CN104144966A - 聚(己二酸丁二酯-共-对苯二甲酸丁二酯)，及其生产方法和应用 - Google Patents

聚(己二酸丁二酯-共-对苯二甲酸丁二酯)，及其生产方法和应用 Download PDF

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Publication number
CN104144966A
CN104144966A CN201280071054.6A CN201280071054A CN104144966A CN 104144966 A CN104144966 A CN 104144966A CN 201280071054 A CN201280071054 A CN 201280071054A CN 104144966 A CN104144966 A CN 104144966A
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China
Prior art keywords
poly
multipolymer
acid
combination
diester
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Pending
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CN201280071054.6A
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English (en)
Chinese (zh)
Inventor
胡斯努·艾尔普·艾利德代奥卢
加内什·卡纳安
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Publication of CN104144966A publication Critical patent/CN104144966A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4216—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4225—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from residues obtained from the manufacture of dimethylterephthalate and from polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/12—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00—Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D177/12—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
CN201280071054.6A 2012-03-01 2012-12-28 聚(己二酸丁二酯-共-对苯二甲酸丁二酯)，及其生产方法和应用 Pending CN104144966A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/409,898 2012-03-01
US13/409,898 US9034983B2 (en) 2012-03-01 2012-03-01 Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
PCT/US2012/071904 WO2013130174A1 (en) 2012-03-01 2012-12-28 Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof

Publications (1)

Publication Number Publication Date
CN104144966A true CN104144966A (zh) 2014-11-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280071054.6A Pending CN104144966A (zh) 2012-03-01 2012-12-28 聚(己二酸丁二酯-共-对苯二甲酸丁二酯)，及其生产方法和应用

Country Status (5)

Country Link
US (2) US9034983B2 (enExample)
EP (1) EP2820063B1 (enExample)
JP (1) JP5818185B2 (enExample)
CN (1) CN104144966A (enExample)
WO (1) WO2013130174A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237750A (zh) * 2015-10-28 2016-01-13 北京市化学工业研究院 一种高分子量聚己二酸对苯二甲酸丁二醇酯的合成方法

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
ITMI20120250A1 (it) * 2012-02-20 2013-08-21 Novamont Spa Composizione polimerica biodegradabile per la realizzazione di articoli aventi elevata temperatura di inflessione sotto carico.
US9828461B2 (en) 2012-03-01 2017-11-28 Sabic Global Technologies B.V. Poly(alkylene co-adipate terephthalate) prepared from recycled polyethylene terephthalate having low impurity levels
US9034983B2 (en) 2012-03-01 2015-05-19 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
US20160271909A1 (en) * 2013-06-27 2016-09-22 Futerro S.A. Multilayer film comprising biopolymers
CN104448723B (zh) * 2013-09-24 2018-04-27 上海杰事杰新材料(集团)股份有限公司 一种抗静电可生物降解薄膜及其制备方法
WO2017044354A1 (en) * 2015-09-09 2017-03-16 Pepsico, Inc. Process for providing polymers comprising hexagonal boron nitride
US10988572B2 (en) 2017-11-20 2021-04-27 Alliance For Sustainable Energy, Llc Polymers and methods of making the same
CN108384200B (zh) * 2018-02-07 2020-04-17 浙江大学 一种快速结晶的pbat材料及其制备方法
EP3613787A1 (de) * 2018-08-24 2020-02-26 Covestro Deutschland AG Polyurethane mit verbesserter härte
US11939423B2 (en) 2019-07-03 2024-03-26 Northern Technologies International Corporation Biodegradable VCI packaging compositions
CN115103868B (zh) * 2019-12-19 2025-03-18 伊士曼化工公司 制备具有再循环成分的聚酯的方法
TWI882237B (zh) * 2022-07-07 2025-05-01 南亞塑膠工業股份有限公司 瓶蓋用組成物及瓶蓋
KR102563804B1 (ko) * 2022-09-13 2023-08-04 에스케이마이크로웍스 주식회사 폴리에스테르 필름 및 포장재

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6120895A (en) * 1996-09-20 2000-09-19 Basf Aktiengesellschaft Biodegradable polyesters
US6303738B1 (en) * 2000-08-04 2001-10-16 E. I. Du Pont De Nemours And Company Esterification process
US20050113534A1 (en) * 2003-11-21 2005-05-26 Parminder Agarwal Stabilized polycarbonate polyester composition
CN101267941A (zh) * 2005-09-16 2008-09-17 伊士曼化工公司 包含铝和锂催化剂以及钛的氮化物颗粒并具有改进再加热的聚酯组合物
US20110071235A1 (en) * 2009-09-23 2011-03-24 Sabic Innovative Plastics Us Llc Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
WO2011054786A1 (de) * 2009-11-09 2011-05-12 Basf Se Verfahren zur herstellung von schrumpffolien

Family Cites Families (127)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2012267A (en) 1929-08-01 1935-08-27 Du Pont Alkylene ester of polybasic acids
US3634089A (en) 1969-04-04 1972-01-11 Eastman Kodak Co Film-forming polyester compositions
US3669921A (en) 1971-02-08 1972-06-13 Eastman Kodak Co Copolyester melt adhesive
US3833685A (en) 1972-03-10 1974-09-03 Gen Electric Flame retardant thermoplastic compositions
US3989664A (en) 1972-11-24 1976-11-02 Teijin Limited Stabilized polyester composition and method for stabilizing polyester
JPS5323876B2 (enExample) 1973-03-22 1978-07-17
US3953539A (en) 1973-03-28 1976-04-27 Teijin Ltd. Aromatic polyester resin composition having inhibited coloration and method for inhibiting coloration
DE2431072C3 (de) 1974-06-28 1980-04-30 Bayer Ag, 5090 Leverkusen Thermoplastische Copolyester und Verfahren zu ihrer Herstellung
US4128526A (en) 1976-12-23 1978-12-05 General Electric Company Copolyesters of poly(alkylene glycol aromatic acid esters) and diesters comprising aromatic diols
DE2727486C2 (de) 1977-06-18 1982-09-16 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur Herstellung von thermoplastischen Formmassen
DE2945729C2 (de) 1979-11-13 1982-06-09 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von hochmolekularen, linearen Polyestern
US4401804A (en) 1982-05-24 1983-08-30 Eastman Kodak Company Deactivation of polyester catalyst residues
JPS5978234A (ja) 1982-10-28 1984-05-07 Toyo Seikan Kaisha Ltd ホツトメルト接着剤
DE3300315A1 (de) 1983-01-07 1984-07-12 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur herstellung von hellfarbigen polyestern unter verwendung von titankatalysatoren
US4452933A (en) 1983-06-09 1984-06-05 General Electric Company Stabilized polyester-polycarbonate blends and stabilization process therefor
JPS60240724A (ja) 1984-05-14 1985-11-29 Kuraray Co Ltd 共重合ポリエステルフイルム並びに該フイルムからなるホツトメルト接着剤
US4617373A (en) 1985-02-15 1986-10-14 Eastman Kodak Company Condensation polymers and products therefrom
EP0272417A3 (en) 1986-12-22 1989-09-27 General Electric Company Blends of polycarbonate resins and polyester resins exhibiting improved color properties
US5271985A (en) 1987-08-28 1993-12-21 Toray Industries, Inc. Polyester film having specific surface properties
US5008366A (en) 1990-04-25 1991-04-16 Amoco Corporation Process for producing adhesives from polyethylene terephthalate
GB9012524D0 (en) 1990-06-05 1990-07-25 Shell Int Research High surface area zirconia,a process for producing high surface area zirconia and a process for the production of hydrocarbons from synthesis gas
WO1992009654A2 (en) 1990-11-30 1992-06-11 Eastman Kodak Company Aliphatic-aromatic copolyesters and cellulose ester/polymer blends
US6495656B1 (en) 1990-11-30 2002-12-17 Eastman Chemical Company Copolyesters and fibrous materials formed therefrom
US5292783A (en) 1990-11-30 1994-03-08 Eastman Kodak Company Aliphatic-aromatic copolyesters and cellulose ester/polymer blends
JPH05140277A (ja) 1991-11-18 1993-06-08 Teijin Ltd 水性ポリエステル、これを塗設した易接着性ポリエステルフイルム及びその製造方法
EP0573680A1 (en) 1992-06-05 1993-12-15 General Electric Company Impact modified polyester and/or polycarbonate
DE4220473A1 (de) 1992-06-23 1994-01-05 Zimmer Ag Verfahren zur Herstellung von Polybutylenterephthalat aus PET-Abfall
US5844023A (en) 1992-11-06 1998-12-01 Bio-Tec Biologische Naturverpackungen Gmbh Biologically degradable polymer mixture
US5453479A (en) 1993-07-12 1995-09-26 General Electric Company Polyesterification catalyst
US5498749A (en) 1993-10-22 1996-03-12 Eastman Chemical Company Process for separating cyclohexane dimethanol from dimethyl terephthalate
US5413681A (en) 1993-11-15 1995-05-09 Eastman Chemical Company Process for the recovery of terephthalic acid and ethylene glycol from poly(ethylene terephthalate)
US5378796A (en) 1994-02-09 1995-01-03 Eastman Chemical Company Process for preparing copolyesters
US5451611A (en) 1994-03-29 1995-09-19 Council Of Scientific & Industrial Research Process for the conversion of poly(ethylene terephthalate) waste to poly(alkylene terephthalate)
DE4440858A1 (de) 1994-11-15 1996-05-23 Basf Ag Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper
DE4440850A1 (de) 1994-11-15 1996-05-23 Basf Ag Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper
US6096809A (en) 1995-04-07 2000-08-01 Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg Biologically degradable polymer mixture
US5559159A (en) 1995-12-07 1996-09-24 Eastman Chemical Company Process including depolymerization in polyester reactor for recycling polyester materials
US5744503A (en) 1996-02-01 1998-04-28 Hoechst Celanese Corporation Recycling polyester and recovering glycols
US5661193A (en) 1996-05-10 1997-08-26 Eastman Chemical Company Biodegradable foamable co-polyester compositions
GB9612161D0 (en) 1996-06-11 1996-08-14 Tioxide Specialties Ltd Esterification process
DE19624641A1 (de) 1996-06-20 1998-01-08 Biotec Biolog Naturverpack Biologisch abbaubarer Werkstoff, bestehend im wesentlichen aus oder auf Basis thermoplastischer Stärke
DE19643479B4 (de) 1996-10-22 2006-04-20 Zimmer Ag Verfahren zur Herstellung von Polyethylenterephthalat aus Polyethylenterephthalat-Abfall
EP0950690B1 (en) 1996-11-05 2005-01-26 NOVAMONT S.p.A. Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
AUPP261498A0 (en) 1998-03-27 1998-04-23 Swig Pty Ltd Improved conversion of contaminated polyethylene terephthalate to polybutylene terephthalate
US6066714A (en) 1998-04-17 2000-05-23 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith
US6184261B1 (en) 1998-05-07 2001-02-06 Board Of Regents Of University Of Nebraska Water-resistant degradable foam and method of making the same
US6028160A (en) 1998-10-01 2000-02-22 Cortec Corporation Biodegradable vapor corrosion inhibitor products
US6133404A (en) 1998-12-26 2000-10-17 National Institute Of Technology And Quality Polyester and formation process thereof
US6472557B1 (en) 1999-02-10 2002-10-29 Eastman Chemical Company Process for recycling polyesters
US20020111409A1 (en) 1999-05-28 2002-08-15 Talibuddin Sapna H. Polyester compositions having improved color stability
DE60012014T2 (de) 1999-08-06 2004-11-11 Eastman Chemical Co., Kingsport Polyester mit kontrolliertem schmelzpunkt und fasern daraus
DE60029289T2 (de) * 1999-10-05 2007-07-26 Nippon Shokubai Co., Ltd. Biologisch abbaubare Polyesterharzzusammensetzung und ihre Verwendung
US6166170A (en) 1999-12-02 2000-12-26 E. I. Du Pont De Nemours And Company Esterification catalysts and processes therefor and therewith
KR100366484B1 (ko) 1999-12-11 2003-01-14 주식회사 이래화학 코폴리에스테르 수지 조성물 및 그 제조방법
US6605657B1 (en) 1999-12-27 2003-08-12 Polyvalor Societe En Commandite Polymer compositions containing thermoplastic starch
US6231970B1 (en) 2000-01-11 2001-05-15 E. Khashoggi Industries, Llc Thermoplastic starch compositions incorporating a particulate filler component
IT1320163B1 (it) 2000-02-15 2003-11-18 Novamont Spa Foglia e prodotti formati a base di amido espanso.
US6514602B1 (en) 2000-03-07 2003-02-04 The Procter & Gamble Company Water-flushable and biodegradable film useful as backsheets for disposable absorbent articles
WO2002016467A1 (fr) 2000-08-22 2002-02-28 Mitsui Chemicals, Inc. Catalyseurs permettant la production de polyester, procede de production de polyester, et polyester
US6573340B1 (en) 2000-08-23 2003-06-03 Biotec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials
JP3443409B2 (ja) 2000-09-06 2003-09-02 関西ペイント株式会社 ポリエステル樹脂の製造方法
EP1344765B1 (en) 2000-11-27 2014-07-30 Teijin Limited Process for producing a dimethyl terephthalate composition
ITTO20010059A1 (it) 2001-01-25 2002-07-25 Novamont Spa Miscele ternarie di poliesteri alifatici biodegradabili e prodotti daqueste ottenuti.
ITTO20010060A1 (it) 2001-01-25 2002-07-25 Novamont Spa Miscele ternartie di poliesteri alifatici biodegradabili e prodotti da queste ottenuti.
ITTO20010057A1 (it) 2001-01-25 2002-07-25 Novamont Spa Miscele ternarie di poliesteri biodegradabili e prodotti da queste ottenuti.
US7241832B2 (en) 2002-03-01 2007-07-10 bio-tec Biologische Naturverpackungen GmbH & Co., KG Biodegradable polymer blends for use in making films, sheets and other articles of manufacture
US6660211B2 (en) 2001-04-23 2003-12-09 Kimberly-Clark Worldwide, Inc. Methods of making biodegradable films having enhanced ductility and breathability
US6703115B2 (en) 2001-05-01 2004-03-09 Eastman Chemical Company Multilayer films
BR0211556A (pt) 2001-08-01 2004-07-13 Fuller H B Licensing Financ Composição respirável biodegradável fundida por calor
EP1468034A4 (en) 2001-12-15 2005-04-13 Samsung Electronics Co Ltd RECYCLING PROCESS FOR POLYESTER WASTE AND RECYCLED MATERIAL
WO2003066733A1 (en) 2002-02-05 2003-08-14 Mitsui Chemicals, Inc. Biodegradable resin composition and molded object thereof
AU2003241790A1 (en) 2003-05-27 2005-01-21 Asahi Kasei Kabushiki Kaisha Biodegradable resin film or sheet and process for producing the same
US6998462B2 (en) 2003-06-11 2006-02-14 E.I. Du Pont De Nemours And Company Polyester process
DE10336387A1 (de) 2003-08-06 2005-03-03 Basf Ag Biologisch abbaubare Polyestermischung
JP4113074B2 (ja) 2003-08-20 2008-07-02 ソロテックス株式会社 ポリエステルの製造方法
GB0323386D0 (en) 2003-10-07 2003-11-05 Johnson Matthey Plc Catalyst for manufacture of esters
EP1671999B1 (en) 2003-10-10 2016-12-07 Asahi Kasei Kabushiki Kaisha Process for producing polyalkylene terephthalate, process for producing polyalkylene terephthalate molding and polyalkylene terephthalate molding
US20050137304A1 (en) 2003-12-18 2005-06-23 Strand Marc A. Process for calendering of polyesters
US7354653B2 (en) 2003-12-18 2008-04-08 Eastman Chemical Company High clarity films with improved thermal properties
US7241838B2 (en) 2003-12-19 2007-07-10 Eastman Chemical Company Blends of aliphatic-aromatic copolyesters with ethylene-vinyl acetate copolymers
US7368503B2 (en) 2003-12-22 2008-05-06 Eastman Chemical Company Compatibilized blends of biodegradable polymers with improved rheology
US7160977B2 (en) 2003-12-22 2007-01-09 Eastman Chemical Company Polymer blends with improved notched impact strength
US7368511B2 (en) 2003-12-22 2008-05-06 Eastman Chemical Company Polymer blends with improved rheology and improved unnotched impact strength
ATE407967T1 (de) 2003-12-30 2008-09-15 Metabolix Inc Nukleierungsmittel
US7807745B2 (en) 2006-01-27 2010-10-05 Sabic Innovative Plastics Ip B.V. Molding compositions containing polycarbonate and modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET)
US7157139B2 (en) 2004-04-19 2007-01-02 Grant W. Doney Polymer manufacturing process
US20070264460A1 (en) 2004-05-25 2007-11-15 Novamont S.P.A. Perforated Biodegradable Films and Sanitary Products Obtained Therefrom
US20060004151A1 (en) 2004-06-30 2006-01-05 General Electric Company Copolymers containing indan moieties and blends thereof
US7129301B2 (en) 2005-01-07 2006-10-31 Far Eastern Textile Ltd. Method for preparing a biodegradable copolyester
WO2006104013A1 (ja) 2005-03-25 2006-10-05 Mitsubishi Plastics, Inc. ポリ乳酸系カード基材およびカード
US7655746B2 (en) 2005-09-16 2010-02-02 Eastman Chemical Company Phosphorus containing compounds for reducing acetaldehyde in polyesters polymers
US8038658B2 (en) 2005-09-28 2011-10-18 Terumo Kabushiki Kaisha Synthetic resin needles and synthetic resin composition for needles
US20070082573A1 (en) 2005-10-11 2007-04-12 The Procter & Gamble Company Water stable fibers and articles comprising starch, and methods of making the same
CN101296966A (zh) 2005-10-28 2008-10-29 伊士曼化工公司 包含最小量的环丁二醇的聚酯组合物
JP2007153942A (ja) 2005-11-30 2007-06-21 Toray Ind Inc 再生ポリエステルの製造方法。
US7737246B2 (en) 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
CA2820149A1 (en) 2005-12-29 2007-07-05 Bp Corporation North America Inc. Ethanolysis of pet to form det and oxidation thereof
CN101351494A (zh) 2005-12-29 2009-01-21 Bp北美公司 用乙醇分解pet以形成det及其氧化
US8680167B2 (en) 2006-01-27 2014-03-25 Sabic Innovative Plastics Ip B.V. Molding compositions containing fillers and modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET)
US7855238B2 (en) 2006-01-27 2010-12-21 Sabic Innovative Plastics Ip B.V. Molding compositions containing polyalkylene terephthalates and modified polybutylene terephthalate (PBT) random copolymers derived from PET
WO2007089747A1 (en) 2006-01-27 2007-08-09 General Electric Company Articles derived from compositions containing modified polybutylene terephthalate (pbt) random copolymers derived from polyethylene terephthalate (pet)
US7902263B2 (en) 2006-01-27 2011-03-08 Sabic Innovative Plastics Ip B.V. Process for making polybutylene terephthalate (PBT) from polyethylene terephthalate (PET)
US7799836B2 (en) 2006-03-01 2010-09-21 Sabic Innovative Plastics Ip B.V. Process for making polybutylene terephthalate (PBT) from polyethylene terephthalate (PET)
TWI402293B (zh) 2006-04-06 2013-07-21 Teijin Fibers Ltd Production method of polyethylene terephthalate
JP5098238B2 (ja) 2006-04-27 2012-12-12 星光Ｐｍｃ株式会社 ポリエステル系樹脂の製造方法、及びその製造方法により得られたポリエステル系樹脂、並びに該樹脂を用いたトナー用樹脂
US20080081898A1 (en) 2006-10-02 2008-04-03 Ross Jeffrey S Polyester fiber compositions
US20080242751A1 (en) 2006-12-27 2008-10-02 Kurian Joseph V Processes for manufacturing polyesters from post-consumer polyester
JP2009179740A (ja) 2008-01-31 2009-08-13 Toray Ind Inc ポリエステル組成物およびその製造方法
EP2628758B1 (de) 2008-04-15 2014-10-08 Basf Se Verfahren zur kontinuierlichen Herstellung von biologisch abbaubaren Polyestern
KR101543489B1 (ko) 2008-04-15 2015-08-10 바스프 에스이 생분해성 폴리에스테르의 연속 제조 방법
US7799892B2 (en) 2008-05-02 2010-09-21 Sabic Innovative Plastics Ip B.V. Method of making polybutylene terephthalate and compositions and articles comprising the same
US8188185B2 (en) 2008-06-30 2012-05-29 Kimberly-Clark Worldwide, Inc. Biodegradable packaging film
US20110120346A1 (en) 2008-07-29 2011-05-26 Basf Se Aqueous universal pigment paste
US20100041831A1 (en) 2008-08-15 2010-02-18 Bayer Materialscience Llc Impact modified polycarbonate-polylactic acid composition
PL2350162T3 (pl) 2008-09-29 2018-05-30 Basf Se Poliestry alifatyczne
JP5326741B2 (ja) 2008-09-29 2013-10-30 東レ株式会社 ポリエステル重合触媒およびそれを用いるポリエステルの製造方法
AU2009333402A1 (en) * 2008-12-15 2010-07-08 E. I. Du Pont De Nemours And Company Copolyesters with enhanced tear strength
US7910657B2 (en) 2008-12-30 2011-03-22 Sabic Innovative Plastics Ip B.V. Process for the manufacture of polybutylene terephthalate copolymers from polyethylene terephthalate, and compositions and articles thereof
US20100168371A1 (en) 2008-12-31 2010-07-01 Corrado Berti Bio-Based Terephthalate Polyesters
AU2009332928B2 (en) 2009-05-15 2013-05-09 Kingfa Science & Technology Co., Ltd. A kind of biodegradable polyester and its preparation method
US20130030116A1 (en) 2010-04-30 2013-01-31 Jsr Corporation Film, resin composition and polymer
US8877862B2 (en) 2011-07-15 2014-11-04 Saudi Basic Industries Corporation Method for color stabilization of poly(butylene-co-adipate terephthalate
US8933162B2 (en) 2011-07-15 2015-01-13 Saudi Basic Industries Corporation Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
US8895660B2 (en) * 2012-03-01 2014-11-25 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof
US9034983B2 (en) 2012-03-01 2015-05-19 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6120895A (en) * 1996-09-20 2000-09-19 Basf Aktiengesellschaft Biodegradable polyesters
US6303738B1 (en) * 2000-08-04 2001-10-16 E. I. Du Pont De Nemours And Company Esterification process
US20050113534A1 (en) * 2003-11-21 2005-05-26 Parminder Agarwal Stabilized polycarbonate polyester composition
CN101267941A (zh) * 2005-09-16 2008-09-17 伊士曼化工公司 包含铝和锂催化剂以及钛的氮化物颗粒并具有改进再加热的聚酯组合物
US20110071235A1 (en) * 2009-09-23 2011-03-24 Sabic Innovative Plastics Us Llc Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
WO2011054786A1 (de) * 2009-11-09 2011-05-12 Basf Se Verfahren zur herstellung von schrumpffolien
CN102712766A (zh) * 2009-11-09 2012-10-03 巴斯夫欧洲公司 生产收缩膜的方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237750A (zh) * 2015-10-28 2016-01-13 北京市化学工业研究院 一种高分子量聚己二酸对苯二甲酸丁二醇酯的合成方法
CN105237750B (zh) * 2015-10-28 2017-06-06 北京市化学工业研究院 一种高分子量聚己二酸对苯二甲酸丁二醇酯的合成方法

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