CN104277318A - 一种质轻、减震橡塑发泡材料及其制备方法 - Google Patents
一种质轻、减震橡塑发泡材料及其制备方法 Download PDFInfo
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- CN104277318A CN104277318A CN201410430484.3A CN201410430484A CN104277318A CN 104277318 A CN104277318 A CN 104277318A CN 201410430484 A CN201410430484 A CN 201410430484A CN 104277318 A CN104277318 A CN 104277318A
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- plastic foam
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 74
- 239000005060 rubber Substances 0.000 title claims abstract description 74
- 239000000463 material Substances 0.000 title claims abstract description 66
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000004033 plastic Substances 0.000 title claims abstract description 15
- 229920003023 plastic Polymers 0.000 title claims abstract description 15
- 238000010521 absorption reaction Methods 0.000 title abstract 5
- 229920001577 copolymer Polymers 0.000 claims abstract description 18
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- 238000005469 granulation Methods 0.000 claims abstract description 4
- 230000003179 granulation Effects 0.000 claims abstract description 4
- 238000013016 damping Methods 0.000 claims description 52
- 239000003795 chemical substances by application Substances 0.000 claims description 42
- 239000002984 plastic foam Substances 0.000 claims description 34
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 11
- -1 soon ripe dose Substances 0.000 claims description 11
- 239000012764 mineral filler Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 6
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 5
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 238000004383 yellowing Methods 0.000 abstract description 4
- 229920005549 butyl rubber Polymers 0.000 abstract description 3
- 239000003431 cross linking reagent Substances 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 2
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 2
- 229920000426 Microplastic Polymers 0.000 abstract 1
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- 238000001746 injection moulding Methods 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
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- 208000027418 Wounds and injury Diseases 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 230000019771 cognition Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- 150000002013 dioxins Chemical class 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
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- 230000000750 progressive effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Classifications
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
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- C08J9/103—Azodicarbonamide
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/104—Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
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- C08J2323/22—Copolymers of isobutene; butyl rubber
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- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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- C08J2423/22—Copolymers of isobutene; butyl rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 | 5 |
密度 (g/cm3) | 0.268 | 0.249 | 0.225 | 0.247 | 0.252 |
邵氏硬度 | 39 | 47 | 43 | 41 | 37 |
回弹率(%) | 15 | 39 | 10 | 20 | 16 |
永久压缩歪度(%) | 25 | 21 | 32 | 22 | 27 |
尺寸收缩(%) | 0.5 | 0.2 | 2.7 | 0.7 | 0.4 |
撕裂强度(N/mm) | 7.2 | 9.5 | 8.3 | 7.6 | 6.4 |
延伸率(%) | 259 | 268 | 294 | 273 | 223 |
拉伸强度(MPa) | 2.9 | 2.4 | 3.4 | 3.1 | 2.1 |
耐黄变测试(A法) | 5级 | 5级 | 4-5级 | 4-5级 | 5级 |
耐黄变测试(B法) | 5级 | 5级 | 4-5级 | 4-5级 | 5级 |
Claims (7)
Priority Applications (1)
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CN201410430484.3A CN104277318B (zh) | 2014-08-28 | 2014-08-28 | 一种质轻、减震橡塑发泡材料及其制备方法 |
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CN201410430484.3A CN104277318B (zh) | 2014-08-28 | 2014-08-28 | 一种质轻、减震橡塑发泡材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104277318A true CN104277318A (zh) | 2015-01-14 |
CN104277318B CN104277318B (zh) | 2017-07-28 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104830007A (zh) * | 2015-04-09 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | 一种高阻尼发泡材料及其制备方法 |
CN106832544A (zh) * | 2017-01-12 | 2017-06-13 | 天津市浩迪橡塑科技有限公司 | 带有网状结构的阻尼板 |
CN107746482A (zh) * | 2017-01-18 | 2018-03-02 | 泉州嘉泰鞋业有限公司 | 橡胶微发泡注射大底及其制造方法 |
CN107987306A (zh) * | 2017-11-03 | 2018-05-04 | 中国科学院宁波材料技术与工程研究所 | 一种流体辅助注射制备橡胶发泡材料的方法及其制品 |
CN108485143A (zh) * | 2018-03-28 | 2018-09-04 | 中国皮革和制鞋工业研究院(晋江)有限公司 | 鞋用发泡材料及其制备方法 |
CN108586899A (zh) * | 2018-04-09 | 2018-09-28 | 广东国立科技股份有限公司 | 一种质轻的eva发泡鞋材及其制备方法 |
CN108864557A (zh) * | 2018-05-29 | 2018-11-23 | 福建师范大学 | 一种运动鞋底用超轻注射离子/共价交联闭孔式发泡聚合物材料及其制备方法 |
CN111138726A (zh) * | 2020-01-15 | 2020-05-12 | 福建五持恒科技发展有限公司 | 石墨烯天然橡胶防辐射复合发泡材料及其制备方法 |
CN113388185A (zh) * | 2021-06-22 | 2021-09-14 | 厦门联合信诺新材料有限公司 | 一种eva发泡材料及其制备方法与应用 |
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JPS55118944A (en) * | 1979-03-07 | 1980-09-12 | Aron Kasei Co Ltd | Synthetic resin composition for footwear sole |
CN102775652A (zh) * | 2012-08-16 | 2012-11-14 | 株洲时代新材料科技股份有限公司 | 一种热塑性弹性体微孔发泡材料及其制备方法 |
CN103709581A (zh) * | 2012-09-29 | 2014-04-09 | 安踏(中国)有限公司 | 一种耐磨止滑鞋底用发泡组合物及其制备方法 |
CN103951872A (zh) * | 2014-05-20 | 2014-07-30 | 南京东亚橡塑制品有限公司 | 一种轻质eva鞋底材料及其制备方法 |
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2014
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Patent Citations (4)
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JPS55118944A (en) * | 1979-03-07 | 1980-09-12 | Aron Kasei Co Ltd | Synthetic resin composition for footwear sole |
CN102775652A (zh) * | 2012-08-16 | 2012-11-14 | 株洲时代新材料科技股份有限公司 | 一种热塑性弹性体微孔发泡材料及其制备方法 |
CN103709581A (zh) * | 2012-09-29 | 2014-04-09 | 安踏(中国)有限公司 | 一种耐磨止滑鞋底用发泡组合物及其制备方法 |
CN103951872A (zh) * | 2014-05-20 | 2014-07-30 | 南京东亚橡塑制品有限公司 | 一种轻质eva鞋底材料及其制备方法 |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104830007A (zh) * | 2015-04-09 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | 一种高阻尼发泡材料及其制备方法 |
CN106832544B (zh) * | 2017-01-12 | 2019-03-15 | 天津市浩迪橡塑科技有限公司 | 带有网状结构的阻尼板 |
CN106832544A (zh) * | 2017-01-12 | 2017-06-13 | 天津市浩迪橡塑科技有限公司 | 带有网状结构的阻尼板 |
CN107746482A (zh) * | 2017-01-18 | 2018-03-02 | 泉州嘉泰鞋业有限公司 | 橡胶微发泡注射大底及其制造方法 |
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