CN105638648B - A kind of Thymol-emamectin-benzoate aqueous emulsion - Google Patents
A kind of Thymol-emamectin-benzoate aqueous emulsion Download PDFInfo
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- CN105638648B CN105638648B CN201610010530.3A CN201610010530A CN105638648B CN 105638648 B CN105638648 B CN 105638648B CN 201610010530 A CN201610010530 A CN 201610010530A CN 105638648 B CN105638648 B CN 105638648B
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- CN
- China
- Prior art keywords
- thymol
- emamectin
- benzoate
- aqueous emulsion
- water
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Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 42
- MGSRCZKZVOBKFT-UHFFFAOYSA-N Thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000005844 Thymol Substances 0.000 claims abstract description 44
- 229960000790 thymol Drugs 0.000 claims abstract description 44
- 229930007823 thymol Natural products 0.000 claims abstract description 44
- CXEGAUYXQAKHKJ-FYOMLGFFSA-N Emamectin Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@H](C)[C@@H](NC)[C@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-FYOMLGFFSA-N 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 22
- 239000003995 emulsifying agent Substances 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 20
- 239000002562 thickening agent Substances 0.000 claims description 20
- 230000002528 anti-freeze Effects 0.000 claims description 16
- 229940051841 POLYOXYETHYLENE ETHER Drugs 0.000 claims description 15
- 239000002518 antifoaming agent Substances 0.000 claims description 15
- 235000019441 ethanol Nutrition 0.000 claims description 15
- -1 polyoxyethylene Polymers 0.000 claims description 15
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 15
- 229920001661 Chitosan Polymers 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 230000002265 prevention Effects 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 4
- GHNRTXCRBJQVGN-UHFFFAOYSA-N 4-dodecan-6-ylbenzenesulfonic acid Chemical group CCCCCCC(CCCCC)C1=CC=C(S(O)(=O)=O)C=C1 GHNRTXCRBJQVGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005660 Abamectin Substances 0.000 claims description 3
- 241000238876 Acari Species 0.000 claims description 3
- 229920001817 Agar Polymers 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229940068918 Polyethylene Glycol 400 Drugs 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- JNYAEWCLZODPBN-CTQIIAAMSA-N Sorbitan Chemical compound OCC(O)C1OCC(O)[C@@H]1O JNYAEWCLZODPBN-CTQIIAAMSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000008272 agar Substances 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-M benzoate Chemical compound [O-]C(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-M 0.000 claims description 3
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2R)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
- 239000001814 pectin Substances 0.000 claims description 3
- 235000010987 pectin Nutrition 0.000 claims description 3
- 229920001277 pectin Polymers 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 2
- 238000001802 infusion Methods 0.000 claims description 2
- 229950008167 Abamectin Drugs 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 12
- 241000607479 Yersinia pestis Species 0.000 abstract description 8
- 201000010099 disease Diseases 0.000 abstract description 7
- 230000000749 insecticidal Effects 0.000 abstract description 6
- 238000001228 spectrum Methods 0.000 abstract description 4
- 230000002195 synergetic Effects 0.000 abstract description 4
- 241001124076 Aphididae Species 0.000 abstract description 3
- 241000255967 Helicoverpa zea Species 0.000 abstract description 3
- 241000255969 Pieris brassicae Species 0.000 abstract description 3
- 241000500437 Plutella xylostella Species 0.000 abstract description 3
- 241000256247 Spodoptera exigua Species 0.000 abstract description 3
- 241000255901 Tortricidae Species 0.000 abstract description 3
- 230000003449 preventive Effects 0.000 abstract description 2
- 230000001225 therapeutic Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 15
- 239000003814 drug Substances 0.000 description 14
- 231100000419 toxicity Toxicity 0.000 description 11
- 230000001988 toxicity Effects 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 210000000481 Breast Anatomy 0.000 description 3
- 241000488581 Panonychus citri Species 0.000 description 3
- 229940079593 drugs Drugs 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZWRUINPWMLAQRD-UHFFFAOYSA-N 1-Nonanol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- 210000002383 AT1 Anatomy 0.000 description 2
- 241000223602 Alternaria alternata Species 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N Dodecanol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 241000258937 Hemiptera Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 241000227653 Lycopersicon Species 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 241000233616 Phytophthora capsici Species 0.000 description 2
- 241000220324 Pyrus Species 0.000 description 2
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 2
- 240000008529 Triticum aestivum Species 0.000 description 2
- 229940057402 UNDECYL ALCOHOL Drugs 0.000 description 2
- KJIOQYGWTQBHNH-UHFFFAOYSA-N Undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 2
- 230000000895 acaricidal Effects 0.000 description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 2
- 230000008506 pathogenesis Effects 0.000 description 2
- 235000021017 pears Nutrition 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 230000004083 survival Effects 0.000 description 2
- 230000017613 viral reproduction Effects 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 235000021307 wheat Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 229940064005 Antibiotic throat preparations Drugs 0.000 description 1
- 229940083879 Antibiotics FOR TREATMENT OF HEMORRHOIDS AND ANAL FISSURES FOR TOPICAL USE Drugs 0.000 description 1
- 229940042052 Antibiotics for systemic use Drugs 0.000 description 1
- 229940042786 Antitubercular Antibiotics Drugs 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229940093922 Gynecological Antibiotics Drugs 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- GCKZANITAMOIAR-WNXAHBPRSA-N Methylamino abamectin benzoate Chemical compound OC(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@@H](NC)[C@H](OC)C3)[C@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-WNXAHBPRSA-N 0.000 description 1
- 210000004080 Milk Anatomy 0.000 description 1
- 231100000614 Poison Toxicity 0.000 description 1
- 210000002784 Stomach Anatomy 0.000 description 1
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 1
- 241000344252 Tetranychus piercei Species 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
- 241000488533 Tetranychus viennensis Species 0.000 description 1
- 229940024982 Topical Antifungal Antibiotics Drugs 0.000 description 1
- 229940099259 Vaseline Drugs 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000003042 antagnostic Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial Effects 0.000 description 1
- 230000003078 antioxidant Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003115 biocidal Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000002224 dissection Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229940079866 intestinal antibiotics Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 229940005935 ophthalmologic Antibiotics Drugs 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000000607 poisoning Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 230000001954 sterilising Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention discloses a kind of Thymol emamectin-benzoate aqueous emulsions.The aqueous emulsion contains Thymol and emamectin-benzoate, and weight ratio is (100:1)~(1:2).The aqueous emulsion of Thymol emamectin-benzoate provided by the invention has synergistic function, reduces dosage, can also expand insecticidal spectrum, improves Insecticiding-miticiding efficiency.It has excellent control effect to evil mite pest agriculturally, particularly has good control effect to mite class, diamondback moth, beet armyworm, bollworm, leaf roller, cabbage butterfly, aphid etc., while has preferable preventive and therapeutic effect to various diseases.
Description
Technical field
The invention belongs to the technical fields of agriculture chemical compounding, and in particular to a kind of Thymol-emamectin benzoate benzene first
Hydrochlorate aqueous emulsion.
Background technology
Thymol also known as thymol are slightly soluble in water, molecular formula C10H14O, chemical name are 2- isopropyls -5-
Methylphenol, structural formula are：
It is white crystal or semi-transparent clear crystal under Thymol room temperature, fusing point：51.5 DEG C, boiling point：233-235 DEG C,
Ethyl alcohol, ether, acetic acid, chloroform and benzene are highly soluble in, has certain fragrance and with very strong bactericidal effect.Thymol is except use
Make fragrance, outside food additives, Medicines are also used as, for sterilizing oral, it is also possible to handle wound, storage dissection
Sample is alternatively arranged as pest repellant and antioxidant.On June 19th, 2013, EU Committee's approval was protected Thymol as plant
Protect launch products.Thymol is withered to graw mold of tomato, cotton seedling blight, Alternaria alternate, rice blast, wheat line
The germ of the multiple diseases such as disease, Phytophthora capsici disease is inhibited, while also has acaricidal action.Thymol is easy to obtain
, chemical property is stablized, and toxicity is low, degradable in the environment, but also fewer in application agriculturally at present.
Emamectin benzoate, full name are emamectin-benzoate, are synthesized since fermented product AVERMECTIN B1
A kind of new and effective semisynthetic antibiotics insecticide, it has ultra high efficiency, low toxicity（Preparation is closely nontoxic）, low-residual, nuisanceless etc.
The characteristics of biological pesticide；It is widely used in the prevention of the various pests on the crops such as vegetables, fruits and vegetables；With efficient, wide spectrum, peace
Entirely, the characteristics of longevity of residure is long is excellent insecticidal/acaricidal agent, has stomach toxicity, action of contace poison.To mite class, Lepidoptera, coleoptera and
Homoptera pest has high activity, and is not easy that pest is made to develop immunity to drugs, and to safety of human and livestock, does not have poisoning to crop.This
Outside, emamectin benzoate is high to fish, honeybee toxicity, and at water source etc., places use is subject to certain restrictions.Due to emamectin benzoate benzene
Formates generates the different degrees of resistance to the action of a drug in various regions at present in China's large area using for many years, affects control of insect effect
Fruit.
The content of the invention
It is an object of the invention to provide a kind of Thymol-emamectin-benzoate aqueous emulsion and its preparations
Method.
The technical solution used in the present invention is：
A kind of Thymol-emamectin-benzoate aqueous emulsion, contains Thymol and methylamino Avermectin
Plain benzoate, weight ratio are (100:1)~(1:2).
Preferably, the weight ratio of Thymol and emamectin-benzoate is (20:1)~(1:1).
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-50%, emamectin-benzoate 0.01%-30%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-10%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water；
The solvent is at least one of ethyl alcohol, acetone, cyclohexanone, hexamethylene, acetic acid；
The emulsifier is alkylbenzenesulfonate, aliphatic alcohol polyethenoxy base ether, phenol derivatives polyoxyethylene ether, polyoxy
Ethylene fatty acid esters of sorbitan, alkylphenol polyoxyethylene ether, styrylphenol polyoxyethylene ether, polyoxyethylene sorbitan mountain
At least one of pears alcohol fatty acid ester, castor oil polyoxyethylene ether；
The thickener is at least one of pectin, chitosan, agar, gelatin, xanthans；
The dispersant is sodium lignin sulfonate, calcium lignosulfonate, alkylphenol-polyethenoxy base phosphate, polycarboxylic acids
At least one of salt, sodium tripolyphosphate, lauryl sodium sulfate；
The antifreeze is at least one of ethylene glycol, propylene glycol, glycerine, urea and polyethylene glycol 400；
The antifoaming agent is at least one of organic silicon defoamer, polyoxyethylene polyoxypropylene glycerine, alcohols；Alcohols bag
Containing enanthol, octanol, isooctanol, nonyl alcohol, undecyl alcohol, lauryl alcohol.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-20%, emamectin-benzoate 0.1%-5%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-10%, emamectin-benzoate 0.1%-3%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1.0%-6.0%, emamectin-benzoate 0.4%-1%, solvent 5%-15%, emulsifier
6%-9%, thickener 3%-5%, dispersant 0.5%-3.0%, surplus are water, while Thymol and emamectin benzoate benzoic acid
The weight ratio of salt is 20:1~1:1；
The solvent is acetic acid, one kind in ethyl alcohol；
The emulsifier is styrylphenol polyoxyethylene ether or polyoxyethylene sorbitan fatty acid ester；
The thickener is chitosan；
The dispersant is polycarboxylate.
A kind of preparation method of Thymol-emamectin-benzoate aqueous emulsion, comprises the following steps：According to
Proportioning described in any of the above item weighs each component, and Thymol and emamectin-benzoate are dissolved in solvent,
Emulsifier, dispersant are added in, is uniformly mixed and obtains oil phase；Thickener, antifreeze, antifoaming agent are added to the water, are uniformly mixed
To water phase；Under high speed shear, oil phase is mixed with water conjunction, aqueous emulsion is made.
Thymol-emamectin-benzoate aqueous emulsion described in any of the above item is in Agricultural Mites prevention
Application.
The beneficial effects of the invention are as follows：
The present invention provides a kind of water and milk of Thymol-emamectin-benzoate（Compounding）Agent has collaboration
Synergistic effect reduces dosage, can also expand insecticidal spectrum, improves Insecticiding-miticiding efficiency.It has evil mite pest agriculturally
Excellent control effect particularly has mite class, diamondback moth, beet armyworm, bollworm, leaf roller, cabbage butterfly, aphid etc. very well
Control effect, while to various diseases have preferable preventive and therapeutic effect.
The present composition is compound insecticidal miticide composition, and Insecticiding-miticiding effect is significantly enhanced compared with single product
Fruit delays the generation of pest resistance to insecticide, especially there is special efficacy to evil mite, and expands effective active prevention spectrum, substantially reduces pesticide
Dosage.Thymol and emamectin-benzoate are respectively provided with the biological pesticides such as low toxicity, low-residual, environmental-friendly
Characteristic, and the preparation developed of the present invention saves substantial amounts of organic solvent, Environmental compatibility is good, applies using water as main matrix
With rear noresidue, meet current environmentally protective trend.
Thymol-emamectin-benzoate aqueous emulsion of the present invention, for preventing mite class, Lepidoptera, sheath
Wing mesh and homoptera pest, such as mite class, diamondback moth, beet armyworm, bollworm, leaf roller, cabbage butterfly, aphid；It is especially suitable
In prevention mite class, such as Tetranychus piercei, tarsonemid, panonychus citri, Tetranychus cinnabarinus, T.urticae Koch, tetranychus viennensis.It can also be used to prevent
Control the multiple diseases such as graw mold of tomato, cotton seedling blight, Alternaria alternate, rice blast, wheat sharp eyespot, Phytophthora capsici disease.
Specific embodiment
A kind of Thymol-emamectin-benzoate aqueous emulsion, contains Thymol and methylamino Avermectin
Plain benzoate, weight ratio are (100:1)~(1:2).
Preferably, the weight ratio of Thymol and emamectin-benzoate is (20:1)~(1:1).
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-50%, emamectin-benzoate 0.01%-30%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-10%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water；
The solvent is at least one of ethyl alcohol, acetone, cyclohexanone, hexamethylene, acetic acid；
The emulsifier is alkylbenzenesulfonate, aliphatic alcohol polyethenoxy base ether, phenol derivatives polyoxyethylene ether, polyoxy
Ethylene fatty acid esters of sorbitan, alkylphenol polyoxyethylene ether, styrylphenol polyoxyethylene ether, polyoxyethylene sorbitan mountain
At least one of pears alcohol fatty acid ester, castor oil polyoxyethylene ether；
The thickener is at least one of pectin, chitosan, agar, gelatin, xanthans；
The dispersant is sodium lignin sulfonate, calcium lignosulfonate, alkylphenol-polyethenoxy base phosphate, polycarboxylic acids
At least one of salt, sodium tripolyphosphate, lauryl sodium sulfate；
The antifreeze is at least one of ethylene glycol, propylene glycol, glycerine, urea and polyethylene glycol 400；
The antifoaming agent is at least one of organic silicon defoamer, polyoxyethylene polyoxypropylene glycerine, alcohols；Alcohols bag
Containing enanthol, octanol, isooctanol, nonyl alcohol, undecyl alcohol, lauryl alcohol.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-20%, emamectin-benzoate 0.1%-5%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1%-10%, emamectin-benzoate 0.1%-3%, solvent 3%-40%, emulsifier 1%-
20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5%, antifoaming agent 0%-3%, surplus are water.
Preferably, the Thymol-emamectin-benzoate aqueous emulsion, includes in percentage by weight
Following components：Thymol 1.0%-6.0%, emamectin-benzoate 0.4%-1%, solvent 5%-15%, emulsifier
6%-9%, thickener 3%-5%, dispersant 0.5%-3.0%, surplus are water, while Thymol and emamectin benzoate benzoic acid
The weight ratio of salt is 20:1~1:1；
The solvent is acetic acid, one kind in ethyl alcohol；
The emulsifier is styrylphenol polyoxyethylene ether or polyoxyethylene sorbitan fatty acid ester；
The thickener is chitosan；
The dispersant is polycarboxylate.
A kind of preparation method of Thymol-emamectin-benzoate aqueous emulsion, comprises the following steps：According to
Proportioning described in any of the above item weighs each component, and Thymol and emamectin-benzoate are dissolved in solvent,
Emulsifier, dispersant are added in, is uniformly mixed and obtains oil phase；Thickener, antifreeze, antifoaming agent are added to the water, are uniformly mixed
To water phase；Under high speed shear, oil phase is mixed with water conjunction, aqueous emulsion is made.
Thymol-emamectin-benzoate aqueous emulsion described in any of the above item is in Agricultural Mites prevention
Application.
With reference to specific embodiment, the present invention is further illustrated, but is not limited thereto.
GY-D07 is polycarboxylate salt dispersant in embodiment（Beijing Guang Yuan Yi Nong Chemical Co., Ltd.s produce）, agriculture breast 602#
For the emulsifier of styrylphenol polyoxyethylene ether series.
Embodiment 1
Thymol-emamectin-benzoate aqueous emulsion includes following components in percentage by weight：
Thymol 5%
Emamectin benzoate 0.5%
Acetic acid 8%
Agriculture breast 602# 8%
Chitosan 5%
GY-D07 2%
Surplus is water.
Thymol and emamectin-benzoate wherein in aqueous emulsion（Emamectin benzoate）Weight percent in total
For 5.5%.
Embodiment 2
Thymol-emamectin-benzoate aqueous emulsion includes following components in percentage by weight：
Thymol 2.0%
Emamectin benzoate 0.5%
Acetic acid 8%
Tween 80 8%
Chitosan 5%
GY-D07 1%
Surplus is water.
Thymol and emamectin-benzoate wherein in aqueous emulsion（Emamectin benzoate）Weight percent in total
For 2.5%.
Embodiment 3
Thymol-emamectin-benzoate aqueous emulsion includes following components in percentage by weight：
Thymol 1%
Emamectin benzoate 1%
Ethyl alcohol 10%
Tween 80 7%
Chitosan 5%
GY-D07 1%
Surplus is water.
Embodiment 4
Thymol-emamectin-benzoate aqueous emulsion includes following components in percentage by weight：
Thymol 3%
Emamectin benzoate 1%
Ethyl alcohol 12%
Agriculture breast 602# 8%
Chitosan 4%
GY-D07 1%
Surplus is water.
In addition, proper quantity of defoaming agent can also be added in mentioned emulsifier, colder northern area is if it is for, on
Suitable antifreeze can also be added in by stating in aqueous emulsion.
Thymol-emamectin-benzoate aqueous emulsion different ratio synergy effect experiment
The composition proportion of Thymol and emamectin-benzoate in aqueous emulsion is adjusted, other compositions are constant
In the case of, carry out synergy effect Experimental comparison.
Using slide infusion process, Thymol, emamectin-benzoate and different quality proportioning are measured respectively
Mix preparation indoor virulence, calculate virulence equation and lethal concentration of 50 LC with least square method50（3 it is small when）, according to Sun Yunpei
Method calculates the toxicity index of medicament and mixed co-toxicity coefficient（CTC values）.Co-toxicity coefficient CTC, calculation formula are as follows（With methylamino
Abamectin benzoate is standard agent, toxicity index 100）：
ATI=S/M×100
In formula：
ATI--- mixture surveys toxicity index
S--- the LC of standard pesticide agent50, unit is milligrams per liter (mg/L);
M--- the LC of mixture50, unit is milligrams per liter (mg/L).
TTI=TI
A
×P
A
+TI
B
×P
B
In formula：
TTI--- mixture theoretical toxicity index；
TI A --- A medicament toxicity index；
P A --- percentage composition of the A medicaments in mixture, unit are percentage（%）；
TI B --- B medicament toxicity index；
P B --- percentage composition of the B medicaments in mixture, unit are percentage（%）.
CTC=ATI/TTI×100
In formula：
CTC--- co-toxicity coefficient；
ATI--- mixture surveys toxicity index；
TTI--- mixture theoretical toxicity index.
The co-toxicity coefficient of compounding agent（CTC）>=120 show as synergistic effect；CTC≤80 show as antagonism；80 ＜
CTC ＜ 120 show as summation action.
It the results are shown in Table 1.
The toxicity test result of 1 different ratio relation pair panonychus citri of table
From table 1 it follows that in the mixture of different proportion, co-toxicity coefficient is all higher than 120, shows to increase well
Effect acts on.
Field efficacy is tested
To verify the field efficacy of embodiment medicament, carried out on October 25th, 2015 in Baiyun District, Guangzhou City Mt. Mountain orchard
Field efficacy experiment.Using fixed point, singling, determine leaf and hold board method inspection, hold board blade base and smear vaseline to prevent tetranychid
It escapes.3d, 7d survival mite number after radix, medicine are checked respectively for before medicine, the results are shown in Table 2.Control effect is calculated by following publicity.
Mite mouthful decline rate=（Survival mite number after mite number-medicine living before medicine）Mite number × 100% living before/medicine
Corrected mortality=（Treatment region mite mouthful decline rate-check plot mite mouthful decline rate）/（1- check plots mite mouthful decline rate）×
100%。
It the results are shown in Table 2.
2 treatment agent of table prevents panonychus citri field control effectiveness test result
As seen from the results in Table 2：Thymol and emamectin-benzoate compound in Examples 1 and 2
Aqueous emulsion works well, and has synergistic effect, is as a result better than 10% Thymol and 0.5% emamectin-benzoate.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (7)
1. a kind of Thymol-emamectin-benzoate aqueous emulsion, it is characterised in that：Contain Thymol and first ammonia
Base abamectin benzoate, weight ratio are (20:1)~(1:1).
2. Thymol-emamectin-benzoate aqueous emulsion according to claim 1, it is characterised in that：It presses
Include following components according to weight percent meter：Thymol 1%-50%, emamectin-benzoate 0.01%-
30%, solvent 3%-40%, emulsifier 1%-20%, thickener 0%-10%, dispersant 0%-10%, antifreeze 0%-5%,
Antifoaming agent 0%-3%, surplus are water；
The solvent is at least one of ethyl alcohol, acetone, cyclohexanone, hexamethylene, acetic acid；
The emulsifier is alkylbenzenesulfonate, aliphatic alcohol polyethenoxy base ether, phenol derivatives polyoxyethylene ether, polyoxyethylene
Fatty acid esters of sorbitan, alkylphenol polyoxyethylene ether, styrylphenol polyoxyethylene ether, polyoxyethylene sorbitan
At least one of aliphatic ester, castor oil polyoxyethylene ether；
The thickener is at least one of pectin, chitosan, agar, gelatin, xanthans；
The dispersant is sodium lignin sulfonate, calcium lignosulfonate, alkylphenol-polyethenoxy base phosphate, polycarboxylate, three
At least one of polyphosphate sodium, lauryl sodium sulfate；
The antifreeze is at least one of ethylene glycol, propylene glycol, glycerine, urea and polyethylene glycol 400；
The antifoaming agent is at least one of organic silicon defoamer, polyoxyethylene polyoxypropylene glycerine, alcohols.
3. Thymol-emamectin-benzoate aqueous emulsion according to claim 2, it is characterised in that：It presses
Include following components according to weight percent meter：Thymol 1%-20%, emamectin-benzoate 0.1%-5%,
Solvent 3%-40%, emulsifier 1%-20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5%, antifoaming agent
0%-3%, surplus are water.
4. Thymol-emamectin-benzoate aqueous emulsion according to Claims 2 or 3, it is characterised in that：
Include following components in percentage by weight：Thymol 1%-10%, emamectin-benzoate 0.1%-
3%, solvent 3%-40%, emulsifier 1%-20%, thickener 0%-10%, dispersant 0%-5%, antifreeze 0%-5% disappear
Infusion 0%-3%, surplus are water.
5. Thymol-emamectin-benzoate aqueous emulsion according to Claims 2 or 3, it is characterised in that：
Include following components in percentage by weight：Thymol 1.0%-6.0%, emamectin-benzoate 0.4%-
1%, solvent 5%-15%, emulsifier 6%-9%, thickener 3%-5%, dispersant 0.5%-3.0%, surplus are water, simultaneously
The weight ratio of Thymol and emamectin-benzoate is 20:1~1:1.
6. a kind of preparation method of Thymol-emamectin-benzoate aqueous emulsion, which is characterized in that including following
Step：
Each component is weighed according to claim 1-5 any one of them proportioning, by Thymol and emamectin benzoate benzene first
Hydrochlorate is dissolved in solvent, adds in emulsifier, dispersant, is uniformly mixed and is obtained oil phase；Thickener, antifreeze, antifoaming agent are added in
In water, it is uniformly mixed and obtains water phase；Under high speed shear, oil phase is mixed with water conjunction, aqueous emulsion is made.
7. claim 1-5 any one of them Thymol-emamectin-benzoate aqueous emulsion is in Agricultural Mites
Application in prevention.
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| CN104381334A (en) * | 2014-12-20 | 2015-03-04 | 唐睿 | Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol |
| CN104478607A (en) * | 2014-12-19 | 2015-04-01 | 唐睿 | Thymol bactericide and preparation method thereof |
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| CN104478607A (en) * | 2014-12-19 | 2015-04-01 | 唐睿 | Thymol bactericide and preparation method thereof |
| CN104381334A (en) * | 2014-12-20 | 2015-03-04 | 唐睿 | Formula and preparation method of micro-capsule suspoemulsion containing abamectin and thymol |
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