A kind of anti-dandruff shampoo composition
Technical field
The present invention relates to household chemicals field, particularly relate to a kind of anti-dandruff shampoo composition.
Background technology
Medically the dandruff is called capitis pityriasis, it is that a kind of the excessive of scalp corneocyte caused by chlosma (fungus) comes off, often with symptoms such as inflammation, pruritus, scalp are rubescent.According to epidemiology report, leading the adult onset of China is more than 70%, occurs in various degree before 20 years old, within 50 years old, can automatically disappear later.Winter is more, and summer is less, and men and women's property does not have very large difference.Oily skin has the probability of dandruff much higher.
Anti-dandruff agent mainly chemical small molecule anti-dandruff agent conventional in current shampoo: as pyrithione zinc (ZPT) and piroctone olamine salt (OCT), these two kinds of anti-dandruff agent are very strong to the fungistatic effect of chlosma, there is good anti-dandruff effect, but the zest of these anti-dandruff agent is large, sedimentation and metachromatism is often there will be in the application of shampoo formula, to photo-labile and degreasing power is excessively strong, life-time service can cause hair withered, low and deep, do not have the problems such as gloss; And along with the prolongation of service time, anti-dandruff effect declines and the situation having dandruff to have to increase the weight of produces.At present, market needs more healthy, safer anti-dandruff component meets the demand of the anti-dandruff of consumer and health of hair.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of anti-dandruff shampoo composition, adopt organic Fructus Rubi extract of natural botanical source, organic camomile extract, existing chemical small molecule (the pyrithione zinc of mixture replacing of organic Ramulus et Folium Mussaendae Pubescentis extract, piroctone olamine salt etc.) as antibacterial, this mixture is gentle to scalp, non-stimulated, the hair that life-time service chemical small molecule antibacterial can be avoided to cause dries up, dim mute, and the situation that anti-dandruff effect declines and dandruff increases the weight of, conditioner life-time service in matched combined thing can remove dandruff, the scalp problems such as head pruritus.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of anti-dandruff shampoo composition, the constituent mass percentage ratio of described compositions is:
Anion surfactant 5-30%;
Amphoteric surfactant 2-20%;
Conditioner 2-12%;
Anti-dandruff mixture 2-5%;
Pearling agent 0.5-3%;
Viscosity modifier 0.2-0.5%;
Chelating agen 0.02-0.3%;
In above-mentioned, the component of described compositions also comprises pH adjusting agent, essence and pigment, and all the other are deionized water.
In a preferred embodiment of the present invention, described anti-dandruff mixture is organic Fructus Rubi extract, organic camomile extract, the mixture of organic Ramulus et Folium Mussaendae Pubescentis extract, wherein, the weight ratio content of organic Fructus Rubi extract is 10-40%, and the weight ratio content of organic camomile extract is 10-40%, and all the other are organic Ramulus et Folium Mussaendae Pubescentis extract.
In a preferred embodiment of the present invention, described anion surfactant includes but not limited to alkyl sulfate, alkyl ether sulfate, sulfonate and sarcosinate, wherein, described alkyl sulfate comprises lauryl alcohol sulfuric ester ammonium, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, sodium cocosulfate and composition thereof; Described alkyl ether sulfate comprises laureth sulfuric ester ammonium, laureth potassium sulfate and sodium laureth sulfate; Described sulfonate comprises tridecyl benzene sulfonate, dodecylbenzene sodium sulfonate and lauryl sulfosuccinates; Described sarcosinate comprises sodium lauryl sarcosinate.
In a preferred embodiment of the present invention, described anion surfactant is preferably alkyl sulfate and alkyl ether sulfate.
In a preferred embodiment of the present invention, described anion surfactant be preferably in lauryl alcohol sulfuric ester ammonium or laureth sulfuric ester ammonium one or both.
In a preferred embodiment of the present invention, described conditioner is the compositions of cation Radix Arctii extract, xylitol, glycerol, PPG-3 Octyl Ether, shea butter, polyquaternary ammonium salt and polydimethylsiloxane.
In a preferred embodiment of the present invention, described conditioner is preferably the compositions of polyquaternary ammonium salt and polydimethylsiloxane.
In a preferred embodiment of the present invention, described viscosity modifier is one or more mixture in sodium chloride, ammonium chloride, sodium sulfate, ammonium sulfate, polyglycol distearate, polyethylene glycol mono stearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, Polyethylene Glycol, polyvinylpyrrolidone.
In a preferred embodiment of the present invention, described pearling agent is one in ethylene glycol stearate monoesters and dibasic acid esters or its mixture.
In a preferred embodiment of the present invention, described chelating agen is one or more mixture in disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, ascorbic acid.
The invention has the beneficial effects as follows: anti-dandruff shampoo composition of the present invention, adopt organic Fructus Rubi extract of natural botanical source, organic camomile extract, existing chemical small molecule (the pyrithione zinc of mixture replacing of organic Ramulus et Folium Mussaendae Pubescentis extract, piroctone olamine salt etc.) as antibacterial, this mixture is gentle to scalp, non-stimulated, the hair that life-time service chemical small molecule antibacterial can be avoided to cause dries up, dim mute, and the situation that anti-dandruff effect declines and dandruff increases the weight of, conditioner life-time service in matched combined thing can remove dandruff, the scalp problems such as head pruritus.
Detailed description of the invention
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of anti-dandruff shampoo composition, the constituent mass percentage ratio of described compositions is:
Anion surfactant 5-30%;
Amphoteric surfactant 2-20%;
Conditioner 2-12%;
Anti-dandruff mixture 2-5%;
Pearling agent 0.5-3%;
Viscosity modifier 0.2-0.5%;
Chelating agen 0.02-0.3%;
In above-mentioned, the component of described compositions also comprises pH adjusting agent, essence and pigment, and all the other are deionized water.
Further, described anti-dandruff mixture is organic Fructus Rubi extract, organic camomile extract, the mixture of organic Ramulus et Folium Mussaendae Pubescentis extract, wherein, the weight ratio content of organic Fructus Rubi extract is 10-40%, and the weight ratio content of organic camomile extract is 10-40%, and all the other are organic Ramulus et Folium Mussaendae Pubescentis extract.
Organic Fructus Rubi extract main component comprises water, glycerol, Fructus Rubi juice; Have antibacterial, nourish, protection effect;
Organic camomile extract main component comprises maltodextrin, camomile extract; Have irritation, skin of waking up, excites effect of scalp vigor;
Organic Ramulus et Folium Mussaendae Pubescentis extract main component comprises ethanol, Folium Camelliae sinensis extract; There is moisturizing, antibacterial and anti-oxidation efficacy;
Three composite can realize the anti-dandruff and repairing effect of good scalp.
Described described anion surfactant includes but not limited to alkyl sulfate, alkyl ether sulfate, sulfonate and sarcosinate.Wherein, described alkyl sulfate comprises lauryl alcohol sulfuric ester ammonium, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, sodium cocosulfate and composition thereof; Described alkyl ether sulfate comprises laureth sulfuric ester ammonium, laureth potassium sulfate and sodium laureth sulfate; Described sulfonate comprises tridecyl benzene sulfonate, dodecylbenzene sodium sulfonate and lauryl sulfosuccinates; Described sarcosinate comprises sodium lauryl sarcosinate.
Wherein, described anion surfactant is preferably alkyl sulfate and alkyl ether sulfate; Described anion surfactant be particularly preferably in lauryl alcohol sulfuric ester ammonium or laureth sulfuric ester ammonium one or both.
Described amphoteric surfactant is one or both in cocamido propyl betaine, lauryl both sexes sodium acetate.
Described conditioner is the compositions of cation Radix Arctii extract, xylitol, glycerol, PPG-3 Octyl Ether, shea butter, polyquaternary ammonium salt and polydimethylsiloxane.Wherein, described conditioner is preferably the compositions of polyquaternary ammonium salt and polydimethylsiloxane.
Described viscosity modifier is one or more mixture in sodium chloride, ammonium chloride, sodium sulfate, ammonium sulfate, polyglycol distearate, polyethylene glycol mono stearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, Polyethylene Glycol, polyvinylpyrrolidone.
Described pearling agent is one in ethylene glycol stearate monoesters and dibasic acid esters or its mixture.
Described chelating agen is one or more mixture in disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, ascorbic acid.
Described pH regulator is one or both in citric acid, phosphoric acid.
Embodiment:
Prepare anti-dandruff mixture (I)
Organic Fructus Rubi extract 10%;
Organic camomile extract 10%;
Organic Ramulus et Folium Mussaendae Pubescentis extract 80%.
Prepare anti-dandruff mixture (II)
Organic Fructus Rubi extract 30%;
Organic camomile extract 30%;
Organic Ramulus et Folium Mussaendae Pubescentis extract 40%.
Prepare anti-dandruff mixture (III)
Organic Fructus Rubi extract 40%;
Organic camomile extract 40%;
Organic Ramulus et Folium Mussaendae Pubescentis extract 20%.
The antibacterial test of anti-dandruff mixture: test anti-dandruff mixture (I), anti-dandruff mixture (II) and anti-dandruff mixture (III) to the MIC value of Malassezia cilobosa.
Method of testing: anti-dandruff mixture is diluted successively by 1:2
1. strain: selection standard strain
2. culture medium: M11 agar
3. method: agar dilution
In the present invention, the preparation method of anti-dandruff shampoo composition is: suitable quantity of water joined in retort, add cation polyquaternary ammonium salt under slow stirring to disperse, slowly stirring makes temperature rise to 70 DEG C again, add pH regulator Fructus Citri Limoniae acid for adjusting pH to 6.5, continue to add lauryl alcohol sulfuric ester ammonium, laureth sulfuric ester ammonium, cocamido propyl betaine and lauryl both sexes sodium acetate, fatty acid monoethanolamide, pearlescent flake ethylene glycol stearate monoesters and disodiumedetate, after these materials are disperseed completely, anti-dandruff mixture (II) is added when being cooled to about 50 DEG C, polydimethylsiloxane, be cooled to about 40 DEG C after these materials are disperseed completely and add color element, essence etc. continue to stir, guarantee to obtain uniform mixture.Adding all substances and surveying a pH again after making it be uniformly dispersed, appropriate viscosity modifier and pH regulator can be added as required again, to regulate the viscosity of product and pH to suitable degree.
In the present invention, the formulation Example of anti-dandruff shampoo composition sees the following form:
Removing scurf and relieving itching performance and smooth easy Carding Degree detect the mode taking volunteer's sensory evaluation, and volunteer all exists dandruff and scalp and to scratch where it itches problem, asks nine groups of people, often organizes ten people.Sensory evaluation shampoo washing hair removing scurf and relieving itching effect and with after smooth easy Carding Degree, wherein anti-dandruff effect is marked according to the number of dandruff and size, antipruritic effect is that the degree of time and the head pruritus started according to head pruritus is marked, smoothness be naturally stretch out again after artificially tiing a knot according to hair needed for time length give a mark, dried easy Carding Degree carries out giving a mark according to the combing difficulty or ease situation of hair after drying.Evaluation cycle is 3 months, and evaluate employing 5 points system, 5 are divided into best result, and 1 is divided into minimum point, and mark is higher, and to represent effect better.Pyrithione zinc (ZPT) is current the most widely used micromolecule anti-dandruff agent, adds one group of shampoo containing 1% pyrithione zinc (ZPT) and compare with the embodiment of the application in evaluation.The Analyses Methods for Sensory Evaluation Results of formulation Example sees the following form:
Note: instead of this patent desquamation compositions containing 1% pyrithione zinc (ZPT) shampoo, 1% pyrithione zinc (ZPT), the composition component of other compositions and this patent is completely the same.
As can be seen from the Analyses Methods for Sensory Evaluation Results of formulation Example, the result satisfaction of each evaluation index can change because the proportion of composition each in formula is different, after using three months continuously, embodiment 2,3 and 4 all shows the removing scurf and relieving itching effect be better than containing 1% pyrithione zinc (ZPT) shampoo.Along with the prolongation of service time, embodiment 2,3 and 4 does not all affect the smoothness of hair and dried cardability, and employing containing 1% pyrithione zinc (ZPT) shampoo composite after three months, smoothness and the dried easy cardability of hair all obviously decline.
In sum, anti-dandruff shampoo composition of the present invention, adopt organic Fructus Rubi extract of natural botanical source, organic camomile extract, existing chemical small molecule (the pyrithione zinc of mixture replacing of organic Ramulus et Folium Mussaendae Pubescentis extract, piroctone olamine salt etc.) as antibacterial, this mixture is gentle to scalp, non-stimulated, the hair that life-time service chemical small molecule antibacterial can be avoided to cause dries up, dim mute, and the situation that anti-dandruff effect declines and dandruff increases the weight of, the conditioner life-time service in matched combined thing can remove the scalp problems such as dandruff, head pruritus.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.