CN104603173B - 纤维增强的复合材料组件及其制备 - Google Patents

纤维增强的复合材料组件及其制备 Download PDF

Info

Publication number
CN104603173B
CN104603173B CN201380044329.1A CN201380044329A CN104603173B CN 104603173 B CN104603173 B CN 104603173B CN 201380044329 A CN201380044329 A CN 201380044329A CN 104603173 B CN104603173 B CN 104603173B
Authority
CN
China
Prior art keywords
component
group number
ratio
mixture
viscosity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380044329.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN104603173A (zh
Inventor
F.胡普卡
M.肖恩施泰因
D.韦格纳
H.拉泽尔恩贝格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Covestro Deutschland AG
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Covestro Deutschland AG, Bayer MaterialScience AG filed Critical Covestro Deutschland AG
Publication of CN104603173A publication Critical patent/CN104603173A/zh
Application granted granted Critical
Publication of CN104603173B publication Critical patent/CN104603173B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4045—Mixtures of compounds of group C08G18/58 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7685—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing two or more non-condensed aromatic rings directly linked to each other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/0872—Prepregs
    • B29K2105/089—Prepregs fabric
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Reinforced Plastic Materials (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
CN201380044329.1A 2012-08-20 2013-08-16 纤维增强的复合材料组件及其制备 Expired - Fee Related CN104603173B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12180970 2012-08-20
EP12180970.1 2012-08-20
PCT/EP2013/067163 WO2014029701A1 (de) 2012-08-20 2013-08-16 Faserverstärkte verbundbauteile und deren herstellung

Publications (2)

Publication Number Publication Date
CN104603173A CN104603173A (zh) 2015-05-06
CN104603173B true CN104603173B (zh) 2017-03-01

Family

ID=46940234

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380044329.1A Expired - Fee Related CN104603173B (zh) 2012-08-20 2013-08-16 纤维增强的复合材料组件及其制备

Country Status (7)

Country Link
US (1) US9290661B2 (enExample)
EP (1) EP2885331B1 (enExample)
JP (1) JP6117360B2 (enExample)
CN (1) CN104603173B (enExample)
DK (1) DK2885331T3 (enExample)
RU (1) RU2638302C2 (enExample)
WO (1) WO2014029701A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014029700A1 (de) * 2012-08-20 2014-02-27 Bayer Materialscience Ag POLYURETHAN-GIEßHARZE UND DARAUS HERGESTELLTE VERGUSSMASSEN
DE102014226842A1 (de) 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Katalysator-Zusammensetzung zur Härtung von Epoxidgruppen-haltigen Harzen
DE102014226838A1 (de) * 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Oxazolidinon- und Isocyanurat-vernetzte Matrix für faserverstärktes Material
CN107683297B (zh) * 2015-05-29 2020-09-08 巴斯夫欧洲公司 用于纤维复合材料的具有较长开放时间的聚氨酯-聚异氰脲酸酯树脂
EP3138685B1 (de) * 2015-09-03 2019-02-27 Evonik Degussa GmbH Hybridbauteil mit einer lokalen versteifung aus einem zweistufig vernetzten, auf polyurethan basierenden faserverbundwerkstoff
ES2736530T3 (es) 2015-10-30 2020-01-02 Evonik Operations Gmbh Productos preimpregnados con adherencia controlable
JP6660717B2 (ja) * 2015-11-16 2020-03-11 旭化成株式会社 繊維強化複合材、自動車、航空機及び風車ブレード用材料部材
WO2017191216A1 (de) * 2016-05-04 2017-11-09 Covestro Deutschland Ag Verfahren zur herstellung eines polyisocyanurat-kompositwerkstoffs
EP3263793A1 (de) * 2016-06-28 2018-01-03 HILTI Aktiengesellschaft Brandschutzelement mit einem trägergewebe
US10710348B2 (en) * 2017-07-26 2020-07-14 The Boeing Company Methods and apparatus to increase fire resistance and fracture toughness of a composite structure
JP6447791B1 (ja) * 2017-07-31 2019-01-09 東レ株式会社 シートモールディングコンパウンド、プリプレグおよび繊維強化複合材料
EP3663338A4 (en) * 2017-07-31 2021-07-07 Toray Industries, Inc. BLEND FOR SHEET MOLDING, PRE-IMPREGNATE AND FIBER REINFORCED COMPOSITE MATERIAL
ES2909407T3 (es) 2017-12-21 2022-05-06 Covestro Deutschland Ag Compuestos de poliuretano a base de catalizadores termolatentes
EP3508459A1 (en) 2018-01-09 2019-07-10 OCV Intellectual Capital, LLC Fiber reinforced materials with improved fatigue performance
DE102021124906A1 (de) 2021-09-27 2023-03-30 Bayerische Motoren Werke Aktiengesellschaft Herstellungsverfahren für Faserverbundelemente, Faserverbundelement und Faserverbundwerkzeuganordnung
CN116574231A (zh) * 2023-05-16 2023-08-11 道生天合材料科技(上海)股份有限公司 阻燃树脂组合物及其制备方法和纤维增强复合材料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223598A (en) * 1990-07-30 1993-06-29 Teijin Limited Plural liquid pack type, heat-curable polyisocyanate-polyol-polyepoxy resin composition and process for producing a shaped resin article therefrom
DE4416323A1 (de) * 1994-05-09 1995-11-16 Bayer Ag Wärmehärtbare Reaktionsharzgemische und deren Verwendung
US5714565A (en) * 1995-03-07 1998-02-03 Bayer Corporation Heat resistant structural rim product
WO2008147641A1 (en) * 2007-05-29 2008-12-04 Dow Global Technologies Inc. Isocyanate-epoxy formulations for improved cure control
WO2009141215A1 (en) * 2008-05-19 2009-11-26 Evonik Degussa Gmbh Two-component composition for producing flexible polyurethane gelcoats
WO2012022683A1 (de) * 2010-08-16 2012-02-23 Bayer Materialscience Ag Faserverbundbauteil und ein verfahren zu dessen herstellung

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63309510A (ja) 1987-06-12 1988-12-16 Nippon Polyurethan Kogyo Kk ポリイソシアヌレ−ト複合体の製造法
FR2882756B1 (fr) * 2005-03-04 2007-04-27 Gaz Transp Et Technigaz Soc Pa Mousse de polyurethanne-polyisocyanurate renforcee de fibres de verre
JP5294387B2 (ja) * 2008-02-29 2013-09-18 コニシ株式会社 ２液型硬化性組成物
RU2457220C1 (ru) * 2011-05-03 2012-07-27 Федеральное государственное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" Способ получения эпоксиполиуретанов
WO2014029700A1 (de) 2012-08-20 2014-02-27 Bayer Materialscience Ag POLYURETHAN-GIEßHARZE UND DARAUS HERGESTELLTE VERGUSSMASSEN

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223598A (en) * 1990-07-30 1993-06-29 Teijin Limited Plural liquid pack type, heat-curable polyisocyanate-polyol-polyepoxy resin composition and process for producing a shaped resin article therefrom
DE4416323A1 (de) * 1994-05-09 1995-11-16 Bayer Ag Wärmehärtbare Reaktionsharzgemische und deren Verwendung
US5714565A (en) * 1995-03-07 1998-02-03 Bayer Corporation Heat resistant structural rim product
WO2008147641A1 (en) * 2007-05-29 2008-12-04 Dow Global Technologies Inc. Isocyanate-epoxy formulations for improved cure control
WO2009141215A1 (en) * 2008-05-19 2009-11-26 Evonik Degussa Gmbh Two-component composition for producing flexible polyurethane gelcoats
WO2012022683A1 (de) * 2010-08-16 2012-02-23 Bayer Materialscience Ag Faserverbundbauteil und ein verfahren zu dessen herstellung

Also Published As

Publication number Publication date
DK2885331T3 (da) 2019-12-09
JP6117360B2 (ja) 2017-04-19
WO2014029701A1 (de) 2014-02-27
EP2885331A1 (de) 2015-06-24
US20150218375A1 (en) 2015-08-06
RU2638302C2 (ru) 2017-12-15
US9290661B2 (en) 2016-03-22
CN104603173A (zh) 2015-05-06
RU2015109627A (ru) 2016-10-10
EP2885331B1 (de) 2019-09-25
JP2015525828A (ja) 2015-09-07

Similar Documents

Publication Publication Date Title
CN104603173B (zh) 纤维增强的复合材料组件及其制备
DK2768891T3 (en) FIBER REINFORCED POLYISOCYANURATE COMPONENT AND A PROCEDURE FOR PREPARING IT
US9512260B2 (en) Storage stable resin films and fibre composite components produced therefrom
CN103201304B (zh) 纤维复合部件及其制备方法
CN104185649B (zh) 储存稳定的聚氨酯‑预浸料坯和由其生产的纤维复合材料组件
CN102844165B (zh) 具有高压缩强度和刚度的聚氨酯复合材料体系
EP3526267B1 (en) 3d spacer fabric reinforced pu composite and its use
CN103619895B (zh) 纤维复合材料构件及其制备方法
US9868831B2 (en) Composite fibre components and the production thereof
CN105246952A (zh) 聚氨酯预浸料和由其制造的纤维复合元件
CN106459363B (zh) 基于疏水性多元醇的复合部件
CN104768993B (zh) 用于制备复合组件的方法
CN108779268A (zh) 制造纤维复合部件的方法
JP2018520239A (ja) 風力タービンにおける層構造用のポリウレタン系
CN120813621A (zh) 用于具有稳定且较长保质期的拉挤成型连续纤维复合材料的聚氨酯聚异氰脲酸酯树脂

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: Germany Leverkusen

Applicant after: COVESTRO DEUTSCHLAND AG

Address before: Germany Leverkusen

Applicant before: BAYER MATERIALSCIENCE AG

COR Change of bibliographic data
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170301