CN104350036B - 4‑烷酰氧基‑2‑甲基丁酸的生产方法 - Google Patents

4‑烷酰氧基‑2‑甲基丁酸的生产方法 Download PDF

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CN104350036B
CN104350036B CN201380029603.8A CN201380029603A CN104350036B CN 104350036 B CN104350036 B CN 104350036B CN 201380029603 A CN201380029603 A CN 201380029603A CN 104350036 B CN104350036 B CN 104350036B
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formula
compound
transition metal
production
compounds
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CN104350036A (zh
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沃纳尔·邦拉蒂
简·斯彻特兹
贝蒂娜·乌斯腾伯格
托马斯·内切尔
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DSM IP Assets BV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/24—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/008—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with tri- or tetrahalomethyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
    • C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
    • C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380029603.8A 2012-06-05 2013-06-05 4‑烷酰氧基‑2‑甲基丁酸的生产方法 Active CN104350036B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12170781 2012-06-05
EP12170781.4 2012-06-05
PCT/EP2013/061605 WO2013182607A1 (en) 2012-06-05 2013-06-05 Process for the production of 4-alkanoyloxy-2-methylbutanoic acid

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CN104350036A CN104350036A (zh) 2015-02-11
CN104350036B true CN104350036B (zh) 2017-05-17

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US (1) US9447017B2 (https=)
EP (1) EP2855418B1 (https=)
JP (1) JP6209776B2 (https=)
KR (1) KR102100521B1 (https=)
CN (1) CN104350036B (https=)
EA (1) EA026148B1 (https=)
ES (1) ES2643221T3 (https=)
IN (1) IN2014DN09213A (https=)
WO (1) WO2013182607A1 (https=)

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
CN109609758B (zh) * 2018-12-29 2022-02-18 江苏雄风科技有限公司 一种低氯离子高纯硫酸钴的萃取洗涤方法
JP2023506710A (ja) * 2019-12-23 2023-02-20 ディーエスエム アイピー アセッツ ビー．ブイ． １，３－α－ジエン（ＩＩ）の官能化

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DE1918694C3 (de) * 1969-04-12 1974-07-04 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Carbonsäureestern des 3-Formylbutanol-(l) durch die Oxo-Synthese
US4500727A (en) * 1981-03-23 1985-02-19 Kuraray Co., Ltd. Process for producing methyl lactate
JPS57156442A (en) * 1981-03-23 1982-09-27 Kuraray Co Ltd Preparation of methyl lactate
JPS58140038A (ja) * 1982-02-16 1983-08-19 Kuraray Co Ltd アゼライン酸の製造法
US4668699A (en) * 1985-08-05 1987-05-26 Merck & Co., Inc. Novel HMG-CoA reductase inhibitors
US4665091A (en) * 1985-11-04 1987-05-12 Merck & Co., Inc. Macrocyclic lactone HMG-CoA reductase inhibitors
JPH04198149A (ja) * 1990-11-29 1992-07-17 Mitsui Toatsu Chem Inc ２―クロロプロピオンアルデヒドの酸化方法
JP3756537B2 (ja) * 1994-11-16 2006-03-15 株式会社クラレ ジメチルデカンジアールおよびその製造方法
JP2000063373A (ja) * 1998-08-21 2000-02-29 Kuraray Co Ltd ４−ヒドロキシメチル−γ−ブチロラクトンの製造方法および該製造方法に有用な中間体並びに該中間体の製造方法
CN101391948B (zh) * 2007-09-20 2012-06-13 浙江新和成股份有限公司 3-甲基-2-丁烯酸的制备方法
JP2011246426A (ja) * 2010-05-31 2011-12-08 Mitsubishi Chemicals Corp ホルミルアシロキシアルカン及び環状エーテルの製造方法
KR101914806B1 (ko) * 2011-01-19 2018-11-02 디에스엠 아이피 어셋츠 비.브이. 탄소-탄소 이중 결합 접촉 수소화에 의한 4-아세톡시-2-메틸부탄알의 제조

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Formic acid-palladium acetate-1,4-bis(diphenylphosphino)butane： an effective catalytic system for regioselective hydrocarboxylation of simple and functionalized olefins;Bassam El Ali et al.;《Journal of Molecular Catalysis》;19921231;第77卷;第7-13页 *

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Publication number Publication date
CN104350036A (zh) 2015-02-11
US20150099894A1 (en) 2015-04-09
EP2855418A1 (en) 2015-04-08
EA026148B1 (ru) 2017-03-31
KR20150016544A (ko) 2015-02-12
EA201401323A1 (ru) 2015-03-31
IN2014DN09213A (https=) 2015-07-10
KR102100521B1 (ko) 2020-04-14
EP2855418B1 (en) 2017-08-09
JP6209776B2 (ja) 2017-10-11
ES2643221T3 (es) 2017-11-21
JP2015520177A (ja) 2015-07-16
WO2013182607A1 (en) 2013-12-12
US9447017B2 (en) 2016-09-20

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