CN104642348A - Insecticide bactericidal composition containing thifluzamide - Google Patents
Insecticide bactericidal composition containing thifluzamide Download PDFInfo
- Publication number
- CN104642348A CN104642348A CN201510109882.XA CN201510109882A CN104642348A CN 104642348 A CN104642348 A CN 104642348A CN 201510109882 A CN201510109882 A CN 201510109882A CN 104642348 A CN104642348 A CN 104642348A
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- CN
- China
- Prior art keywords
- insecticidal
- thifluzamide
- active ingredient
- bactericidal composition
- bactericide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide bactericidal composition containing thifluzamide. The composition contains thifluzamide as a first effective component and one or more second effective components selected from bisamide insecticides, the second effective component bisamide insecticide is chlorantraniliprole, cyantraniliprole and tetrachlororantraniliprole, wherein the weight ratio of the first effective component thifluzamide to the second effective component is 10: 1-1: 10. The test result shows that the composition can be obviously beneficiated after being compounded, the preventing and controlling effect on the pests is improved; the compounded composition has an obvious growth-promoting effect to the growth of the seedling, the application target of the pesticide is effectively enlarged, the insecticide and the bacteriostasis are performed at the same time; and the application is convenient, and the application dosage is effectively reduced.
Description
[technical field]
The invention belongs to agricultural insecticide technical field.More specifically, the present invention relates to a kind of insecticidal and bactericidal composition containing thifluzamide, and containing the insecticidal bactericide of described insecticidal and bactericidal composition, and described insecticidal and bactericidal composition and described insecticidal bactericide are in the application of water prevention chilo suppressalis and Rhizoctonia solani Kuhn.
[background technology]
Striped rice borer Chilo suppressalis (Walker) belongs to Lepidoptera, Pyralidae, that China paddy rice endangers one of Occurrence the most serious, be injured in tillering stage and cause withered sheath, withered heart seedling, be injured in the fringe phase and cause insect bite strain and dead ears, the general time underproduction 3% ~ 5%, time serious, the underproduction is more than 3 one-tenth.All there is distribution in domestic Ge Dao district, comparatively paddy stem borer and pink rice borer distribution wide, but mainly with the Yangtze river basin and on the south rice district occur heavier.
One of large disease of rice sheath blight disease Shi Shi China paddy rice three, in the whole nation, there is generation in each paddy rice producing region, and South Rice Region of China is very serious.Banded sclerotial blight all can occur to the fringe phase at rice seedling, causes harm the heaviest with tillering regularity to heading stage.The photosynthesis of this sick chief destructive rice strain, weakens root absorption ability, reduces the accumulation of nutriment, affects paddy rice solid.The withered sclerotium of line is sprouted naturally can infect 40 various plants, wherein mainly paddy rice, wheat, corn etc., and weeds parasitism mainly contains barnyard grass, trip grass etc.In general, early rice overweights Single Late Rice to rice pathogenesis, and double cropping late rice morbidity is lighter.The not plump paddy rate increase of field that morbidity is heavy, thousand kernel weight reduces, and underproduction 5-10%, serious can underproduction 50-70%.
Thifluzamide (Trifluzamide), belongs to thiazole amide bactericide, has strong Uptake and translocation and long lasting effect.Thifluzamide all has activity to pathomycetes such as Rhizoctonia, Puccinia, Ustilago, Tilletia, corticium, nuclear cavity Pseudomonas, especially has special efficacy to the fungus-caused disease of Basidiomycetes such as banded sclerotial blight, damping off etc.Can the mode such as foliar spray, seed treatment, soil treatment use.Thifluzamide all has good control efficiency to many kinds of fungal diseases, can be widely used in the various crop such as water paddy and wheat class, peanut, cotton, beet, coffee, potato, lawn.Production is mainly used in the banded sclerotial blight of preventing and treating paddy rice and wheat class.Further, it is more healthy and stronger that thifluzamide can make plant stem-leaf grow, and effectively can improve the resistance of crop.
Bisamide insecticides, by efficiently activating the calcium ion that insect ryanodine receptor makes in its excessive release cells in calcium storehouse, destroy insect cell device intra-and extra-cellular calcium ionic equilibrium, thus it is dead to cause insect to be paralysed.
Wherein, Rynaxypyr (chiorantraniliprole) is the insecticide that du pont company develops from o-amino benzoyl diamide compound, its mode of action is based on stomach toxicity, have certain action of contace poison concurrently, have good interior absorption and permeability, speed of action is fast, the lasting period is long.To the most of Lepidoptera, the coleopteran pest that endanger the crops such as cereal crops, fruit tree, vegetables, there is preventive and therapeutic effect that is quick, long-acting, wide spectrum, and toxicity is only micro-poison.
Bromine cyanogen insect amide (Cyantraniliprole), for the 2nd generation ryanodine receptor of E.I.Du Pont Company's exploitation suppresses insecticides, there is root absorption, can conduct in xylem, compared with Rynaxypyr, its applicable crops is more extensive, can prevent and treat pests with chewing mouthparts, can sucking pest be prevented and treated again, comprise Lepidoptera, Semiptera and coleopteran pest.
Four chlorantraniliproles, belong to ryanodine receptor activator insecticides, it is combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein combination, cause muscle contracts last.Insect bodies Symptoms is tic, food refusal, finally dead.Four chlorantraniliproles are low toxicity, broad spectrum pesticide, all have good activity to lepidoptera pest.
Traditional rice pest prevention and controls is mainly spray-on process, and labour intensity is high, and work efficiency is low, and water consumption is large, is difficult to the needs meeting large-scale planting; Along with the enforcement of China's land transformation policy, soil presents the trend of intensive management, and crop contiguous plant area increases; And China's population aging degree continues to increase now, between twenty and fifty Out-migrant for work mostly in rural area, agricultural labour becomes rare resource gradually, and human cost improves constantly, and the cost directly causing agricultural to become to produce continues to increase.
Granule is the granular preparation processed by auxiliary agents such as former medicine, carriers.During dispenser, there is directionality, make medicament fully reach target organisms and not threaten to beneficial organisms such as natural enemies; Powder is not attached on the cauline leaf of plant, avoids directly contact and produces poisoning; Without dust from flying during dispenser, both free from environmental pollution, the attachment of operating personnel's health can be reduced again or suck dose, avoiding intoxication accident; The rate of release of active ingredient in controlled granulation agent, extends the lasting period; Can directly spread fertilizer over the fields during use, time saving and energy saving.
At present, mostly the granule of domestic use is single insecticidal constituent or sterilization component, can not effectively double insect pest of curing the disease, and time-consumingly takes a lot of work, and the regulating action of most active ingredient to crop is little, and crop growing state is weak, and resistance against diseases is weak.Heavy in order to solve current paddy field dispenser work, granule prevention and elimination of disease and pests effect is single, control spectrum is narrow, needs medication repeatedly, little to the regulating action of crop, the problems such as crop disease-resistant ability is weak, the present patent application discloses a kind of insecticidal and bactericidal composition containing thifluzamide.
[summary of the invention]
[technical problem that will solve]
The object of the present invention is to provide a kind of insecticidal and bactericidal composition containing thifluzamide.
Another object of the present invention is to provide the insecticidal bactericide containing described insecticidal and bactericidal composition.
Another object of the present invention is to provide the application at water prevention chilo suppressalis and Rhizoctonia solani Kuhn of described insecticidal and bactericidal composition and described insecticidal bactericide.
[technical scheme]
The present invention relates to a kind of insecticidal and bactericidal composition, described insecticidal and bactericidal composition contains the first active ingredient thifluzamide and one or more are selected from the second active ingredient of bisamide insecticides, described second active ingredient bisamide insecticides is Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles, and the weight ratio of wherein said first active ingredient thifluzamide and the second active ingredient is 10:1 ~ 1:10.
A preferred embodiment of the invention, the weight ratio of described first active ingredient thifluzamide and described second active ingredient is 3:1 ~ 1:8.
The invention still further relates to a kind of insecticidal bactericide, described insecticidal bactericide contains insecticidal and bactericidal composition described in 0.1 ~ 80 % by weight, and surplus is acceptable carrier and auxiliary agent on agricultural chemicals.
According to another kind of preferred embodiment of the present invention, described insecticidal bactericide contains insecticidal and bactericidal composition described in 0.1 ~ 30 % by weight, and surplus is acceptable carrier and auxiliary agent on agricultural chemicals.
According to another kind of embodiment of the present invention, the formulation of described insecticidal bactericide is granule, suspending agent, wetting powder or water dispersible granules.
According to another kind of preferred embodiment of the present invention, the formulation of described insecticidal bactericide is granule.
The invention still further relates to the application of described insecticidal and bactericidal composition at water prevention chilo suppressalis and Rhizoctonia solani Kuhn.
The invention still further relates to a kind of method of preventing and treating rice pest, adopt seedling dish process or the mode of spreading fertilizer over the fields to use described insecticidal and bactericidal composition or described insecticidal bactericide.
Below will illustrate in greater detail technical scheme of the present invention.
The present invention relates to a kind of insecticidal and bactericidal composition, described insecticidal and bactericidal composition contains the first active ingredient thifluzamide and one or more are selected from the second active ingredient of bisamide insecticides, described second active ingredient bisamide insecticides is Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles, the weight ratio of wherein said first active ingredient thifluzamide and the second active ingredient is 10:1 ~ 1:10, preferably 3:1 ~ 1:8.
The invention still further relates to a kind of insecticidal bactericide containing above-mentioned insecticidal and bactericidal composition, described insecticidal bactericide contains insecticidal and bactericidal composition described in 0.1 ~ 80 % by weight, and surplus is acceptable carrier and auxiliary agent on agricultural chemicals.Preferably, described insecticidal bactericide contains insecticidal and bactericidal composition described in 0.1 ~ 30 % by weight.
Except as otherwise noted, " % " involved in the present invention is " percentage by weight ".
According to method known in those skilled in the art, insecticidal and bactericidal composition of the present invention can be mixed with the formulation agriculturally allowed when practical application, and good formulation is granule, suspending agent, wetting powder or water dispersible granules, preferably granule.
To granule, spendable auxiliary agent has: dispersant is selected from alkylnaphthalene sulfonate formaldehyde condensation products, sodium lignin sulfonate, calcium lignosulfonate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, alkyl naphthalene formaldehyde condensate sulfonates, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products; Sustained release agent is selected from polyvinyl alcohol, gum Arabic; Disintegrant is selected from sodium sulphate, urea, sodium carboxymethyl starch, starch, sodium carbonate, ammonium sulfate, sodium chloride, calcium chloride, bentonite; Binding agent is selected from polyethylene glycol, carboxymethyl cellulose, polyvinyl alcohol; Coating agent is selected from polyvinyl alcohol, polyvinylpyrrolidone, mylar, acrylic acid synthetic polymer, acrylic resin film forming agent, butadiene resin film forming agent, polyurethane finishing agent, cellulose nitrate film forming agent; Carrier is selected from kaolin, diatomite, precipitated calcium carbonate, white carbon, attapulgite, bentonite, starch, stone flour, quartz sand.
To suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2425 (Huntsman Corporation of the U.S. produces, alkyl naphthalene sulfonic acid salt); Wetting agent is selected from alkylphenol-polyethenoxy and gathers base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500 (Huntsman Corporation of U.S. product); Thickener is selected from xanthans, aluminium-magnesium silicate, bentonite; Preservative is selected from benzoic acid, Sodium Benzoate, BIT (BIT); Defoamer is silicone based defoamer; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts as sodium chloride.
To wetting powder, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay etc.
For water dispersible granules, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from polyoxyethylene alcohol, alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Disintegrant is selected from ammonium sulfate, urea, sucrose, glucose, citric acid, succinic acid, sodium bicarbonate; Binding agent is selected from diatomite, corn starch, PVA, carboxymethyl (ethyl) cellulose family and microcrystalline cellulose class; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, sepiolite, talcum powder, attapulgite, potter's clay etc.
The invention still further relates to the application of described insecticidal and bactericidal composition at water prevention chilo suppressalis and Rhizoctonia solani Kuhn.
The invention still further relates to a kind of method of preventing and treating rice pest, adopt seedling dish process or the mode of spreading fertilizer over the fields to use described insecticidal and bactericidal composition or described insecticidal bactericide.
[beneficial effect]
Compared with prior art, the present invention by thifluzamide and bisamide insecticides composite, there is following beneficial effect:
(1) can notable synergistic after composite.Because it is more healthy and stronger that thifluzamide can make plant stem-leaf grow, effectively can improve the resistance of crop, after pesticide compositional, significantly improve the control efficiency of damage by disease and insect;
(2) the composite rear growth to seedling has obvious growth-promoting functions;
(3) the application target of composite rear expansion agricultural chemicals, killing pests and suppressing bacteria carries out simultaneously;
(4) prevent and treat rice pest, adopt seedling dish process or spread fertilizer over the fields, use conveniently, without the need to using machinery, time saving and energy saving;
(5) root absorption, active ingredient plays a role entering into crop plant tissue inside, and drug effect is more obvious, lasting period is long, after applied once, the paddy rice middle and later periods does not need the spraying preventing and controlling again carrying out rice leaf roller, rice fulgorid, banded sclerotial blight, accomplishes time and labour saving;
(6) the active ingredient release in the controlled granulation agent of sustained release agent, extends the lasting period;
(7) safety and environmental protection.Do not add the environmentally harmful materials such as toluene class, DMF, acetone, at production, transport, storage, safety non-pollution in use procedure, without dust, do not drift about during use.
[embodiment]
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
One, embodiment is prepared
In all preparation proportionings, percentage composition is all weight percentage.
1, granule
Embodiment 1:4% thifluzamide Rynaxypyr granule (active ingredient 3:1)
Take the former medicine of 3% thifluzamide, the former medicine of 1% Rynaxypyr, 0.5% alkylnaphthalene sulfonate formaldehyde condensation products, 2% polyvinyl alcohol, 1% sodium sulphate, 5% polyethylene glycol, 0.1% polyvinyl alcohol, kaolin adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 2:30% thifluzamide Rynaxypyr granule (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% Rynaxypyr, 2% lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, 1.2% polyvinyl alcohol, 4% sodium carbonate, 3.5% polyethylene glycol, 0.3% acrylic acid synthetic polymer, white carbon adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 3:4% thifluzamide Rynaxypyr granule (active ingredient 1:3)
Take the former medicine of 1% thifluzamide, the former medicine of 3% Rynaxypyr, 3% sodium lignin sulfonate, 0.1% gum Arabic, 6% urea, 0.1% carboxymethyl cellulose, 0.5% polyvinylpyrrolidone, diatomite adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 4:18% thifluzamide Rynaxypyr granule (active ingredient 1:8)
Take the former medicine of 2% thifluzamide, the former medicine of 16% Rynaxypyr, 1.5% calcium lignosulfonate, 1% gum Arabic, 3% sodium carboxymethyl starch, 3% polyvinyl alcohol, 0.3% mylar, precipitated calcium carbonate adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 5:4% thifluzamide bromine cyanogen insect amide granule (active ingredient 3:1)
Take the former medicine of 3% thifluzamide, the former medicine of 1% bromine cyanogen insect amide, 0.5% alkylnaphthalene sulfonate formaldehyde condensation products, 2% polyvinyl alcohol, 1% sodium sulphate, 5% polyethylene glycol, 0.1% polyvinyl alcohol, kaolin adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 6:30% thifluzamide bromine cyanogen insect amide granule (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% bromine cyanogen insect amide, 2% lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, 1.2% polyvinyl alcohol, 4% sodium carbonate, 3.5% polyethylene glycol, 0.3% acrylic acid synthetic polymer, white carbon adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 7:4% thifluzamide bromine cyanogen insect amide granule (active ingredient 1:3)
Take the former medicine of 1% thifluzamide, the former medicine of 3% bromine cyanogen insect amide, 3% sodium lignin sulfonate, 0.1% gum Arabic, 6% urea, 0.1% carboxymethyl cellulose, 0.5% polyvinylpyrrolidone, diatomite adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 8:18% thifluzamide bromine cyanogen insect amide granule (active ingredient 1:8)
Take the former medicine of 2% thifluzamide, the former medicine of 16% bromine cyanogen insect amide, 1.5% calcium lignosulfonate, 1% gum Arabic, 3% sodium carboxymethyl starch, 3% polyvinyl alcohol, 0.3% mylar, precipitated calcium carbonate adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 9:4% thifluzamide four chlorantraniliprole granule (active ingredient 3:1)
Take the former medicine of 3% thifluzamide, the former medicine of 1% 4 chlorantraniliprole, 0.5% alkylnaphthalene sulfonate formaldehyde condensation products, 2% polyvinyl alcohol, 1% sodium sulphate, 5% polyethylene glycol, 0.1% polyvinyl alcohol, kaolin adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 10:30% thifluzamide four chlorantraniliprole granule (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% 4 chlorantraniliprole, 2% lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, 1.2% polyvinyl alcohol, 4% sodium carbonate, 3.5% polyethylene glycol, 0.3% acrylic acid synthetic polymer, white carbon adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 11:4% thifluzamide four chlorantraniliprole granule (active ingredient 1:3)
Take the former medicine of 1% thifluzamide, the former medicine of 3% 4 chlorantraniliprole, 3% sodium lignin sulfonate, 0.1% gum Arabic, 6% urea, 0.1% carboxymethyl cellulose, 0.5% polyvinylpyrrolidone, diatomite adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
Embodiment 12:18% thifluzamide four chlorantraniliprole granule (active ingredient 1:8)
Take the former medicine of 2% thifluzamide, the former medicine of 16% 4 chlorantraniliprole, 1.5% calcium lignosulfonate, 1% gum Arabic, 3% sodium carboxymethyl starch, 3% polyvinyl alcohol, 0.3% mylar, precipitated calcium carbonate adds to 100% as carrier.
By formula rate, by mixing granulations such as former medicine, dispersant, sustained release agent, disintegrant, binding agent, coating agent and carriers.
2, suspending agent
Embodiment 13:30% thifluzamide Rynaxypyr suspending agent (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% Rynaxypyr, 8%FS3000 (phosphate type anion surfactant), 2%TXC (sulfonic acid type anion surfactant), 0.2% xanthans, 1% aluminium-magnesium silicate, 4% ethylene glycol, 0.5%BIT (1,2-benzisothiazole-3-ketone), 0.5% organically-modified silica alkane defoamer, deionized water adds to 100%.
By formula rate, take water as medium, former medicine, dispersant, wetting agent, preservative, defoamer and antifreezing agent etc. are joined in high-shear emulsion machine and shears 30min, then after using sand mill sand milling, obtain suspending agent.
Embodiment 14:30% thifluzamide bromine cyanogen insect amide suspending agent (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% Rynaxypyr, 6%FS3000,2%NP-10 (polyoxyethylene nonylphenol ether), 0.15% xanthans, 0.8% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% benzoic acid, 0.3% organically-modified silica alkane defoamer, deionized water adds to 100%.
By formula rate, take water as medium, former medicine, dispersant, wetting agent, preservative, defoamer and antifreezing agent etc. are joined in high-shear emulsion machine and shears 30min, then after using sand mill sand milling, obtain suspending agent.
Embodiment 15:30% thifluzamide four chlorantraniliprole suspending agent (active ingredient 1:1)
Take the former medicine of 15% thifluzamide, the former medicine of 15% 4 chlorantraniliprole, 6%FS3000 (phosphate type anion surfactant), 3%TXC (sulfonic acid type anion surfactant), 0.2% xanthans, 0.6% aluminium-magnesium silicate, 4% ethylene glycol, 0.4%BIT (1,2-benzisothiazole-3-ketone), 0.3% organically-modified silica alkane defoamer, deionized water adds to 100%.
By formula rate, take water as medium, former medicine, dispersant, wetting agent, preservative, defoamer and antifreezing agent etc. are joined in high-shear emulsion machine and shears 30min, then after using sand mill sand milling, obtain suspending agent.
3, wetting powder
Embodiment 20:40% thifluzamide Rynaxypyr wetting powder (active ingredient is than 3:1)
Take the former medicine of 30% thifluzamide, the former medicine of 10% Rynaxypyr, 6%NNO, 3% Nekal BX, 20% white carbon, fine particle calcium carbonate add to 100%.
By formula rate, after former medicine and dispersant, wetting agent and filler etc. are mixed after Roughpulverizer is pulverized, enter airslide disintegrating mill and be fully pulverized and mixed obtained wetting powder.
Embodiment 21:22% thifluzamide bromine cyanogen insect amide wetting powder (active ingredient is than 1:10)
Take the former medicine of 2% thifluzamide, the former medicine of 20% bromine cyanogen insect amide, 8%NNO, 1% Nekal BX, 10% white carbon, fine particle calcium carbonate add to 100%.
By formula rate, after former medicine and dispersant, wetting agent and filler etc. are mixed after Roughpulverizer is pulverized, enter airslide disintegrating mill and be fully pulverized and mixed obtained wetting powder.
4, water dispersible granules
Embodiment 18:40% thifluzamide four chlorantraniliprole water dispersant (active ingredient is than 3:1)
Take the former medicine of 30% thifluzamide, the former medicine of 10% 4 chlorantraniliprole, 5%NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 6%K-12 (lauryl sodium sulfate), 1% carboxymethyl (ethyl) cellulose, 2% diatomite, 5% glucose, kaolin adds to 100%.
By formula rate, former medicine and dispersant, wetting agent, binding agent, filler etc. are mixed, after air-flow crushing, obtain pulvis, add water mixing, in comminutor, carry out granulation, then dry, sieve and obtain granular product.
Embodiment 19:22% thifluzamide bromine cyanogen insect amide water dispersant (active ingredient is than 1:10)
Take the former medicine of 2% thifluzamide, the former medicine of 20% 4 chlorantraniliprole, 5%NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 1% Nekal BX (nekal), 7%K-12 (lauryl sodium sulfate), 1% carboxymethyl (ethyl) cellulose, 1% diatomite, 3% glucose, kaolin adds to 100%.
By formula rate, former medicine and dispersant, wetting agent, disintegrant, binding agent and filler etc. are mixed, after air-flow crushing, obtain pulvis, add water mixing, in comminutor, carry out granulation, then dry, sieve and obtain granular product.
Two, BIOLOGICAL ACTIVITY EXAMPLES
BIOLOGICAL ACTIVITY EXAMPLES is divided into indoor biological activity Example and land for growing field crops BIOLOGICAL ACTIVITY EXAMPLES.
Active example: thifluzamide is the composite Toxicity Determination to rice-stem borer and Rhizoctonia solani Kuhn with Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles respectively
Experiment target is designated as rice sheath blight disease (Rhizoctoniasolani) and rice-stem borer.
Rice sheath blight disease Toxicity Determination: under aseptic technique, quantitatively adds the sterilising medium melted in advance in aseptic conical flask, from low concentration to high concentration, quantitatively draws liquid successively, adds in conical flask respectively, fully shakes up.Then equivalent pours diameter into is in the culture dish of 9cm, and each concentration establishes 3 repetitions.By cultured rice sheath blight disease pathogen, aseptically use the card punch of diameter 5mm, bacterium cake is cut from colony edge, with inoculator, pure culture biscuits involvng inoculation is dull and stereotyped central in pastille, mycelia faces up, and covers ware lid, cultivates under being placed in preference temperature, clear water blank is set, observed result after 48h.Each bacterium colony right-angled intersection method vertical survey diameter is each once, gets its mean value.The mycelial growth inhibition rate of each concentration for the treatment of to germ is calculated according to investigation result.Data SPSS software carries out statistical disposition.
Striped rice borer Toxicity Determination: adopt capillary micro intravenous drip method, capillary micro intravenous drip device volume is 1.0 microlitres.With micro intravenous drip device by liquid by the back side of head drop in Chilo spp larvae, each concentration process 30 larvas, put into the culture dish that a diameter is 9 centimetres for every 5, place a small amount of feed in ware for taking food.Separately with clear water in contrast.Larva after treatment is still placed in receptacle, checks lethality after 48h.Data SPSS software carries out statistical disposition.
The composite Toxicity Determination result to rice-stem borer and Rhizoctonia solani Kuhn of table 1 and Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles
From the data in table 1, after thifluzamide and Rynaxypyr, bromine cyanogen insect amide or four chlorantraniliproles are composite in varing proportions, the lethal dose of 50 all has reduction in various degree relative to single dose, particularly in embodiment 1,5,6,9, after the composite Rynaxypyr, bromine cyanogen insect amide or four chlorantraniliproles that rice sheath blight disease be there is no to a bactericidal action, unexpectedly, the EC of thifluzamide
50remarkable reduction, the highest range of decrease can reach 46%.Visible, the equal preventive effect of composite insecticidal bactericide of the present invention to rice-stem borer and banded sclerotial blight has obvious synergistic effect, can reduce bactericide consumption under the prerequisite expanding fungicidal spectrum.
Thifluzamide is growth-promoting functions to rice seedling composite with Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles respectively
Thifluzamide and Rynaxypyr, bromine cyanogen insect amide, four chlorantraniliproles are pressed the composite rear dilution of different proportion, then does seed soaking respectively.Seed soaking 48h, every 12h changes treatment fluid 1 time.Clear water is contrast.Each process repeats for 3 times, each repetition 30 seeds.By seed in vermiculite, 28 DEG C of illumination cultivation, 10d " Invest, Then Investigate " growth-promoting effect.
Height of seedling and root long: measure each process seedling and the length of root with ruler, wherein root is with the longest root for measuring object, and final result is averaged.
Radical: statistics all length is greater than the quantity of the root of 1cm, averages.
Dry weight: seedling and root are separated and wrap with blotting paper, complete in 105 DEG C of baking ovens, dry 24h at 90 DEG C, weighs in the balance after being cooled to room temperature heavily, averages.
Table 2 thifluzamide is growth-promoting functions to rice seedling composite with Rynaxypyr, bromine cyanogen insect amide and four chlorantraniliproles respectively
Can be learnt by the data analysis in table 2, when being used alone, rice seedling all be there is no to thifluzamide and Rynaxypyr, bromine cyanogen insect amide, four chlorantraniliproles of growth-promoting functions, all high than contrast to the numerical value of the height of seedling of rice seedling, seedling dry weight, root length, radical and root thousandweight after compound drug process, wherein root is long remarkable with radical amount of increase.Visible compositely have obvious growth-promoting effect to paddy rice afterwards.
Field information is tested: water prevention chilo suppressalis and rice sheath blight disease field control effectiveness test
According to the regulation of medicine inspecting institute of the Ministry of Agriculture " GB/T17980.20-2000 pesticide field efficacy medicine test criterion ()---bactericidal agent for preventing and treating rice sheath blight disease ", the community process of test medicine, contrast medicament and blank adopts the group arrangement of random district, plot area 15m
2, repeat for 4 times, this test amounts to dispenser twice.Be in their early stage during first time dispenser, after two weeks, execute second time medicine.This test amounts to investigation 2 times, and every experimental plot adopts diagonal 5 sampling, and often some investigation is connected 5 clumps, totally 25 clumps, record disease grade.
Disease scale standard is as follows:
0 grade: complete stool is anosis;
1 grade: quaterfoil and following leaf sheath, blade morbidity (taking sword-like leave as first leaf);
3 grades: three leaf and following leaf sheath thereof, blade morbidity;
5 grades: second leaf and following leaf sheath thereof, blade morbidity;
7 grades: sword-like leave blade and following leaf sheath thereof, blade morbidity;
9 grades: complete stool falls ill, withered ahead of time.
Drug effect computational methods:
According to investigation result, (1), (2) formulae discovery disease index and preventive effect according to below.
In formula: CK
0, CK
1be respectively the disease index that the dispenser of blank district is forward and backward; PT
0, PT
1be respectively the disease index that chemicals treatment district medicine is forward and backward.
According to the regulation of medicine inspecting institute of the Ministry of Agriculture " GB/T17980.1-2000 pesticide field efficacy medicine test criterion ()---insecticide control paddy rice Lepidoptera borer pest ", the community process of test medicine, contrast medicament and blank adopts the group arrangement of random district, plot area 15m
2, repeat for 4 times, parallel great-jump-forward sampling during investigation, 25 clumps of rice are investigated in every community, add up withered heart rate and striped rice borer lethality.
Drug effect computational methods:
According to investigation result, (1), the withered heart rate of (2) formulae discovery and preventive effect according to below.
The withered calculation of withered heart rate (%)=investigate/investigate total strain number × 100 ... (1)
In formula: CK is withered heart rate after blank district medicine; PT is withered heart rate after chemicals treatment district medicine.
Table 3 water prevention chilo suppressalis and rice sheath blight disease field control effectiveness test
From the data in upper table 3, after thifluzamide and Rynaxypyr, bromine cyanogen insect amide, four chlorantraniliproles are composite, all high than thifluzamide, Rynaxypyr, bromine cyanogen insect amide, the preventive effect of four chlorantraniliprole single doses to rice-stem borer and banded sclerotial blight to the preventive effect of rice-stem borer and banded sclerotial blight, as can be seen here, obvious synergistic effect is had in field to the preventive effect of rice-stem borer and banded sclerotial blight after composite; Under identical active ingredient, same amount, the field efficacy of granule is apparently higher than the drug effect of suspending agent.
Above-mentioned indoor biometrics and field control effectiveness test result show that the beneficial effect that bactericidal composition of the present invention produces is:
(1) can notable synergistic after composite.Because it is more healthy and stronger that thifluzamide can make plant stem-leaf grow, effectively can improve the resistance of crop, after pesticide compositional, significantly improve the control efficiency of damage by disease and insect;
(2) the composite rear growth to seedling has obvious growth-promoting functions;
(3) the application target of composite rear expansion agricultural chemicals, killing pests and suppressing bacteria carries out simultaneously;
(4) prevent and treat rice pest, adopt seedling dish process or spread fertilizer over the fields, use conveniently, without the need to using machinery, time saving and energy saving, effectively reduce formulation rate.
Claims (8)
1. an insecticidal and bactericidal composition, described insecticidal and bactericidal composition contains the first active ingredient thifluzamide and one or more are selected from the second active ingredient of bisamide insecticides, described second active ingredient bisamide insecticides is Rynaxypyr, bromine cyanogen insect amide or four chlorantraniliproles, it is characterized in that the weight ratio of the first active ingredient thifluzamide and the second active ingredient is 10:1 ~ 1:10.
2. insecticidal and bactericidal composition according to claim 1, is characterized in that the weight ratio of described first active ingredient thifluzamide and described second active ingredient is 3:1 ~ 1:8.
3. an insecticidal bactericide, is characterized in that described insecticidal bactericide contains the insecticidal and bactericidal composition described in claim 1 or 2 of 0.1 ~ 80 % by weight, and surplus is acceptable carrier and auxiliary agent on agricultural chemicals.
4. insecticidal bactericide according to claim 3, is characterized in that described insecticidal bactericide contains the insecticidal and bactericidal composition described in claim 1 or 2 of 0.1 ~ 30 % by weight, and surplus is acceptable carrier and auxiliary agent on agricultural chemicals.
5. the insecticidal bactericide according to claim 3 or 4, is characterized in that the formulation of described insecticidal bactericide is granule, suspending agent, wetting powder or water dispersible granules.
6. insecticidal bactericide according to claim 5, is characterized in that the formulation of described insecticidal bactericide is granule.
7. insecticidal and bactericidal composition according to claim 1 and 2 is preventing and treating the application of striped rice borer and sheath blight fungus.
8. prevent and treat a method for rice pest, adopt seedling dish process or the mode of spreading fertilizer over the fields to use the insecticidal and bactericidal composition described in claim 1 or 2 or the insecticidal bactericide described in claim 3 or 4.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106172449A (en) * | 2016-07-08 | 2016-12-07 | 广东中迅农科股份有限公司 | Containing thifluzamide and Fluoxastrobin and the seed treatment compositions of bromine cyanogen insect amide |
| CN107318867A (en) * | 2016-04-29 | 2017-11-07 | 中化作物保护品有限公司 | A kind of pesticide-germicide composition pesticide and its application |
| CN107996589A (en) * | 2017-11-29 | 2018-05-08 | 江苏省农业科学院 | A kind of winged anti-preparation for Scale in Paddy Field Rice Diseases prevention |
| CN109221147A (en) * | 2018-09-25 | 2019-01-18 | 江苏省农药研究所股份有限公司 | A kind of ternary composition of 2-cyano-3-amino-3-phenylancryic acetate-containing, seed treatment suspending agent and its application |
| CN113712034A (en) * | 2021-09-07 | 2021-11-30 | 四川眉山凯尔化工有限公司 | Pesticide containing chlorantraniliprole and dinotefuran and preparation method thereof |
| CN114451421A (en) * | 2022-01-24 | 2022-05-10 | 赤天化科技集团有限公司 | Insecticidal and bactericidal composition containing clothianidin and tetrachlorantraniliprole and application thereof |
| CN116616303A (en) * | 2023-05-24 | 2023-08-22 | 江苏丘陵地区镇江农业科学研究所 | Rice seed treatment agent containing chlorantraniliprole, monosultap and thifuramide and its application |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106665589A (en) * | 2016-12-28 | 2017-05-17 | 成都格瑞赛斯科技有限公司 | Tetra-chlorantraniliprole-containing insecticidal and bactericidal composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN102396475A (en) * | 2011-12-20 | 2012-04-04 | 广西田园生化股份有限公司 | Insecticide composition containing cyantraniliprole and abamectin |
| CN104206395A (en) * | 2014-09-23 | 2014-12-17 | 江苏丘陵地区镇江农业科学研究所 | Compound pesticide containing chlorantraniliprole, thifluzamide and polyving akohol, preparation method and application thereof |
| CN104396974A (en) * | 2014-11-18 | 2015-03-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition |
-
2015
- 2015-03-13 CN CN201510109882.XA patent/CN104642348B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN102396475A (en) * | 2011-12-20 | 2012-04-04 | 广西田园生化股份有限公司 | Insecticide composition containing cyantraniliprole and abamectin |
| CN104206395A (en) * | 2014-09-23 | 2014-12-17 | 江苏丘陵地区镇江农业科学研究所 | Compound pesticide containing chlorantraniliprole, thifluzamide and polyving akohol, preparation method and application thereof |
| CN104396974A (en) * | 2014-11-18 | 2015-03-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition |
Non-Patent Citations (2)
| Title |
|---|
| 杨桂秋等: ""新型杀虫剂溴氰虫酰胺研究概述"", 《世界农药》 * |
| 杨桂秋等: ""新方法合成溴氰虫酰胺"", 《现代农药》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107318867A (en) * | 2016-04-29 | 2017-11-07 | 中化作物保护品有限公司 | A kind of pesticide-germicide composition pesticide and its application |
| CN106172449A (en) * | 2016-07-08 | 2016-12-07 | 广东中迅农科股份有限公司 | Containing thifluzamide and Fluoxastrobin and the seed treatment compositions of bromine cyanogen insect amide |
| CN107996589A (en) * | 2017-11-29 | 2018-05-08 | 江苏省农业科学院 | A kind of winged anti-preparation for Scale in Paddy Field Rice Diseases prevention |
| CN109221147A (en) * | 2018-09-25 | 2019-01-18 | 江苏省农药研究所股份有限公司 | A kind of ternary composition of 2-cyano-3-amino-3-phenylancryic acetate-containing, seed treatment suspending agent and its application |
| CN113712034A (en) * | 2021-09-07 | 2021-11-30 | 四川眉山凯尔化工有限公司 | Pesticide containing chlorantraniliprole and dinotefuran and preparation method thereof |
| CN114451421A (en) * | 2022-01-24 | 2022-05-10 | 赤天化科技集团有限公司 | Insecticidal and bactericidal composition containing clothianidin and tetrachlorantraniliprole and application thereof |
| CN116616303A (en) * | 2023-05-24 | 2023-08-22 | 江苏丘陵地区镇江农业科学研究所 | Rice seed treatment agent containing chlorantraniliprole, monosultap and thifuramide and its application |
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