | 燃烧烟气的处理方法 |
Country Status (5)
Country | Link |
---|---|
KR (1) | KR920007857B1 (ko) |
CN (1) | CN1047042A (ko) |
DE (1) | DE4014388A1 (ko) |
GB (1) | GB2232972B (ko) |
IT (1) | IT1240462B (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102974207A (zh) * | 2012-11-07 | 2013-03-20 | 环境保护部华南环境科学研究所 | 用于水泥回转窑烟气同时脱硝脱硫的方法及装置 |
CN113423990A (zh) * | 2019-02-20 | 2021-09-21 | 萨普工业公司 | 用于处理来自燃烧单元的烟气的方法 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE468273B (sv) * | 1990-02-07 | 1992-12-07 | Eka Nobel Ab | Foerfarande och anordning foer kemisk och/eller fysikalisk behandling av ett fluidum |
DE4100645A1 (de) * | 1991-01-11 | 1992-07-16 | Hansjoerg Regler | Verfahren zur abscheidung von schadstoffen, insbesondere von sauren schadstoffen, aus gasen und abgasen |
DK170891A (da) * | 1991-02-19 | 1992-08-20 | Intevep Sa | Fremgangsmaade til fjernelse af effluenter fra udgangsgasser dannet ved forbraending af et braendstof |
WO1993011066A1 (en) * | 1991-11-27 | 1993-06-10 | Nalco Fuel Tech | PROCESS AND COMPOSITION FOR NOx and SOx REDUCTION |
BE1006780A5 (nl) * | 1992-02-10 | 1994-12-06 | Etienne Vansant | Produkten, werkwijzen en inrichtingen voor de verwijdering van polluenten uit een fluidum. |
US5282999A (en) * | 1992-06-12 | 1994-02-01 | Intevep, S.A. | Sorbent for treatment of effluent gas stream |
US5630991A (en) * | 1994-08-16 | 1997-05-20 | General Electric Co. | Limestone-based wet flue gas desulfurization process |
EP1779919A1 (fr) * | 2005-10-31 | 2007-05-02 | Constructions Industrielles De La Mediterranee- Cnim | Procédé amélioré de réduction des NOx, dispositif et application au traitement des fumées issues de la combustion des déchets ménagers |
DE102010007588A1 (de) * | 2010-02-05 | 2011-08-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 | Herstellungsverfahren für ein Synthesegas aus einer Biomasse |
US9387438B2 (en) | 2014-02-14 | 2016-07-12 | Tenneco Automotive Operating Company Inc. | Modular system for reduction of sulphur oxides in exhaust |
KR101836047B1 (ko) * | 2017-09-18 | 2018-03-08 | 이철 | 탈황용 촉매를 이용한 탈황 시스템 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3426796C2 (de) * | 1984-07-20 | 1987-04-23 | Hölter, Heinz, Dipl.-Ing., 4390 Gladbeck | Verfahren zur Abscheidung von SO↓2↓,SO↓3↓,NO↓x↓ sowie von Stäuben aus Abgasen |
EP0190416A3 (de) * | 1984-11-30 | 1988-07-27 | Waagner-Biro Aktiengesellschaft | Verfahren zur Abscheidung von Schadstoffen as Verbrennungsabgasen |
DE3513484A1 (de) * | 1985-04-16 | 1986-10-16 | Krupp Polysius Ag, 4720 Beckum | Verfahren zur verringerung der stickoxid-emission aus zementbrennanlagen |
US4795586A (en) * | 1986-01-09 | 1989-01-03 | Thompson Richard E | Method and composition for utilizing lime-urea hydrates to simultaneously reduce NOx and SOx in combustion effluents |
US4731233A (en) * | 1986-01-09 | 1988-03-15 | Thompson Richard E | Method and composition for utilizing lime-urea hydrates to simultaneously reduce NOx and SOx in combustion effluents |
DE3705267C1 (en) * | 1987-02-19 | 1988-03-31 | Rwk Rhein Westfael Kalkwerke | Use of a reactor grain for desulphurising flue gases |
US4851201A (en) * | 1987-04-16 | 1989-07-25 | Energy And Environmental Research Corporation | Methods of removing NOx and SOx emissions from combustion systems using nitrogenous compounds |
DE3823223A1 (de) * | 1987-08-06 | 1989-02-16 | Rheinische Braunkohlenw Ag | Verfahren zum reinigen von schwefeloxide und stickoxide enthaltenden rauchgasen |
DK339588A (da) * | 1987-09-03 | 1989-03-04 | Smidth & Co As F L | Fremgangsmaade og anlaeg til samtidig rensning af roeggas og flyveaske for svovloxider og kvaelstofoxider |
-
1990
- 1990-05-02 GB GB9009921A patent/GB2232972B/en not_active Expired - Fee Related
- 1990-05-03 IT IT67327A patent/IT1240462B/it active IP Right Grant
- 1990-05-04 DE DE4014388A patent/DE4014388A1/de not_active Ceased
- 1990-05-04 KR KR1019900006318A patent/KR920007857B1/ko not_active IP Right Cessation
- 1990-05-05 CN CN90102605A patent/CN1047042A/zh active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102974207A (zh) * | 2012-11-07 | 2013-03-20 | 环境保护部华南环境科学研究所 | 用于水泥回转窑烟气同时脱硝脱硫的方法及装置 |
CN102974207B (zh) * | 2012-11-07 | 2015-02-18 | 环境保护部华南环境科学研究所 | 用于水泥回转窑烟气同时脱硝脱硫的方法及装置 |
CN113423990A (zh) * | 2019-02-20 | 2021-09-21 | 萨普工业公司 | 用于处理来自燃烧单元的烟气的方法 |
Also Published As
Publication number | Publication date |
---|---|
IT9067327A0 (it) | 1990-05-03 |
IT1240462B (it) | 1993-12-17 |
GB2232972B (en) | 1993-09-15 |
DE4014388A1 (de) | 1990-11-08 |
IT9067327A1 (it) | 1991-11-03 |
GB9009921D0 (en) | 1990-06-27 |
KR920007857B1 (ko) | 1992-09-18 |
GB2232972A (en) | 1991-01-02 |
KR900017647A (ko) | 1990-12-19 |
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