CN104332628A - 锂离子电池正极材料的制备方法及其锂离子电池 - Google Patents
锂离子电池正极材料的制备方法及其锂离子电池 Download PDFInfo
- Publication number
- CN104332628A CN104332628A CN201410449694.7A CN201410449694A CN104332628A CN 104332628 A CN104332628 A CN 104332628A CN 201410449694 A CN201410449694 A CN 201410449694A CN 104332628 A CN104332628 A CN 104332628A
- Authority
- CN
- China
- Prior art keywords
- preparation
- lithium ion
- ion battery
- lithium
- precursor mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 32
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000000151 deposition Methods 0.000 claims abstract description 5
- 239000004411 aluminium Substances 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 20
- 239000005955 Ferric phosphate Substances 0.000 claims description 18
- 229940032958 ferric phosphate Drugs 0.000 claims description 18
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims description 18
- 229910000399 iron(III) phosphate Inorganic materials 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 16
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 9
- 239000010405 anode material Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000006230 acetylene black Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 239000007767 bonding agent Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 238000000875 high-speed ball milling Methods 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- 239000005030 aluminium foil Substances 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 159000000013 aluminium salts Chemical class 0.000 claims description 3
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 229910052493 LiFePO4 Inorganic materials 0.000 abstract description 13
- 238000001354 calcination Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 229910052744 lithium Inorganic materials 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000000975 co-precipitation Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 5
- 239000012300 argon atmosphere Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- OIAKUYQUAMNLMV-UHFFFAOYSA-H P(=O)([O-])([O-])[O-].[Fe+2].[Li+].[Al+3].P(=O)([O-])([O-])[O-] Chemical compound P(=O)([O-])([O-])[O-].[Fe+2].[Li+].[Al+3].P(=O)([O-])([O-])[O-] OIAKUYQUAMNLMV-UHFFFAOYSA-H 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (10)
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CN201410449694.7A CN104332628B (zh) | 2014-09-04 | 2014-09-04 | 锂离子电池正极材料的制备方法及其锂离子电池 |
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CN201410449694.7A CN104332628B (zh) | 2014-09-04 | 2014-09-04 | 锂离子电池正极材料的制备方法及其锂离子电池 |
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CN104332628A true CN104332628A (zh) | 2015-02-04 |
CN104332628B CN104332628B (zh) | 2017-09-15 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104743536A (zh) * | 2015-02-10 | 2015-07-01 | 常州普格纳能源材料有限公司 | 一种磷酸盐系正极材料的制备方法 |
CN111977628A (zh) * | 2020-09-04 | 2020-11-24 | 中南大学 | 从锂离子电池中回收制备磷酸铁锂的方法 |
WO2022242184A1 (zh) * | 2021-05-17 | 2022-11-24 | 广东邦普循环科技有限公司 | 一种掺杂磷酸铁及其制备方法和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1775665A (zh) * | 2005-11-30 | 2006-05-24 | 重庆大学 | 一种制备磷酸亚铁锂的方法 |
CN101070149A (zh) * | 2007-06-07 | 2007-11-14 | 孝感学院 | 一种真空碳还原制备的磷酸铁锂材料及方法 |
CN101212049A (zh) * | 2007-12-21 | 2008-07-02 | 中国科学院上海硅酸盐研究所 | 掺杂的磷酸铁锂活性物质与碳组成的正极材料及制备方法 |
CN101692488A (zh) * | 2009-09-11 | 2010-04-07 | 河南新飞科隆电源有限公司 | 掺杂金属元素磷酸铁的合成方法 |
CN102593453A (zh) * | 2012-03-29 | 2012-07-18 | 安徽工业大学 | 以冶金含铁尘泥为主要原料制备多离子掺杂型磷酸铁的方法 |
CN103232028A (zh) * | 2012-04-26 | 2013-08-07 | 张健 | 磷酸铁钡产品及其制备方法和用途 |
-
2014
- 2014-09-04 CN CN201410449694.7A patent/CN104332628B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1775665A (zh) * | 2005-11-30 | 2006-05-24 | 重庆大学 | 一种制备磷酸亚铁锂的方法 |
CN101070149A (zh) * | 2007-06-07 | 2007-11-14 | 孝感学院 | 一种真空碳还原制备的磷酸铁锂材料及方法 |
CN101212049A (zh) * | 2007-12-21 | 2008-07-02 | 中国科学院上海硅酸盐研究所 | 掺杂的磷酸铁锂活性物质与碳组成的正极材料及制备方法 |
CN101692488A (zh) * | 2009-09-11 | 2010-04-07 | 河南新飞科隆电源有限公司 | 掺杂金属元素磷酸铁的合成方法 |
CN102593453A (zh) * | 2012-03-29 | 2012-07-18 | 安徽工业大学 | 以冶金含铁尘泥为主要原料制备多离子掺杂型磷酸铁的方法 |
CN103232028A (zh) * | 2012-04-26 | 2013-08-07 | 张健 | 磷酸铁钡产品及其制备方法和用途 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104743536A (zh) * | 2015-02-10 | 2015-07-01 | 常州普格纳能源材料有限公司 | 一种磷酸盐系正极材料的制备方法 |
CN104743536B (zh) * | 2015-02-10 | 2017-02-01 | 常州普格纳能源材料有限公司 | 一种磷酸盐系正极材料的制备方法 |
CN111977628A (zh) * | 2020-09-04 | 2020-11-24 | 中南大学 | 从锂离子电池中回收制备磷酸铁锂的方法 |
WO2022242184A1 (zh) * | 2021-05-17 | 2022-11-24 | 广东邦普循环科技有限公司 | 一种掺杂磷酸铁及其制备方法和应用 |
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