CN104284714B - 用于使烃低聚以形成至少一种共聚单体产物的方法 - Google Patents

用于使烃低聚以形成至少一种共聚单体产物的方法 Download PDF

Info

Publication number
CN104284714B
CN104284714B CN201380024458.4A CN201380024458A CN104284714B CN 104284714 B CN104284714 B CN 104284714B CN 201380024458 A CN201380024458 A CN 201380024458A CN 104284714 B CN104284714 B CN 104284714B
Authority
CN
China
Prior art keywords
organic liquid
phenyl
solvent
reactor
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380024458.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN104284714A (zh
Inventor
丹尼丝·路易塞特·文特尔
肯尼·滕扎
帕莱萨·农戈德瓦纳
马修·詹姆斯·奥韦雷特
凯文·布朗
尼古劳斯·拉迪斯劳斯·施塔克
克雷格·麦格雷戈
理查德·内尔·沃尔什
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
Original Assignee
Sasol Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Technology Pty Ltd filed Critical Sasol Technology Pty Ltd
Publication of CN104284714A publication Critical patent/CN104284714A/zh
Application granted granted Critical
Publication of CN104284714B publication Critical patent/CN104284714B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201380024458.4A 2012-05-09 2013-05-08 用于使烃低聚以形成至少一种共聚单体产物的方法 Active CN104284714B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA2012/03387 2012-05-09
ZA201203387 2012-05-09
PCT/IB2013/053687 WO2013168099A1 (en) 2012-05-09 2013-05-08 A process for oligomerising a hydrocarbon to form at least one co-monomer product

Publications (2)

Publication Number Publication Date
CN104284714A CN104284714A (zh) 2015-01-14
CN104284714B true CN104284714B (zh) 2016-06-29

Family

ID=48626506

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380024458.4A Active CN104284714B (zh) 2012-05-09 2013-05-08 用于使烃低聚以形成至少一种共聚单体产物的方法

Country Status (10)

Country Link
US (1) US9522856B2 (cg-RX-API-DMAC7.html)
KR (1) KR102074753B1 (cg-RX-API-DMAC7.html)
CN (1) CN104284714B (cg-RX-API-DMAC7.html)
BR (1) BR112014027663A2 (cg-RX-API-DMAC7.html)
CA (1) CA2869701C (cg-RX-API-DMAC7.html)
IN (1) IN2014DN08658A (cg-RX-API-DMAC7.html)
MY (1) MY168547A (cg-RX-API-DMAC7.html)
SG (1) SG11201407269TA (cg-RX-API-DMAC7.html)
WO (1) WO2013168099A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201407127B (cg-RX-API-DMAC7.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI929134B (zh) 2021-03-30 2026-06-21 法商Ｉｆｐ新能源公司 烯烴原料之寡聚方法

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9701699B2 (en) 2013-11-18 2017-07-11 Lg Chem, Ltd. Ligand compound, catalyst system for olefin oligomerization, and method for olefin oligomerization using the same
JP6565525B2 (ja) 2014-09-22 2019-08-28 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法及び製造装置
EP3045438B1 (de) * 2015-01-19 2017-11-29 Evonik Degussa GmbH Kombinierte Herstellung von zumindest Buten und Octen aus Ethen
KR101928765B1 (ko) 2015-06-09 2018-12-13 주식회사 엘지화학 에틸렌을 회수하기 위한 분리방법 및 분리공정 시스템
KR101928766B1 (ko) 2015-06-09 2018-12-13 주식회사 엘지화학 에틸렌을 회수하기 위한 분리방법 및 분리공정 시스템
KR101749542B1 (ko) * 2015-09-03 2017-06-21 한택규 에틸렌의 선택적 올리고머화 반응 공정
WO2017115305A1 (en) * 2015-12-30 2017-07-06 Sabic Global Technologies B.V. Method of separating linear alpha olefins
WO2017187289A1 (en) * 2016-04-25 2017-11-02 Sabic Global Technologies B.V. Process for removing heat from an oligomerization reaction
WO2020050738A1 (en) * 2018-09-06 2020-03-12 Public Joint Stock Company "Sibur Holding" Bubble shell-and-tube apparatus
KR102721498B1 (ko) * 2019-07-24 2024-10-25 에스케이이노베이션 주식회사 에틸렌 올리고머화 공정의 미반응 에틸렌 회수 방법
FR3099476B1 (fr) * 2019-07-31 2021-07-30 Ifp Energies Now Procede d’oligomerisation mettant en œuvre un recycle du ciel gazeux
KR102581118B1 (ko) 2019-12-09 2023-09-20 주식회사 엘지화학 올리고머 제조 장치
FR3105019B1 (fr) * 2019-12-18 2022-07-22 Ifp Energies Now Reacteur gaz/liquide d’oligomerisation a zones successives de diametre variable
FR3112775B1 (fr) * 2020-07-24 2022-07-01 Ifp Energies Now Procédé d’oligomérisation mettant en oeuvre un recycle du ciel gazeux
KR102690688B1 (ko) * 2020-11-03 2024-07-31 주식회사 엘지화학 올리고머 제조장치
FR3121439B1 (fr) * 2021-03-30 2023-03-24 Ifp Energies Now Procede d'oligomerisation comprenant une etape de recyclage d'un solvant prealablement refroidi
FR3123354B1 (fr) * 2021-05-28 2023-05-26 Ifp Energies Now Procede d'oligomerisation dans un reacteur a zones de diametres variables comprenant une etape de recyclage d'un solvant prealablement refroidi
CN115025744B (zh) * 2022-07-11 2024-07-12 东北石油大学 乙烯齐聚生产线性1-己烯的工艺
KR20250068090A (ko) * 2023-11-09 2025-05-16 주식회사 엘지화학 올리고머화 반응 부산물의 처리 방법

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1515525A (zh) * 1994-02-18 2004-07-28 一种稳定烯烃生产催化剂体系的方法
CN101888987A (zh) * 2007-11-07 2010-11-17 沙索技术有限公司 用于烃聚合或低聚的方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676523A (en) 1971-07-16 1972-07-11 Shell Oil Co Alpha-olefin production
US4668838A (en) 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
US5811618A (en) 1991-10-16 1998-09-22 Amoco Corporation Ethylene trimerization
TW354300B (en) 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
FR2764524B1 (fr) 1997-06-17 1999-07-16 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1
AU5490099A (en) 1998-08-18 2000-03-14 E.I. Du Pont De Nemours And Company Manufacture of alpha-olefins
CA2470885C (en) 2001-12-20 2011-05-24 Sasol Technology (Pty) Ltd Trimerisation and oligomerisation of olefins using a chromium based catalyst
JP2006511694A (ja) 2002-12-20 2006-04-06 サソル テクノロジー （ピーティーワイ） リミテッド オレフィンのタンデム四量体化−重合
PL377406A1 (pl) 2002-12-20 2006-02-06 Sasol Technology (Pty) Limited Tetrameryzacja olefin
CA2570056C (en) 2004-06-18 2012-09-11 Sasol Technology (Pty) Limited Oligomerisation in the presence of both a tetramerisation catalyst and a further oligomerisation catalyst
CN101052605B (zh) 2004-06-18 2011-12-21 Sasol技术股份有限公司 烯属化合物在脂族介质中的低聚
US7414006B2 (en) 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
US7259123B2 (en) 2005-04-08 2007-08-21 Shell Oil Company Catalytic trimerization and tetramerization of olefinic monomers
EP1915329B2 (en) 2005-07-12 2016-05-11 Sasol Technology (Pty) Ltd Oligomerisation of olefinic compounds in the presence of a diluted metal containing activator
GB0520085D0 (en) 2005-10-03 2005-11-09 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
EP1951429B1 (en) 2005-11-21 2010-01-06 Shell Internationale Research Maatschappij B.V. Catalytic oligomerization of olefinic monomers
WO2007092136A2 (en) 2006-02-03 2007-08-16 Exxonmobil Chemical Patents, Inc. Process for generating alpha olefin comonomers
BRPI0707407A2 (pt) 2006-02-03 2011-05-03 Ineos Europe Ltd catalisadores de metais de transição
US7378537B2 (en) 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
WO2008038173A2 (en) 2006-09-26 2008-04-03 Sasol Technology (Pty) Limited Polymerisation (including oligomerisation) of olefinic compounds in the presence of catalyst, and a catalyst activator including a halogenated organic group
US8252874B2 (en) 2006-12-22 2012-08-28 Shell Oil Company Ligands and catalyst systems for the oligomerization of olefinic monomers
SG191441A1 (en) 2006-12-22 2013-07-31 Shell Int Research Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
KR101074202B1 (ko) 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
KR101241656B1 (ko) 2007-07-11 2013-03-11 린데 악티엔게젤샤프트 촉매 조성물 및 에틸렌의 이량체화, 삼량체화 및/또는 사량체화를 위한 공정
KR101057576B1 (ko) 2007-08-16 2011-08-17 에스케이종합화학 주식회사 선택적 에틸렌 올리머고화 촉매계
ES2476242T3 (es) 2009-02-16 2014-07-14 Sasol Technology (Pty) Ltd Oligomerización de compuestos olefínicos en presencia de un catalizador de oligomerización activado
EP2490990B1 (en) 2009-10-19 2013-12-04 Sasol Technology (Proprietary) Limited Oligomerisation of olefinic compounds with reduced polymer formation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1515525A (zh) * 1994-02-18 2004-07-28 一种稳定烯烃生产催化剂体系的方法
CN101888987A (zh) * 2007-11-07 2010-11-17 沙索技术有限公司 用于烃聚合或低聚的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI929134B (zh) 2021-03-30 2026-06-21 法商Ｉｆｐ新能源公司 烯烴原料之寡聚方法

Also Published As

Publication number Publication date
CA2869701C (en) 2020-01-07
KR102074753B1 (ko) 2020-02-07
SG11201407269TA (en) 2014-12-30
KR20150051190A (ko) 2015-05-11
MY168547A (en) 2018-11-12
CA2869701A1 (en) 2013-11-14
CN104284714A (zh) 2015-01-14
US9522856B2 (en) 2016-12-20
ZA201407127B (en) 2015-12-23
IN2014DN08658A (cg-RX-API-DMAC7.html) 2015-05-22
BR112014027663A2 (pt) 2017-06-27
WO2013168099A1 (en) 2013-11-14
US20150126790A1 (en) 2015-05-07

Similar Documents

Publication Publication Date Title
CN104284714A (zh) 用于使烃低聚以形成至少一种共聚单体产物的方法
CN104284703B (zh) 从多组分烃流分离组分
CN102666443B (zh) 从包含乙烯的多组分烃流分离组分
CN104661989B (zh) 用于低聚乙烯的方法
RU2635551C2 (ru) Способ олигомеризации этилена
CN101888986B (zh) 用于烃聚合或低聚的方法
CN101888987B (zh) 用于烃低聚的方法
CN104245640B (zh) 乙烯的四聚
CN106488898B (zh) 用于回收乙烯的分离方法和分离工艺系统
CN106715369B (zh) 用于回收乙烯的分离方法和分离工艺系统
CN116854554B (zh) 一种丙烯四聚体的制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant