CN104072977B - 一种阻燃热塑性聚氨酯弹性体及其制备方法 - Google Patents
一种阻燃热塑性聚氨酯弹性体及其制备方法 Download PDFInfo
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- CN104072977B CN104072977B CN201410324281.6A CN201410324281A CN104072977B CN 104072977 B CN104072977 B CN 104072977B CN 201410324281 A CN201410324281 A CN 201410324281A CN 104072977 B CN104072977 B CN 104072977B
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- flame retardant
- hollow glass
- polypropylene
- glass micropearl
- thermoplastic polyurethane
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 114
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 97
- 239000004433 Thermoplastic polyurethane Substances 0.000 title claims abstract description 44
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims abstract description 44
- 229920001971 elastomer Polymers 0.000 title claims abstract description 40
- 239000000806 elastomer Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 239000011521 glass Substances 0.000 claims abstract description 80
- 238000002156 mixing Methods 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- VOROEQBFPPIACJ-UHFFFAOYSA-N 5-Phosphononorvaline Chemical group OC(=O)C(N)CCCP(O)(O)=O VOROEQBFPPIACJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 76
- -1 polypropylene Polymers 0.000 abstract description 74
- 229920001155 polypropylene Polymers 0.000 abstract description 72
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 52
- 239000001301 oxygen Substances 0.000 abstract description 52
- 229910052760 oxygen Inorganic materials 0.000 abstract description 52
- 238000002485 combustion reaction Methods 0.000 abstract description 49
- 239000002131 composite material Substances 0.000 abstract description 13
- 230000002195 synergetic effect Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 9
- 238000012360 testing method Methods 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 5
- 235000019504 cigarettes Nutrition 0.000 abstract description 3
- 230000001629 suppression Effects 0.000 abstract description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 description 48
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 23
- 239000000463 material Substances 0.000 description 17
- 230000000979 retarding effect Effects 0.000 description 11
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- FIQNIRPYLPNUDK-UHFFFAOYSA-K calcium;nickel(2+);phosphate Chemical compound [Ca+2].[Ni+2].[O-]P([O-])([O-])=O FIQNIRPYLPNUDK-UHFFFAOYSA-K 0.000 description 4
- 229910052901 montmorillonite Inorganic materials 0.000 description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920003225 polyurethane elastomer Polymers 0.000 description 3
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 239000012757 flame retardant agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000012667 polymer degradation Methods 0.000 description 2
- 238000010094 polymer processing Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- COAPBYURHXLGMG-UHFFFAOYSA-N azane;1,3,5-triazine-2,4,6-triamine Chemical compound N.NC1=NC(N)=NC(N)=N1 COAPBYURHXLGMG-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- SJPVUFMOBDBTHQ-UHFFFAOYSA-N barium(2+);dioxido(dioxo)tungsten Chemical compound [Ba+2].[O-][W]([O-])(=O)=O SJPVUFMOBDBTHQ-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
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CN201410324281.6A CN104072977B (zh) | 2013-06-17 | 2013-06-17 | 一种阻燃热塑性聚氨酯弹性体及其制备方法 |
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CN201410324281.6A CN104072977B (zh) | 2013-06-17 | 2013-06-17 | 一种阻燃热塑性聚氨酯弹性体及其制备方法 |
CN201310239417.9A CN103333364B (zh) | 2013-06-17 | 2013-06-17 | 复合膨胀型阻燃剂及其在阻燃聚丙烯和聚氨酯中的应用 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106554612B (zh) * | 2015-09-29 | 2019-08-06 | 万华化学集团股份有限公司 | 无卤阻燃热塑性聚氨酯弹性体组合物及其制品、阻燃剂包 |
CN105440652B (zh) * | 2015-12-25 | 2018-12-04 | 青岛科技大学 | 一种阻燃热塑性聚氨酯弹性体及其制备方法 |
CN105949744A (zh) * | 2016-05-11 | 2016-09-21 | 洛阳辰祥机械科技有限公司 | 一种阻燃疏水材料及其制备方法 |
CN106009044A (zh) * | 2016-06-29 | 2016-10-12 | 青岛科技大学 | 一种空心玻璃微珠的表面改性方法及其阻燃应用 |
CN108017890B (zh) * | 2016-10-28 | 2020-11-06 | 浙江鑫宙竹基复合材料科技有限公司 | 一种阻燃竹缠绕复合制品及其制备方法 |
CN108250602A (zh) * | 2016-12-29 | 2018-07-06 | 郑州宇通客车股份有限公司 | 一种阻燃环保耐磨材料、地板革及其制备方法、客车地板 |
Citations (2)
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CN101058669A (zh) * | 2007-04-18 | 2007-10-24 | 杭州捷尔思阻燃化工有限公司 | 一种含无卤膨胀型阻燃剂的阻燃热塑性聚氨酯混合物 |
CN102352057A (zh) * | 2011-09-08 | 2012-02-15 | 西北师范大学 | 无卤复合阻燃剂及在制备阻燃热塑性弹性体复合材料中的应用 |
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Patent Citations (2)
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CN101058669A (zh) * | 2007-04-18 | 2007-10-24 | 杭州捷尔思阻燃化工有限公司 | 一种含无卤膨胀型阻燃剂的阻燃热塑性聚氨酯混合物 |
CN102352057A (zh) * | 2011-09-08 | 2012-02-15 | 西北师范大学 | 无卤复合阻燃剂及在制备阻燃热塑性弹性体复合材料中的应用 |
Non-Patent Citations (2)
Title |
---|
无卤阻燃ABS/空心微珠复合材料的研究;夏英等;《塑料工业》;20050228;第33卷(第2期);第18-20页 * |
空心玻璃微珠对聚氨酯泡沫燃烧和力学性能的影响;陈伟红等;《化学研究》;20111130;第22卷(第6期);第69-72页 * |
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