CN104553212A - 一种新型防水抗压隔热复合纸板 - Google Patents
一种新型防水抗压隔热复合纸板 Download PDFInfo
- Publication number
- CN104553212A CN104553212A CN201510015797.7A CN201510015797A CN104553212A CN 104553212 A CN104553212 A CN 104553212A CN 201510015797 A CN201510015797 A CN 201510015797A CN 104553212 A CN104553212 A CN 104553212A
- Authority
- CN
- China
- Prior art keywords
- layer
- heat insulation
- degradable foaming
- foaming layer
- board
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000006835 compression Effects 0.000 title claims abstract description 22
- 238000007906 compression Methods 0.000 title claims abstract description 22
- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 239000011087 paperboard Substances 0.000 title abstract description 12
- 238000005187 foaming Methods 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 34
- 238000009413 insulation Methods 0.000 claims abstract description 33
- 239000000123 paper Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- 239000012528 membrane Substances 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 64
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 230000007613 environmental effect Effects 0.000 claims description 21
- 229920001610 polycaprolactone Polymers 0.000 claims description 20
- 239000004632 polycaprolactone Substances 0.000 claims description 20
- 239000012790 adhesive layer Substances 0.000 claims description 19
- 239000011111 cardboard Substances 0.000 claims description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 15
- 238000001125 extrusion Methods 0.000 claims description 14
- 239000000853 adhesive Substances 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 13
- -1 poly-ester carbonate Chemical class 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 8
- 239000004964 aerogel Substances 0.000 claims description 8
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 229940037003 alum Drugs 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 230000003750 conditioning effect Effects 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 230000001815 facial effect Effects 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 239000012286 potassium permanganate Substances 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- 229920001410 Microfiber Polymers 0.000 claims description 5
- 239000007767 bonding agent Substances 0.000 claims description 5
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 239000004604 Blowing Agent Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 230000004888 barrier function Effects 0.000 abstract description 4
- 239000003292 glue Substances 0.000 abstract 1
- 239000012784 inorganic fiber Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000004078 waterproofing Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/08—Corrugated paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/02—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to polysaccharides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
本发明公开一种新型防水抗压隔热复合纸板，包括纸板基板，纸板基板上、下均设有全降解发泡层，全降解发泡层外设有阻隔膜层，阻隔膜层外设有面纸层，纸板基板与全降解发泡层以环保淀粉胶进行黏合，全降解发泡层与阻隔膜层通过无机纤维粘合层进行黏合。全降解发泡层具有良好的力学性能，且能提供良好的隔热性和防水防潮性；而纸板基板本身也具备了较好的强度和抗冲性，与发泡层相互配合可得到更优秀的抗冲性。从而，发泡层与纸板基板配合将使得复合纸板具有更优异的力学性能和隔热、防水特性。本复合纸板具有优异的防水性、抗压性及隔热性。同时，该复合纸板用料环保，可一次性成型，工艺简单，是一种可广泛应用的环保型板材。
Description
技术领域
本发明涉及复合纸板领域，尤其是涉及一种具有优异防水性、抗压性及隔热性的，且环保的防水抗压隔热复合纸板。
背景技术
在包装领域，各种不同的材料被广泛应用。塑料材料具有良好的和可调整的性能，但由于其来源于石油，非可再生，而且塑料材料不可降解，会造成白色污染。故各种不同的环保替代材料被开发出来。而纸板材料以其环保的特性、良好的性能及低廉的成本被广泛应用。瓦楞纸板是近年来出现并使用最多的纸板材料，因为瓦楞的存在而使得瓦楞纸板具有了较高的强度，瓦楞的形式较多，如U型、V型、方型、交替波等，不同的瓦楞波型赋予了瓦楞纸板差异性的性能特点。但总体来说，其抗冲性较差。蜂窝纸板的出现弥补了这一缺陷，蜂窝纸板内有蜂窝状的结构，可较好的平均吸收能量从而拥有很好的缓冲性，两者结合使用将使得复合纸板具有更平衡的力学性能，即优异的抗压和抗冲特性。而在当今商品极大丰富和电子商务迅速发展的今天，除了力学性能外，也对包装的其他功能化性能也提出了要求，如为了保护内包物，还需要包装体具有良好的抗压、防水防潮特性，如内包物对温度敏感，还需要包装体具有明显的隔热效果。在以外的包装中，如需达到以上效果，发泡塑料是一种较好的选择，如PS发泡材料、PE发泡材料等，发泡材料的孔结构使得材料具有了良好的阻隔性，而一定的厚度也使得材料具有良好的抗冲性能，但此类材料同样存在环保的问题，尤其在部分欧盟国家，已被明令禁止使用。故开发具有良好环保特性的功能性包装材料已成为研究领域的热点。在纸板复合领域，多种形式的复合被开发出来，包括瓦楞与蜂窝的特殊结构搭配，其他复合板如木塑板，发泡板的复合等，但从总体来说，原有的各种复合板尤其是发泡板无论是从综合力学性能还是从各种功能性上来说均存在一定缺陷，尤其是可降解发泡材料普遍较软，且容易吸潮而严重影响复合板的性能，故开发一种新型的纸板复合材料以克服此缺陷，将极大的提高复合板的应用范围。
发明内容
本发明的目的是提供一种具有优异防水性、抗压性及隔热性的，且环保的防水抗压隔热复合纸板。
本发明提出一种新型防水抗压隔热复合纸板，由多层材料复合而成，包括上层结构、下层结构及设置在所述上层结构与所述下层结构之间的纸板基板，所述上层结构从上至下依次包括上面纸层、上阻隔膜层和上全降解发泡层，所述下层结构从下至上依次包括下面纸层、下阻隔膜层和下全降解发泡层，所述纸板基板与所述上全降解发泡层、所述下全降解发泡层之间通过环保淀粉胶粘合，所述上全降解发泡层与所述上阻隔膜层之间通过无机纤维粘合层I粘合，所述下全降解发泡层与所述下阻隔膜层之间通过无机纤维粘合层II粘合。
所述上全降解发泡层和所述下全降解发泡层均为以植物纤维、聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇为主料，并加入辅料SiO2气凝胶粉末、聚乳酸-聚己内酯嵌段共聚物、抗氧化剂、加工助剂，以水蒸汽为发泡剂通过原位挤出发泡而成的板材；所述上全降解发泡层和所述下全降解发泡层中各组分的质量比按以下份数复配：植物纤维 40-60份，聚乳酸 30-50份，聚己内酯 15-30份，脂肪族聚碳酸酯 15-30份，聚乙烯醇 8-15份，SiO2气凝胶粉末3-6份，聚乳酸-聚己内酯嵌段共聚物 5-10份，抗氧化剂 2-4份，加工助剂 2-4份。其采用挤出机直接挤出发泡成板，其工艺包括材料的预处理和挤出发泡工艺：
材料预处理：
I：植物纤维的处理：将植物粗纤维投入破碎机中破碎至500-1000目，后将其浸泡入质量浓度8-14wt%的碱液中，于室温下浸泡3-5小时后，于20-30wt%质量浓度的酸液中在60℃下浸泡2-4小时后过滤，以弱碱水清洗后于清水洗至中性并出料。其中，酸液中酸的组成为质量比为3：1的盐酸和醋酸。
II：物料的干燥：将准备好的植物纤维于真空干燥箱内在30℃下干燥12小时，聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇、聚乳酸-聚己内酯嵌段共聚物于普通干燥箱内在60℃下干燥6-8小时，备用。
挤出发泡工艺：
挤出发泡过程采用多段进料控温控压挤出设备，即在螺杆输送段料筒内送入聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇、SiO2气凝胶粉末、聚乳酸-聚己内酯嵌段共聚物，于压缩段送入植物纤维，并通入水蒸气。温度控制在170-190度之间，水蒸气压力控制在1-1.5MPa之间。物料在挤出机中停留时间为2-3分钟。
进一步，所述环保淀粉胶为以淀粉、氧化剂高锰酸钾、脱水明矾、轻质氧化镁、酯化剂磷酸钠、接枝共聚试剂脲醛胶粘剂、聚乙烯醇和去离子水为主料，并加入辅料膨胀剂、PH调节剂、淀粉接枝甲基丙烯酸缩水甘油酯，在一定条件下调和后形成的胶粘剂；所述环保淀粉胶的各组分的质量比按以下份数复配：淀粉 320-500份，氧化剂高锰酸钾 2-8份，酯化剂磷酸5-20份，脱水明矾 6-20份，轻质氧化镁 7-15份，接枝共聚剂脲醛胶粘剂 5-15份，聚乙烯醇 2-4份，膨胀剂 2-10份， PH调节剂 15-20份，淀粉接枝甲基丙烯酸缩水甘油酯5-15份，去离子水 1000-1200份。
进一步，所述纸板基板为单层或多层的蜂窝纸板、瓦楞纸板或蜂窝纸板与瓦楞纸板的复合。
进一步，所述纸板基板为两层蜂窝纸板夹一层瓦楞纸板的结构，两层所述蜂窝纸板的蜂窝结构完全对应，所述蜂窝纸板与所述瓦楞纸板之间通过所述环保淀粉胶粘合。
进一步，所述蜂窝纸板的蜂窝纸芯的截面形态为菱形、正四边形或正六边形，所述瓦楞纸板的的瓦楞纸芯的截面形态为U型、V型或方型的波浪瓦楞。
进一步，所述上阻隔膜层和所述下阻隔膜层均为多层共挤尼龙膜或多层共挤EVOH膜。
进一步，所述EVOH膜或所述尼龙膜的层数介于3-5层之间。
进一步，所述无机纤维粘合层I和所述无机纤维粘合层II由无机超细纤维棉与水基性粘接剂混合后喷涂而成。其制作工艺是：将预先经特殊工艺制造加工的无机超细纤维棉与特有水基性粘接剂混合，混合材料经过喷途后，自然干燥，形成具有一定强度和厚度的无接缝、整体稳定密闭的无机纤维粘合层。该无机纤维粘合层呈现弹性的自然纹理和纤维质地，具有保温隔热的效果和粘合效果。
本发明的新型防水抗压隔热复合纸板的有益效果为：
本发明的新型防水抗压隔热复合纸板由多层材料复合而成，其中，上全降解发泡层和下全降解发泡层具有良好的力学性能，如抗冲性、抗压性等，同时，由于其均匀闭孔结构的存在，发泡层能提供良好的隔热性和防水防潮性；而纸板基板本身也具备了较好的强度和抗冲性，与发泡层相互配合可得到更优秀的抗冲性。从而，发泡层与纸板基板配合将使得复合纸板具有更优异的力学性能和隔热、防水特性。
而且，在粘合时所采用的环保淀粉胶因为特殊酯化剂、脲醛胶粘剂的添加，使环保淀粉胶具有良好的防水性；上、下阻隔膜层的设置有效的防止了水汽的渗入；无机纤维粘合层I和II作为粘合剂，其本身也具有优异的隔热和防水效果。故综合以上各层的性能及其搭配赋予了本复合纸板优异的性能，本复合纸板具有优异的防水性、抗压性及隔热性。
附图说明
图1为本发明的一种新型防水抗压隔热复合纸板的实施例的结构示意图。
本发明目的的实现、功能特点及优点将结合实施例，参照附图做进一步说明。
具体实施方式
应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
参照图1，提出本发明的一种新型防水抗压隔热复合纸板的一实施例：
一种新型防水抗压隔热复合纸板，由多层材料复合而成，包括上层结构、下层结构及设置在上层结构与下层结构之间的纸板基板1，上层结构从上至下依次包括上面纸层5-1、上阻隔膜层4-1和上全降解发泡层2-1，下层结构从下至上依次包括下面纸层5-2、下阻隔膜层4-2和下全降解发泡层2-2，纸板基板1与上全降解发泡层2-1、下全降解发泡层2-2之间通过环保淀粉胶粘合，上全降解发泡层2-1与上阻隔膜层4-1之间通过无机纤维粘合层I3-1粘合，下全降解发泡层2-2与下阻隔膜层4-2之间通过无机纤维粘合层II3-2粘合。
其中，纸板基板1为两层蜂窝纸板夹一层瓦楞纸板的结构，两层蜂窝纸板的蜂窝结构完全对应，蜂窝纸板与瓦楞纸板之间通过环保淀粉胶粘合。
该蜂窝纸板的蜂窝纸芯的截面形态为菱形，瓦楞纸板的的瓦楞纸芯的截面形态为U型的波浪瓦楞。
该上全降解发泡层2-1和下全降解发泡层2-2均为以植物纤维、聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇为主料，并加入辅料SiO2气凝胶粉末、聚乳酸-聚己内酯嵌段共聚物、抗氧化剂、加工助剂，以水蒸汽作为发泡剂，通过原位挤出发泡而成的板材。上全降解发泡层2-1和下全降解发泡层2-2中各组分的质量比按以下份数复配：植物纤维 50份，聚乳酸 40份，聚己内酯 20份，脂肪族聚碳酸酯 25份，聚乙烯醇 10份，SiO2气凝胶粉末5份，聚乳酸-聚己内酯嵌段共聚物 8份，抗氧化剂 3份，加工助剂 3份。其采用挤出机直接挤出发泡成板，其工艺包括材料的预处理和挤出发泡工艺：
材料预处理：
I：植物纤维的处理：将植物粗纤维投入破碎机中破碎至500-1000目，后将其浸泡入质量浓度10wt%的碱液中，于室温下浸泡4小时后，于25wt%质量浓度的酸液中在60℃下浸泡3小时后过滤，以弱碱水清洗后于清水洗至中性并出料。其中，酸液中酸的组成为质量比为3：1的盐酸和醋酸。
II：物料的干燥：将准备好的植物纤维于真空干燥箱内在30℃下干燥12小时，聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇、聚乳酸-聚己内酯嵌段共聚物于普通干燥箱内在60℃下干燥8小时，备用。
挤出发泡工艺：
挤出发泡过程采用多段进料控温控压挤出设备，即在螺杆输送段料筒内送入聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇、SiO2气凝胶粉末、聚乳酸-聚己内酯嵌段共聚物，于压缩段送入植物纤维，并通入水蒸气。温度控制在170-190度之间，水蒸气压力控制在1-1.5MPa之间。物料在挤出机中停留时间为2-3分钟。
该环保淀粉胶为以淀粉、氧化剂高锰酸钾、脱水明矾、轻质氧化镁、酯化剂磷酸钠、接枝共聚试剂脲醛胶粘剂、聚乙烯醇和去离子水为主料，并加入少量辅料膨胀剂、PH调节剂、淀粉接枝甲基丙烯酸缩水甘油酯，在一定条件下调和后形成的胶粘剂；环保淀粉胶的各组分的质量比按以下份数复配：淀粉 450份，氧化剂高锰酸钾 6份，酯化剂磷酸15份，脱水明矾 15份，轻质氧化镁 12份，接枝共聚剂脲醛胶粘剂 10份，聚乙烯醇 3份，膨胀剂 6份， PH调节剂 18份，淀粉接枝甲基丙烯酸缩水甘油酯10份，去离子水 1050份。
该上阻隔膜层4-1和下阻隔膜层4-2均为4层共挤EVOH膜。
该无机纤维粘合层I3-1和无机纤维粘合层II3-2由无机超细纤维棉与水基性粘接剂混合后喷涂而成，其制作工艺是：将预先经特殊工艺制造加工的无机超细纤维棉与特有水基性粘接剂混合，混合材料经过喷途后，自然干燥，形成具有一定强度和厚度的无接缝、整体稳定密闭的无机纤维粘合层。该无机纤维粘合层呈现弹性的自然纹理和纤维质地，具有保温隔热的效果和粘合效果。
本新型防水抗压隔热复合纸板由多层材料复合而成，其中，上全降解发泡层2-1和下全降解发泡层2-2具有良好的力学性能，如抗冲性、抗压性等，同时，由于其均匀闭孔结构的存在，上全降解发泡层2-1和下全降解发泡层2-2能提供良好的隔热性和防水防潮性；而纸板基板1本身也具备了较好的强度和抗冲性，与上全降解发泡层2-1、下全降解发泡层2-2相互配合可得到更优秀的抗冲性。从而，上全降解发泡层2-1、下全降解发泡层2-2与纸板基板1配合将使得复合纸板具有更优异的力学性能和隔热、防水特性。
而且，在粘合时所采用的环保淀粉胶因为特殊酯化剂、脲醛胶粘剂的添加，使环保淀粉胶具有良好的防水性；上、下阻隔膜层4-1、4-2的设置有效的防止了水汽的渗入；无机纤维粘合层I3-1和无机纤维粘合层II3-2作为粘合剂，其本身也具有优异的隔热和防水效果。故综合以上各层的性能及其搭配赋予了本复合纸板优异的性能，本复合纸板具有优异的防水性、抗压性及隔热性。
以上所述仅为本发明的优选实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书及附图内容所作的等效结构变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。
Claims (7)
1.一种新型防水抗压隔热复合纸板，由多层材料复合而成，其特征在于，包括上层结构、下层结构及设置在所述上层结构与所述下层结构之间的纸板基板，所述上层结构从上至下依次包括上面纸层、上阻隔膜层和上全降解发泡层，所述下层结构从下至上依次包括下面纸层、下阻隔膜层和下全降解发泡层，所述纸板基板与所述上全降解发泡层、所述下全降解发泡层之间通过环保淀粉胶粘合，所述上全降解发泡层与所述上阻隔膜层之间通过无机纤维粘合层I粘合，所述下全降解发泡层与所述下阻隔膜层之间通过无机纤维粘合层II粘合；
所述上全降解发泡层和所述下全降解发泡层均为以植物纤维、聚乳酸、聚己内酯、脂肪族聚碳酸酯、聚乙烯醇为主料，并加入辅料SiO2气凝胶粉末、聚乳酸-聚己内酯嵌段共聚物、抗氧化剂、加工助剂，以水蒸汽为发泡剂通过原位挤出发泡而成的板材；所述上全降解发泡层和所述下全降解发泡层中各组分的质量比按以下份数复配：植物纤维 40-60份，聚乳酸 30-50份，聚己内酯 15-30份，脂肪族聚碳酸酯 15-30份，聚乙烯醇 8-15份，SiO2气凝胶粉末3-6份，聚乳酸-聚己内酯嵌段共聚物 5-10份，抗氧化剂 2-4份，加工助剂 2-4份；
所述环保淀粉胶为以淀粉、氧化剂高锰酸钾、脱水明矾、轻质氧化镁、酯化剂磷酸钠、接枝共聚试剂脲醛胶粘剂、聚乙烯醇和去离子水为主料，并加入辅料膨胀剂、PH调节剂、淀粉接枝甲基丙烯酸缩水甘油酯，调和后形成的胶粘剂；所述环保淀粉胶的各组分的质量比按以下份数复配：淀粉 320-500份，氧化剂高锰酸钾 2-8份，酯化剂磷酸5-20份，脱水明矾 6-20份，轻质氧化镁 7-15份，接枝共聚剂脲醛胶粘剂 5-15份，聚乙烯醇 2-4份，膨胀剂 2-10份， PH调节剂 15-20份，淀粉接枝甲基丙烯酸缩水甘油酯5-15份，去离子水 1000-1200份。
2.根据权利要求1所述的新型防水抗压隔热复合纸板，其特征在于，所述纸板基板为单层或多层的蜂窝纸板、瓦楞纸板或蜂窝纸板与瓦楞纸板的复合。
3.根据权利要求1或2所述的新型防水抗压隔热复合纸板，其特征在于，所述纸板基板为两层蜂窝纸板夹一层瓦楞纸板的结构，两层所述蜂窝纸板的蜂窝结构完全对应，所述蜂窝纸板与所述瓦楞纸板之间通过所述环保淀粉胶粘合。
4.根据权利要求3所述的新型防水抗压隔热复合纸板，其特征在于，所述蜂窝纸板的蜂窝纸芯的截面形态为菱形、正四边形或正六边形，所述瓦楞纸板的的瓦楞纸芯的截面形态为U型、V型或方型的波浪瓦楞。
5.根据权利要求1所述的新型防水抗压隔热复合纸板，其特征在于，所述上阻隔膜层和所述下阻隔膜层均为多层共挤尼龙膜或多层共挤EVOH膜。
6.根据权利要求5所述的新型防水抗压隔热复合纸板，其特征在于，所述EVOH膜或所述尼龙膜的层数介于3-5层之间。
7.根据权利要求1所述的新型防水抗压隔热复合纸板，其特征在于，所述无机纤维粘合层I和所述无机纤维粘合层II由无机超细纤维棉与水基性粘接剂混合后喷涂而成。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510015797.7A CN104553212B (zh) | 2015-01-13 | 2015-01-13 | 一种防水抗压隔热复合纸板 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510015797.7A CN104553212B (zh) | 2015-01-13 | 2015-01-13 | 一种防水抗压隔热复合纸板 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104553212A true CN104553212A (zh) | 2015-04-29 |
| CN104553212B CN104553212B (zh) | 2017-03-01 |
Family
ID=53070748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510015797.7A Active CN104553212B (zh) | 2015-01-13 | 2015-01-13 | 一种防水抗压隔热复合纸板 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104553212B (zh) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104943306A (zh) * | 2015-06-23 | 2015-09-30 | 湖南工业大学 | 一种高强度多层共挤生物质复合包装膜 |
| CN105415828A (zh) * | 2015-07-17 | 2016-03-23 | 湖南工业大学 | 一种弹性阻隔环保复合膜 |
| CN105415788A (zh) * | 2015-06-23 | 2016-03-23 | 湖南工业大学 | 一种多层复合轻质抗冲板 |
| CN105461967A (zh) * | 2015-06-23 | 2016-04-06 | 湖南工业大学 | 一种轻质淀粉基高韧性复合发泡材料 |
| CN106514800A (zh) * | 2016-11-15 | 2017-03-22 | 王云 | 不含甲醛的阻燃型木屋专用复合板材及其制作方法 |
| CN110527167A (zh) * | 2019-08-12 | 2019-12-03 | 江苏二十六度节能科技有限公司 | 一种生态木塑材料 |
| CN111977187A (zh) * | 2020-08-25 | 2020-11-24 | 亳州学院 | 一种耐火阻热仓储收纳箱 |
| US11401661B2 (en) | 2017-11-14 | 2022-08-02 | J & J Green Paper, Inc. | Recyclable composition for waterproofing paper utilizing a plant derived wax, pellets of the composition, recyclable waterproof paper laminate including the composition, recyclable hot beverage cup including the laminate, pod for making hot beverages including the laminate, and drinking straw including the laminate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08189106A (ja) * | 1994-12-29 | 1996-07-23 | Achilles Corp | 軽量防火断熱材 |
| JP2004231197A (ja) * | 2003-01-28 | 2004-08-19 | Toppan Printing Co Ltd | 発泡紙カップ容器 |
| CN102069610A (zh) * | 2010-10-15 | 2011-05-25 | 曾广胜 | 一种复合包装材料 |
| CN204020088U (zh) * | 2014-04-30 | 2014-12-17 | 湖南工业大学 | 一种缓冲阻燃复合板 |
-
2015
- 2015-01-13 CN CN201510015797.7A patent/CN104553212B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08189106A (ja) * | 1994-12-29 | 1996-07-23 | Achilles Corp | 軽量防火断熱材 |
| JP2004231197A (ja) * | 2003-01-28 | 2004-08-19 | Toppan Printing Co Ltd | 発泡紙カップ容器 |
| CN102069610A (zh) * | 2010-10-15 | 2011-05-25 | 曾广胜 | 一种复合包装材料 |
| CN204020088U (zh) * | 2014-04-30 | 2014-12-17 | 湖南工业大学 | 一种缓冲阻燃复合板 |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105415788B (zh) * | 2015-06-23 | 2017-04-05 | 湖南工业大学 | 一种多层复合轻质抗冲板 |
| CN105461967B (zh) * | 2015-06-23 | 2017-12-08 | 湖南工业大学 | 一种轻质淀粉基高韧性复合发泡材料 |
| CN105415788A (zh) * | 2015-06-23 | 2016-03-23 | 湖南工业大学 | 一种多层复合轻质抗冲板 |
| CN105461967A (zh) * | 2015-06-23 | 2016-04-06 | 湖南工业大学 | 一种轻质淀粉基高韧性复合发泡材料 |
| CN104943306A (zh) * | 2015-06-23 | 2015-09-30 | 湖南工业大学 | 一种高强度多层共挤生物质复合包装膜 |
| CN105415828B (zh) * | 2015-07-17 | 2017-08-08 | 湖南工业大学 | 一种弹性阻隔环保复合膜 |
| CN105415828A (zh) * | 2015-07-17 | 2016-03-23 | 湖南工业大学 | 一种弹性阻隔环保复合膜 |
| CN106514800A (zh) * | 2016-11-15 | 2017-03-22 | 王云 | 不含甲醛的阻燃型木屋专用复合板材及其制作方法 |
| CN106514800B (zh) * | 2016-11-15 | 2019-07-12 | 郑州一安水性高分子材料有限公司 | 不含甲醛的阻燃型木屋专用复合板材及其制作方法 |
| US11401661B2 (en) | 2017-11-14 | 2022-08-02 | J & J Green Paper, Inc. | Recyclable composition for waterproofing paper utilizing a plant derived wax, pellets of the composition, recyclable waterproof paper laminate including the composition, recyclable hot beverage cup including the laminate, pod for making hot beverages including the laminate, and drinking straw including the laminate |
| CN110527167A (zh) * | 2019-08-12 | 2019-12-03 | 江苏二十六度节能科技有限公司 | 一种生态木塑材料 |
| CN111977187A (zh) * | 2020-08-25 | 2020-11-24 | 亳州学院 | 一种耐火阻热仓储收纳箱 |
| CN111977187B (zh) * | 2020-08-25 | 2022-03-01 | 亳州学院 | 一种耐火阻热仓储收纳箱 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104553212B (zh) | 2017-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104553212A (zh) | 一种新型防水抗压隔热复合纸板 | |
| CN108179661B (zh) | 一种高强度防水多层复合瓦楞纸板 | |
| US20170361573A1 (en) | An intermediate laminate product, an expanded laminate structure, and process manufacturing thereof | |
| WO2007091770A1 (en) | Sheet paper for interior use and preparing mehtod thereof | |
| CN104527145B (zh) | 一种高强度高抗压复合纸板 | |
| CN206374313U (zh) | 一种新型高强度防水抗压纸板 | |
| CN106566322B (zh) | 一种可膨胀石墨阻燃纸板的制备方法及应用 | |
| CN103223746A (zh) | 一种环保型聚乳酸/聚己内酯复合阻隔板 | |
| CN105735053A (zh) | 一种节能环保型瓦楞纸板 | |
| CN103252956A (zh) | 一种高缓冲阻隔复合包装纸板 | |
| CN107175846A (zh) | 一种低克重加强型轻量化瓦楞纸箱生产工艺 | |
| CN107825800A (zh) | 一种高弹性保温防潮蜂窝纸板 | |
| CN105015125B (zh) | 一种轻质高强度隔热防潮复合纸板 | |
| CN102733501B (zh) | Stp建筑外墙保温阻燃材料保护膜 | |
| US20060000878A1 (en) | Insulating and light reflective material for packaging applications | |
| CN104553095A (zh) | 一种高缓冲隔热复合纸板 | |
| CN203527983U (zh) | 一种包含废弃发泡塑料的多层结构缓冲包装制品 | |
| CN206357760U (zh) | 环保型瓦楞纸板及瓦楞纸箱 | |
| KR20230141090A (ko) | 친환경 포장재 및 이의 제조방법 | |
| CN104108220A (zh) | 一种环保型瓦楞纸装饰纸板 | |
| CN105922700A (zh) | 一种可降解复合强度板 | |
| CN202669115U (zh) | 重型高强度三瓦楞纸板 | |
| CN206357749U (zh) | 黏贴牢固的纸板箱及其瓦楞纸板 | |
| CN207509927U (zh) | 一种防震抗压复合包装材料 | |
| CN206653697U (zh) | 一种热熔胶竖瓦楞纸板 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |