CN104381334A - Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol - Google Patents

Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol Download PDF

Info

Publication number
CN104381334A
CN104381334A CN201410792831.7A CN201410792831A CN104381334A CN 104381334 A CN104381334 A CN 104381334A CN 201410792831 A CN201410792831 A CN 201410792831A CN 104381334 A CN104381334 A CN 104381334A
Authority
CN
China
Prior art keywords
micro
thymol
avermectin
weight percentage
capsule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410792831.7A
Other languages
Chinese (zh)
Other versions
CN104381334B (en
Inventor
吴淑科
唐睿
任承才
杜荣锴
吴景霄
王昌显
严崇泽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hainan Bowei Biotechnology Co.,Ltd.
Original Assignee
唐睿
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 唐睿 filed Critical 唐睿
Priority to CN201410792831.7A priority Critical patent/CN104381334B/en
Publication of CN104381334A publication Critical patent/CN104381334A/en
Application granted granted Critical
Publication of CN104381334B publication Critical patent/CN104381334B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention relates to micro-capsule suspoemulsion, in particular to a formula and a preparation method of the micro-capsule suspoemulsion containing abamectin, thymol, neem oil and raw pinellia ternate active ingredients. The micro-capsule suspoemulsion comprises components in percentage by weight as follows: 0.5%-3% of the abamectin, 1%-30% of the thymol, 5%-10% of the neem oil, 5%-10% of the raw pinellia ternate active ingredients, 2%-9% of a capsule wall material, 10%-30% of a solvent, 3%-8% of an emulsifier, 2%-5% of a dispersing agent, 0.5%-2% of a wetting agent, 2%-6% of a thickener, 0.15%-0.5% of an antifoaming agent and the balance of water. The abamectin and the thymol have a synergy function, the compound function is obvious, the using amount of pesticides is reduced greatly, an insecticidal spectrum can be enlarged, and the insect killing efficiency can be increased.

Description

Micro-capsule suspension emulsion containing Avermectin and Thymol is filled a prescription and preparation method
Technical field
The present invention relates to a kind of composite micro-capsule suspension emulsion, the formula of the micro-capsule suspension emulsion particularly containing Avermectin, Thymol, indenes chinaberry oil, raw tuber of pinellia active component, and preparation method.
Background technology
Avermectin is a kind of ten hexa-atomic Macrocyclic lactone compounds, belongs to a class antibiotic that is efficient, wide spectrum, has desinsection, kills mite, eelworm-killing activity.It can disturb the neurophysiology of the animals such as worm, mite, nematode movable, discharges γ-aminobutyric acid, suppress its nerve conduction to cause paralysis then stiff, aphagia under stimulation, 2 ~ 4 days can be dead.Avermectin energy broad-spectrum high efficacy ground desinsection, kill mite, kill nematode, also have at plant surface residual few, the features such as little are damaged to beneficial insect, makes it can play in economic crops and field crop and important effect, in the agricultural chemicals insect countermeasure system of China, occupy more important status.But unreasonable and blindness uses Avermectin to cause the animal intraindividual variations such as worm, mite, nematode for a long time, makes it develop immunity to drugs to Avermectin single dose.Along with drug-fast increase, Avermectin single dose also develops into present 8% from initial amount 0.1% in 2000, and dosage also increases increasingly, thus causes the residual problem such as to exceed standard of crop, is unfavorable for environment sustainable development.
Thymol is a separation and Extraction class plant resource active component out from thyme, and can degrade in large natural environment, pleasant aroma, has very strong sterilization and insecticidal action.Its safety is very high, toxicity is also lower, on June 19th, 2013, and EU Committee has ratified Thymol to put on market as plant protection products.Thymol is used for processing wound at present, makes preservative, medical bactericide, stores dissec, pest repellant and spices etc.Zhang Jing, Feng Gang etc. of Geng You Research Institute of Environment and Plant Protection, Chinese Academy of Tropi invent thymol mite-killing microemulsion Thymol research, and its miticidal effect clearly.
The method that solution pesticide resistance is commonly used is undertaken composite by the active ingredient of the different mechanism of action.Provided by the invention a kind ofly have synergistic function containing Avermectin and Thymol in the micro-capsule suspension emulsion of Avermectin and Thymol, and complex role is obvious, greatly reduces the dosage of agricultural chemicals, also can expand insecticidal spectrum, improves insecticide efficiency.The invention provides a kind of micro-capsule suspension emulsion, wherein the effect of micro-capsule is that suppression causes the decomposition of active component because of environmental factor and other factors etc., improves the stability of medicament itself; Controlled release release can extend its lasting period, reduce quantity and the frequency of dispenser, improve the pressure of agricultural chemicals to environment.And about the micro-capsule suspension emulsion of Avermectin and Thymol, there is not yet relevant report at home and abroad at present.
A kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, it all has excellent control efficiency to the harmful mite insect of thin dish, fruit tree, particularly has good control efficiency to two spotted spider mite, blister mite, tarsonemid, thrips, Americal rice leaf miner, M. sojae, aphid, diamond-back moth, imported cabbageworm, prodenia litura etc.
Summary of the invention
The invention provides and a kind of there is low, the effective micro-capsule suspension emulsion containing Avermectin and Thymol of synergistic function, use cost.
A kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, is made up of the component of following weight percent:
Avermectin 0.5 ~ 8%,
Thymol 1% ~ 30%,
Indenes chinaberry oil 2% ~ 19%,
Raw tuber of pinellia active component 1% ~ 20%,
Cyst material 1 ~ 15%,
Solvent 5% ~ 40%,
Emulsifier 1% ~ 8%,
Dispersant 0.5% ~ 5%,
Wetting agent 0.1% ~ 5%
Thickener 0.5% ~ 6%,
Defoamer 0.1% ~ 0.5%,
Surplus is water.
Described cyst material is that one or more in Lauxite, polyisocyanates, gelatin, modified starch, gum Arabic or melamine resin mix arbitrarily.Solvent is that one or more in toluene, acetone, isopropyl alcohol, chloroform, ethanol, methyl alcohol, cyclohexane mix arbitrarily.Emulsifier is anhydrous sorbitol laurate, one or more in Tripolyglycerol monostearates, polyoxyethylene monopalmitate, polyoxyethylene laurel ether, polyoxypropylene wool alcohol ether, polyoxyl 40 stearate mix arbitrarily.Dispersant is sodium lignin sulfonate, one or more in calcium lignosulfonate, alkylphenol-polyethenoxy base phosphate, sodium phosphate trimer mix arbitrarily.Wetting agent is that one or more in lauryl sodium sulfate, DBSA, nekal, dioctyl sodium sulfosuccinate mix arbitrarily.Thickener is that one or more in starch, pectin, agar, gelatin, methylcellulose, Sodium Polyacrylate, white carbon, Silica hydrogel, carbomer, CMC, polyvinylether mix arbitrarily.Defoamer is that one or more in mineral oil, vegetable oil, polyoxyethylene nonylphenol ether, higher alcohols mix arbitrarily.Water is the one in running water, distilled water or deionized water.The weight percentage of described Thymol is preferably 10 ~ 20%.Described cyst material is Lauxite.Described solvent is preferably the one in ethanol or methyl alcohol.Described emulsifier is preferably Tripolyglycerol monostearates.Described dispersant is preferably sodium lignin sulfonate.Described wetting agent is preferably DBSA.Described thickener is preferably polyvinylether.Described defoamer is preferably mineral oil.The weight percentage of described Avermectin is preferably 1% ~ 3%.The weight percentage of described Thymol is preferably 10% ~ 20%.The weight percentage of described indenes chinaberry oil is preferably 5% ~ 9%.The weight percentage of described raw tuber of pinellia active component is preferably 5% ~ 10%.The weight percentage of described cyst material is preferably 2 ~ 6%.The weight percentage of described solvent is preferably 10% ~ 30%.The weight percentage of described emulsifier is preferably 3% ~ 6%.The weight percentage of described dispersant is preferably 1% ~ 3%.The weight percentage of described wetting agent is preferably 0.5% ~ 2%.The weight percentage of described thickener is preferably 1% ~ 3%.The weight percentage of described defoamer is preferably 0.15% ~ 0.25%.
The invention provides a kind of micro-capsule suspension emulsion containing Avermectin and Thymol, wherein in formula, the extracting method of raw tuber of pinellia active component first the life tuber of pinellia is cleaned oven dry to pulverize 100 mesh sieves and obtain giving birth to Pinellia Tuber, add ammoniacal liquor, after stirring, add a certain amount of chloroform, after cold soaking 3h, ultrasonic extraction 1h under ice bath, filter, at 80 DEG C, reclaim chloroform evaporate to dryness gains is exactly raw tuber of pinellia active component.
A kind of preparation method containing the micro-capsule suspension emulsion of Avermectin and Thymol provided by the present invention, that Avermectin and raw tuber of pinellia active component are added in solvent, cyst material is added under insulated and stirred, the spraying dry that sieves obtains micro-capsule, in micro-capsule, add dispersant, wetting agent and water make avermectin microcapsule suspending agent, take out for subsequent use, fixing tentatively is I.Emulsifier, thickener, defoamer be added to the water and stir to dissolving completely, take out for subsequent use, fixing tentatively is II.Thymol, indenes chinaberry oil add in solvent and stir to dissolving completely, and take out for subsequent use, fixing tentatively is III. and add III in II, high speed shear, then add I, mix and obtain the micro-capsule suspension emulsion of Avermectin and Thymol.
The invention provides a kind of micro-capsule suspension emulsion, wherein the effect of micro-capsule is that suppression causes the decomposition of active component because of environmental factor and other factors etc., improves the stability of medicament itself; Controlled release release can extend its lasting period, reduce quantity and the frequency of dispenser, improve the pressure of agricultural chemicals to environment.
Embodiment
Embodiment one: the extraction of raw tuber of pinellia active component is cleaned by raw for the 10kg tuber of pinellia to dry in an oven, in disintegrating machine, 100 mesh sieves are crossed in fragmentation, the ammoniacal liquor of 12% is added in the raw Pinellia Tuber stirring of gained, treat its moistening chloroform evenly adding 180L again, soak 3h at 4 DEG C, under ice bath, have ultrasonic extraction 1h, filter, 80 DEG C are reclaimed chloroform evaporate to dryness, and gains are exactly raw tuber of pinellia active component.
Embodiment two: a kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, is made up of the component of following weight percent:
Avermectin 2%,
Thymol 10%,
Indenes chinaberry oil 6%,
Raw tuber of pinellia active component 6%,
Cyst material 3%,
Solvent 18%,
Emulsifier 5%,
Dispersant 2%,
Wetting agent 1%,
Thickener 2%,
Defoamer 0.2%,
Surplus is water.
0.2kg Avermectin and the raw tuber of pinellia active component of 0.6kg are added in 1L ethanol, 0.3kg Lauxite is added under insulated and stirred, the spraying dry that sieves obtains micro-capsule, in micro-capsule, add 0.2kg sodium lignin sulfonate, 0.1kg DBSA and enough water stirs to dissolving obtained avermectin microcapsule suspending agent completely, take out for subsequent use, fixing tentatively is I.0.2kg Tripolyglycerol monostearates, 0.2kg polyvinylether, 0.02kg mineral oil, be added to the water and stir to dissolving completely, takes out for subsequent use, and fixing tentatively is II.Add 1kg Thymol, 0.6kg indenes chinaberry oil adds 0.8L ethanol and stir to dissolving completely, take out for subsequent use, fixing tentatively is III. add III in II, use high-speed shearing Mixer high speed shear, add I again, namely shear-mixed evenly obtains the micro-capsule suspension emulsion of Avermectin and Thymol.
Embodiment three: a kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, is made up of the component of following weight percent:
Avermectin 2%,
Thymol 15%,
Indenes chinaberry oil 6%,
Raw tuber of pinellia active component 6%,
Cyst material 3%,
Solvent 20%,
Emulsifier 7%,
Dispersant 3%,
Wetting agent 1.5%,
Thickener 3%,
Defoamer 0.4%,
Surplus is water.
0.2kg Avermectin and the raw tuber of pinellia active component of 0.6kg are added in 1L ethanol, 0.3kg Lauxite is added under insulated and stirred, the spraying dry that sieves obtains micro-capsule, in micro-capsule, add 0.3kg sodium lignin sulfonate, 0.15kg DBSA and enough water stirs to dissolving obtained avermectin microcapsule suspending agent completely, take out for subsequent use, fixing tentatively is I.0.7kg Tripolyglycerol monostearates, 0.2kg polyvinylether, 0.04kg mineral oil, be added to the water and stir to dissolving completely, takes out for subsequent use, and fixing tentatively is II.Add 1.5kg Thymol, the stirring of 0.6kg indenes chinaberry oil adds 1L ethanol evenly to dissolving completely, take out for subsequent use, fixing tentatively is III. add III in II, use high-speed shearing Mixer high speed shear, add I again, namely shear-mixed evenly obtains the micro-capsule suspension emulsion of Avermectin and Thymol.
Embodiment four: a kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, is made up of the component of following weight percent:
Avermectin 2%,
Thymol 20%,
Indenes chinaberry oil 6%,
Raw tuber of pinellia active component 6%,
Cyst material 3%,
Solvent 25%,
Emulsifier 8%,
Dispersant 5%,
Wetting agent 2.5%,
Thickener 3%,
Defoamer 0.4%,
Surplus is water.
0.2kg Avermectin and the raw tuber of pinellia active component of 0.6kg are added in 1L ethanol, 0.3kg Lauxite is added under insulated and stirred, the spraying dry that sieves obtains micro-capsule, in micro-capsule, add 0.5kg sodium lignin sulfonate, 0.25kg DBSA and enough water stirs to dissolving obtained avermectin microcapsule suspending agent completely, take out for subsequent use, fixing tentatively is I.0.8kg Tripolyglycerol monostearates, 0.3kg polyvinylether, 0.04kg mineral oil, be added to the water and stir to dissolving completely, takes out for subsequent use, and fixing tentatively is II.Add 2kg Thymol, 0.6kg indenes chinaberry oil adds 1.5L ethanol and stir to dissolving completely, take out for subsequent use, fixing tentatively is III. add III in II, use high-speed shearing Mixer high speed shear, add I again, namely shear-mixed evenly obtains the micro-capsule suspension emulsion of Avermectin and Thymol.
Get the micro-capsule suspension emulsion that above embodiment joins and do following indoor pharmacodynamic test and field trial, wherein the micro-capsule suspension emulsion of 2% Avermectin that is made into of embodiment two and 10% Thymol is A, the micro-capsule suspension emulsion of 2% Avermectin that embodiment three is made into and 15% Thymol is B, and the micro-capsule suspension emulsion of 2% Avermectin that embodiment four is made into and 20% Thymol is C.
Embodiment five: the micro-capsule suspension emulsion of the Avermectin be made in embodiment two, three, four and Thymol is done indoor pharmacodynamic test to two spotted spider mite, contrasts with 2% abamectin emulsifiable concentrate.Result of the test is in table one.
Table one:
A, B, C of the present invention tri-kinds of Avermectin are more much better than the effect of 2% abamectin emulsifiable concentrate with the insecticidal effect of the micro-capsule suspension emulsion of Thymol as can be known from the above table, especially C best results, and C is the micro-capsule suspension emulsion of 2% Avermectin and 20% Thymol.
Embodiment six: the micro-capsule suspension emulsion of the Avermectin be made in embodiment two, three, four and Thymol is carried out field trial.2% abamectin emulsifiable concentrate contrasts.Experiment place: Sanya, Hainan, object of experiment: tomato two spotted spider mite, result of the test is in table two:
From upper table, the micro-capsule suspension emulsion of known Avermectin of the present invention and Thymol is given prominence to banana prodenia litura preventive effect, and the lasting period can reach more than 14 days, and the effect of C is the most outstanding, and C is the micro-capsule suspension emulsion of 2% Avermectin and 20% Thymol.

Claims (4)

1. a kind of micro-capsule suspension emulsion containing Avermectin and Thymol provided by the present invention, is made up of the component of following weight percent:
Avermectin 0.5 ~ 8%,
Thymol 1% ~ 30%,
Indenes chinaberry oil 2% ~ 19%,
Raw tuber of pinellia active component 1% ~ 20%,
Cyst material 1 ~ 15%,
Solvent 5% ~ 40%,
Emulsifier 1% ~ 8%,
Dispersant 0.5% ~ 5%,
Wetting agent 0.1% ~ 5%
Thickener 0.5% ~ 6%,
Defoamer 0.1% ~ 0.5%,
Surplus is water,
It is characterized in that described cyst material is that one or more in Lauxite, polyisocyanates, gelatin, modified starch, gum Arabic or melamine resin mix arbitrarily; Described cyst material is preferably Lauxite; Solvent is that one or more in toluene, acetone, isopropyl alcohol, chloroform, ethanol, methyl alcohol, cyclohexane mix arbitrarily; Described solvent is preferably the one in ethanol or methyl alcohol; Emulsifier is anhydrous sorbitol laurate, one or more in Tripolyglycerol monostearates, polyoxyethylene monopalmitate, polyoxyethylene laurel ether, polyoxypropylene wool alcohol ether, polyoxyl 40 stearate mix arbitrarily; Described emulsifier is preferably Tripolyglycerol monostearates; Dispersant is sodium lignin sulfonate, one or more in calcium lignosulfonate, alkylphenol-polyethenoxy base phosphate, sodium phosphate trimer mix arbitrarily; Described dispersant is preferably sodium lignin sulfonate; Wetting agent is that one or more in lauryl sodium sulfate, DBSA, nekal, dioctyl sodium sulfosuccinate mix arbitrarily; Described wetting agent is preferably DBSA; Thickener is that one or more in starch, pectin, agar, gelatin, methylcellulose, Sodium Polyacrylate, white carbon, Silica hydrogel, carbomer, CMC, polyvinylether mix arbitrarily; Described thickener is preferably polyvinylether; Defoamer is that one or more in mineral oil, vegetable oil, polyoxyethylene nonylphenol ether, higher alcohols mix arbitrarily; Described defoamer is preferably mineral oil; Water is the one in running water, distilled water or deionized water; The weight percentage of described Avermectin is preferably 1% ~ 3%; The weight percentage of described Thymol is preferably 10% ~ 20%; The weight percentage of described indenes chinaberry oil is preferably 5% ~ 9%; The weight percentage of described raw tuber of pinellia active component is preferably 5% ~ 10%; The weight percentage of described cyst material is preferably 2 ~ 6%; The weight percentage of described solvent is preferably 10% ~ 30%; The weight percentage of described emulsifier is preferably 3% ~ 6%; The weight percentage of described dispersant is preferably 1% ~ 3%; The weight percentage of described wetting agent is preferably 0.5% ~ 2%; The weight percentage of described thickener is preferably 1% ~ 3%; The weight percentage of described defoamer is preferably 0.15% ~ 0.25%.
2. according to a kind of micro-capsule suspension emulsion containing Avermectin and Thymol described in claim 1, it is characterized in that the extracting method of described raw tuber of pinellia active component first the life tuber of pinellia is cleaned oven dry to pulverize 100 mesh sieves and obtain raw Pinellia Tuber, add 12% ammoniacal liquor, after stirring, add the chloroform of 18 times of volumes, after cold soaking 3h, ultrasonic extraction 1h under ice bath, filter, at 80 DEG C, reclaim chloroform evaporate to dryness gains is exactly raw tuber of pinellia active component.
3. according to a kind of micro-capsule suspension emulsion containing Avermectin and Thymol described in claim 1, it is characterized in that the preparation method of described micro-capsule suspension emulsion, that Avermectin and raw tuber of pinellia active component are added in solvent, cyst material is added under insulated and stirred, the spraying dry that sieves obtains micro-capsule, in micro-capsule, add dispersant, wetting agent and water make avermectin microcapsule suspending agent, take out for subsequent use, fixing tentatively is I; Emulsifier, thickener, defoamer be added to the water and stir to dissolving completely, take out for subsequent use, fixing tentatively is II; Thymol, indenes chinaberry oil add in solvent and stir to dissolving completely, and take out for subsequent use, fixing tentatively is III; Add III in II, high speed shear, then add I, mix and obtain the micro-capsule suspension emulsion of Avermectin and Thymol.
4., according to a kind of micro-capsule suspension emulsion containing Avermectin and Thymol described in claim 1, it is characterized in that described micro-capsule suspension emulsion has good control efficiency to two spotted spider mite, blister mite, tarsonemid, thrips, Americal rice leaf miner, M. sojae, aphid, diamond-back moth, imported cabbageworm, prodenia litura etc.
CN201410792831.7A 2014-12-20 2014-12-20 Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol Active CN104381334B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410792831.7A CN104381334B (en) 2014-12-20 2014-12-20 Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410792831.7A CN104381334B (en) 2014-12-20 2014-12-20 Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol

Publications (2)

Publication Number Publication Date
CN104381334A true CN104381334A (en) 2015-03-04
CN104381334B CN104381334B (en) 2017-02-22

Family

ID=52599384

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410792831.7A Active CN104381334B (en) 2014-12-20 2014-12-20 Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol

Country Status (1)

Country Link
CN (1) CN104381334B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105123699A (en) * 2015-10-22 2015-12-09 唐睿 Miticide and insecticide composite containing thymol and pyriproxyfen
CN105638648A (en) * 2016-01-08 2016-06-08 广州市生物防治站 Thymol-emamectin benzoate emulsion in water
CN106035239A (en) * 2016-05-30 2016-10-26 中国农业大学 Method for studying influences exerted by approach-avoidance substances on oviposition behaviors of diamondback moths
PL422293A1 (en) * 2017-07-21 2019-01-28 Instytut Inżynierii Materiałów Polimerowych I Barwników Method for producing biodegradable carrier with insecticidal properties against Alphitobius diaperinus Panzer
CN109833296A (en) * 2019-03-28 2019-06-04 佛山市正典生物技术有限公司 Can the new merit chigger disease of prevention and control plants essential oil microemulsion formulation and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1676001A (en) * 2005-05-10 2005-10-05 龚鸿昌 Nim oil-water emulsion and its use
CN102224830A (en) * 2011-05-30 2011-10-26 杨凌农科大无公害农药研究服务中心 Plant source synergistic complex acaricide and preparation method thereof
CN103563892A (en) * 2013-10-14 2014-02-12 广东中迅农科股份有限公司 Novel water-based preparation formulation of methylamino abamectin benzoate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1676001A (en) * 2005-05-10 2005-10-05 龚鸿昌 Nim oil-water emulsion and its use
CN102224830A (en) * 2011-05-30 2011-10-26 杨凌农科大无公害农药研究服务中心 Plant source synergistic complex acaricide and preparation method thereof
CN103563892A (en) * 2013-10-14 2014-02-12 广东中迅农科股份有限公司 Novel water-based preparation formulation of methylamino abamectin benzoate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国土农药志编辑委员会: "《中国土农药志》", 31 May 1959, 科学出版社 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105123699A (en) * 2015-10-22 2015-12-09 唐睿 Miticide and insecticide composite containing thymol and pyriproxyfen
CN105123699B (en) * 2015-10-22 2017-03-29 海南博士威农用化学有限公司 A kind of insecticide and acaricide containing thymol and Nylar
CN105638648A (en) * 2016-01-08 2016-06-08 广州市生物防治站 Thymol-emamectin benzoate emulsion in water
CN105638648B (en) * 2016-01-08 2018-05-18 广州市生物防治站 A kind of Thymol-emamectin-benzoate aqueous emulsion
CN106035239A (en) * 2016-05-30 2016-10-26 中国农业大学 Method for studying influences exerted by approach-avoidance substances on oviposition behaviors of diamondback moths
CN106035239B (en) * 2016-05-30 2018-11-09 中国农业大学 A method of research walks quickly and keeps away substance to Oviposition of Diamondback Moth behavioral implications
PL422293A1 (en) * 2017-07-21 2019-01-28 Instytut Inżynierii Materiałów Polimerowych I Barwników Method for producing biodegradable carrier with insecticidal properties against Alphitobius diaperinus Panzer
CN109833296A (en) * 2019-03-28 2019-06-04 佛山市正典生物技术有限公司 Can the new merit chigger disease of prevention and control plants essential oil microemulsion formulation and preparation method thereof

Also Published As

Publication number Publication date
CN104381334B (en) 2017-02-22

Similar Documents

Publication Publication Date Title
CN104381334A (en) Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol
CN103444771A (en) Formula of pesticide formula for preventing and treating sugarcane moth borer and production method of pesticide
CN104351189B (en) Binary pesticide composition and uses thereof
CN104082300B (en) Insecticide acaricide composition containing pyriproxyfen and spirodiclofen
CN102599167A (en) Chlorantraniliprole and Spinetoram compound suspending agent and preparation method thereof
CN103355326A (en) High-efficiency pesticide composition
CN102415401A (en) Synergistic insecticidal composition containing dinotefuran and acetamiprid and application thereof
CN102669126A (en) Composite containing methoxyfenozide and botanical pesticide
CN103651503A (en) Pesticidal composition containing fluorine furan pyrazole ketone
CN102165958B (en) Pesticide composite containing bifenazate and triazophos
CN105613511B (en) A kind of agricultural pesticide composition and application thereof
CN104206405A (en) Pesticide and method for preventing and controlling evergestis extimalis scopoli
CN101971858B (en) Pesticide composition containing bifenazate and fenpropathrin
CN103651403A (en) Efficient insecticidal composition containing spiromesifen
CN102365961B (en) Insecticidal composition
CN104585178A (en) Synergetic acaricidal composition containing cyenopyrafen and spirodiclofen
CN102550573A (en) Chlorantraniliprole and rotenone compound suspending agent and its preparation method
CN103053604A (en) Synergistic insecticidal composition containing flonicamid and silafluofen and application thereof
CN103749529B (en) A kind of insecticidal and bactericidal composition
CN103053585A (en) Synergistic insecticidal composition containing dinotefuran and clothianidin, and application thereof
CN105475339A (en) Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof
CN105557760A (en) Synergistic insecticidal composition containing propargite and tetranactin, and application thereof
CN104542606A (en) Synergetic acaricidal composition containing cyenopyrafen and cyflumetofen
CN103828823A (en) Pesticide composition
CN104273139A (en) Mite-killing composition containing fenpyroximate and ivermectin

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20161019

Address after: 571924 the development of Hainan County of Chengmai Province City District Industrial Avenue Meilanglu east of Hainan boshiway Agricultural Chemical Co Ltd

Applicant after: Boshiwei Agricultural Chemical Co., Ltd., Hainan Province

Address before: 571924 Hainan province Chengmai County Old Town Economic Development Zone Industrial Avenue Meilanglu east of Hainan boshiway Agricultural Chemical Co Ltd

Applicant before: Tang Rui

C14 Grant of patent or utility model
GR01 Patent grant
CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 570100 east of meilang Road, Industrial Avenue, Laocheng Development Zone, Chengmai County, Hainan Province

Patentee after: Hainan Bowei Biotechnology Co.,Ltd.

Address before: 571924 county level administrative unit directly under the central government of Hainan Province Hainan boshwei agrochemical Co., Ltd., east of meilang Road, Industrial Avenue, Laocheng Development Zone, Chengmai County, Hainan Province

Patentee before: HAINAN BOSSWELL AGRICHEMICAL CO.,LTD.