CN104559817B - 电子产品用保护贴膜 - Google Patents

电子产品用保护贴膜 Download PDF

Info

Publication number
CN104559817B
CN104559817B CN201310467600.4A CN201310467600A CN104559817B CN 104559817 B CN104559817 B CN 104559817B CN 201310467600 A CN201310467600 A CN 201310467600A CN 104559817 B CN104559817 B CN 104559817B
Authority
CN
China
Prior art keywords
coating
cloudy surface
polymer solution
parts
surface coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310467600.4A
Other languages
English (en)
Other versions
CN104559817A (zh
Inventor
金闯
张庆杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sidike New Materials Jiangsu Co Ltd
Original Assignee
Sidike New Materials Jiangsu Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sidike New Materials Jiangsu Co Ltd filed Critical Sidike New Materials Jiangsu Co Ltd
Priority to CN201610619245.1A priority Critical patent/CN106147641A/zh
Priority to CN201310467600.4A priority patent/CN104559817B/zh
Priority to CN201610619296.4A priority patent/CN106433501A/zh
Publication of CN104559817A publication Critical patent/CN104559817A/zh
Application granted granted Critical
Publication of CN104559817B publication Critical patent/CN104559817B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/005—Presence of polyester in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00—Presence of polysiloxane
    • C09J2483/005—Presence of polysiloxane in the release coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

一种电子产品用保护贴膜，包括一基材层、抗静电涂层、压敏胶涂层和雾面离型膜，雾面离型膜由聚酯薄膜层、雾面涂层和离型剂涂层层叠构成，该雾面涂层剂通过以下工艺获得：将0.3~1份纳米SiO2粉体、0.2~0.6份纳米Al2O3粉体和0.3~1份硅烷偶联剂加入8~10份甲苯中进行超声波处理获得预分散液；将100份乙烯基硅氧烷、0.3~1份含氢硅氧烷加入120~150份丁酮中进行机械搅拌获得聚合物溶液；将预分散液、聚合物溶液混合并依次进行机械搅拌和超声波搅拌，从而获得调制后的聚合物溶液；在调制后的聚合物溶液加入0.2~0.5份铂金。本发明使得压敏胶涂层雾度效果好，使得胶面达到低反光效果；且提高了与离型剂涂层接触的雾面涂层表面粗糙度均匀性。

Description

电子产品用保护贴膜
技术领域
本发明涉及一种保护贴膜，特别涉及一种电子产品用保护贴膜。
背景技术
玻璃、金属板材、塑料板材以及电子产品等产品在搬运和使用过程中，其表面容易受到接触性污染或磨痕划伤，通常采用保护膜覆盖在其表面使之免受损伤和污染。保护膜一般由基材层和涂覆在该基材层上的胶粘剂层构成，传统的保护膜，采用普通聚酷薄膜作为基材层，由于聚酷薄膜是高分子聚合物，其介电常数小，属于非导体，绝缘性能较高，因此，静电的产生是不能避免的。当传统的保护膜应用于电子行业时，容易吸附灰尘和杂质，甚至产生静电引起严重损失。
发明内容
本发明提供一种电子产品用保护贴膜，该电子产品用保护贴膜使得压敏胶涂层面雾度效果好，使得胶面达到低反光效果；且提高了与离型剂涂层接触的雾面涂层表面粗糙度均匀性，解决离型纸的淋膜层与离型剂涂层结合力不稳定的技术问题，有利于剥离以及避免残留压敏胶和将离型剂残留于压敏胶层上。
为达到上述目的，本发明采用的技术方案是：一种电子产品用保护贴膜，包括一基材层，此基材层下表面依此涂覆有抗静电涂层、压敏胶涂层和雾面离型膜，所述雾面离型膜从上往下依次由聚酯薄膜层、雾面涂层和离型剂涂层层叠构成，所述雾面涂层朝向离型剂涂层表面具有若干个凸起部；所述雾面离型膜制备工艺主要由下列步骤组成：
第一步：在聚酯薄膜层上涂覆一层厚度为0.2～2微米的雾面涂层剂，该雾面涂层剂进一步通过以下工艺获得：
步骤1. 将0.3~1份纳米SiO2粉体、0.2~0.6份纳米Al2O3粉体和0.3~1份硅烷偶联剂加入8~10份甲苯中进行超声波处理获得预分散液；
步骤2. 将100份乙烯基硅氧烷、0.3~1份含氢硅氧烷加入120~150份丁酮中进行机械搅拌获得聚合物溶液；
步骤3. 将步骤1的预分散液、步骤2的聚合物溶液混合并依次进行机械搅拌和超声波搅拌，从而获得调制后的聚合物溶液；
步骤4. 在所述调制后的聚合物溶液加入0.2~0.5份铂金并依次进行机械搅拌和超声波搅拌获得所述雾面离型溶剂；
第二步：将离型纸的雾面涂层剂通过烘烤进行聚合反应得到雾面涂层；
第三步：在所述雾面涂层的表面涂覆一层离型剂涂层。
上述技术方案中进一步改进的技术方案如下：
1. 上述方案中，所述纳米SiO2粉体的直径范围为10~15nm，所述纳米Al2O3粉体的直径范围为25~35nm。
2. 上述方案中，所述聚酯薄膜层为聚丙烯薄膜、聚乙烯薄膜或者聚氯乙烯薄膜。
由于上述技术方案运用，本发明与现有技术相比具有下列优点和效果：
本发明电子产品用保护贴膜，通过首先对基材层表面底涂硅烷系抗静电剂涂层，然后涂布胶粘剂，不仅可以增加胶粘剂与基材层之间的粘着力，而且赋予胶粘剂胶面良好的防静电效果，且其特定直径的纳米SiO2粉体、纳米Al2O3粉体在溶剂下与硅烷偶联剂经超声波共同作用，且机械搅拌和超声波搅拌组合，有利于纳米SiO2粉体、Al2O3粉体呈均匀分布，特定的聚合物溶液和预分散液采用不同的溶剂，降低纳米SiO2粉体、Al2O3颗粒的表面能，进一步利于粉体颗粒在溶剂中的分散，提高了与离型剂涂层接触的雾面涂层表面粗糙度均匀性，解决离型纸的淋膜层与离型剂涂层结合力不稳定的技术问题，有利于剥离以及避免残留压敏胶和将离型剂残留于压敏胶层上。
附图说明
附图1为本发明电子产品用保护贴膜结构示意图；
附图2a为对比例贴膜中雾面涂层微观形貌SEM测试图；
附图2b为本发明保护贴膜中雾面涂层微观形貌SEM测试图。
以上附图中：1、基材层；2、抗静电涂层；3、压敏胶涂层；4、雾面离型膜；5、聚酯薄膜层；6、雾面涂层；7、离型剂涂层；8、凸起部。
具体实施方式
下面结合附图及实施例对本发明作进一步描述：
实施例1~5：一种电子产品用保护贴膜，包括一基材层1，此基材层1下表面依此涂覆有抗静电涂层2、压敏胶涂层3和雾面离型膜4，所述雾面离型膜4从上往下依次由聚酯薄膜层5、雾面涂层6和离型剂涂层7层叠构成，所述雾面涂层6朝向离型剂涂层7表面具有若干个凸起部8；所述雾面离型膜制备工艺主要由下列步骤组成：
第一步：在聚酯薄膜层1上涂覆一层厚度为0.2～2微米的雾面涂层剂，该雾面涂层剂进一步通过以下工艺获得：
步骤1. 将0.3~1份纳米SiO2粉体、0.2~0.6份纳米Al2O3粉体和0.3~1份硅烷偶联剂加入8~10份甲苯中进行超声波处理获得预分散液；
步骤2. 将100份乙烯基硅氧烷、0.3~1份含氢硅氧烷加入120~150份丁酮中进行机械搅拌获得聚合物溶液；
步骤3. 将步骤1的预分散液、步骤2的聚合物溶液混合并依次进行机械搅拌和超声波搅拌，从而获得调制后的聚合物溶液；
步骤4. 在所述调制后的聚合物溶液加入0.2~0.5份铂金并依次进行机械搅拌和超声波搅拌获得所述雾面离型溶剂；
实施例1~5雾面涂层各组分重量份含量见表1。
表1
实施例一 实施例二 实施例三 实施例四 实施例五
乙烯基硅氧烷 100份 100份 100份 100份 100份
含氢硅氧烷 0.3份 0.5份 0.4份 0.35份 0.9份
纳米SiO2粉体 0.5份 0.6份 1份 0.8份 0.4份
纳米Al2O3粉体 0.45份 0.25份 0.2份 0.5份 0.6份
硅烷偶联剂 0.35份 1份 0.4份 0.45份 0.9份
甲苯 8~10份 8份 8.5份 9份 8份
丁酮 120份 125份 150份 135份 130份
第二步：将离型纸的雾面涂层剂通过烘烤进行聚合反应得到雾面涂层；
第三步：在所述雾面涂层的表面涂覆一层离型剂涂层。
上述纳米SiO2粉体的直径范围为12nm，所述纳米Al2O3粉体的直径范围为30nm。
上述实施例1中聚酯薄膜层1为聚丙烯薄膜，实施例2中聚酯薄膜层1为聚乙烯薄膜，实施例3中聚酯薄膜层1为聚氯乙烯薄膜，实施例4中聚酯薄膜层1为聚乙烯薄膜，实施例5中聚酯薄膜层1为聚氯乙烯薄膜。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。

Claims (1)

1.一种电子产品用保护贴膜，其特征在于：包括一基材层（1），此基材层（1）下表面依次涂覆有抗静电涂层（2）、压敏胶涂层（3）和雾面离型膜（4），所述雾面离型膜（4）从上往下依次由聚酯薄膜层（5）、雾面涂层（6）和离型剂涂层（7）层叠构成，所述雾面涂层（6）朝向离型剂涂层（7）表面具有若干个凸起部（8）；所述雾面离型膜制备工艺主要由下列步骤组成：
第一步：在聚酯薄膜层上涂覆一层厚度为0.2～2微米的雾面涂层剂，该雾面涂层剂进一步通过以下工艺获得：
步骤1. 将0.3~1份纳米SiO2粉体、0.2~0.6份纳米Al2O3粉体和0.3~1份硅烷偶联剂加入8~10份甲苯中进行超声波处理获得预分散液；
步骤2. 将100份乙烯基硅氧烷、0.3~1份含氢硅氧烷加入120~150份丁酮中进行机械搅拌获得聚合物溶液；
步骤3. 将步骤1的预分散液、步骤2的聚合物溶液混合并依次进行机械搅拌和超声波搅拌，从而获得调制后的聚合物溶液；
步骤4. 在所述调制后的聚合物溶液加入0.2~0.5份铂金并依次进行机械搅拌和超声波搅拌获得雾面离型溶剂；
第二步：将位于聚酯薄膜层的雾面涂层剂通过烘烤进行聚合反应得到雾面涂层；
第三步：在所述雾面涂层的表面涂覆一层离型剂涂层。
CN201310467600.4A 2013-10-09 2013-10-09 电子产品用保护贴膜 Active CN104559817B (zh)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201610619245.1A CN106147641A (zh) 2013-10-09 2013-10-09 智能电子产品用抗静电保护贴膜
CN201310467600.4A CN104559817B (zh) 2013-10-09 2013-10-09 电子产品用保护贴膜
CN201610619296.4A CN106433501A (zh) 2013-10-09 2013-10-09 防残胶保护胶带

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310467600.4A CN104559817B (zh) 2013-10-09 2013-10-09 电子产品用保护贴膜

Related Child Applications (2)

Application Number Title Priority Date Filing Date
CN201610619296.4A Division CN106433501A (zh) 2013-10-09 2013-10-09 防残胶保护胶带
CN201610619245.1A Division CN106147641A (zh) 2013-10-09 2013-10-09 智能电子产品用抗静电保护贴膜

Publications (2)

Publication Number Publication Date
CN104559817A CN104559817A (zh) 2015-04-29
CN104559817B true CN104559817B (zh) 2017-01-04

Family

ID=53076916

Family Applications (3)

Application Number Title Priority Date Filing Date
CN201610619245.1A Pending CN106147641A (zh) 2013-10-09 2013-10-09 智能电子产品用抗静电保护贴膜
CN201310467600.4A Active CN104559817B (zh) 2013-10-09 2013-10-09 电子产品用保护贴膜
CN201610619296.4A Pending CN106433501A (zh) 2013-10-09 2013-10-09 防残胶保护胶带

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201610619245.1A Pending CN106147641A (zh) 2013-10-09 2013-10-09 智能电子产品用抗静电保护贴膜

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201610619296.4A Pending CN106433501A (zh) 2013-10-09 2013-10-09 防残胶保护胶带

Country Status (1)

Country Link
CN (3) CN106147641A (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113308007A (zh) * 2021-05-19 2021-08-27 浙江日久新材料科技有限公司 一种偏光片用抗静电光学离型膜及其制备方法
CN116023696A (zh) * 2021-10-25 2023-04-28 浙江欧仁新材料有限公司 抗静电离型膜的制备工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202935748U (zh) * 2012-10-17 2013-05-15 斯迪克新型材料（江苏）有限公司 防眩型抗刮贴膜
CN203093169U (zh) * 2013-01-29 2013-07-31 苏州斯迪克新材料科技股份有限公司 抗静电型玻璃窗保护膜
EP2639277A1 (en) * 2012-03-13 2013-09-18 Nitto Denko Corporation Heat-resistant pressure-sensitive adhesive tape for production of semiconductor device and method for producing semiconductor device using the tape

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09316411A (ja) * 1996-05-30 1997-12-09 Sekisui Chem Co Ltd グリーンシート用表面保護フィルム
DE102006008387A1 (de) * 2006-02-21 2007-08-30 Goldschmidt Gmbh Verfahren zur Herstellung von siloxanhaltigen Trennbeschichtungen
CN103147358B (zh) * 2011-07-12 2014-10-15 苏州斯迪克新材料科技股份有限公司 雾面防粘纸的制备方法
CN203128473U (zh) * 2012-08-16 2013-08-14 深圳市摩码科技有限公司 一种防静电自排气保护胶带
CN202936354U (zh) * 2012-10-16 2013-05-15 苏州斯迪克新材料科技股份有限公司 防静电抗刮贴膜
CN202935745U (zh) * 2012-10-16 2013-05-15 苏州斯迪克新材料科技股份有限公司 轻剥离型增印保护膜

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2639277A1 (en) * 2012-03-13 2013-09-18 Nitto Denko Corporation Heat-resistant pressure-sensitive adhesive tape for production of semiconductor device and method for producing semiconductor device using the tape
CN202935748U (zh) * 2012-10-17 2013-05-15 斯迪克新型材料（江苏）有限公司 防眩型抗刮贴膜
CN203093169U (zh) * 2013-01-29 2013-07-31 苏州斯迪克新材料科技股份有限公司 抗静电型玻璃窗保护膜

Also Published As

Publication number Publication date
CN106433501A (zh) 2017-02-22
CN106147641A (zh) 2016-11-23
CN104559817A (zh) 2015-04-29

Similar Documents

Publication Publication Date Title
WO2015074611A1 (zh) 一种高透光抗冲击保护膜及其制备方法
CN110305540A (zh) 一种水性高阻隔涂布液及其制备方法
CN108834388B (zh) 一种电磁屏蔽膜及其制备方法
CN104559817B (zh) 电子产品用保护贴膜
CN109694663A (zh) 一种高透光率保护膜及其制备方法
CN208038374U (zh) 双面抗静电单面硅胶保护膜
CN107338005A (zh) 一种黑白遮光聚酯薄膜胶带及制备方法
CN202934848U (zh) 用于玻璃屏保护的贴膜
CN106433398B (zh) 透明导电涂胶组合物、触控面板及其制备方法、显示装置
CN105925208A (zh) 一种雾面遮光聚酯薄膜单面胶带及制备方法
CN103173154A (zh) Pet防静电保护膜
CN104553101B (zh) 增印保护膜
CN110791211A (zh) 一种全遮光pet基膜双面胶带及其制备方法
CN208562223U (zh) 抗静电亚克力保护膜
CN104562838A (zh) 高附着力雾面离型纸的制备工艺
JP2021014059A (ja) 電磁波透過性金属光沢物品
CN206406558U (zh) 一种亲水性防雾膜
CN104549973A (zh) 便于剥离的雾面离型膜的制备工艺
CN109251659A (zh) 复合离型液及其制备方法和功能薄膜
CN114591673A (zh) 双面抗静电lr薄膜、组件和显示设备
CN115044315B (zh) 耐气候性保护膜
CN208035540U (zh) 双面抗静电双面离型膜
CN205890033U (zh) 一种防雾防静电保护膜
CN107057593A (zh) 一种防刮花防静电保护膜
CN105153844A (zh) 具有转移层表面高滑爽性水性环保型转移涂料及制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant