CN106420511A - Antidandruff and antipruritic silicone-oil-free shampoo and preparation method thereof - Google Patents
Antidandruff and antipruritic silicone-oil-free shampoo and preparation method thereof Download PDFInfo
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- CN106420511A CN106420511A CN201611139633.6A CN201611139633A CN106420511A CN 106420511 A CN106420511 A CN 106420511A CN 201611139633 A CN201611139633 A CN 201611139633A CN 106420511 A CN106420511 A CN 106420511A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Abstract
The invention belongs to the technical field of cosmetics, and discloses antidandruff and antipruritic silicone-oil-free shampoo, which is prepared from the following raw materials in parts by weight: 9 to 13 parts of ammonium lauryl polyoxyethylene ether sulfate, 4 to 9 parts of cocamidopropyl betaine, 1 to 5 parts of sodium lauroamphoacetate, 0.5 to 2.5 parts of polyquaternium-10, 0.1 to 0.9 part of guar hydroxypropyltrimonium chloride, 1 to 4 parts of mosla chinensis maxim extract, 2 to 5 parts of ficus pumila extract, 0.1 to 0.6 part of trimethylpropane tricaprylate, 2 to 6 parts of balanites roxburghii seed oil, 0.2 to 0.7 part of citric acid, 0.1 to 0.5 part of ethylene diamine tetraacetic acid disodium salt, 0.1 to 0.4 part of a thickening agent, 0.1 to 0.3 part of a preservative, 0.2 to 0.5 part of essence and 40 to 60 parts of water. The raw materials of the shampoo do not contain a silicone oil component, the shampoo is prepared by adding a water-soluble plant essential oil component and the natural plant extracting solutions as main raw materials instead of silicone oil, and the raw materials supplement one other, so that high foaming property and conditioning property are achieved, a pharmacological function is realized, and good antidandruff and antipruritic effects are achieved.
Description
Technical field
The present invention relates to cosmetic field, more particularly to a kind of antidandruff and antipruritic shampoo of no silicone oil and preparation method thereof.
Background technology
Shampoo as requisite fast-moving consumer goods in daily life, its major function be except on head clearing, hair
Dirt, suppression dandruff and prurituss, protection scalp and hair cleaning and beautiful, often add silicon in common shampoo formula
Oil is to reach after hair cleaning with smooth feeling and cardability.
As disclosed a kind of nursing type shampoo in Chinese patent application CN103655262A, it is characterised in that include
The composition of following weight content:Alkylpolyoxyethylene sodium sulfate 20-40 part, cocoanut oil diethan olamide 10-20 part,
Small particle emulsified silicone oil 15-25 part, seaweed extract thing 5-10 part, deionized water 2000-3000 part, a large amount of silicon are just contained in the inside
Oil component.
Treat the shampoo of quintessence oil as a kind of virtue containing compound plant is disclosed in Chinese patent application CN102342902A, its
Composition and percentage by weight are respectively:Deionized water 69~72%, sodium laureth sulfate 10~12%, ammonium lauryl sulfate 5~
7%th, cocamido propyl betaine 5~76%, emulsified silicone oil 2~3%, ethanedioic acid double stearate 0.5~1.5%, citric acids 0.4
~0.8%, ammonium chloride 0.4~0.8%, stearyl polyoxyethanyl hydroxyethyl ammonium chloride 0.3~0.7%, chitin 0.3~0.7%,
Guar gum 0.2~0.6%, hydantoin 0.05~0.15%, essence 0.05~0.15%, compound plant virtue treat quintessence oil 0.2~
0.6%, contain silicone oil component in shampoo obtained in which.
After silicone oil enables to hair washing, hair has cardability and smooth feeling, but silicone oil component is contacted and is detained scalp meeting
Correct leatherware has certain damage, can bring the harm of health if life-time service to consumer.
Content of the invention
It is an object of the invention in the presence of overcoming existing hair washing product due to add silicone oil cause life-time service pair
Scalp causes the above-mentioned deficiency that damages, and provides a kind of antidandruff and antipruritic shampoo of no silicone oil and preparation method thereof, by adding water
Soluble plant essential oil component and natural botanical extraction liquid substitute silicone oil and are configured to shampoo as primary raw material, complement each other, take
Foaming properties well and conditioning performance is obtained, possesses pharmacological function, removing scurf and relieving itching effect is good.
In order to realize foregoing invention purpose, the invention provides technical scheme below:
A kind of antidandruff and antipruritic shampoo of no silicone oil, is obtained by the raw material of following weight parts:Polyoxyethylene lauryl ether sulfuric ester
Ammonium 9-13 part, cocamido propyl betaine 4-9 part, LAA 1-5 part, -10 0.5-2.5 of polyquaternium
Part, guar hydroxypropyltrimonium ammonium chloride 0.1-0.9 part, Mosla chinensis Maxim. extract 1-4 part, Caulis fici pumilae (Fructus Fici Pumilae) extract 2-5 part, three hydroxyls
Three octanoic acid 0.1-0.6 part of methylpropane, Roche acorn seed oil 2-6 part, citric acid 0.2-0.7 part, disodiumedetate
0.1-0.5 part, thickening agent 0.1-0.4 part, preservative 0.1-0.3 part, essence 0.2-0.5 part, water 40-60 part.
Preferably, a kind of antidandruff and antipruritic shampoo of no silicone oil, is obtained by the raw material of following weight parts:Lauryl alcohol polyoxy second
Alkene ether sulfuric ester ammonium 10-12 part, cocamido propyl betaine 6-8 part, LAA 2-4 part, polyquaternium-
10 1.5-2 parts, guar hydroxypropyltrimonium ammonium chloride 0.4-0.8 part, Mosla chinensis Maxim. extract 1-3 part, Caulis fici pumilae (Fructus Fici Pumilae) extract 3-5
Part, trimethylolpropane tris octanoic acid 0.2-0.4 part, Roche acorn seed oil 3-5 part, citric acid 0.4-0.6 part, ethylenediaminetetraacetic acid
Disodium 0.2-0.4 part, thickening agent 0.2-0.4 part, preservative 0.1-0.2 part, essence 0.3-0.5 part, water 50-55 part.
Most preferably, a kind of antidandruff and antipruritic shampoo of no silicone oil, is obtained by the raw material of following weight parts::Lauryl alcohol gathers
11 parts of oxygen ethylene ether sulfuric ester ammonium, 7 parts of cocamido propyl betaine, 3 parts of LAA, polyquaternium -10
1.8 parts, 0.6 part of guar hydroxypropyltrimonium ammonium chloride, 2 parts of Mosla chinensis Maxim. extract, 4 parts of Caulis fici pumilae (Fructus Fici Pumilae) extract, trihydroxy methyl third
0.3 part of the octanoic acid of alkane three, 4 parts of Roche acorn seed oil, 0.5 part of citric acid, 0.3 part of disodiumedetate, 0.3 part of thickening agent,
0.16 part of preservative, 0.4 part of essence, 53 parts of water.
The preparation method of above-mentioned Caulis fici pumilae (Fructus Fici Pumilae) extract is the 80vt% ethanol that Caulis fici pumilae (Fructus Fici Pumilae) is added 3-5 times of weight, reflux, extract, 2-
4h, filters, and reclaims ethanol, obtain concentrated solution and residue retain respectively standby;Residue is added the water of 8-10 times of weight, is decocted
Boil, decocting time 1.5h, isolated decoction liquor is standby;Concentrated solution and decoction liquor are merged, concentrated, dry, obtain Caulis fici pumilae (Fructus Fici Pumilae) and carry
Take thing;
The preparation method of above-mentioned Mosla chinensis Maxim. extract is the 80vt% ethanol that Mosla chinensis Maxim. is added 3-5 times of weight, reflux, extract, 2-
4h, filters, and reclaims ethanol, obtain concentrated solution and residue retain respectively standby;Residue is added the water of 8-10 times of weight, is decocted
Boil, decocting time 1.5h, isolated decoction liquor is standby;Concentrated solution and decoction liquor are merged, concentrated, dry, obtain Mosla chinensis Maxim.
Extract;
Preferably, thickening agent be stearic acid, Palmic acid, PEG-4000, Polyethylene Glycol -600, in PEG-8 00 one
Plant or several.
Another object of the present invention is to a kind of preparation method of the antidandruff and antipruritic shampoo of no silicone oil is provided, including following
Step:
(1)Polyoxyethylene lauryl ether sulfuric ester ammonium, alkyl sulfate monoethanolamine, lauroyl are added by proportioning in reactor
Both sexes guanidine-acetic acid sodium, polyquaternium -10, guar hydroxypropyltrimonium ammonium chloride, Mosla chinensis Maxim. extract and Roche acorn seed oil,
60-70 DEG C is heated to, 10-20min is stirred, form mixed liquor;
(2)Mixed liquor in step (1) is heated to 75-85 DEG C, the mixing speed of reactor is improved to 800-1000rpm,
And Caulis fici pumilae (Fructus Fici Pumilae) extract, trimethylolpropane tris octanoic acid and citric acid is added, after stirring 15-30min, add ethylenediaminetetraacetic acid
Disodium and water continue stirring 5-10min;
(3)After being cooled to 35-45 DEG C, thickening agent, preservative and essence is added, after stirring, obtains finished product.
Compared with prior art, beneficial effects of the present invention:
The invention provides a kind of antidandruff and antipruritic shampoo of no silicone oil and preparation method thereof, in the shampoo raw material of the present invention not
Containing silicone oil component, will not scalp be caused to damage during use.By adding water-soluble plant essential oil component and natural plant
Thing extracting solution substitutes silicone oil and is configured to shampoo as primary raw material, complements each other, and obtains good foaming properties and hair conditioning
Can, possessing pharmacological function, removing scurf and relieving itching effect is good, it is to avoid in scalp Long Term Contact shampoo, the health brought by silicone oil component
Harm, to human body non-hazardous, environmentally safe, with low cost.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood
Below example is only limitted to for the scope of the above-mentioned theme of the present invention, all technology that is realized based on present invention belong to this
The scope of invention.
Embodiment 1
A kind of antidandruff and antipruritic shampoo of no silicone oil, is obtained by the raw material of following weight parts:Polyoxyethylene lauryl ether sulfuric ester
11 parts of ammonium, 7 parts of cocamido propyl betaine, 3 parts of LAA, -10 1.8 parts of polyquaternium, guar gum hydroxyl
0.6 part of hydroxypropyltrimonium chloride, 2 parts of Mosla chinensis Maxim. extract, 4 parts of Caulis fici pumilae (Fructus Fici Pumilae) extract, trimethylolpropane tris octanoic acid 0.3 part,
4 parts of Roche acorn seed oil, 0.5 part of citric acid, 0.3 part of disodiumedetate, 0.3 part of thickening agent, 0.16 part of preservative, perfume
Smart 0.4 part, 53 parts of water.
Its preparation method is comprised the following steps:
(1)Polyoxyethylene lauryl ether sulfuric ester ammonium, alkyl sulfate monoethanolamine, lauroyl are added by proportioning in reactor
Both sexes guanidine-acetic acid sodium, polyquaternium -10, guar hydroxypropyltrimonium ammonium chloride, Mosla chinensis Maxim. extract and Roche acorn seed oil,
63 DEG C are heated to, 17min is stirred, form mixed liquor;
(2)Mixed liquor in step (1) is heated to 81 DEG C, the mixing speed of reactor is improved to 900rpm, and is added Pi
Litchi extract, trimethylolpropane tris octanoic acid and citric acid, after stirring 23min, add disodiumedetate and water to continue
Stirring 8min;
(3)After being cooled to 40 DEG C, thickening agent, preservative and essence is added, after stirring, obtains finished product.
Claims (5)
1. a kind of antidandruff and antipruritic shampoo of no silicone oil, it is characterised in that be obtained by the raw material of following weight parts:Lauryl alcohol polyoxy
Ethylene ether sulfuric ester ammonium 9-13 part, cocamido propyl betaine 4-9 part, LAA 1-5 part, poly- quaternary amine
- 10 0.5-2.5 part of salt, guar hydroxypropyltrimonium ammonium chloride 0.1-0.9 part, Mosla chinensis Maxim. extract 1-4 part, Caulis fici pumilae (Fructus Fici Pumilae) are extracted
Thing 2-5 part, trimethylolpropane tris octanoic acid 0.1-0.6 part, Roche acorn seed oil 2-6 part, citric acid 0.2-0.7 part, ethylenediamine
Tetraacethyl disodium 0.1-0.5 part, thickening agent 0.1-0.4 part, preservative 0.1-0.3 part, essence 0.2-0.5 part, water 40-60 part.
2. the antidandruff and antipruritic shampoo of a kind of no silicone oil according to claim 1, it is characterised in that by following weight parts
Raw material is obtained:Polyoxyethylene lauryl ether sulfuric ester ammonium 10-12 part, cocamido propyl betaine 6-8 part, lauroyl both sexes base
Sodium acetate 2-4 part, -10 1.5-2 part of polyquaternium, guar hydroxypropyltrimonium ammonium chloride 0.4-0.8 part, Mosla chinensis Maxim. are extracted
Thing 1-3 part, Caulis fici pumilae (Fructus Fici Pumilae) extract 3-5 part, trimethylolpropane tris octanoic acid 0.2-0.4 part, Roche acorn seed oil 3-5 part, citric acid
0.4-0.6 part, disodiumedetate 0.2-0.4 part, thickening agent 0.2-0.4 part, preservative 0.1-0.2 part, essence 0.3-
0.5 part, water 50-55 part.
3. the antidandruff and antipruritic shampoo of a kind of no silicone oil according to claim 2, it is characterised in that by following weight parts
Raw material is obtained:11 parts of polyoxyethylene lauryl ether sulfuric ester ammonium, 7 parts of cocamido propyl betaine, lauroyl both sexes guanidine-acetic acid
3 parts of sodium, -10 1.8 parts of polyquaternium, 0.6 part of guar hydroxypropyltrimonium ammonium chloride, 2 parts of Mosla chinensis Maxim. extract, Caulis fici pumilae (Fructus Fici Pumilae) are carried
Take 4 parts of thing, 0.3 part of trimethylolpropane tris octanoic acid, 4 parts of Roche acorn seed oil, 0.5 part of citric acid, disodiumedetate
0.3 part, 0.3 part of thickening agent, 0.16 part of preservative, 0.4 part of essence, 53 parts of water.
4. a kind of antidandruff and antipruritic shampoo of the no silicone oil according to any one of claim 1-3, it is characterised in that the increasing
Thick dose be stearic acid, Palmic acid, PEG-4000, Polyethylene Glycol -600, one or more in PEG-8 00.
5. the preparation method of the antidandruff and antipruritic shampoo of no silicone oil according to claim 1, it is characterised in that including following
Step:
(1)Polyoxyethylene lauryl ether sulfuric ester ammonium, alkyl sulfate monoethanolamine, lauroyl are added by proportioning in reactor
Both sexes guanidine-acetic acid sodium, polyquaternium -10, guar hydroxypropyltrimonium ammonium chloride, Mosla chinensis Maxim. extract and Roche acorn seed oil,
60-70 DEG C is heated to, 10-20min is stirred, form mixed liquor;
(2)Mixed liquor in step (1) is heated to 75-85 DEG C, the mixing speed of reactor is improved to 800-1000rpm,
And Caulis fici pumilae (Fructus Fici Pumilae) extract, trimethylolpropane tris octanoic acid and citric acid is added, after stirring 15-30min, add ethylenediaminetetraacetic acid
Disodium and water continue stirring 5-10min;
(3)After being cooled to 35-45 DEG C, thickening agent, preservative and essence is added, after stirring, obtains finished product.
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Cited By (5)
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CN107028824A (en) * | 2017-03-15 | 2017-08-11 | 广东金山百草健康产业有限公司 | A kind of beautiful millettia root shampoo and preparation method thereof |
CN107998044A (en) * | 2017-12-11 | 2018-05-08 | 百朗德生物化学(海门)有限公司 | A kind of submissive shampoo of hair tonic and preparation method thereof |
CN108042403A (en) * | 2018-02-05 | 2018-05-18 | 淮安智品企业管理有限公司 | A kind of no silicone oil anticreep hair-care shampoo |
CN108354852A (en) * | 2018-04-09 | 2018-08-03 | 广州奥蓓斯化妆品有限公司 | A kind of shampoo |
CN108904311A (en) * | 2018-09-30 | 2018-11-30 | 广州启正化工科技有限公司 | A kind of no silicone oil shampoo |
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CN107998044A (en) * | 2017-12-11 | 2018-05-08 | 百朗德生物化学(海门)有限公司 | A kind of submissive shampoo of hair tonic and preparation method thereof |
CN108042403A (en) * | 2018-02-05 | 2018-05-18 | 淮安智品企业管理有限公司 | A kind of no silicone oil anticreep hair-care shampoo |
CN108354852A (en) * | 2018-04-09 | 2018-08-03 | 广州奥蓓斯化妆品有限公司 | A kind of shampoo |
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