CN104284875B - 用于化学选择性还原末端饱和羧酸酯类的方法 - Google Patents

用于化学选择性还原末端饱和羧酸酯类的方法 Download PDF

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CN104284875B
CN104284875B CN201380025207.8A CN201380025207A CN104284875B CN 104284875 B CN104284875 B CN 104284875B CN 201380025207 A CN201380025207 A CN 201380025207A CN 104284875 B CN104284875 B CN 104284875B
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terminal unsaturation
ester
carboxylate
alkene
sacrifice
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Chinese (zh)
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CN104284875A (zh
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R·W·吉瑟
A·戈克
F·施罗德
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Givaudan SA
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Givaudan SA
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0255—Ligands comprising the N2S2 or N2P2 donor atom set, e.g. diiminodithiolates or diiminodiphosphines with complete pi-conjugation between all donor centres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380025207.8A 2012-05-16 2013-05-16 用于化学选择性还原末端饱和羧酸酯类的方法 Active CN104284875B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1208589.0 2012-05-16
GBGB1208589.0A GB201208589D0 (en) 2012-05-16 2012-05-16 Improvements in or relating to organic compounds
PCT/EP2013/060150 WO2013171302A1 (en) 2012-05-16 2013-05-16 Process for the chemoselective reduction of terminally saturated carboxylic esters

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CN104284875A CN104284875A (zh) 2015-01-14
CN104284875B true CN104284875B (zh) 2017-10-03

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US (1) US9193651B2 (enExample)
EP (1) EP2850050B1 (enExample)
JP (1) JP6279552B2 (enExample)
CN (1) CN104284875B (enExample)
BR (1) BR112014028156A2 (enExample)
GB (1) GB201208589D0 (enExample)
IN (1) IN2014DN08413A (enExample)
MX (1) MX363196B (enExample)
SG (1) SG11201406503VA (enExample)
WO (1) WO2013171302A1 (enExample)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
FR3013047B1 (fr) 2013-11-08 2016-01-01 Pivert Procede de synthese d'esters
JP6483134B2 (ja) 2013-12-18 2019-03-13 フイルメニツヒ ソシエテ アノニムＦｉｒｍｅｎｉｃｈ Ｓａ Ｆｅ／三座配位子錯体によるエステルの水素化
US9416091B1 (en) * 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
CN105582961B (zh) * 2014-10-24 2018-04-06 中国石油化工股份有限公司 1,4‑环己烷二甲酸二甲酯氢化催化剂
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
AU2016357756B2 (en) 2015-11-18 2021-09-30 Provivi, Inc. Production of fatty olefin derivatives via olefin metathesis
US10428177B2 (en) 2016-06-03 2019-10-01 Sirrus, Inc. Water absorbing or water soluble polymers, intermediate compounds, and methods thereof
JP7153937B2 (ja) 2017-02-17 2022-10-17 プロビビ インコーポレイテッド オレフィンメタセシスによるフェロモンおよび関連材料の合成方法
GB201800276D0 (en) 2018-01-08 2018-02-21 Univ Court Univ St Andrews Maganese-catalysed hydrogenation of esters
EP3994117B1 (de) 2019-07-03 2024-07-03 Basf Se Hydrierung von estern zu alkoholen in gegenwart eines ru-pnn-komplexes

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101541716A (zh) * 2006-11-27 2009-09-23 弗门尼舍有限公司 通过钌/二齿配位体的络合物进行的酯的氢化

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Publication number Priority date Publication date Assignee Title
CN101137601B (zh) * 2005-04-05 2011-08-10 弗门尼舍有限公司 通过钌/二齿配体的络合物进行的酯的氢化
WO2006106484A1 (en) 2005-04-05 2006-10-12 Firmenich Sa Hydrogenation of esters with ru/tetradentate ligands complexes
JP5849710B2 (ja) * 2011-02-03 2016-02-03 セントラル硝子株式会社 β−フルオロアルコール類の製造方法
EP2744815B1 (en) 2011-08-18 2019-01-16 Goussev, Dmitri Hydrogenation and dehydrogenation catalyst, and methods of making and using the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101541716A (zh) * 2006-11-27 2009-09-23 弗门尼舍有限公司 通过钌/二齿配位体的络合物进行的酯的氢化

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Dihydrogen Reduction of Carboxylic Esters to Alcohols under the Catalysis of Homogeneous Ruthenium Complexes: High Efficiency and Unprecedented Chemoselectivity;Lionel A. Saudan et al.,;《Angew. Chem.》;20071231;第119卷;7617 –7620 *
Hydrogenation Processes in the Synthesis of Perfumery Ingredients;LIONEL A. SAUDAN;《Acc. Chem. Res.》;20071026;第40卷(第12期);1309–1319 *

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Publication number Publication date
MX2014012447A (es) 2015-01-15
BR112014028156A2 (pt) 2017-06-27
US20150152029A1 (en) 2015-06-04
SG11201406503VA (en) 2014-11-27
WO2013171302A1 (en) 2013-11-21
US9193651B2 (en) 2015-11-24
IN2014DN08413A (enExample) 2015-05-08
EP2850050B1 (en) 2018-12-12
JP6279552B2 (ja) 2018-02-14
EP2850050A1 (en) 2015-03-25
JP2015520156A (ja) 2015-07-16
MX363196B (es) 2019-03-14
GB201208589D0 (en) 2012-06-27
CN104284875A (zh) 2015-01-14

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