CN104026143A - Binary pesticide composition and its use - Google Patents
Binary pesticide composition and its use Download PDFInfo
- Publication number
- CN104026143A CN104026143A CN201310073053.1A CN201310073053A CN104026143A CN 104026143 A CN104026143 A CN 104026143A CN 201310073053 A CN201310073053 A CN 201310073053A CN 104026143 A CN104026143 A CN 104026143A
- Authority
- CN
- China
- Prior art keywords
- binary
- parts
- insecticides
- composition
- active component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention belongs to the field of pesticides, and relates to a binary pesticide composition and its use. The active component 1 of the composition is tetrachlorantraniliprole, and the active component 2 of the composition is a semicarbazone compound; and the structural formula of tetrachlorantraniliprole is shown in the specification, the emicarbazone compound is metaflumizone, and a weight part ratio of the two active components is 1:99-99:1. The composition has the characteristics of obvious synergy, resistance delay and the like, and can be used for controlling many pests.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of binary insecticides and uses thereof.
Background technology
Insecticide is that a kind of subject is the agricultural chemicals of insect, is mainly used in preventing and treating the medicine of pest and urban health insect. use historical long-range, consumption is large, wide in variety.At aspects such as the various crops of protection and urban afforestation, there is obvious effect.
Chinese invention patent CN101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and has controlled the purposes of insect pest and disease, compound 1.25(tetrachloro insect amide wherein) can be used for preventing and treating various pests, especially lepidoptera pest is had to outstanding control efficiency.
Pesticidal composition is that two or more agricultural chemicals mix, and can effectively solve pest pesticide resistance distinct issues.The insecticide that contains single-activity component is used continuously in control of insect, easily makes insect develop immunity to drugs.Select mechanism of action different, without the insecticide of two kinds of active components of cross resistance, be mixed into by a certain percentage, can improve control efficiency, reduce the agricultural chemicals in unit are amount of application, reduce pesticide cost, can delay the generation of pest resistance to insecticide simultaneously.
Although disclose general tetrachloro insect amide or its homologue and other Mixture Use of Insecticides in prior art, can produce additional advantage and effect, it is concrete open that the technical scheme of the binary insecticides that contains tetrachloro insect amide has no.
Summary of the invention
The object of the invention is to meet agricultural and pest control aspect, urban health field day by day improves the demand of constantly updating with kind to insecticide effect, and a kind of binary insecticides and uses thereof is provided.
For achieving the above object, the technical solution used in the present invention is:
A binary insecticides, active component one is tetrachloro insect amide, active component two is semicarbazone compounds; Described tetrachloro insect amide structural formula is as follows:
Described semicarbazone compounds is metaflumizone, and wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
Further, the ratio of weight and number between two kinds of active components is 1:20-20:1.
Composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
In composition active component percentage by weight between 0.5%-95%.
Say further, in composition active component percentage by weight between 1%-85%.
The application of binary insecticides is characterized in that: described composition can be used as the insecticide of controlling agriculture and forestry injurious insect or urban health insect.
Described composition imposes on and needs on the insect of control or the medium of its growth with effective dose; Applying dosage is the effective dose of 10 grams-500 grams of per hectares.
Say further, applying dosage is the effective dose of 15 grams-100 grams of per hectares.
Tool of the present invention has the following advantages:
The one, composition of the present invention shows obvious synergistic effect in certain ratio range, has improved the control efficiency of this compound to insect.
The 2nd, said composition reduces the using dosage of compound in application, thereby reduces use cost, reduces environmental pollution.
The 3rd, in said composition, the mechanism of action of each active ingredient is different, does not have the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improves the control efficiency of antagonism population.
Embodiment
A binary insecticides, active component one is tetrachloro insect amide, structural formula is as follows:
Active component two is selected from metaflumizone; Through indoor biological activity determination, demonstrate binary insecticides of the present invention and there is good synergistic effect.Active component two in composition is metaflumizones.
Composition of the present invention can be dosage form to be provided.Make as required missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder, oil-suspending agent etc.In composition, the percentage by weight cumulative amount of active component is between 0.5%-95%, and preferably cumulative amount is between 1%-85%.The amount of application when content of active component depends on independent use in composition of the present invention, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composite preparation of the present invention can be prepared by conventional processing method, after soon active substance will mix with liquid-carrier (solvent) or solid carrier, add one or more auxiliary agents as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Conventionally in composition, contain at least one carrier and at least one surfactant.In all cases, should guarantee that present composition active component is uniformly distributed.
Missible oil contains the active component of 10-75% conventionally, 2-20% emulsifier, other additive such as the stabilizing agent of 0-20%, bleeding agent, corrosion inhibitor etc., and solvent (also containing if desired cosolvent).
Suspending agent needs sand milling conventionally, to obtain stable non-deposition flowable product.In suspending agent, conventionally contain 5-50% active component, 5-15% dispersant, 0.1-10% wetting agent, 4-10% antifreezing agent, other additive of 0-10% is as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
(aqueous dispersion) granula is made 10-100 international standard sieve mesh (1.676-0.152mm) particle conventionally, can prepare by extruding, dipping or mist projection granulating method, conventionally the active component that (aqueous dispersion) granule contains 0.5-80% and the auxiliary agent of 5-20% be dispersant, wetting agent, disintegrant and adhesive for example, and inert carrier surplus.
Wetting powder contains the active component of 10-85% conventionally, except solid inert carrier, conventionally contains the dispersant of 3-10%, can also contain wetting agent and (or) other additive of 0-10%, for example bleeding agent or stabilizing agent.
Aqueous emulsion is that former medicine, organic solvent, emulsifier are mixed to formation oil phase, and water, antifreezing agent are mixed, and becomes transparent and homogeneous liquid.With high-shear emulsion machine high speed shear oil phase, slowly water is added to oil phase, common active component 1-60%, surfactant 5-20%, antifreezing agent 2-10%, water surplus simultaneously.
Microemulsion is that former medicine, organic solvent, surfactant, water are mixed, and becomes transparent and homogeneous water.Common active component 1-50%, surfactant 10-40%, antifreezing agent 2-10%, water surplus.
Soluble liquid is that active component, organic solvent, surfactant are mixed, and becomes transparent and homogeneous liquid.Common active component 1-50%, surfactant 6-20%, organic solvent surplus.
Oil-suspending agent is by having active component, surfactant, oil base carrier to add sand milling in sand mill, until particle diameter is qualified, and common active component 2-60%, surfactant 6-20%, oil base carrier surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can there is dense thick pulpous state denseness.
The preparation of composite preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.For example include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises natural or synthetic clay and silicate, and the solid carrier that is applicable to pulvis comprises the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and the synthetic mineral matter grinding (as microdispersed silicic acid or aluminium oxide).Applicable particulate vector comprises broken and natural rock classification for example calcite, marble, float stone, sepiolite and dolomite and the synthetic particle made by the powder of organic matter and inorganic matter.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201#, agriculture breast OX-8686, agriculture breast 1601#, agriculture breast NP-15, agriculture breast OX-2681 etc.
Suitable dispersant can be for sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylamino ethylsulfonic acid sodium, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or the natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.) synthesizing, and with powder, particle or latex form, adds in preparation.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.
While being used for preventing and treating city insect, can make aerosol, need to add therein propellant, also bait formulation composition be can make, except containing active component, one or more foodstuffs that are suitable for insect's food-taking, optional attractant and optional wetting agent also contained.
Composition of the present invention is suitable for preventing and treating multiple important agriculture and forestry injurious insect or urban health insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, Asiatic migratory locust, soil insect, leaf miner, liriomyza bryoniae, class Diabrotica etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree, as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum etc., and flowers.While being used for preventing and treating city insect, can be for family, various public place, office space etc.Therefore, the present composition can be controlled agriculture and forestry injurious insect or urban health insect.
Following specific embodiment is used for further describing the present invention, but the present invention only limits to absolutely not these examples.In embodiment, each component percentage composition or proportioning are all by weight.Active component in each formula is calculated with effective content.
Formulation Example
The preparation of embodiment 1,10% tetrachloro insect amide metaflumizone missible oil
By formula requirement, count by weight, by 5 parts of tetrachloro insect amides, 5 parts of metaflumizones, 6 parts of agriculture breast 0201B, 4 parts of agriculture breast 0203B, 1.5 parts of agriculture breast 1601#, 5 parts of methyl alcohol, 73.5 parts of dimethylbenzene, mix, use if desired hot bath heating for dissolving, obtain 10% tetrachloro insect amide metaflumizone missible oil.
The preparation of embodiment 2,30% tetrachloro insect amide metaflumizone wetting powder
By formula requirement, count by weight, by 5 parts of tetrachloro insect amides, 25 parts of metaflumizones, 2 parts of lauryl sodium sulfate, 4 parts of calcium lignosulfonates, 8 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 6 parts of White Carbon blacks, 2 parts of detergent LS, 48 parts of precipitated calcium carbonates, fully mix, after ultra-fine pulverizer disintegrating, obtain 30% tetrachloro insect amide metaflumizone wetting powder.
The preparation of embodiment 3,10% tetrachloro insect amide metaflumizone aqueous emulsion
By formula requirement, count by weight, by 5 parts of tetrachloro insect amides, 5 parts of metaflumizones, 10 parts of agriculture breast 2201#, 4.5 parts of alkylaryl polyoxyethylene poly-oxygen propylene aethers, 2.5 parts of piperonyl butoxides, 10 parts of cyclohexanone, 5 parts of glycerine, be added together, make to be dissolved into even oil phase.Under high-speed stirred, 58 parts of water, join oil phase, form 10% tetrachloro insect amide metaflumizone aqueous emulsion of favorable dispersibility.
The preparation of embodiment 4,15% tetrachloro insect amide metaflumizone aqueous emulsion
By formula requirement, count by weight, by 12.5 parts of tetrachloro insect amides, 2.5 parts of metaflumizones, 8.5 parts of agriculture breast 507#, 3.5 parts of agriculture breast OX-8686,3 parts of agriculture breast 1601#, 8 parts of dimethyl formamides, 0.5 part of tetradecanol, 5 parts of ethylene glycol, be added together, make to be dissolved into even oil phase.Under high-speed stirred, add 56.5 parts of water, join oil phase, form 15% tetrachloro insect amide metaflumizone aqueous emulsion of favorable dispersibility.
The preparation of embodiment 5,30% tetrachloro insect amide metaflumizone water-dispersible granules
By formula requirement; count by weight; by 25 parts of tetrachloro insect amides, 5 parts of metaflumizones, 8 parts of naphthalenesulfonic acid-formaldehyde condensates, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 6 parts of N-methyl-oleoyl-sodium taurocholates, 10 parts of sodium sulphate, 42 parts of kaolin; carry out co-grinding; after adding again water and mediating, add and in the comminutor that certain specification screen cloth is housed, carry out granulation.And then drying, screening (by screen cloth scope) obtain 30% tetrachloro insect amide metaflumizone water-dispersible granules.
The preparation of embodiment 6,20% tetrachloro insect amide metaflumizone suspending agent
By formula requirement, count by weight, by 10 parts of tetrachloro insect amides, 10 parts of metaflumizones, 3 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of sodium lignin sulfonates, 6 parts of agriculture breast 0201B, 0.3 part of xanthans, 0.6 part of white carbon, 5 parts of ethylene glycol, 62.1 parts of water, add in sand milling still, carry out porphyrize, make 20% tetrachloro insect amide metaflumizone suspending agent.
The preparation of embodiment 7,9% tetrachloro insect amide metaflumizone soluble concentrate
By formula requirement, count by weight, by 7.5 parts of tetrachloro insect amides, 1.5 parts of metaflumizones, 15 parts of agriculture breast 2201#, 2 parts of agriculture breast T-20,8 parts of agriculture breast NP-15,12 parts of dimethyl formamides, 8 parts of methyl alcohol, 46 parts of methyl alcohol, mix, use if desired hot bath heating for dissolving, can make 9% tetrachloro insect amide metaflumizone soluble concentrate.
The preparation of embodiment 8,20% tetrachloro insect amide metaflumizone microemulsion
By formula requirement, count by weight, by 10 parts of tetrachloro insect amides, 10 parts of metaflumizones, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 8 parts of agricultures breast 36#, 10 parts of agriculture breast OX-2681,20 parts of cyclohexanone be added together, and makes to be dissolved into even oil phase.Add again 29 parts of water, 5 parts of ethylene glycol to be mixed, become homogeneous water.Under high-speed stirred, water is joined to oil phase or oil phase is joined to water, form 20% tetrachloro insect amide metaflumizone microemulsion of favorable dispersibility.The preparation of embodiment 9,30% tetrachloro insect amide metaflumizone oil-suspending agent
By formula requirement, count by weight, by 27 parts of tetrachloro insect amides, 3 parts of metaflumizones, 3 parts of agriculture breast S-80,2 parts of agriculture breast T-20,6 parts of agriculture breast 0201B, 3 parts of agriculture breast 500#, 2 parts of white carbons, 54 portions of soybean oils that methylate, add in sand milling still, carry out porphyrize, make 30% tetrachloro insect amide metaflumizone oil-suspending agent.
Indoor biological activity determination
Embodiment 10 tetrachloro insect amides mix use to corn borer toxicity determination test with metaflumizone
For trying object: corn borer (Ostrinia furnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 ℃, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: the active component tetrachloro insect amide, the metaflumizone that accurately take respectively insecticide of the present invention with electronic analytical balance, then former medicine is added proper amount of acetone to dissolve, after dissolving completely, with the water containing 0.1% Tween 80, be mixed with desired concn mother liquor, in the ratio between two kinds of active components in insecticide of the present invention, above-mentioned mother liquor is hybridly prepared into mixed solution by a certain percentage, by experimental scheme dosage, is diluted to respectively the serial liquid of tool finite concentration gradient.
Test method: adopt artificial feed culture plate method, 24 well culture plates of selection standard cleaning, every hole adds 1ml artificial feed, after cooled and solidified, with continuous sampler, to each hole of culture plate, adds 0.05ml liquid, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, every processing repeats 4 times.Examination worm after processing is placed in observation ward, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, the borer population of living.
By Abbott formula calculation correction lethality, appliance computer program is obtained each for examination single dose and mixed virulence regression equation formula, the LC of variant proportioning
50value and 95% confidence limit, by Sun Yunpei (Sun Y-P) method, obtain the mixed co-toxicity coefficient of each proportioning, evaluates.If co-toxicity coefficient approaches 100 for summation action, apparently higher than 100 being synergistic effect, be starkly lower than 100 for antagonism.
Result of the test is in Table 1.As can be seen from the table, for trying, each proportioning is mixed all shows synergistic effect to corn borer to tetrachloro insect amide with metaflumizone.
Table 1: tetrachloro insect amide metaflumizone is to the indoor joint toxicity measuring result of corn borer
embodiment 11 tetrachloro insect amides mix use to beet armyworm toxicity determination test with metaflumizone
For trying object: beet armyworm (Spodoptera exigua), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 ℃, humidity: RH60%, illumination: L:D=14:10
Liquid compound method is with embodiment 10.Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, make diameter 2cm leaf dish, leaf dish is flooded to 5s respectively in above-described embodiment liquid or contrast liquid, after taking-up, dry in the shade, put into the 9cm culture dish that is lined with filter paper, select in the examination worm access culture dish of neat and consistent, every processing repeats 4 times.Examination worm after processing is placed in observation ward, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, the borer population of living.Contrast liquid is respectively tetrachloro insect amide, metaflumizone.
Calculate evaluation method with embodiment 10.
Result of the test is in Table 2.As can be seen from the table, for trying, each proportioning is mixed all shows synergistic effect to beet armyworm to tetrachloro insect amide with metaflumizone.
Table 2: tetrachloro insect amide metaflumizone is to the indoor joint toxicity measuring result of beet armyworm
Claims (8)
1. a binary insecticides, is characterized in that: active component one is tetrachloro insect amide, and active component two is semicarbazone compounds; Described tetrachloro insect amide structural formula is as follows:
Described semicarbazone compounds is metaflumizone, and wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
2. according to binary insecticides claimed in claim 1, it is characterized in that: the ratio of weight and number between two kinds of active components is 1:20-20:1.
3. according to binary insecticides claimed in claim 1, it is characterized in that: composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
4. according to binary insecticides claimed in claim 3, it is characterized in that: in composition active component percentage by weight between 0.5%-95%.
5. according to binary insecticides claimed in claim 4, it is characterized in that: in composition active component percentage by weight between 1%-85%.
6. the application of a binary insecticides claimed in claim 1 is characterized in that: described composition can be used as the insecticide of controlling agriculture and forestry injurious insect or urban health insect.
7. by the application of binary insecticides claimed in claim 6, it is characterized in that: described composition imposes on the insect of needs control or the medium of its growth with effective dose; Applying dosage is the effective dose of 10 grams-500 grams of per hectares.
8. by the application of binary insecticides claimed in claim 7, it is characterized in that: applying dosage is the effective dose of 15 grams-100 grams of per hectares.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310073053.1A CN104026143B (en) | 2013-03-07 | 2013-03-07 | Binary pesticide composition and uses thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310073053.1A CN104026143B (en) | 2013-03-07 | 2013-03-07 | Binary pesticide composition and uses thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104026143A true CN104026143A (en) | 2014-09-10 |
| CN104026143B CN104026143B (en) | 2016-03-23 |
Family
ID=51457312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310073053.1A Active CN104026143B (en) | 2013-03-07 | 2013-03-07 | Binary pesticide composition and uses thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104026143B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103858910A (en) * | 2013-12-19 | 2014-06-18 | 北京燕化永乐生物科技股份有限公司 | Insecticide composition containing metaflumizone |
| CN104012558A (en) * | 2014-05-14 | 2014-09-03 | 青岛瀚生生物科技股份有限公司 | Compound insecticide containing metaflumizone and tetrchlorantraniliprole |
| CN104585198A (en) * | 2014-12-28 | 2015-05-06 | 江苏天容集团股份有限公司 | Quadric-chlorantraniliprole insecticidal composition |
| CN104814022A (en) * | 2015-05-02 | 2015-08-05 | 广东中迅农科股份有限公司 | Insecticidal composition containing tetrachlorantraniliprole and lufenuron |
| CN105532698A (en) * | 2014-11-03 | 2016-05-04 | 中化农化有限公司 | Composition containing SYP9080 and benzoyl urea pesticide, and application thereof |
| CN111567545A (en) * | 2020-06-01 | 2020-08-25 | 沈阳化工研究院（南通）化工科技发展有限公司 | Composition containing tetrachloro-zoon amide and metaflumizone and application thereof |
| WO2021127126A1 (en) * | 2019-12-19 | 2021-06-24 | Fmc Corporation | Diamide suspension concentrate compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302029A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Compounded pesticide |
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
-
2013
- 2013-03-07 CN CN201310073053.1A patent/CN104026143B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302029A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Compounded pesticide |
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103858910A (en) * | 2013-12-19 | 2014-06-18 | 北京燕化永乐生物科技股份有限公司 | Insecticide composition containing metaflumizone |
| CN104012558A (en) * | 2014-05-14 | 2014-09-03 | 青岛瀚生生物科技股份有限公司 | Compound insecticide containing metaflumizone and tetrchlorantraniliprole |
| CN105532698A (en) * | 2014-11-03 | 2016-05-04 | 中化农化有限公司 | Composition containing SYP9080 and benzoyl urea pesticide, and application thereof |
| CN104585198A (en) * | 2014-12-28 | 2015-05-06 | 江苏天容集团股份有限公司 | Quadric-chlorantraniliprole insecticidal composition |
| CN104814022A (en) * | 2015-05-02 | 2015-08-05 | 广东中迅农科股份有限公司 | Insecticidal composition containing tetrachlorantraniliprole and lufenuron |
| WO2021127126A1 (en) * | 2019-12-19 | 2021-06-24 | Fmc Corporation | Diamide suspension concentrate compositions |
| CN114828628A (en) * | 2019-12-19 | 2022-07-29 | Fmc公司 | Diamide suspension concentrate compositions |
| CN111567545A (en) * | 2020-06-01 | 2020-08-25 | 沈阳化工研究院（南通）化工科技发展有限公司 | Composition containing tetrachloro-zoon amide and metaflumizone and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104026143B (en) | 2016-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104026143B (en) | Binary pesticide composition and uses thereof | |
| CN104663670B (en) | One kind collaboration miticide composition | |
| CN104413038B (en) | Binary insecticide composition and application | |
| CN104663692B (en) | A kind of insecticide acaricide composition containing insect growth regulator, IGR insecticides | |
| CN104663704B (en) | One kind contains the acaricidal insecticide acaricide composition of ATP synthetase inhibitors classes | |
| CN104663702B (en) | A kind of insecticide acaricide composition containing chrysanthemum ester insecticide | |
| CN102379282A (en) | Ultralow volume liquid containing benzoylurea insecticide | |
| CN104663679B (en) | A kind of insecticide acaricide composition containing macrolide insecticide | |
| CN103155929B (en) | Binary pesticide composition and application thereof | |
| CN104663672B (en) | One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class | |
| CN103380778A (en) | Pesticide composition of thiamethoxam and azoxystrobin | |
| CN104663668A (en) | Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide | |
| CN104663666B (en) | One kind transmits the acaricidal insecticide acaricide composition of inhibitor class containing Mitochondrial electron | |
| CN103155935B (en) | Binary pesticide composition | |
| CN109247340A (en) | A kind of composition pesticide and its preparation method and application compounded containing microbial bacteria | |
| CN104585224A (en) | Pesticide composition containing fluensulfone and pyrethroid insecticide | |
| CN104663688B (en) | A kind of insecticide acaricide composition containing Bifenazate | |
| CN104738063B (en) | Binary insecticide composition and application | |
| CN104663687B (en) | A kind of insecticide acaricide composition containing carbamate insecticides | |
| CN104026146B (en) | A kind of binary insecticides and purposes | |
| CN104026156A (en) | Binary pesticide composition and its use | |
| CN104957167A (en) | Thiamethoxam and azoxystrobin pesticide composition | |
| CN104412991A (en) | Binary insecticide composition and application thereof | |
| CN107455384B (en) | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial | |
| CN105660646A (en) | Agricultural insecticide composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |